Electrocatalysis最新文献

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Parametric Optimization of Transition Metal-Based Nanocomposite Electrocatalysts for Oxygen Evolution Reaction in Alkaline Media 碱性介质中析氧反应过渡金属基纳米复合电催化剂的参数优化
IF 2.8 4区 化学
Electrocatalysis Pub Date : 2025-04-11 DOI: 10.1007/s12678-025-00952-8
Vedasri Bai Khavala, Abhijai Velluva, Adhithyan Kathiravan, Harish Kuruva, Chandan Singh Khavala, B. S. Murty, Tiju Thomas
{"title":"Parametric Optimization of Transition Metal-Based Nanocomposite Electrocatalysts for Oxygen Evolution Reaction in Alkaline Media","authors":"Vedasri Bai Khavala,&nbsp;Abhijai Velluva,&nbsp;Adhithyan Kathiravan,&nbsp;Harish Kuruva,&nbsp;Chandan Singh Khavala,&nbsp;B. S. Murty,&nbsp;Tiju Thomas","doi":"10.1007/s12678-025-00952-8","DOIUrl":"10.1007/s12678-025-00952-8","url":null,"abstract":"<div><p>Data-driven approaches have the potential to make a priori predictions. However, there are very few models that have been explored for the prediction of nanocomposite electrocatalysts under testing conditions. Here we report for the first time the parametric optimization coupled with data-driven approaches of efficient electrocatalysts for the oxygen evolution reaction (OER) in alkaline media. The parametric optimization suggests that the porous Ni- or Fe-based nitride composites, with combinatorial structures or thin films with average d-electrons between 5 and 8 and catalyst loading between 1 and 10 mg cm<sup>−2</sup> will exhibit the best OER activity. Machine learning classification of OER overpotential grades (<i>η</i><sub>10</sub>, overpotential at 10 mA cm<sup>−2</sup>) of transition metal oxynitrides (TMONs) and transition metal oxides (TMOs) is achieved using random forest (RF) and CatBoost algorithms. <i>η</i><sub>10</sub> is classified as grade ‘A’ if <i>η</i><sub>10</sub> &lt; 351 mV, else grade ‘F’. We note that 80–85% of electrocatalysts containing nickel foam (NF) have been in grade A, implying NF is a prospective hindrance against true activity determination of the electrocatalyst but suitable for achieving grade ‘A’ electrocatalyst for electrolysers. RF and CatBoost models achieved an accuracy of 78.09% on the TMON dataset and RF model achieved 72.88% on the TMO dataset. This work aims to reduce the experimental time for the design and development of an electrocatalyst using a data-driven paradigm.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":535,"journal":{"name":"Electrocatalysis","volume":"16 4","pages":"696 - 712"},"PeriodicalIF":2.8,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145164522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ethylene Glycol Electrooxidation on Phyto-synthesized Pd-Fe Composites by Aqueous Extract Plants 水溶液萃取植物合成Pd-Fe复合材料的乙二醇电氧化研究
IF 2.8 4区 化学
Electrocatalysis Pub Date : 2025-04-01 DOI: 10.1007/s12678-025-00951-9
Fatemeh Rigi, Zahra Yavari, Fatemeh Arbabi
{"title":"Ethylene Glycol Electrooxidation on Phyto-synthesized Pd-Fe Composites by Aqueous Extract Plants","authors":"Fatemeh Rigi,&nbsp;Zahra Yavari,&nbsp;Fatemeh Arbabi","doi":"10.1007/s12678-025-00951-9","DOIUrl":"10.1007/s12678-025-00951-9","url":null,"abstract":"<div><p>In the present work, the four Fe-based structures were prepared from the phyto-synthetic approaches and their subsequent calcinations. The aqueous extracts of <i>Salsola</i> sp. and <i>Heliotropium</i> <i>bacciferum</i> plants were used as the bio-reductant and stabilizer in these approaches. The green synthesized structures were characterized using FT-IR, XRD, FESEM, EDX, and VSM techniques. The characterization results showed that calcination created a cubic γ-Fe<sub>2</sub>O<sub>3</sub> phase with spherical morphology. The preparation of Pd-Fe composites was completed by reducing palladium ions on iron-containing samples using <i>Salsola</i> sp. aqueous extract. The effect of calcination and the type of extract used in the synthesis of Pd-Fe composites on their electrocatalytic activity towards the electrooxidation of ethylene glycol by voltammetry technique. The catalyst prepared with <i>Salsola</i> sp. (2.35 mA.cm<sup>−2</sup>) extract had better catalytic activity than the one <i>Heliotropium bacciferum</i> (1.67 mA.cm<sup>−2</sup>) for 0.28 M ethylene glycol oxidation<i>.</i> The catalytic activity of iron in the not-calcined form was higher than in the calcined due to the transformation in the electronic structure, confirmed by the change in the magnetic behavior of the sample. This work highlights the importance of green synthesis methodologies in electrochemistry applications. In summary, the main advantages of this work are the principles of green chemistry followed by an eco-friendly approach, sustainable resource utilization, cost-effectiveness, and enhanced catalytic properties.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":535,"journal":{"name":"Electrocatalysis","volume":"16 4","pages":"683 - 695"},"PeriodicalIF":2.8,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145160629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic Effects of Antimony Oxide Embedded Graphitic Carbon Nitride Nanocomposite as a sensing Interface for Hazardous Bisphenol A: An Electrochemical and Computational Approach 氧化锑嵌入石墨氮化碳纳米复合材料作为有害双酚a传感界面的协同效应:电化学和计算方法
IF 2.8 4区 化学
Electrocatalysis Pub Date : 2025-03-31 DOI: 10.1007/s12678-025-00948-4
Saheed E. Elugoke, Pakamisa E. Bono, Pattan-Siddappa Ganesh, Sang-Youn Kim, Eno E. Ebenso
{"title":"Synergistic Effects of Antimony Oxide Embedded Graphitic Carbon Nitride Nanocomposite as a sensing Interface for Hazardous Bisphenol A: An Electrochemical and Computational Approach","authors":"Saheed E. Elugoke,&nbsp;Pakamisa E. Bono,&nbsp;Pattan-Siddappa Ganesh,&nbsp;Sang-Youn Kim,&nbsp;Eno E. Ebenso","doi":"10.1007/s12678-025-00948-4","DOIUrl":"10.1007/s12678-025-00948-4","url":null,"abstract":"<div><p>Herein, an electrochemical sensor based on antimony oxide/graphitic carbon nitride nanocomposite (Sb<sub>2</sub>O<sub>3</sub>/GCN) was applied for bisphenol A (BPA) electroanalysis in a water sample. This composite and its components were characterized with X-ray diffraction (XRD) spectroscopy, UV–visible spectroscopy, Raman spectroscopy, Scanning electron microscopy (SEM) and Energy dispersive X-ray spectroscopy (EDX). Electrochemical characterization of a pencil graphite electrode (PGE) modified with Sb<sub>2</sub>O<sub>3</sub>/GCN, Sb<sub>2</sub>O<sub>3</sub> nanoparticles (Sb<sub>2</sub>O<sub>3</sub> NPs) and graphitic carbon nitride (GCN) show that the Sb<sub>2</sub>O<sub>3</sub>/GCN modified pencil graphite electrode (PGE/Sb<sub>2</sub>O<sub>3</sub>/GCN) has the highest electroactive surface area and electronic conductivity. Theoretical calculation of the adsorption energies of BPA/GCN complex and its variants revealed that hydrogen bonding and π- π interaction between GCN and BPA contributed to the electrocatalytic oxidation of BPA at the proposed sensor. The limit of detection of BPA at PGE/Sb<sub>2</sub>O<sub>3</sub>/GCN was estimated to be 5.61 μM. The calibration curve depicting the changes in peak current with BPA concentration showed two linear ranges at 8–60 μM and 60–140 μM. Also, the proposed sensor offered a percentage recovery of 102.43% for BPA in spiked bottled water. These figures of merit as well as the outstanding selectivity, remarkable repeatability and good reproducibility of the proposed sensor are indications that PGE/Sb<sub>2</sub>O<sub>3</sub>/GCN is a useful analytical tool for BPA electroanalysis in water samples.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":535,"journal":{"name":"Electrocatalysis","volume":"16 4","pages":"667 - 682"},"PeriodicalIF":2.8,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of Carbon Materials on Formation of CoN4Cx Active Site of Co-P4VPy/Carbon Catalysts for Selective CO2 Electroreduction to CO 碳材料对CO - p4vpy /碳选择性电还原CO催化剂CoN4Cx活性位点形成的影响
IF 2.8 4区 化学
Electrocatalysis Pub Date : 2025-03-28 DOI: 10.1007/s12678-025-00945-7
Siyuan Jia, Shoji Iguchi, Ichiro Yamanaka
{"title":"Effects of Carbon Materials on Formation of CoN4Cx Active Site of Co-P4VPy/Carbon Catalysts for Selective CO2 Electroreduction to CO","authors":"Siyuan Jia,&nbsp;Shoji Iguchi,&nbsp;Ichiro Yamanaka","doi":"10.1007/s12678-025-00945-7","DOIUrl":"10.1007/s12678-025-00945-7","url":null,"abstract":"<div><p>Development of active electrocatalyst for CO<sub>2</sub> reduction to useful chemicals would be essential factor to achieve the carbon neutral society. The Co poly-4-vinyl-pyridine (P4VPy)/Ketjenblack (KB) activated thermally was found for an active electrocatalyst in the electroreduction of CO<sub>2</sub> with water by the solid-polymer-electrolyte, SPE, electrolysis cell. Various carbon supports were applied instead of KB. Contents of CoN<sub>4</sub>C<sub>x</sub>, CoO and Co<sup>0</sup> compounds on activated electrocatalysts were determined by linear combination fitting, LCF, of X-ray absorption near edge structure, XANES. Pyrolysis of the catalyst precursor for activation was essential and kinds of carbon supports strongly influenced formation of the Co compounds. It was revealed that the content of CoN<sub>4</sub>C<sub>x</sub> related to the current efficiency of the CO formation and that of CoO and Co<sup>0</sup> related the H<sub>2</sub> formation.</p><h3>Graphical Abstract</h3><p>Relation between Faraday efficiency to CO and content of CoN<sub>4</sub>C<sub>x</sub></p>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":535,"journal":{"name":"Electrocatalysis","volume":"16 4","pages":"601 - 609"},"PeriodicalIF":2.8,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s12678-025-00945-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bimetallic Cobalt-Vanadium Boride as a Bifunctional Electrocatalyst for Overall Water Splitting 双金属钴钒硼化物作为全水分解的双功能电催化剂
IF 2.8 4区 化学
Electrocatalysis Pub Date : 2025-03-26 DOI: 10.1007/s12678-025-00946-6
Maheshwar B. Falake, Rinkoo Bhabal, Avani Chunduri, Vinita Dhulia, Rupali Patel, Nainesh Patel
{"title":"Bimetallic Cobalt-Vanadium Boride as a Bifunctional Electrocatalyst for Overall Water Splitting","authors":"Maheshwar B. Falake,&nbsp;Rinkoo Bhabal,&nbsp;Avani Chunduri,&nbsp;Vinita Dhulia,&nbsp;Rupali Patel,&nbsp;Nainesh Patel","doi":"10.1007/s12678-025-00946-6","DOIUrl":"10.1007/s12678-025-00946-6","url":null,"abstract":"<div><p>The transition to a hydrogen-based economy necessitates the development of sustainable and cost-effective electrocatalysts for green hydrogen production via water electrolysis. In this study, we report a novel cobalt-vanadium boride (CoVB) catalyst, which exhibits enhanced bifunctional activity for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in alkaline media. CoVB was synthesized using a facile one-step chemical reduction method with varying vanadium concentrations, optimizing performance at a 3% vanadium content. Electrochemical analyses demonstrated that CoVB significantly outperformed cobalt boride (CoB), achieving an HER and OER overpotential (η<sub>10</sub>) of 80 mV and 320 mV, respectively, comparable to noble metal benchmarks. Characterization results revealed that V plays a promoting role in inhibiting the growth of particles and agglomeration of particles, leading to an increase in surface area and producing unique mixed amorphous and crystalline structures in CoVB to enhance catalytic activity by increasing the number of active sites and conductivity across the interface. Furthermore, in two-electrode systems, the cell voltage of 1.66 V was needed to achieve 10 mA/cm<sup>2</sup> of current density with superior stability and reusability. Overall, the CoVB catalyst, a new candidate from the metal boride family, presents a promising alternative to precious metals for efficient and sustainable water-splitting in alkaline electrolyzers.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":535,"journal":{"name":"Electrocatalysis","volume":"16 4","pages":"645 - 654"},"PeriodicalIF":2.8,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145169560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Carbon Nanotube-Supported Co–Ni-Pt Ternary Alloy Ultrafine Nanoparticles with Enhanced Performance for Methanol Oxidation 碳纳米管负载的Co-Ni-Pt三元合金超细纳米颗粒甲醇氧化性能增强
IF 2.8 4区 化学
Electrocatalysis Pub Date : 2025-03-26 DOI: 10.1007/s12678-025-00947-5
Ruiwen Yan, Shuiyan Ning, Yizhong Wang, Guiqi Gao, Chuanqiang Wu
{"title":"Carbon Nanotube-Supported Co–Ni-Pt Ternary Alloy Ultrafine Nanoparticles with Enhanced Performance for Methanol Oxidation","authors":"Ruiwen Yan,&nbsp;Shuiyan Ning,&nbsp;Yizhong Wang,&nbsp;Guiqi Gao,&nbsp;Chuanqiang Wu","doi":"10.1007/s12678-025-00947-5","DOIUrl":"10.1007/s12678-025-00947-5","url":null,"abstract":"<div><p>The study focuses on improving methanol electrocatalytic oxidation (MOR) by optimizing platinum-based alloy electrocatalysts. Co–Ni-Pt ternary alloy nanoparticles were successfully deposited on carbon nanotubes via a chemical reduction method, forming a composite of Co–Ni-Pt nanoparticles/carbon nanotubes (Co–Ni-Pt NPs/CNTs). Various characterization techniques, including X-ray diffraction (XRD), transmission electron microscopy (TEM), special aberration corrected transmission electron microscopy (STEM), and X-ray photoelectron spectroscopy (XPS), were employed to analyze the morphology and structure of the material. The results illustrated a uniform distribution of Co–Ni-Pt alloy nanoparticles on the carbon nanotube surface. The catalytic performance of the Co–Ni-Pt NPs/CNTs composite materials was assessed using chronoamperometry (CA), linear sweep voltammetry (LSV), and cyclic voltammetry (CV). By adjusting the ratios of Co, Ni, and Pt, catalytic performance in MOR was improved. Among the Co–Ni-Pt NPs/CNTs composites tested, the Co<sub>1.5</sub>Ni<sub>1.5</sub>Pt<sub>1</sub> NPs /CNTs composite exhibited the highest catalytic activity, achieving a mass activity of 2537 mA mg<sup>−1</sup><sub>Pt</sub>, outperforming that of commercial Pt/C catalysts by 1.37 times.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":535,"journal":{"name":"Electrocatalysis","volume":"16 4","pages":"655 - 666"},"PeriodicalIF":2.8,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145169561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hyamine 1622-I/I2-Incorporated Sensing Platform for Selective Measurement of Ascorbic Acid, Dopamine, Acetaminophen, Ibuprofen, and Tyrosine Hyamine 1622-I/I2-Incorporated传感平台选择性测量抗坏血酸,多巴胺,对乙酰氨基酚,布洛芬和酪氨酸
IF 2.8 4区 化学
Electrocatalysis Pub Date : 2025-03-25 DOI: 10.1007/s12678-025-00949-3
S. Bahmanzadeh, M. Noroozifar
{"title":"Hyamine 1622-I/I2-Incorporated Sensing Platform for Selective Measurement of Ascorbic Acid, Dopamine, Acetaminophen, Ibuprofen, and Tyrosine","authors":"S. Bahmanzadeh,&nbsp;M. Noroozifar","doi":"10.1007/s12678-025-00949-3","DOIUrl":"10.1007/s12678-025-00949-3","url":null,"abstract":"<div><p>In this study, we present a simple and sensitive carbon paste electrode embedded with Hyamine 1622-iodide/iodine for the simultaneous detection of ascorbic acid (AA), dopamine (DA), acetaminophen (AC), ibuprofen (IBP), and tyrosine (Tyr). Various electrochemical techniques, including cyclic and sweep voltammetry, chronoamperometry, and electrochemical impedance spectroscopy, were employed to investigate the electrode’s performance. The optimized electrode demonstrated excellent sensitivity, with detection limits of 0.74, 0.46, 0.45, 0.52, and 0.44 µM for AA, DA, AC, IBP, and Tyr, respectively. Additionally, it exhibited a broad linear range: 2.4–960.0 µM, 1.5–800.0 µM, 1.5–800.0 µM, 1.7–960.0 µM, and 1.5–860.0 µM for the respective analytes. Further electrochemical analysis provided key parameters, including diffusion coefficients, apparent electrode surface area, heterogeneous rate constants, electrode surface coverage, electron transfer coefficients, and catalytic rate constants for the oxidation processes of the target analytes. The proposed electrode successfully detected AA, DA, AC, IBP, and Tyr in human biological samples, demonstrating good precision with relative standard deviations (RSD) of 2.1%–3.9% and recovery rates between 97 and 103%. The accuracy of the method was validated against a standard technique, confirming its reliability and robustness.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":535,"journal":{"name":"Electrocatalysis","volume":"16 4","pages":"631 - 644"},"PeriodicalIF":2.8,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145168808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of Multiwall Carbon Nanotubes on Photocatalytic Response of Cadmium Oxide Nanocomposites for Water Pollutants 多壁碳纳米管对氧化镉纳米复合材料对水污染物光催化反应的影响
IF 2.8 4区 化学
Electrocatalysis Pub Date : 2025-03-15 DOI: 10.1007/s12678-025-00942-w
Suchitra Manjhu, Anu Malhotra, Sonia Srivastava, Anju Lavania, Karishma Jain, Deepika Maan, S. K. Jain, Shalini Dixit, Balram Tripathi
{"title":"Impact of Multiwall Carbon Nanotubes on Photocatalytic Response of Cadmium Oxide Nanocomposites for Water Pollutants","authors":"Suchitra Manjhu,&nbsp;Anu Malhotra,&nbsp;Sonia Srivastava,&nbsp;Anju Lavania,&nbsp;Karishma Jain,&nbsp;Deepika Maan,&nbsp;S. K. Jain,&nbsp;Shalini Dixit,&nbsp;Balram Tripathi","doi":"10.1007/s12678-025-00942-w","DOIUrl":"10.1007/s12678-025-00942-w","url":null,"abstract":"<div><p>In this study, we are reporting photocatalytic response of multiwall carbon nanotubes (MWCNTs)/cadmium oxide (CdO) nanocomposites. We dispersed MWCNT (1–5 wt%) into CdO system via sonication to obtain MWCNT/CdO nanocomposites. The methylene blue (MB) dye has been used as a photocatalytic probe to study response of degradation with respect to contact reaction time, effect of pH, temperature, and concentration of MWCNT into the CdO system. The optimum values are acquired at pH value of 6 and temperature range 50–60 °C for all composition of the catalysts. The intrinsic characteristics of resulting composites have been studied by X-ray diffraction, scanning electron microscopy, FT-IR analysis, and photoluminescence spectroscopy. It has been found that the as-prepared MWCNT/CdO nanocomposites possess dye absorptivity of 97.85%, significantly higher than the 64.85% observed for pristine CdO at a contact time of 75 min. Additionally, these nanocomposites exhibited an extended light absorption range and improved charge separation efficiency. The photodegradation of methylene blue shows significant enhancement in the reaction rate which reaches up to 0.058 min⁻<sup>1</sup> for the MWCNT/CdO composites, compared to 0.0189 min⁻<sup>1</sup> for the pristine CdO system.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":535,"journal":{"name":"Electrocatalysis","volume":"16 4","pages":"610 - 621"},"PeriodicalIF":2.8,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145165148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Creation of a 2-Nitrophenol Sensor by Using ZrO2-Encapsulated Barium Oxide in the Presence of 4-Nitrophenol 在4-硝基苯酚存在下用zro2包封氧化钡制备2-硝基苯酚传感器
IF 2.8 4区 化学
Electrocatalysis Pub Date : 2025-03-04 DOI: 10.1007/s12678-025-00943-9
Sudhan Narayanan, Pitchaimuthu Sakthivel, Balasubramanian Venkataraman
{"title":"Creation of a 2-Nitrophenol Sensor by Using ZrO2-Encapsulated Barium Oxide in the Presence of 4-Nitrophenol","authors":"Sudhan Narayanan,&nbsp;Pitchaimuthu Sakthivel,&nbsp;Balasubramanian Venkataraman","doi":"10.1007/s12678-025-00943-9","DOIUrl":"10.1007/s12678-025-00943-9","url":null,"abstract":"<div><p>By employing ZrO<sub>2</sub> coupled barium oxide nanoparticles modified glassy carbon electrode (ZrO<sub>2</sub> coupled BaO/GCE), we create a novel platform to sense the environmental contaminant 2-nitrophenol. Using XRD, FTIR, and SEM, the phase formation of BaO and ZrO<sub>2</sub> coupled BaO nanomaterials was examined. In comparison to bare GCE, both ZrO<sub>2</sub> coupled BaO-modified GCE and pure BaO-modified GCE demonstrate strong electrocatalytic activity towards 2-nitrophenol. The ZrO<sub>2</sub> coupled BaO-modified sensing platform has good sensitivity for 2-nitrophenol measurement across a broad linear range of 0.2 to 60 µM, with a 0.09 µM detection limit at the lowest. Moreover, it exhibits strong selectivity towards significant interfering substances including 4-nitrophenol, 4-aminophenol, catechol, hydroquinone, etc. Good agreement is observed between the analytical application of the suggested sensor and actual real water sample analysis.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":535,"journal":{"name":"Electrocatalysis","volume":"16 4","pages":"622 - 630"},"PeriodicalIF":2.8,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145162219","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Voltammetric Sensor for Simultaneous Determination of Ponceau 4R, Amaranth, and Tartrazine as Additives in Foodstuffs 伏安传感器同时测定食品中添加剂Ponceau 4R、苋菜红和酒黄石
IF 2.7 4区 化学
Electrocatalysis Pub Date : 2025-03-03 DOI: 10.1007/s12678-025-00936-8
Hanieh Ghanbari, Mansour Arab Chamjangali, Mohammad Faraji
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