{"title":"Supramolecular chemistry for the incorporation of multi-guest molecules into two-dimensional metal hydroxide hosts","authors":"Taeho Kim, Jin Kuen Park, Jae-Min Oh","doi":"10.1002/bkcs.12895","DOIUrl":"https://doi.org/10.1002/bkcs.12895","url":null,"abstract":"<p>The incorporation of functional molecules into the interlayer space of layered double hydroxide (LDH) has been extensively studied for its role in immobilization, stabilization, manipulation of the molecular configuration, and the release from the host. To create dramatically enhanced properties and achieve unexpectedly high performances, it is necessary to incorporate multi-guests as well as control the guest-guest interaction. In the present review, we have summarized the multi-guest incorporation into LDH based on the supramolecular chemistry, which provides insights into non-covalent molecular interaction through host-guest chemistry. Four well-known intercalation methods in LDH, that is, coprecipitation, ion exchange, reconstruction, and exfoliation-reassembly, are generally applied to multi-guest intercalation. Combinative methods, in which two different intercalation approaches are combined, are also summarized. The multi-guest incorporation, despite the difficulty involved in its synthesis design, could provide fine-tuned and enhanced properties that are useful for a variety of applications.</p>","PeriodicalId":54252,"journal":{"name":"Bulletin of the Korean Chemical Society","volume":"45 9","pages":"724-737"},"PeriodicalIF":1.7,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142313263","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Removal of Acid Orange 7 dye using Makgeolli lees with ultrasonic assistance","authors":"Nguyen Van Kien, Sunghwan Kim, Jae Jeong Ryoo","doi":"10.1002/bkcs.12892","DOIUrl":"https://doi.org/10.1002/bkcs.12892","url":null,"abstract":"<p>This study investigated the efficient removal of Acid Orange 7 (AO7) dye in water by using Makgeolli lees, a popular by-product obtained during the production of traditional Makgeolli beverages in Korea. By incorporating ultrasound, the effects of contact time, Makgeolli lees dosage, initial AO7 dye concentration, and initial pH of the dye solution were investigated and comprehensively compared with the same experiment using the stirring method. The results consistently showed ultrasound not only enhances the excellent adsorption ability of Makgeolli lees but also accelerates the process compared to the stirring method. The Langmuir isotherm model best described the adsorption process for both methods, suggesting monolayer adsorption on the surface of Makgeolli lees, with maximum capacities of 25.13 mg/g for ultrasound at 40 kHz and 20.41 mg/g for stirring methods. Furthermore, the study showed that optimal dye removal efficiency can be achieved with ultrasound conditions at 28 kHz frequency, 125 W/L power density, and 100% ultrasound intensity. This research promises that the integration of low-cost biomass coupled with ultrasound could provide a potential solution for dye wastewater treatment.</p>","PeriodicalId":54252,"journal":{"name":"Bulletin of the Korean Chemical Society","volume":"45 9","pages":"770-777"},"PeriodicalIF":1.7,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bkcs.12892","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142313433","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Elucidating plasmon damping in silver-coated gold nanorods: Single particle analysis and damping adjustment","authors":"Rafifah Hana Raihana Syam, Ji Won Ha","doi":"10.1002/bkcs.12894","DOIUrl":"https://doi.org/10.1002/bkcs.12894","url":null,"abstract":"<p>We demonstrate the morphology and spectral properties of silver-coated gold nanorods (AuNRs@Ag), synthesized via seed-mediated growth, using scanning electron microscopy (SEM) and dark-field (DF) spectroscopy. The relationship between surface damping and the thickness of the Ag shell in AuNRs was analyzed at the single-particle level. Additionally, we adjusted the bulk damping and radiation damping of AuNRs to elucidate the contribution of surface damping. SEM images demonstrated an increase in length and width following Ag deposition. Elemental mapping analysis confirmed the Ag deposition on the AuNR surface, with Ag content measured at 26.7% for AuNR@Ag<sub>26.7</sub> with a 1-day incubation period and 34.8% for AuNR@Ag<sub>34.8</sub> with a 2-day incubation period. DF spectroscopy revealed a notable blue shift and slight broadening in their LSPR spectra. Moreover, surface damping decreased with an increase in Ag content. Consequently, this study advances the understanding of plasmon damping mechanisms in single AuNR@Ag for their potential applications.</p>","PeriodicalId":54252,"journal":{"name":"Bulletin of the Korean Chemical Society","volume":"45 9","pages":"764-769"},"PeriodicalIF":1.7,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142313286","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of sildenafil and its derivatives bearing pyrazolo-pyrimidinones scaffold","authors":"Seung Su Lee, Chang Ho Oh","doi":"10.1002/bkcs.12893","DOIUrl":"https://doi.org/10.1002/bkcs.12893","url":null,"abstract":"<p>The pyrazole ring structure is extensively spotted as a pharmacophore and fortify-cation of the modern organic synthesis toolbox, which demands synthetic tactics to generate its derivatives. Especially, pyrazolo-pyrimidinones are crucial part to synthesize phosphodiesterase type 5 (PDE5) such as sildenafil and lodenafil. Herein, we report a simple and efficient route for Sildenafil and derivatives from easily available materials.</p>","PeriodicalId":54252,"journal":{"name":"Bulletin of the Korean Chemical Society","volume":"45 9","pages":"759-763"},"PeriodicalIF":1.7,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bkcs.12893","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142313285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Cover Picture: Post-synthetic modifications of MOF-74 type frameworks for enhancing CO2 capture and moisture stability (BKCS 8/2024) Jintu Francis Kurisingal, Jong Hyeak Choe, Hyojin Kim, Jeongwon Youn, Gayoung Cheon, Chang Seop Hong","authors":"","doi":"10.1002/bkcs.12744","DOIUrl":"https://doi.org/10.1002/bkcs.12744","url":null,"abstract":"<p>The cover image depicts a post-combustion CO2 capture process using a MOF-74 type framework functionalized with diamine groups to enhance the interaction with incoming CO2 molecules. Modified with hydrophobic components, these frameworks are excellent for CO2 capture while maintaining structural integrity even under humid conditions. More details are available in the article by Jintu Francis Kurisingal, Jong Hyeak Choe, Hyojin Kim, Jeongwon Youn, Gayoung Cheon, Chang Seop Hong\u0000 \u0000 \u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":54252,"journal":{"name":"Bulletin of the Korean Chemical Society","volume":"45 8","pages":"645"},"PeriodicalIF":1.7,"publicationDate":"2024-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bkcs.12744","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142050510","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Radhiha Ravindran, Inchan Kim, Yun-Hi Kim, Soon-Ki Kwon
{"title":"Novel low-band gap non-fullerene acceptors based on IDIC core as potential photovoltaic materials","authors":"Radhiha Ravindran, Inchan Kim, Yun-Hi Kim, Soon-Ki Kwon","doi":"10.1002/bkcs.12891","DOIUrl":"https://doi.org/10.1002/bkcs.12891","url":null,"abstract":"<p>Three novel non-fullerene acceptors (NFAs) (PhBu-IDT-BT-IC, PhBu-IDT-BT-IC4F and PhBu-IDT-BT-IC4Cl) based on 3,8-dioctyl-indaceno[1,2-b:5,6-b’]dithiophene (IDT) core have been designed and synthesized with and without halogen (F and Cl) substitution. The NFAs showed high thermal stability. The ultraviolet–visible absorption studies in solution and thin film for the three acceptors revealed maximum absorption from 687 to 732 nm and 731 to 847 nm, respectively. The onset of absorption in the thin film was found to be extending up to around 960 nm for PhBu-IDT-BT-IC4Cl. The optical band gap ranged from 1.30 to 1.41 eV, which are very low and useful for photovoltaic application. The introduction of halogen appreciably altered the LUMO energy levels, whereas the HOMO energy levels were nearly intact. These small molecule non-fullerene acceptors could be used as potential acceptors in bulk heterojunction organic photovoltaic (BHJ-OPV) applications.</p>","PeriodicalId":54252,"journal":{"name":"Bulletin of the Korean Chemical Society","volume":"45 9","pages":"788-794"},"PeriodicalIF":1.7,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142313222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A time-efficient computational binding affinity estimation protocol with utilization of limited experimental data: A case study for adenosine receptor","authors":"Ilkwon Cho, Sunghyun Moon, Kwang-Hwi Cho","doi":"10.1002/bkcs.12890","DOIUrl":"https://doi.org/10.1002/bkcs.12890","url":null,"abstract":"<p>Estimating binding affinity is a crucial step in the drug discovery process. In computer-aided drug design, this challenge can be divided into two main tasks: finding the correct binding pose and estimating the binding free energy. In this study, we propose a new binding affinity estimation protocol that utilizes molecular docking with limited experimental data and estimates binding affinity using molecular dynamics simulation. A custom scoring function was employed during docking to identify an improved initial binding pose, and the linear interaction energy method with an optimized coefficient was used for binding affinity estimation. The protocol was validated with an external data set and applied to modafinil and its derivatives to rank their binding affinities to adenosine A2A receptors (ADORA2A) as a case study. This approach could be both time-efficient and valuable for computational drug discovery, particularly when experimental data is limited.</p>","PeriodicalId":54252,"journal":{"name":"Bulletin of the Korean Chemical Society","volume":"45 9","pages":"778-787"},"PeriodicalIF":1.7,"publicationDate":"2024-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bkcs.12890","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142313365","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Off–On fluorescent benzothiazole-fused coumarin for sensitive detection of nitroreductases and hydrogen sulfide","authors":"Song Yi Yoo, Na Yoon Kim, Min Hee Lee","doi":"10.1002/bkcs.12889","DOIUrl":"https://doi.org/10.1002/bkcs.12889","url":null,"abstract":"<p>Hydrogen sulfide (H<sub>2</sub>S) and nitroreductases (NTR) are key biological reductants, with H<sub>2</sub>S acting as a key signaling molecule and NTR reducing nitro groups to amines in cellular metabolism. Visualizing these reducing components, often overexpressed in cancer cells or bacterial environments, is crucial for metabolic understanding. Existing fluorescent probes detect these individually, but simultaneous detection methods are unexplored. We designed probe <b>1</b>, which shows high fluorescence only when both NTR and H<sub>2</sub>S are overexpressed. The probe transformed into benzothiazole-fused coumarin by NTR, exhibiting fluorescence, and shows a stronger signal in the presence of both NTR and H<sub>2</sub>S, making it a potential tool for detecting their simultaneous overexpression.</p>","PeriodicalId":54252,"journal":{"name":"Bulletin of the Korean Chemical Society","volume":"45 8","pages":"699-705"},"PeriodicalIF":1.7,"publicationDate":"2024-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142050531","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Minsoo Lee, Eunhye Hwang, Taehyo Kim, Tae-Hyuk Kwon
{"title":"Advancements in non-fullerene acceptors for organic solar cells: Brief review of research trends","authors":"Minsoo Lee, Eunhye Hwang, Taehyo Kim, Tae-Hyuk Kwon","doi":"10.1002/bkcs.12888","DOIUrl":"https://doi.org/10.1002/bkcs.12888","url":null,"abstract":"<p>In the last few decades, fullerene-based acceptors have been extensively utilized in organic solar cells (OSCs). However, OSCs based on fullerenes suffer from low photocurrent and photovoltage due to their poor light absorption capacity and limited tunability of energy levels, which impedes efficiency improvements. Recently, non-fullerene acceptors (NFAs) have enabled rapid progress in OSCs, owing to their favorable properties such as strong light absorption, facile energy level tuning, and improved charge transport characteristics. These features have led to rapid efficiency enhancements. This review discusses the latest research trends related to NFAs, covering several factors that can be applied in the development of NFAs. Finally, we suggest prospects and challenges for high-performance NFA-based OSCs on the path to commercialization.</p>","PeriodicalId":54252,"journal":{"name":"Bulletin of the Korean Chemical Society","volume":"45 8","pages":"664-674"},"PeriodicalIF":1.7,"publicationDate":"2024-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142050503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yong-Sog Kwon, Kyu-Chul Jung, Shufang Zhao, Yujing Ji, Shahid Saqlain, Young Dok Kim
{"title":"TiO2 for efficient photocatalytic decomposition of acetaldehyde: An investigation of the effects of annealing temperature, humidity, and binder","authors":"Yong-Sog Kwon, Kyu-Chul Jung, Shufang Zhao, Yujing Ji, Shahid Saqlain, Young Dok Kim","doi":"10.1002/bkcs.12887","DOIUrl":"10.1002/bkcs.12887","url":null,"abstract":"<p>TiO<sub>2</sub> photocatalysts were synthesized by simple sol gel method and annealed at 300, 500, and 600°C. Photocatalytic performance of as-prepared TiO<sub>2</sub> and annealed TiO<sub>2</sub> samples was evaluated for the decomposition of acetaldehyde under UV light irradiation. TiO<sub>2</sub> annealed at 500°C (T500) showed the highest acetaldehyde removal performance, which was attributed to combined effects of its crystallinity, defect density, surface area, narrow band gap with the dual phase of TiO<sub>2</sub>, and lifetimes of charge carriers. In humid conditions, overall acetaldehyde removal performance of T500 slightly decreased, but the extent of total oxidation of acetaldehyde into CO<sub>2</sub> increased in high humidity as compared to dry conditions. Moreover, fixation of T500 on mica sheet using binders resulted in promising photocatalytic performance, making it a potential candidate for air purification applications. Fourier-transform infra-red (FT-IR) analysis confirmed the stable existence of binder structure under dry air and UV treatment, which is crucial for real applications.</p>","PeriodicalId":54252,"journal":{"name":"Bulletin of the Korean Chemical Society","volume":"45 8","pages":"706-719"},"PeriodicalIF":1.7,"publicationDate":"2024-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141806036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}