Journal of Bioresources and Bioproducts最新文献_第2页

Sustainable dual-response optical modulation: WO3-based transparent cellulose composite membrane for photo- and electro-responsive chromatic devices 可持续双响应光调制：wo3基透明纤维素复合膜用于光和电响应色器件

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Journal of Bioresources and Bioproducts Pub Date : 2026-06-01 Epub Date: 2026-01-12 DOI: 10.1016/j.jobab.2026.100229

Xiuling Yang, Jingjiang Yang, Gaigai Duan, Xiaoshuai Han, Hui Fu, Yong Huang, Chunmei Zhang, Shuijian He, Shaohua Jiang

{"title":"Sustainable dual-response optical modulation: WO3-based transparent cellulose composite membrane for photo- and electro-responsive chromatic devices","authors":"Xiuling Yang, Jingjiang Yang, Gaigai Duan, Xiaoshuai Han, Hui Fu, Yong Huang, Chunmei Zhang, Shuijian He, Shaohua Jiang","doi":"10.1016/j.jobab.2026.100229","DOIUrl":"10.1016/j.jobab.2026.100229","url":null,"abstract":"<div><div>Photo- and electro-chromic devices can facilitate the realization of a wide set of future applications, ranging from transparent displays, dynamic windows, optical switches, and variable optical attenuators. Tungsten oxide (WO<sub>3</sub>) has always been the most studied material in the field of photo- and electro-chromic, although it has some bottlenecks. Here, we report a flexible transparent wood membrane for photo- and electro-chromic applications. The photochromic membrane (PCM) shows excellent photochromic properties, including high optical modulation (Δ<em>T</em><sub>1030 nm</sub> = 68.8%), ultraviolet (UV) shielding (>92%) and dynamic light regulation. Meanwhile, the electrochromic membrane (ECM, active area: 1 cm × 2.5 cm) and assembled complementary devices (active area: 3.4 cm × 3.4 cm) produce high optical modulation (Δ<em>T</em><sub>1030 nm</sub> = 78.2%) at 1030 nm, and the transmittance in colored state of below 10%. Noteworthy, the ECM (active area: 3.4 cm × 3.4 cm) comprised of WO<sub>3</sub>/Ag nanowires (NWs)/flexible wood-derived transparent cellulose membranes, reveals enhanced optical modulation (60.7%) and rapid response time (coloring/bleaching time: 7.6 s/10.8 s). Moreover, the electrode also presents good cycling stability (96.2% after 120 cycles). The design of these chromic devices introduces an innovative strategy, which is expected to open up a new way for the development of photo- and electro-chromic devices. Crucially, the inherent flexibility and scalability of the transparent wooden substrate enable it to maintain relatively stable performance across different device dimensions, thereby resolving practical challenges in real-world applications.</div></div>","PeriodicalId":52344,"journal":{"name":"Journal of Bioresources and Bioproducts","volume":"11 3","pages":"Article 100229"},"PeriodicalIF":13.0,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147920123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ambient-pressure-dried cellulose/MXene sediment aerogel for spectra compatible defense and Joule heating 常压干燥纤维素/MXene沉积物气凝胶光谱兼容防御和焦耳加热

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Journal of Bioresources and Bioproducts Pub Date : 2026-06-01 Epub Date: 2026-05-12 DOI: 10.1016/j.jobab.2026.100266

Jiasheng Wei, Di Li, Ping He, Yudong Wang, Zhu Long, Hao Jia, Guiqiang Fei, Lei Dai

{"title":"Ambient-pressure-dried cellulose/MXene sediment aerogel for spectra compatible defense and Joule heating","authors":"Jiasheng Wei, Di Li, Ping He, Yudong Wang, Zhu Long, Hao Jia, Guiqiang Fei, Lei Dai","doi":"10.1016/j.jobab.2026.100266","DOIUrl":"10.1016/j.jobab.2026.100266","url":null,"abstract":"<div><div>Ambient pressure-dried aerogels show great potential in the field of spectra compatible defense, such as integrating electromagnetic interference shielding and infrared stealth, due to their porous structure. However, they face the critical challenge of structural collapse caused by the strong capillary forces generated during solvent evaporation. Herein, MXene sediment (MS) and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-oxidized cellulose nanofiber (TOCNF) were employed to fabricate TOCNF/MS (TMS) aerogels through an ambient pressure drying process assisted by a dual crosslinking strategy of hydrogen bonds and Zr<sup>4+</sup> ionic cross-linking. Notably, Zr<sup>4+</sup> formed a robust cross‑linking network due to its high charge density and multidentate coordination capability, which could effectively resist capillary forces during ambient pressure drying. Moreover, ethanol was introduced to reduce the surface tension of the solvent, thereby further mitigating these capillary forces. The resultant TMS aerogels maintained an intact porous structure after ambient pressure drying, which facilitated multiple reflections and absorptions of electromagnetic waves while suppressing heat transfer. As a result, the TMS aerogel achieved an electromagnetic interference (EMI) shielding effectiveness (SE) of 73.2 dB in the X band, along with efficient shielding performance (>60 dB) in the C and Ku bands. It also exhibited exceptional infrared stealth capability, attributed to the synergy of low infrared emissivity and low thermal conductivity. Furthermore, the TMS aerogel exhibited outstanding Joule heating performance, reaching a response temperature of 106.8 °C under an applied voltage of 2.5 V. This ambient pressure-dried TMS aerogel provides a new way for efficiently utilizing MXene sediment to construct advanced spectra compatible defense materials.</div></div>","PeriodicalId":52344,"journal":{"name":"Journal of Bioresources and Bioproducts","volume":"11 3","pages":"Article 100266"},"PeriodicalIF":13.0,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148503389","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Closing loop: Systems-level integration of synthetic consortia and process engineering for lignocellulosic microbial lipid biomanufacturing 闭环：木质纤维素微生物脂质生物制造的合成联盟和工艺工程的系统级集成

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Journal of Bioresources and Bioproducts Pub Date : 2026-06-01 Epub Date: 2026-04-19 DOI: 10.1016/j.jobab.2026.100254

Changyu Pi, Jinyang Li, Fangting Jiang, Le Gao, Xin Wu

{"title":"Closing loop: Systems-level integration of synthetic consortia and process engineering for lignocellulosic microbial lipid biomanufacturing","authors":"Changyu Pi, Jinyang Li, Fangting Jiang, Le Gao, Xin Wu","doi":"10.1016/j.jobab.2026.100254","DOIUrl":"10.1016/j.jobab.2026.100254","url":null,"abstract":"<div><div>Amidst the urgent quest for carbon neutrality, lignocellulosic biomass has emerged as a key feedstock for sustainable biomanufacturing. However, the commercial viability of converting this recalcitrant resource into microbial lipids remains constrained by fragmented unit operations, particularly the trade-offs between biomass deconstruction efficiency and downstream inhibitor toxicity. This review moves beyond a linear technological summary to propose an integrated roadmap for next-generation biorefineries. We analyze the convergence of flexible and broadly applicable pretreatment strategies across diverse lignocellulosic feedstocks and synthetic biology-driven strain engineering, highlighting how tools such as Clustered Regularly Interspaced Short Palindromic Repeats/CRISPR-associated protein 9 and RNA interference enable more precise control of metabolic flux toward lipid precursors. Furthermore, we extend the discussion from monoculture systems to emerging artificial microbial consortia, which offer opportunities for functional division of labor in simultaneous inhibitor detoxification and lipid accumulation, while also presenting challenges in stability and metabolic coordination. In addition, we discuss how data-driven strategies, including machine learning and techno-economic analysis, can help bridge the gap between laboratory-scale advances and industrial implementation. By integrating insights from feedstock chemistry, microbial physiology, and process engineering, this review provides a systems-level perspective on the development of economically viable and low-carbon lipid biomanufacturing platforms.</div></div>","PeriodicalId":52344,"journal":{"name":"Journal of Bioresources and Bioproducts","volume":"11 3","pages":"Article 100254"},"PeriodicalIF":13.0,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148503463","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High-strength and environmentally stable wood conductive eutectogels enabled by metal-based deep eutectic solvents 高强度和环境稳定的木材导电共凝胶由金属基深共晶溶剂实现

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Journal of Bioresources and Bioproducts Pub Date : 2026-06-01 Epub Date: 2026-01-30 DOI: 10.1016/j.jobab.2026.100237

Muqiu You, Jinhao Xu, Jing Zhou, Yamei Zao, Dagang Li, Yongcan Jin, Zhaoyang Xu, Shinsuke Ifuku, Chuchu Chen

{"title":"High-strength and environmentally stable wood conductive eutectogels enabled by metal-based deep eutectic solvents","authors":"Muqiu You, Jinhao Xu, Jing Zhou, Yamei Zao, Dagang Li, Yongcan Jin, Zhaoyang Xu, Shinsuke Ifuku, Chuchu Chen","doi":"10.1016/j.jobab.2026.100237","DOIUrl":"10.1016/j.jobab.2026.100237","url":null,"abstract":"<div><div>Conductive gels hold significant promise for applications in flexible sensing and wearable electronics, yet face the challenge of limitations in mechanical strength and environmental stability. Herein, a facile and effective strategy was proposed to fabricate high-performance eutectogels by introducing metal-based deep eutectic solvent (MDES) consisting of zinc chloride (ZnCl<sub>2</sub>), ethylene glycol (EG), and acrylic acid (AA) into the wood skeleton (WS), which was extracted from natural wood, followed by in-situ ultraviolet (UV)-initiated polymerization. The resulting metal-based deep eutectic solvent/wood skeleton eutectogels (MDES/WS eutectogels) exhibited high ionic conductivity (2.82 × 10<sup>–2</sup> S/m), higher than most conventional wood-based gels, benefiting from the inherent conductivity of the MDES, as well as the aligned micro and nanochannels in WS that facilitate ion transport. Moreover, the synthesized polyacrylic acid (PAA) network could form strong interfacial interactions with the cellulose nanofibers through hydrogen bonding and Zn<sup>2+</sup> coordination cross-linking, significantly reinforcing the eutectogels with a high tensile strength of 41.50 MPa and toughness of 8.4 MJ/m<sup>3</sup>, while still demonstrating good environmental stability (–60 to 100 °C). Leveraging its high conductivity, robust mechanics, and environmental stability, the developed eutectogels functioned as flexible sensors to generate stable and responsive electrical signals during simulated human movements and possessed potential as a programmable information transmission interface through Morse code input. This work established a novel paradigm for developing sustainable, mechanically robust, and environmentally stable conductive gels, offering a versatile platform for next-generation flexible electronics operable under extreme conditions.</div></div>","PeriodicalId":52344,"journal":{"name":"Journal of Bioresources and Bioproducts","volume":"11 3","pages":"Article 100237"},"PeriodicalIF":13.0,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148503386","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Environmental life cycle assessment of hemp hurd-based biocomposites for packaging and mulch film applications 包装和地膜用大麻草基生物复合材料的环境生命周期评价

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Journal of Bioresources and Bioproducts Pub Date : 2026-06-01 Epub Date: 2026-04-25 DOI: 10.1016/j.jobab.2026.100264

Jhonny Alejandro Poveda-Giraldo, Hae Min Jo, Myeong Rok Ahn, June-Ho Choi, Hoyong Kim, Sunkyu Park

{"title":"Environmental life cycle assessment of hemp hurd-based biocomposites for packaging and mulch film applications","authors":"Jhonny Alejandro Poveda-Giraldo, Hae Min Jo, Myeong Rok Ahn, June-Ho Choi, Hoyong Kim, Sunkyu Park","doi":"10.1016/j.jobab.2026.100264","DOIUrl":"10.1016/j.jobab.2026.100264","url":null,"abstract":"<div><div>This study evaluated the environmental performance of producing biocomposites (packaging and mulch films) from hemp hurd-based microfibers as a sustainable alternative to conventional plastics, with emphasis on the influence of end-of-life (EoL) scenarios in South Korea. Mechanical testing confirmed that the biocomposites exhibited mechanical properties comparable to those of fossil-based and reference materials, such as the tensile strength increase of ∼20% and 33% for packaging and mulch films, respectively. At the same time, their enhanced biodegradability contributes to the improved carbon outcomes. Life cycle assessment (LCA) results showed that anaerobic digestion (AD) is the most favorable EoL scenario, yielding the lowest global warming potential (GWP). These benefits stem from credits associated with electricity generation from biogas and the use of digestate as a soil conditioner, mitigating 6.1 kg CO<sub>2</sub> per 1 kg of mulch film relative to current waste management practices in South Korea. The potential for carbon footprint reduction increased further with high microfiber content and the incorporation of biopolyesters during biocomposite manufacturing, saving up to 4.25 kg CO<sub>2</sub> per 1 kg of mulch film in both cases. Overall, the findings demonstrate that biobased composites provide robust environmental advantages under current conditions and are positioned to deliver even greater benefits as the energy system continues to decarbonize in South Korea. This work offers practical insights into sustainable production pathways and waste management strategies for emerging bioplastic systems, supporting their integration into a circular and low-carbon materials economy.</div></div>","PeriodicalId":52344,"journal":{"name":"Journal of Bioresources and Bioproducts","volume":"11 3","pages":"Article 100264"},"PeriodicalIF":13.0,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148503390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Component modulation of bamboo scraps enhances interfacial compatibility and strength of thermal insulation composites 竹片组分调制提高了保温复合材料的界面相容性和强度

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Journal of Bioresources and Bioproducts Pub Date : 2026-06-01 Epub Date: 2026-04-15 DOI: 10.1016/j.jobab.2026.100252

Haiyan Yao, Long Zheng, Yingfeng Zuo, Xingong Li, Yiqiang Wu

{"title":"Component modulation of bamboo scraps enhances interfacial compatibility and strength of thermal insulation composites","authors":"Haiyan Yao, Long Zheng, Yingfeng Zuo, Xingong Li, Yiqiang Wu","doi":"10.1016/j.jobab.2026.100252","DOIUrl":"10.1016/j.jobab.2026.100252","url":null,"abstract":"<div><div>The combination of bamboo waste and magnesium oxychloride (MOC) cement is a promising pathway to obtain green, lightweight construction materials. However, bamboo scraps tend to hinder the formation of high-quality pores within composites, and the insufficient bonding strength at the inorganic-organic interface leads to poor performance. We present an eco-friendly ammonium carbonate (AC) treatment strategy to replace traditional processes that use NaOH solution to modulate the components of bamboo. The AC treatment removed substances that interfered with hydration and softened the rigid bamboo skeleton, attenuating its negative effects on pore formation. Furthermore, the exposure of hydrophilic groups facilitated the growth of 5-phase crystals into surface micropores, which created a robust anchoring effect that markedly reduced interfacial defects and brittleness. The composites prepared with this method exhibited a 45% increase in compressive strength, a 12% improvement in the softening coefficient, and a 15% reduction in thermal conductivity, endowing them with enhanced mechanical properties, improved water resistance, and excellent thermal insulation performance. This strategy provides a reference for preparing green, high-performance, biomass-based lightweight composites, as well as for interface modification and high-quality pore structure regulation.</div></div>","PeriodicalId":52344,"journal":{"name":"Journal of Bioresources and Bioproducts","volume":"11 3","pages":"Article 100252"},"PeriodicalIF":13.0,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148503394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

An all-in-one water-soluble cellulose adhesive: Exhibiting robust bonding, extreme-temperature tolerance, and reusability 一种水溶性纤维素胶粘剂：表现出坚固的粘合，极端温度耐受性和可重复使用性

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Journal of Bioresources and Bioproducts Pub Date : 2026-06-01 Epub Date: 2026-04-10 DOI: 10.1016/j.jobab.2026.100251

Tianlong He, Yumei Chen, Tao Wu, Juchun Liu, Lihua Zhang, Hongtao Zhang, Haibo Xie, Yuanlong Guo

{"title":"An all-in-one water-soluble cellulose adhesive: Exhibiting robust bonding, extreme-temperature tolerance, and reusability","authors":"Tianlong He, Yumei Chen, Tao Wu, Juchun Liu, Lihua Zhang, Hongtao Zhang, Haibo Xie, Yuanlong Guo","doi":"10.1016/j.jobab.2026.100251","DOIUrl":"10.1016/j.jobab.2026.100251","url":null,"abstract":"<div><div>The replacement of formaldehyde-based wood adhesives with sustainable alternatives remains a significant challenge due to performance and reusability limitations. Herein, we reported a water-soluble cellulose ethyl phosphite (CEP) adhesive synthesized through a one-pot transesterification strategy in a novel CO<sub>2</sub>-based solvent system, where the superbase served dually as solvent and catalyst. The CEP adhesive demonstrated an integrated performance profile: exceptional bonding strength (5.73 MPa), remarkable extreme-temperature tolerance (maintaining 5.54 MPa at –196 °C and 4.99 MPa at 100 °C), robust humidity resistance (4.87 MPa at the relatively humidity of 90%), good long-term stability (4.20 MPa after 28 d), and reusability. The adhesion mechanism combined strong interfacial hydrogen bonding with mechanical interlocking, while its water solubility enabled reversible bonding and substrate recovery. This unique combination of properties positioned CEP as an ideal adhesive for demanding applications, including reconfigurable furniture, recyclable packaging, and structural components in thermally volatile environments, providing a sustainable material platform for the transition toward a circular bioeconomy.</div></div>","PeriodicalId":52344,"journal":{"name":"Journal of Bioresources and Bioproducts","volume":"11 3","pages":"Article 100251"},"PeriodicalIF":13.0,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148503391","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Heterolytic H2 activation over platinum supported on oxygen‑vacancy‑rich CeO2 (Pt/CeO2–Vo) for efficient reductive amination of levulinic acid to pyrrolidones under ambient conditions 富氧空位CeO2 （Pt/CeO2 - vo）负载的铂上杂解H2活化，在环境条件下乙酰丙酸高效还原胺化成吡咯烷酮

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Journal of Bioresources and Bioproducts Pub Date : 2026-06-01 Epub Date: 2026-04-15 DOI: 10.1016/j.jobab.2026.100253

Weizhen Xie, Yining Zhang, Jiacheng Li, Yue Tang, Yaqi Shi, Lu Lin, Xing Tang

{"title":"Heterolytic H2 activation over platinum supported on oxygen‑vacancy‑rich CeO2 (Pt/CeO2–Vo) for efficient reductive amination of levulinic acid to pyrrolidones under ambient conditions","authors":"Weizhen Xie, Yining Zhang, Jiacheng Li, Yue Tang, Yaqi Shi, Lu Lin, Xing Tang","doi":"10.1016/j.jobab.2026.100253","DOIUrl":"10.1016/j.jobab.2026.100253","url":null,"abstract":"<div><div>Reductive amination of biomass-derived levulinic acid (LA) to <em>N</em>-substituted-5-methyl-2-pyrrolidone (BMP), versatile nitrogen-containing chemicals, under ambient conditions is highly desirable but challenging due to inefficient H<sub>2</sub> activation. To address this limitation, a platinum (Pt)-based catalyst supported on oxygen-vacancy-rich CeO<sub>2</sub> (Pt/CeO<sub>2</sub>-V<sub>o</sub>) was developed, comprising uniformly dispersed Pt/PtO<sub>2</sub> heterostructures with adjacent Pt–O–Ce interfacial sites. At these Pt–O–Ce interfaces, electron-deficient Pt and electron-rich O atoms, modulated by neighboring oxygen vacancies, facilitate in situ hydrogen spillover from Pt nanoparticles, generating highly reactive H<em><sup>δ</sup></em><sup>⁺</sup>–O···Pt–H<em><sup>δ</sup></em><sup>–</sup> pairs that enable the efficient hydrogenation of the condensation intermediates formed between LA and amine substrates. Therefore, Pt/CeO<sub>2</sub>-V<sub>o</sub> achieved a high BMP yield of 95.2% with a productivity of 476.0 mol/(mol·h) within 1 h under ambient conditions. Even at a high LA concentration of 11.4% (<em>w</em>), the yield remained above 90%, demonstrating the catalyst’s efficiency under ambient conditions. It also showed excellent recyclability over six consecutive cycles and maintained stable performance for over 80 h in a fixed-bed flow reactor. This work underscores the critical importance of interfacial engineering in optimizing Pt-based catalysts and provides a robust and sustainable strategy for biomass upgrading under mild conditions.</div></div>","PeriodicalId":52344,"journal":{"name":"Journal of Bioresources and Bioproducts","volume":"11 3","pages":"Article 100253"},"PeriodicalIF":13.0,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148503393","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mechanistic hydrogen bond mediated screening of hydroxyl functionalized additives for lignin condensation suppression 氢键介导的木质素缩合抑制羟基功能化添加剂的机理筛选

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Journal of Bioresources and Bioproducts Pub Date : 2026-04-01 Epub Date: 2026-01-20 DOI: 10.1016/j.jobab.2026.100233

Huali Zeng, Linlin Liang, Liuli Zhu, Xianting Zeng, Yanling Bin, Renman Wu, Baojie Liu, Chengrong Qin, Shuangfei Wang, Shuangquan Yao

{"title":"Mechanistic hydrogen bond mediated screening of hydroxyl functionalized additives for lignin condensation suppression","authors":"Huali Zeng, Linlin Liang, Liuli Zhu, Xianting Zeng, Yanling Bin, Renman Wu, Baojie Liu, Chengrong Qin, Shuangfei Wang, Shuangquan Yao","doi":"10.1016/j.jobab.2026.100233","DOIUrl":"10.1016/j.jobab.2026.100233","url":null,"abstract":"<div><div>Hydroxyl functionalized additives (Ga-OHs) that can inhibit lignin re-polymerization have demonstrated significant potential in biomass resource conversion and utilization. However, the molecular mechanisms underlying this inhibitory effect remain poorly understood. This study systematically compares the lignin condensation inhibition capabilities of four hydroxyl functionalized additives with distinct functional group effects: salicylic acid, mannitol, 2-naphthol, and glycolic acid. Results indicate that lignin condensation inhibition is primarily associated with hydrogen bonding interactions formed between hydroxyl functionalized additives and oxygen containing functionalities on lignin side chains, while van der Waals interactions contribute as non-specific stabilizing contacts at the early stages. Rapid electron flow in short-chain compounds molecules stabilized the lignin structure. The strong hydrogen bond interaction between mannitol and oxygen groups in lignin branches (−80.38 kJ/mol) enhanced the stability of a separated lignin in a strong acidic environment, which resulted in a high <em>β</em>-O-4 content (up to 47.12 per 100 aromatic units). Here, we comparatively screened hydroxyl functionalized additives with different structures under dilute acid pretreatment and linked the quantitative outcomes of lignin condensation inhibition to density functional theory (DFT) validated noncovalent interactions. This work provides insight into the separation of low condensation lignin and informs the screening of additives with lignin condensation inhibition potential.</div></div>","PeriodicalId":52344,"journal":{"name":"Journal of Bioresources and Bioproducts","volume":"11 2","pages":"Article 100233"},"PeriodicalIF":13.0,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147754133","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Greenhouse gas recovery performance of chitin-derived porous carbons from waste chitinous biomass 利用废弃几丁质生物质制备几丁质衍生多孔碳的温室气体回收性能

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Journal of Bioresources and Bioproducts Pub Date : 2026-04-01 Epub Date: 2026-01-30 DOI: 10.1016/j.jobab.2026.100236

Hun-Seung Jeong , Byung-Joo Kim

{"title":"Greenhouse gas recovery performance of chitin-derived porous carbons from waste chitinous biomass","authors":"Hun-Seung Jeong , Byung-Joo Kim","doi":"10.1016/j.jobab.2026.100236","DOIUrl":"10.1016/j.jobab.2026.100236","url":null,"abstract":"<div><div>This work upcycled waste chitin-based shells into porous carbons via a chemical-free steam activation route using only N<sub>2</sub> and water vapor, and investigated their adsorption/desorption behaviors toward the greenhouse gas n-butane. The textural and structural properties of chitin-based porous carbons (Ch-PCs) were characterized by N<sub>2</sub> adsorption-desorption, X-ray diffraction, and field-emission scanning electron microscopy. The n-butane working capacity (butane activity and retentivity) was also evaluated. The Ch-PCs exhibited specific surface areas of 720–1350 m<sup>2</sup>/g and total pore volumes of 0.53–1.10 cm<sup>3</sup>/g, with micropore volumes of 0.25–0.48 cm<sup>3</sup>/g and mesopore volumes of 0.28–0.62 cm<sup>3</sup>/g. As the activation time increased, the n-butane adsorption capacity increased from 22.3% to 43.6%, while the retentivity (residual adsorption) decreased from 16.9% to 9.2%. The n-butane adsorption/desorption behaviors were strongly correlated with the pore structure of the Ch-PCs. The adsorption capacity showed a strong relationship with the pore size of 1.0–3.0 nm, whereas the retentivity was mainly associated with the pore size of 3.0–5.0 nm. These findings demonstrated that steam-activated chitin-derived carbons, prepared from waste biomass by a chemical-free activation process, could serve as promising bio-based adsorbents for efficient greenhouse gas capture and recovery.</div></div>","PeriodicalId":52344,"journal":{"name":"Journal of Bioresources and Bioproducts","volume":"11 2","pages":"Article 100236"},"PeriodicalIF":13.0,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147754181","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0