{"title":"Exploring Spatiotemporal Paleoenvironmental and Paleoceanographic Changes on the Continental Shelf Using Authigenic Greigite: A Case Study From the East China Sea","authors":"Jianxing Liu, Taoyu Xu, Qiang Zhang, Xiaoxiao Yu, Yonghua Wu, Qingsong Liu, Xuefa Shi","doi":"10.1029/2023PA004621","DOIUrl":"https://doi.org/10.1029/2023PA004621","url":null,"abstract":"The lack of suitable indicators of changes in such as sea‐level and circulation has been a major limit to paleoenvironmental and paleoceanographic investigations in continental shelf regions. This paper presents an environmental magnetic study by comparing two late‐Quaternary sediment cores (DH02 and DH03) from the outer shelf of the East China Sea (ECS). Late and early Marine Isotope Stage (MIS) 3 sediments were deposited in a prodelta under cold coastal currents and an open‐shelf with the Taiwan Warm Current and upwelling. The dominant iron‐bearing minerals of the late and early MIS 3 sediments are authigenic greigite (Fe3S4) and pyrite (FeS2), respectively, which were assumed to be formed nearly syndepositionally. The overlying sediments, however, are magnetically dominated by detrital magnetite. This pattern corresponds well to the temporal changes in sea‐level over this period. The widespread occurrence of greigite in the late MIS 3 sediments can also be used for future stratigraphic division and correlation in the ECS. Additionally, compared to microfossil assemblages, rock magnetic parameters based on greigite may be more sensitive to environmental changes on continental shelves. Furthermore, the inter‐borehole spatial comparisons imply not only a sedimentary hiatus/erosion of at least 30‐m thickness in core DH02, most probably during the Last Glacial Maximum, but also that core DH02 was in a more reductive environment than core DH03 during late MIS 3. The findings highlight the potential of authigenic greigite as an indicator of spatiotemporal changes in paleoenvironmental and paleoceanographic conditions on the continental shelf at orbital or even suborbital timescales.","PeriodicalId":54239,"journal":{"name":"Paleoceanography and Paleoclimatology","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45279971","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Cramwinckel, N. Burls, A. A. Fahad, Scott Knapp, C. K. West, T. Reichgelt, D. Greenwood, W. Chan, Y. Donnadieu, D. Hutchinson, A. D. de Boer, J. Ladant, P. Morozova, I. Niezgodzki, G. Knorr, S. Steinig, Zhongshi Zhang, Jiang Zhu, R. Feng, D. Lunt, A. Abe‐Ouchi, G. Inglis
{"title":"Global and Zonal‐Mean Hydrological Response to Early Eocene Warmth","authors":"M. Cramwinckel, N. Burls, A. A. Fahad, Scott Knapp, C. K. West, T. Reichgelt, D. Greenwood, W. Chan, Y. Donnadieu, D. Hutchinson, A. D. de Boer, J. Ladant, P. Morozova, I. Niezgodzki, G. Knorr, S. Steinig, Zhongshi Zhang, Jiang Zhu, R. Feng, D. Lunt, A. Abe‐Ouchi, G. Inglis","doi":"10.1029/2022PA004542","DOIUrl":"https://doi.org/10.1029/2022PA004542","url":null,"abstract":"Earth's hydrological cycle is expected to intensify in response to global warming, with a “wet‐gets‐wetter, dry‐gets‐drier” response anticipated over the ocean. Subtropical regions (∼15°–30°N/S) are predicted to become drier, yet proxy evidence from past warm climates suggests these regions may be characterized by wetter conditions. Here we use an integrated data‐modeling approach to reconstruct global and zonal‐mean rainfall patterns during the early Eocene (∼56–48 million years ago). The Deep‐Time Model Intercomparison Project (DeepMIP) model ensemble indicates that the mid‐ (30°–60°N/S) and high‐latitudes (>60°N/S) are characterized by a thermodynamically dominated hydrological response to warming and overall wetter conditions. The tropical band (0°–15°N/S) is also characterized by wetter conditions, with several DeepMIP models simulating narrowing of the Inter‐Tropical Convergence Zone. However, the latter is not evident from the proxy data. The subtropics are characterized by negative precipitation‐evaporation anomalies (i.e., drier conditions) in the DeepMIP models, but there is surprisingly large inter‐model variability in mean annual precipitation (MAP). Intriguingly, we find that models with weaker meridional temperature gradients (e.g., CESM, GFDL) are characterized by a reduction in subtropical moisture divergence, leading to an increase in MAP. These model simulations agree more closely with our new proxy‐derived precipitation reconstructions and other key climate metrics and imply that the early Eocene was characterized by reduced subtropical moisture divergence. If the meridional temperature gradient was even weaker than suggested by those DeepMIP models, circulation‐induced changes may have outcompeted thermodynamic changes, leading to wetter subtropics. This highlights the importance of accurately reconstructing zonal temperature gradients when reconstructing past rainfall patterns.","PeriodicalId":54239,"journal":{"name":"Paleoceanography and Paleoclimatology","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46002849","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Reconstructing the Oxygen Depth Profile in the Arabian Sea During the Last Glacial Period","authors":"Wanyi Lu, K. Costa, D. Oppo","doi":"10.1029/2023PA004632","DOIUrl":"https://doi.org/10.1029/2023PA004632","url":null,"abstract":"Reconstructing the strength and depth boundary of oxygen minimum zones (OMZs) in the glacial ocean advances our understanding of how OMZs respond to climate changes. While many efforts have inferred better oxygenation of the glacial Arabian Sea OMZ from qualitative indices, oxygenation and vertical extent of the glacial OMZ is not well quantified. Here we present glacial‐Holocene oxygen reconstructions in a depth transect of Arabian Sea cores ranging from 600 to 3,650 m water depths. We estimate glacial oxygen concentrations using benthic foraminiferal surface porosity and benthic carbon isotope gradient reconstructions. Compared to the modern Arabian Sea, glacial oxygen concentrations were approximately 10–15 μmol/kg higher in the shallow OMZ (<1,000 m), and 5–80 μmol/kg lower at greater depths (1,500–3,650 m). Our results suggest that the OMZ in the glacial Arabian Sea was slightly better oxygenated but remained in the upper 1,000 m. We propose that the small increase in oxygenation of the Arabian Sea OMZ during the last glacial period was due to weaker upper ocean stratification induced by stronger winter monsoon winds coupled with an increase in oxygen solubility due to lower temperatures, counteracting the effects of more oxygen consumption resulting from higher primary productivity. Large‐scale changes in ocean circulation may have also contributed to better ventilation of the glacial Arabian Sea OMZ.","PeriodicalId":54239,"journal":{"name":"Paleoceanography and Paleoclimatology","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47765512","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Chris Hancock, N. McKay, M. Erb, D. Kaufman, Cody R. Routson, R. Ivanović, L. Gregoire, P. Valdes
{"title":"Global Synthesis of Regional Holocene Hydroclimate Variability Using Proxy and Model Data","authors":"Chris Hancock, N. McKay, M. Erb, D. Kaufman, Cody R. Routson, R. Ivanović, L. Gregoire, P. Valdes","doi":"10.1029/2022PA004597","DOIUrl":"https://doi.org/10.1029/2022PA004597","url":null,"abstract":"Substantial changes in terrestrial hydroclimate during the Holocene are recorded in geological archives and simulated by computer models. To identify spatial and temporal patterns during the past 12 ka, proxy records sensitive to changing precipitation and effective moisture (precipitation minus evaporation) were compiled from across the globe (n = 813). Proxy composite timeseries were computed for 30 of the IPCC AR6 regions and compared to two full‐Holocene transient model simulations (TraCE‐21ka and HadCM3) and twelve mid‐Holocene CMIP6 simulations. We find that throughout Northern Hemisphere monsoon regions, proxy and model simulations indicate wetter‐than‐modern conditions during the early and mid‐Holocene while Southern Hemisphere monsoon regions were drier. This insolation driven trend toward modern values began approximately 6,000 years ago, and the clear agreement among proxy records and models may reflect the large magnitude of precipitation change and consistent atmospheric circulation forcing mechanism for these regions. In the midlatitudes, the pattern of change is less certain. Generally, proxy composites show a wetting trend throughout the Holocene for the northern midlatitudes, possibly due to strengthening westerlies from an increasing latitudinal temperature gradient. However, simulations indicate that the magnitude of change was relatively low, and for portions of North America, there is a proxy‐model disagreement. At high latitudes, hydroclimate is positively correlated with temperature in both proxies and models, consistent with projected wetting as temperatures rise. Overall, this large proxy database reveals a coherent pattern of hydroclimate variability despite the challenges associated with reconstructing hydroclimate fields.","PeriodicalId":54239,"journal":{"name":"Paleoceanography and Paleoclimatology","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2023-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49209634","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Hsieh, R. Vaucher, L. Löwemark, S. Dashtgard, C. Horng, A. Lin, C. Zeeden
{"title":"Influence of a Rapidly Uplifting Orogen on the Preservation of Climate Oscillations","authors":"A. Hsieh, R. Vaucher, L. Löwemark, S. Dashtgard, C. Horng, A. Lin, C. Zeeden","doi":"10.1029/2022PA004586","DOIUrl":"https://doi.org/10.1029/2022PA004586","url":null,"abstract":"Climate oscillations preserved in sedimentary archives tend to decrease in resolution further back in Earth's history. High‐frequency climate cycles (e.g., ∼20‐Kyr precession cycles) are especially prone to poor preservation due to sediment reworking. Recent studies have shown, however, that given sufficient basin accommodation space and sedimentation rate, shallow‐marine paleoclimate archives record precession‐driven hydroclimate change in mid‐low latitude regions. Our study evaluates how the evolution of a rapidly uplifting orogen influences the recording of astronomical climate forcing in shallow‐marine sedimentary strata in the Taiwan Western Foreland Basin (WFB). Time‐series analysis of gamma‐ray records through the late Miocene–Pliocene Kueichulin Formation shows that during early stages of Taiwan orogenesis (before 5.4 Ma), preservation of precession‐driven East Asian Summer Monsoon variability is low despite increasing monsoon intensities between 8 and 3 Ma. The Taiwan Strait had not formed, and the southeast margin of Eurasia was open to the Pacific Ocean. Consequently, depositional environments in the WFB were susceptible to reworking by large waves, resulting in the obscuration of higher‐frequency precession cycles. From 5.4 to 4.92 Ma, during early stages of emergence of Taiwan, basin subsidence increased while sedimentation rates remained low, resulting in poor preservation of orbital oscillations. After 4.92 Ma and up to 3.15 Ma, Taiwan became a major sediment source to the WFB, and sheltered the WFB from erosive waves with the development of Taiwan Strait. The elevated sediment influx, increased basin accommodation as the WFB developed, and formation of a semi‐sheltered strait, resulted in enhanced preservation of precession‐driven East Asian Summer Monsoon variability.","PeriodicalId":54239,"journal":{"name":"Paleoceanography and Paleoclimatology","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2023-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43295174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Chadwick, L. Sime, C. Allen, Maria-Vittoria Guarino
{"title":"Model‐Data Comparison of Antarctic Winter Sea‐Ice Extent and Southern Ocean Sea‐Surface Temperatures During Marine Isotope Stage 5e","authors":"M. Chadwick, L. Sime, C. Allen, Maria-Vittoria Guarino","doi":"10.1029/2022PA004600","DOIUrl":"https://doi.org/10.1029/2022PA004600","url":null,"abstract":"Marine Isotope Stage (MIS) 5e (130–116 ka) represents a “laboratory” for evaluating climate model performance under warmer‐than‐present conditions. Climate model simulations for MIS 5e have previously failed to produce Southern Ocean (SO) sea‐surface temperatures (SSTs) and sea‐ice extent reconstructed from marine sediment core proxy records. Here we compare state of the art HadGEM3 and HadCM3 simulations of Peak MIS 5e SO summer SSTs and September sea‐ice concentrations with the latest marine sediment core proxy data. The model outputs and proxy records show the least consistency in the regions located near the present‐day SO gyre boundaries, implying the possibility that model simulations are currently unable to fully realize changes in gyre extent and position during MIS 5e. Including Heinrich 11 meltwater forcing in Peak MIS 5e climate simulations improves the likeness to proxy data but it is clear that longer (3–4 ka) run times are required to fully test the consistency between models and data.","PeriodicalId":54239,"journal":{"name":"Paleoceanography and Paleoclimatology","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2023-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41966205","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Saitoh, M. Nishizawa, K. Ozaki, M. Ikeda, Y. Ueno, K. Takai, Y. Isozaki
{"title":"Nitrogen Isotope Record From a Mid‐oceanic Paleo‐Atoll Limestone to Constrain the Redox State of the Panthalassa Ocean in the Capitanian (Late Guadalupian, Permian)","authors":"M. Saitoh, M. Nishizawa, K. Ozaki, M. Ikeda, Y. Ueno, K. Takai, Y. Isozaki","doi":"10.1029/2022PA004573","DOIUrl":"https://doi.org/10.1029/2022PA004573","url":null,"abstract":"The Capitanian stage is characterized by marine anoxia possibly related to the extinction, although the global redox structure of the Capitanian ocean has not been constrained. We newly report a nitrogen isotope (δ15N) record from a paleo‐atoll limestone at the top of a mid‐Panthalassan seamount to constrain the spatial extent and duration of the Capitanian marine anoxia. The δ15N value of limestone after acid treatment is substantially high for ∼5‐Myr up to +28‰, the highest through the Phanerozoic oceans, suggesting that the nitrogen source (nitrate) was substantially enriched in 15N via denitrification within subsurface oxygen‐deficient zones (ODZs; O2 < 5 µM). Numerical modeling of nitrogen isotope dynamics in the upwelling system along the seamount suggests that the possible minimum δ15N value of a global deep‐oceanic nitrate reservoir was ca. +9‰ in the Capitanian (∼4‰ higher than at the present). Furthermore, a redox‐dependent nitrogen isotope mass balance model constrained the global redox structure of the Capitanian superocean. Substantially reducing conditions (O2 ≤ 20 µM) prevailed at intermediate water depths (100–1,000 m), in association with expanded ODZs with anoxic/euxinic cores along continental margins (≥ ∼0.4% of global ocean volume), while the deep‐ocean remained to be more oxidizing (O2 ≤ 60 µM). The enhanced open‐ocean productivity associated with the low sea‐level and high nutrient flux to the ocean resulted in the global ocean deoxygenation during the cooling stage. Our model is consistent with previous geologic observations and with a possible link between the long‐term (∼5‐Myr) development of marine dysoxia and the extinction.","PeriodicalId":54239,"journal":{"name":"Paleoceanography and Paleoclimatology","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42191494","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rachel T. So, T. Lowenstein, E. Jagniecki, J. Tierney, S. Feakins
{"title":"Holocene Water Balance Variations in Great Salt Lake, Utah: Application of GDGT Indices and the ACE Salinity Proxy","authors":"Rachel T. So, T. Lowenstein, E. Jagniecki, J. Tierney, S. Feakins","doi":"10.1029/2022PA004558","DOIUrl":"https://doi.org/10.1029/2022PA004558","url":null,"abstract":"Great Salt Lake (GSL), Utah, is a hypersaline terminal lake in the Great Basin, and the remnant of the late glacial Lake Bonneville. Holocene hydroclimate variations cannot be interpreted from the shoreline record, but instead can be investigated by proxies archived in the sediments. GLAD1‐GSL00‐1B was cored in 2000 and recently dated by radiocarbon for the Holocene section with the top 11 m representing ∼7 ka to present. Sediment samples every 30 cm (∼220 years) were studied for the full suite of microbial membrane lipids, including those responsive to temperature and salinity. The Archaeol and Caldarchaeol Ecometric (ACE) index detects the increase in lipids of halophilic archaea, relative to generalists, as salinity increases. We find Holocene ACE values ranged from 81 to 98, which suggests persistent hypersalinity with <50 g/L variability across 7.2 ka. The temperature proxy, MBTʹ5Me, yields values similar to modern mean annual air temperature for months above freezing (MAF = 15.7°C) over the last 5.5 ka. Several glycerol dialkyl glycerol tetraether metrics show a step shift in microbial communities and limnology at 5.5 ka. Extended archaeol detects elevated salinity during the regional mid‐Holocene drought, not readily detected in the ACE record that is often near the upper limit of the index. We infer that the mid‐Holocene GSL was shallower and saltier than the late Holocene. The current drying may be returning the lake to conditions not seen since the mid‐Holocene.","PeriodicalId":54239,"journal":{"name":"Paleoceanography and Paleoclimatology","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2023-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48920748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Modeling the Production of Heinrich Layers With a Sediment‐Enabled Iceberg Model","authors":"M. Fendrock, A. Condron, D. McGee","doi":"10.1029/2022PA004583","DOIUrl":"https://doi.org/10.1029/2022PA004583","url":null,"abstract":"In the North Atlantic, relatively coarse grained sediments can be found periodically throughout sediment cores spanning the Last Glacial Period. These sediments were rafted by icebergs released from the Laurentide Ice Sheet (LIS) in so‐called Heinrich Events. These “Heinrich Layers” coincide with records of global climate change, suggesting that the impact of these events was propagated beyond the North Atlantic. In order to best understand the climate context and significance of Heinrich Events, it is important to constrain the mechanism for their release from the LIS and the nature of the ice sheet itself. One approach for investigating the source of Heinrich Events is to understand the sediment load of icebergs involved, information that would inform interpretations of how those icebergs were produced. By simulating Heinrich Events in a high resolution global climate model (20–40 times the resolution of previous studies), this work investigates the processes involved in the deposition of Heinrich Layers in the North Atlantic. In these simulations, the same volume of sediment is distributed differently through the same volume of icebergs, producing profoundly different sediment records. Due to the high resolution of the model, these simulated sedimentary layers can be inspected in great detail, revealing nuances of the deposit. Only when sediment is distributed throughout the entire iceberg does the model produce a sediment pattern in agreement with observations, yet icebergs with this sediment distribution are not observed in the modern‐day.","PeriodicalId":54239,"journal":{"name":"Paleoceanography and Paleoclimatology","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2023-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43369120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Taylor, T. Westerhold, S. Bohaty, J. Backman, T. Jones, K. Edgar, K. Egan, M. Lyle, H. Pälike, U. Röhl, J. Zachos, P. Wilson
{"title":"Transient Shoaling, Over‐Deepening and Settling of the Calcite Compensation Depth at the Eocene‐Oligocene Transition","authors":"V. Taylor, T. Westerhold, S. Bohaty, J. Backman, T. Jones, K. Edgar, K. Egan, M. Lyle, H. Pälike, U. Röhl, J. Zachos, P. Wilson","doi":"10.1029/2022PA004493","DOIUrl":"https://doi.org/10.1029/2022PA004493","url":null,"abstract":"The major Cenozoic shift from a shallow (∼3–4 km) to deep (∼4.5 km) calcite compensation depth (CCD) occurred at the Eocene‐Oligocene Transition (∼34 Ma), suggesting a strong relationship between calcium carbonate (CaCO3) cycling and Antarctic glaciation. However, the linkages between these two events are debated. Here we present new records of bulk sediment stable isotope and carbonate composition from a depth transect of sites in the low‐latitude Pacific Ocean and one site from the South Atlantic Ocean, together with a new benthic foraminiferal stable isotope record (δ13Cb and δ18Ob) from the Pacific where the sedimentary sequence is most expanded. Our records reveal a short‐lived (∼3,000 Kyr) CCD shoaling event closely associated with a negative carbon isotope excursion in the latest Eocene. This event is immediately followed by CCD deepening which occurs in two rapid (∼40 Kyr‐long) steps. Our data show that the first of these deepening steps represents recovery from the latest Eocene shoaling event while the second was closely associated with a rapid increase in δ18Ob and shows a distinctive over‐deepening and settling pattern to >5 and 4.4 km, respectively. These results, together with good agreement between Pacific and South Atlantic records, strongly suggest that the carbon cycle was perturbed globally shortly before the inception of Antarctic glaciation. Once large‐scale Antarctic glaciation was initiated, rapid further change in global seawater chemistry triggered transitory deep ocean carbonate burial fluxes far exceeding their early Oligocene steady state values.","PeriodicalId":54239,"journal":{"name":"Paleoceanography and Paleoclimatology","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2023-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48259401","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}