Applied Catalysis B: Environment and Energy最新文献_第2页

Rare earth oxide promoted Ru/Al2O3 dual function materials for CO2 capture and methanation: An operando DRIFTS and TGA study 稀土氧化物促进的 Ru/Al2O3 双功能材料用于二氧化碳捕获和甲烷化：一项操作性 DRIFTS 和 TGA 研究

Applied Catalysis B: Environment and Energy Pub Date : 2024-09-10 DOI: 10.1016/j.apcatb.2024.124591

Lizbeth Moreno Bravo, Frederic C. Meunier, Jan Kopyscinski

{"title":"Rare earth oxide promoted Ru/Al2O3 dual function materials for CO2 capture and methanation: An operando DRIFTS and TGA study","authors":"Lizbeth Moreno Bravo, Frederic C. Meunier, Jan Kopyscinski","doi":"10.1016/j.apcatb.2024.124591","DOIUrl":"https://doi.org/10.1016/j.apcatb.2024.124591","url":null,"abstract":"Dual-function materials (DFMs) combine sorbent and catalytic components to perform selective CO capture and subsequent hydrogenation. This study explores the performance of rare-earth oxides (REOs) as CO adsorption sites on Ru/AlO. REOs increase CO uptake by upwards of +60 % by enhancing the overall catalyst surface basicity and favoring metal–support interactions. Thermogravimetric analysis during CO adsorption-hydrogenation cycles exhibited significant catalytic activity and enhanced stability of Ru-REO/AlO at temperatures as low as 200 °C. This leads to methane production of 50–85 µmol g, surpassing recently reported values obtained for alkali and alkali-earth promoted Ru-based materials operated at 250 °C. The highest performing studied DFM, RuNdO/AlO, achieved 85 % CO capture efficiency and steadily produced methane in cyclic operation (+120 % CO uptake relative to Ru/AlO). DRIFTS revealed that the dominant mechanism for methane formation is the hydrogenation of ruthenium carbonyls, which are stabilized by REOs. Upon CO exposure, surface carbonates and bicarbonate species form more abundantly on DFMs than on Ru/AlO. This confirms that REOs enhance the adsorption and retention of carbonates, which generate additional promoter-related reaction pathways during low-temperature hydrogenation. These findings are crucial in the advancement of sustainable, wider operation range carbon capture and utilization technologies.","PeriodicalId":516528,"journal":{"name":"Applied Catalysis B: Environment and Energy","volume":"5 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142250054","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Visible-light driven O2-to-H2O2 synchronized activation of peroxymonosulfate in Z-scheme photocatalytic fuel cell for wastewater purification with power generation 在 Z 型光催化燃料电池中用可见光驱动 O2 到 H2O2 同步活化过一硫酸盐，用于废水净化和发电

Applied Catalysis B: Environment and Energy Pub Date : 2024-09-10 DOI: 10.1016/j.apcatb.2024.124594

Ling-Wei Wei, Shou-Heng Liu, Van-Can Nguyen, Meng-Wei Zheng, Hong Paul Wang

{"title":"Visible-light driven O2-to-H2O2 synchronized activation of peroxymonosulfate in Z-scheme photocatalytic fuel cell for wastewater purification with power generation","authors":"Ling-Wei Wei, Shou-Heng Liu, Van-Can Nguyen, Meng-Wei Zheng, Hong Paul Wang","doi":"10.1016/j.apcatb.2024.124594","DOIUrl":"https://doi.org/10.1016/j.apcatb.2024.124594","url":null,"abstract":"Antibiotics are recognized as emerging contaminants with non-biodegradation, complex structures, and abundant chemical energy, which are difficult to treat and recover energy through traditional wastewater treatment processes. A Z-scheme photocatalytic fuel cell (PFC) system, comprising CN and CuO/CuO dual-photoelectrodes, has been developed for simultaneous power generation and degradation of antibiotics, such as berberine hydrochloride (BH). Especially, the CN with its suitable energy potential for peroxymonosulfate (PMS) activation is synchronized with CuO/CuO, resulting in enhancing the performance of PFC system. Moreover, the interaction between PMS and Cu(I)/Cu(II) active sites on the photocathode can enhance the formation of highly reactive species (HRS) in the PFC-PMS system, thereby improving photocatalytic oxidation performance. Under visible-light illumination for 120 min, PFC-PMS system can rapidly and effectively oxidize BH (ca. 99.2 %, = 0.0039 min) with simultaneous power generation (0.018 mW cm). This approach presents a promising approach for both water cleanup and energy reuse applications.","PeriodicalId":516528,"journal":{"name":"Applied Catalysis B: Environment and Energy","volume":"75 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142249994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

La-exacerbated lattice distortion of high entropy alloys for enhanced electrocatalytic water splitting 用于增强电催化水分离的高熵合金的喇氏加速晶格畸变

Applied Catalysis B: Environment and Energy Pub Date : 2024-09-10 DOI: 10.1016/j.apcatb.2024.124585

Zhen-Long Wang, Gao-Yuan Huang, Guan-Rong Zhu, Huan-Chuan Hu, Cong Li, Xue-Han Guan, Hai-Bin Zhu

引用次数: 0

Tuning ligand-vacancies in Pd-UiO-66 to boost biofuel production from 5-hydroxymethylfurfural hydrodeoxygenation 调节 Pd-UiO-66 中的配体空位，促进 5-羟甲基糠醛加氢脱氧生成生物燃料

Applied Catalysis B: Environment and Energy Pub Date : 2024-09-10 DOI: 10.1016/j.apcatb.2024.124592

Lu Lin, Yongjian Zeng, Suyu Zhang, Di Hu, Zhiwei Jiang, Guoqing Guan, Kai Yan

引用次数: 0

Overlooked role of boron precursors in tuning engineered zero-valent iron to activate peracetic acid for sustainable micropollutant oxidation 硼前体在调整工程零价铁以激活过乙酸从而实现可持续微污染物氧化过程中的作用被忽视了

Applied Catalysis B: Environment and Energy Pub Date : 2024-09-08 DOI: 10.1016/j.apcatb.2024.124580

Yunzhe Zheng, Xinhao Wang, Yudan Dong, Xiaoyu Wu, Donghua Xie, Yang Liu, Peng Zhou, Zhaokun Xiong, Chuan-Shu He, Bo Lai

{"title":"Overlooked role of boron precursors in tuning engineered zero-valent iron to activate peracetic acid for sustainable micropollutant oxidation","authors":"Yunzhe Zheng, Xinhao Wang, Yudan Dong, Xiaoyu Wu, Donghua Xie, Yang Liu, Peng Zhou, Zhaokun Xiong, Chuan-Shu He, Bo Lai","doi":"10.1016/j.apcatb.2024.124580","DOIUrl":"https://doi.org/10.1016/j.apcatb.2024.124580","url":null,"abstract":"This work comprehensively investigated how the characteristics of boron (B) precursors affect the catalytic activity of microscale zero-valent iron (mZVI) towards peracetic acid (PAA) activation for micropollutant degradation. Three boron precursors were introduced into mZVI by ball milling with their physical-chemical properties carefully characterized, and their ability to activate PAA comprehensively evaluated via sulfamethoxazole (SMX) oxidation efficiency. It’s found that BO-ZVI demonstrated the highest capability to activate PAA for SMX degradation, with 2 ∼ 3 times higher than NaBO-ZVI and HBO-ZVI. Specially, B precursors regulate the ability of mZVI to activate PAA via the following two aspects: (1) affecting the formation and content of FeB to accelerate Fe(II) regeneration; (2) increasing the hydrophilicity of the iron particles and the affinity of B-ZVI for binding PAA to different extent. This study highlights the important role of boron precursors in tuning engineered mZVI to initiate Fenton-like process for water purification.","PeriodicalId":516528,"journal":{"name":"Applied Catalysis B: Environment and Energy","volume":"40 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142249997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Highly crystalline benzothiadiazole covalent organic framework for enhanced Cr(VI) photocatalytic reduction by constructing donor-acceptor structure 通过构建供体-受体结构增强六价铬光催化还原能力的高结晶苯并噻二唑共价有机框架

Applied Catalysis B: Environment and Energy Pub Date : 2024-09-08 DOI: 10.1016/j.apcatb.2024.124583

Chen Wang, Wen Lu, Wenhui Song, Zhixiong Zhang, Chengde Xie, Yu Li, Jianjun Wang

{"title":"Highly crystalline benzothiadiazole covalent organic framework for enhanced Cr(VI) photocatalytic reduction by constructing donor-acceptor structure","authors":"Chen Wang, Wen Lu, Wenhui Song, Zhixiong Zhang, Chengde Xie, Yu Li, Jianjun Wang","doi":"10.1016/j.apcatb.2024.124583","DOIUrl":"https://doi.org/10.1016/j.apcatb.2024.124583","url":null,"abstract":"Covalent organic frameworks (COFs) have gained significant attention in environmental remediation. In this paper, we synthesized two sp carbon-conjugated COFs (HDU-107 and HDU-108) using [1,1′:4′,1''-terphenyl]-4,4''-dicarbonitrile and 2,2′-(benzo[][1,2,5]thiadiazole-4,7-diylbis(4,1-phenylene))diacetonitrile as the core, and benzo[1,2-b:3,4-b′:5,6-b″]trithiophene-2,5,8-tricarbaldehyde as the linker, for efficient photocatalytic reduction of Chromium (VI) (Cr(VI)). HDU-108 successfully constructed an electron donor-acceptor (D-A) structure using electron-rich thiophene as the electron donor and benzothiadiazole as the acceptor, exhibiting excellent photocatalytic ability due to its structure, which facilitated the spatial separation of charge carriers and reduced charge complexation. This ability was far superior to that of HDU-107. For 10 mg of HDU-108, the efficiency of Cr(VI) reduction in 120 minutes was more than 99.9 %. And the cycle experiments confirmed its good reusability and stability. e played a dominant role in the photoreduction of Cr(VI). Moreover, density-functional theory (DFT) simulations indicated that constructing D-A structures was an effective strategy for modulating photocatalytic activity. The charge separation was triggered by the polarization of the electron-rich BTT nucleus to the local charge density, while the cyanine conjugation provided the active center to concentrate the electronegativity. In conclusion, HDU-108, is expected to be a highly efficient photocatalytic material for environmental remediation.","PeriodicalId":516528,"journal":{"name":"Applied Catalysis B: Environment and Energy","volume":"2677 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142249996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Bi2SiO5 nanosheets as piezo-photocatalyst for efficient degradation of 2,4-Dichlorophenol 作为压电光催化剂高效降解 2,4-二氯苯酚的 Bi2SiO5 纳米片材

Applied Catalysis B: Environment and Energy Pub Date : 2024-09-07 DOI: 10.1016/j.apcatb.2024.124581

Hangyu Shi, Yifu Li, Lishan Zhang, Guoguan Liu, Qian Zhang, Xuan Ru, Shan Zhong

{"title":"Bi2SiO5 nanosheets as piezo-photocatalyst for efficient degradation of 2,4-Dichlorophenol","authors":"Hangyu Shi, Yifu Li, Lishan Zhang, Guoguan Liu, Qian Zhang, Xuan Ru, Shan Zhong","doi":"10.1016/j.apcatb.2024.124581","DOIUrl":"https://doi.org/10.1016/j.apcatb.2024.124581","url":null,"abstract":"Piezo-photocatalysis is an effective solution for degrading organic pollutants. In this study, BiSiO nanosheets are successfully synthesized via a one-step hydrothermal method. The piezo-photocatalytic degrading mechanisms of 2,4-Dichlorophenol (2,4-DCP) on BiSiO nanosheets are thoroughly investigated through the integration of experimental study and density functional theory (DFT) calculations. Experimental results revealed outstanding piezoelectric properties for BiSiO nanosheets with a piezoelectric coefficient of 250 pC/N, outperforming previously reported piezo-photocatalysts. The degradation rate constant of 2,4-DCP on BiSiO nanosheets reached 0.0891 min by piezo-photocatalysis, which is 17 and 1.8 times higher than that by solitary photo- and piezo-catalysis, respectively. Furthermore, DFT calculations for BiSiO explain the crucial role of piezoelectric effects in bending its band structure, regulating photogenerated carrier behaviors, and promoting reactive oxygen species (ROS) generation. Finally, the degradation pathways of 2,4-DCP on BiSiO nanosheets were revealed with details. The results of this study offer valuable insights for water treatment with piezo-photocatalysis.","PeriodicalId":516528,"journal":{"name":"Applied Catalysis B: Environment and Energy","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142249739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Selective switching hydrogenation products of 5-hydroxymethylfurfural at high substrate concentrations by regulating Pd-MgO interactions 通过调节钯-氧化镁的相互作用，在高浓度底物条件下选择性切换 5-羟甲基糠醛的氢化产物

Applied Catalysis B: Environment and Energy Pub Date : 2024-09-07 DOI: 10.1016/j.apcatb.2024.124578

Mingxin Lv, Liyuan Huai, Guoxin Chen, Xi Zhao, Chunlin Chen, Shenghu Zhou, Jian Zhang

{"title":"Selective switching hydrogenation products of 5-hydroxymethylfurfural at high substrate concentrations by regulating Pd-MgO interactions","authors":"Mingxin Lv, Liyuan Huai, Guoxin Chen, Xi Zhao, Chunlin Chen, Shenghu Zhou, Jian Zhang","doi":"10.1016/j.apcatb.2024.124578","DOIUrl":"https://doi.org/10.1016/j.apcatb.2024.124578","url":null,"abstract":"Controlling the selective activation of one or some functional groups as desired is still a challenge in hydrogenation, especially at high substrate concentrations. Herein, Pd-MgO interfaces over AlO were finely regulated for efficiently selective hydrogenation of furan ring in 5-hydroxymethylfurfural (HMF) to produce 5-hydroxymethyltetrahydro-2-furaldehyde (5-HMTHFF) or total hydrogenation to 2,5-bis(hydroxymethyl)tetrahydrofuran (BHMTHF), also inhibiting side reaction. The Pd-MgO/AlO with 12.0 wt% of MgO selectively hydrogenates the furan rings with a 5-HMTHFF yield of 82.4 % while that with 2.0 wt% of MgO totally hydrogenates HMF with a DHMTHF yield of 96.2 % at high substrate concentrations (400 mM). Characterizations and DFT calculations demonstrated that oligomeric MgO species suppress the agglomeration of Pd nanoparticles and strengthen HMF adsorption, consequently promoting total hydrogenation. Furthermore, Pd-MgO sites between the crystallized MgO and Pd metal favored tilted adsorption on the interface and weakened the activation of the CO bond, consequently selectively producing 5-HMTHFF.","PeriodicalId":516528,"journal":{"name":"Applied Catalysis B: Environment and Energy","volume":"2 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142249998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sustainable and efficient catalytic oxidation of chlorinated volatile organic compounds over Ru-loaded facet-engineered {201}-TiO2 catalyst with tuned defects 在具有可调缺陷的 Ru 负载刻面工程 {201}-TiO2 催化剂上可持续、高效地催化氧化氯化挥发性有机化合物

Applied Catalysis B: Environment and Energy Pub Date : 2024-09-07 DOI: 10.1016/j.apcatb.2024.124582

Bohua Sun, Qianqian Li, Guijin Su, Maoyong Song, Chunyan Ma, Jiaxin Pang, Xu Zhao, Jing Meng, Bin Shi

{"title":"Sustainable and efficient catalytic oxidation of chlorinated volatile organic compounds over Ru-loaded facet-engineered {201}-TiO2 catalyst with tuned defects","authors":"Bohua Sun, Qianqian Li, Guijin Su, Maoyong Song, Chunyan Ma, Jiaxin Pang, Xu Zhao, Jing Meng, Bin Shi","doi":"10.1016/j.apcatb.2024.124582","DOIUrl":"https://doi.org/10.1016/j.apcatb.2024.124582","url":null,"abstract":"Sustainable and efficient catalytic oxidation of chlorinated volatile organic compounds (CVOCs) poses an enduring challenge. This bottleneck arises from the limited catalytic activity of redox reactions and chlorine desorption, causing catalyst deactivation and secondary pollution. Herein, our sound strategy involves Ru-loaded facet-engineered {201}-TiO with tuned defects, thereby boosting its reactivity. Comprehensive characterizations and DFT calculation manifested that Ru/{201}-TiO, with abundant oxygen vacancies, Ti defects, and robust metal-support interaction, enabled flexible electron transfer to activate O and the dissociation of HO, thus facilitating the continuous generation of reactive oxygen species (ROS), such as •O and hydroxyl species. These ROS effectively enhance chlorine desorption and chlorobenzene deep oxidation. Ru/{201}-TiO exhibited superior reactivity for chlorobenzene degradation, with an apparent activation energy (Ea) of 31.0 KJ/mol and 100 % chlorobenzene conversion in a 1000-min stability test, even with HO introduction. Ru/{201}-TiO produced 2.2–3.1 times fewer small-molecule chlorinated byproducts than Ru/{101}-TiO, with no polychlorinated benzenes detected.","PeriodicalId":516528,"journal":{"name":"Applied Catalysis B: Environment and Energy","volume":"9 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142249995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

New Lewis acidic ionic liquid coupled carbon shell coated defective WO3 for efficient photocatalytic N2 reduction 用于高效光催化还原 N2 的新型路易斯酸离子液体耦合碳壳涂层缺陷 WO3

Applied Catalysis B: Environment and Energy Pub Date : 2024-09-07 DOI: 10.1016/j.apcatb.2024.124579

Xiaoling Ren, Honghui Ou, Wei Liu, Yang Lv, Aofei Xu, Zhiwei Ren, Bolun Yang, Guidong Yang

引用次数: 0