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The influence of the physichemical behavior of carbon on the melting and crystallization of gasification slag 碳的物理行为对气化渣熔融结晶的影响
IF 2.5 4区 化学
Chemical Papers Pub Date : 2025-06-01 DOI: 10.1007/s11696-025-04130-4
Rongsheng Xu, Dong Sun, Ze Meng, Mengfang Zhang, Tianxi Rao
{"title":"The influence of the physichemical behavior of carbon on the melting and crystallization of gasification slag","authors":"Rongsheng Xu,&nbsp;Dong Sun,&nbsp;Ze Meng,&nbsp;Mengfang Zhang,&nbsp;Tianxi Rao","doi":"10.1007/s11696-025-04130-4","DOIUrl":"10.1007/s11696-025-04130-4","url":null,"abstract":"<div><p>Residual carbon is an essential component in coal gasification slag, significantly influencing the gasification process. In this study, the impact of the physicochemical behavior of carbon on the melting and crystallization characteristics of gasification slag (GCS) was investigated. When carbon content increased from 2 to 20%, the softening temperature and hemisphere temperature of GCS rose by nearly 120 °C, and the flow temperature by approximately 170 °C. At high temperatures, carbon reduces Fe<sub>2</sub>O<sub>3</sub> of slag to elemental Fe and further forms the refractory mineral Fe<sub>3</sub>Si. Fe<sub>3</sub>Si and residual carbon constitute the framework structure of the melt, delaying the collapse of aluminosilicate melt and thereby increasing the flow temperature of GCS. The increased carbon content in GCS facilitates the formation of Fe<sub>3</sub>Si at high temperatures. During the cooling process, the liquid phase in the melts deposits to form a dense aluminosilicate matrix, while refractory phases (Fe<sub>3</sub>Si and residual carbon) precipitate and coalesce into spherical aggregates. During the quenching process, the high viscosity of aluminosilicate inhibits the precipitation of refractory phases. As residual carbon content increases, the refractory skeleton disperses more in the high-viscosity melt, creating a denser structure that reduces mass transfer efficiency and promotes the formation of smaller, more dispersed particles instead of larger spheres during cooling.</p><h3>Graphic abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div><p>During the coal gasification process, the physicochemical behavior of carbon significantly influences the transformation of minerals and the melting and crystallization characteristics of inorganic ash and slag. At high temperatures, carbon reduces Fe<sub>2</sub>O<sub>3</sub> of slag to elemental Fe and further forms the high-melting-point mineral Fe<sub>3</sub>Si. The increased carbon content in GCS facilitates the formation of Fe<sub>3</sub>Si at high temperatures, while carbon evolves into a refractory framework within the slag, thereby enhancing the fluidity temperature of the GCS. A significant amount of organic carbon precipitates from the aluminosilicate melt in conjunction with iron-rich substances, forming spherical particles under natural cooling conditions. In contrast, during rapid cooling processes, the limited time available prevents extensive migration of carbon from the melt, leading to its partial dispersion within the dense sintered structure. As the carbon content increases, the viscosity of the melt rises, thereby slowing down the precipitation of spherical particles primarily composed of iron-bearing minerals and carbon.</p></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 8","pages":"5353 - 5366"},"PeriodicalIF":2.5,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145160542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green hydrogen unleashed: innovative pathways in photoelectrochemical and renewable energy solutions 绿色氢释放:光电化学和可再生能源解决方案的创新途径
IF 2.5 4区 化学
Chemical Papers Pub Date : 2025-06-01 DOI: 10.1007/s11696-025-04090-9
Wadiae EL BAHRAMI, Hassan MABRAK, Imane BOUMANCHAR, Youssef NAIMI
{"title":"Green hydrogen unleashed: innovative pathways in photoelectrochemical and renewable energy solutions","authors":"Wadiae EL BAHRAMI,&nbsp;Hassan MABRAK,&nbsp;Imane BOUMANCHAR,&nbsp;Youssef NAIMI","doi":"10.1007/s11696-025-04090-9","DOIUrl":"10.1007/s11696-025-04090-9","url":null,"abstract":"<div><p>Among the numerous technical challenges in our twenty-first century is to move away from a fossil fuel-based future and toward renewable sources such as green hydrogen production. This review discusses recent advancements in hydrogen production, with a focus on photoelectrochemical methods and renewable energy-based technologies. Specifically, we discuss the effects of phthalocyanine-based dye sensitizers and catalysts required for photoelectrochemical systems to catalyze hydrogen evolution. This review presents the wide spectrum of hydrogen production technologies, encompassing traditional fossil fuel-based methods and advanced techniques such as water electrolysis with renewable energy input. This review examines the operating principles of water electrolysis cells, maps out technological innovation gaps, and explores development opportunities in proton exchange membranes and solid oxide electrolysis. It gives a review of the recent introduction of phthalocyanines into photoelectrochemical cells, with the beneficial effects of the increased light absorption and electron transfer properties leading to better-earned hydrogen productions. A comparative assessment of these materials for other photocatalysts is also presented in the context that they promise to enhance hydrogen production efficiency while reducing energy consumption. Although significant developments in green hydrogen technologies have been made, the review also suggests that there is still a long road ahead for some of these systems before they can be commercially implemented on a larger scale, even after comprehensive evaluation. The future of sustainable hydrogen production is, in particular, much improved by the promise offered through phthalocyanines.</p></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 7","pages":"4045 - 4074"},"PeriodicalIF":2.5,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145141851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of the mass transfer parameters, kinetic modeling, and detected optimized effective variables of dopamine extraction from the discarded fruit banana peel 对废弃水果香蕉皮提取多巴胺的传质参数进行评价、动力学建模,并检测优化的有效变量
IF 2.5 4区 化学
Chemical Papers Pub Date : 2025-05-31 DOI: 10.1007/s11696-025-04093-6
Mojtaba Nosrati Omidvar, Neda Gilani, Hadiseh Masoumi
{"title":"Evaluation of the mass transfer parameters, kinetic modeling, and detected optimized effective variables of dopamine extraction from the discarded fruit banana peel","authors":"Mojtaba Nosrati Omidvar,&nbsp;Neda Gilani,&nbsp;Hadiseh Masoumi","doi":"10.1007/s11696-025-04093-6","DOIUrl":"10.1007/s11696-025-04093-6","url":null,"abstract":"<div><p>This research aims to inspect factors like solvent, time, pH, and sample-to-solvent ratio on the extraction of dopamine from the banana peel through the leaching technique. Design-Expert DOE software was utilized to examine the effective factors. The most important effective parameter in the efficiency of dopamine extraction in water and ethanol solvents was the sample-to-solvent ratio parameter. The yield was measured at 38.47% using water at optimal values such as pH of 5.38, time of 27.62 min, sample-to-solvent ratio of 0.137, and dopamine concentration of 86.56 ppm. In the case of ethanol, the yield was attained at 91.36% in the optimal values such as pH of 5.78, time of 20 min, the ratio of sample to solvent of 0.16, and dopamine concentration of 205.56 ppm. The most desired kinetic model for dopamine extraction in water and ethanol was a pseudo-second-order equation with a correlation coefficient of <i>R</i><sup>2</sup> &gt; 0.99. Besides, the mass transfer parameters were calculated, demonstrating that dopamine’s flux and mass transfer coefficient in ethanol are higher. The extraction of dopamine from banana peels using water and ethanol as solvents yields satisfactory results, and various kinetic models can be used to describe the kinetics of dopamine extraction, providing a better understanding of the process. Additionally, a new generation of natural eutectic solvents can be employed to extract dopamine. </p></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 7","pages":"4701 - 4719"},"PeriodicalIF":2.5,"publicationDate":"2025-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145145751","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, characterization and antibacterial studies of polyvinyl alcohol (PVA)–zinc sulfide (ZnS) thin films for its application in packaging material 聚乙烯醇(PVA) -硫化锌(ZnS)薄膜的合成、表征及抗菌研究
IF 2.5 4区 化学
Chemical Papers Pub Date : 2025-05-31 DOI: 10.1007/s11696-025-04117-1
I. K. Muralidhar, K. A. Vishnumurthy, M. Madhukara Naik, M. Giridhar, R. Madhuri, H. S. Bhojya Naik, B. E. Kumara Swamy, B. V. Mohan Kumar
{"title":"Synthesis, characterization and antibacterial studies of polyvinyl alcohol (PVA)–zinc sulfide (ZnS) thin films for its application in packaging material","authors":"I. K. Muralidhar,&nbsp;K. A. Vishnumurthy,&nbsp;M. Madhukara Naik,&nbsp;M. Giridhar,&nbsp;R. Madhuri,&nbsp;H. S. Bhojya Naik,&nbsp;B. E. Kumara Swamy,&nbsp;B. V. Mohan Kumar","doi":"10.1007/s11696-025-04117-1","DOIUrl":"10.1007/s11696-025-04117-1","url":null,"abstract":"<div><p>Polyvinyl alcohol (PVA) thin films though excellent packaging material does not show any antibacterial activity, and hence reduces shelf life of food, thus effort to increase its activity against bacteria is a need of time. The current work emphasizes the preparation of undoped and co-doped zinc sulfide (ZnS) nanoparticle (NPs) embedded in PVA thin films were prepared by chemical precipitation and microwave method with concentrations of 0.1, 0.2, and 0.3% of ZnS NPs. PVA was used as a capping agent. The NPs synthesized were analyzed by XRD, SEM–EDS, UV–Visible, and FTIR techniques. XRD studies revealed the formation of the face-centered cubic (FCC) structure of zinc blende. FTIR represents the characteristic peaks of Zn–S stretching vibrations at 614 cm<sup>−1</sup>. The morphology was found to be smooth and spherical shape of nanoparticles from SEM. The antimicrobial activity of as synthesized PVA films was investigated against gram-positive bacteria <i>Enterococcus faecalis</i> (MTCC 439) and gram-negative bacteria <i>Escherichia coli</i> (MTCC 1559). The result showed PVA films which did not show any activity can be made to show antibacterial property by incorporation of NPs which can be used as food packaging material.</p><h3>Graphical abstract</h3><p>Shows the mechanism of antibacterial action of PVA ZnS thin film</p>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 8","pages":"5185 - 5196"},"PeriodicalIF":2.5,"publicationDate":"2025-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing the antibacterial activity of transition metal dichalcogenides nanosheets through doping: a study on ReS₂ nanosheets Re(1−x)CoxS2 通过掺杂增强过渡金属二硫族化合物纳米片的抗菌活性:ReS₂纳米片Re(1−x)CoxS2的研究
IF 2.5 4区 化学
Chemical Papers Pub Date : 2025-05-31 DOI: 10.1007/s11696-025-04115-3
Zana Jamal, Naktal Al-Dulaimi, Bakhtyar K. Aziz, Hevar Neaz, Nabaz Hamarashid, Dlzar D. Ghafoor
{"title":"Enhancing the antibacterial activity of transition metal dichalcogenides nanosheets through doping: a study on ReS₂ nanosheets Re(1−x)CoxS2","authors":"Zana Jamal,&nbsp;Naktal Al-Dulaimi,&nbsp;Bakhtyar K. Aziz,&nbsp;Hevar Neaz,&nbsp;Nabaz Hamarashid,&nbsp;Dlzar D. Ghafoor","doi":"10.1007/s11696-025-04115-3","DOIUrl":"10.1007/s11696-025-04115-3","url":null,"abstract":"<div><p>In this study, ReS₂ and Co-doped ReS₂ thin films were synthesized via aerosol-assisted chemical vapor deposition (AACVD) at 525 °C using single-source precursors: [Re<sub>2</sub>(<i>μ</i>-S)<sub>2</sub>(S<sub>2</sub>CNEt<sub>2</sub>)<sub>4</sub>] (1) and [Co(S₂CN(Et)₂)₂] (2). The resulting films were characterized using powder X-ray diffraction (p-XRD), scanning electron microscopy (SEM), inductively coupled plasma optical emission spectroscopy (ICP-OES), energy-dispersive X-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS), confirming the successful formation of Re<sub>₁−</sub><i>x</i>Co<i>x</i>S<sub>2</sub> alloys. Various feed ratios of precursors (1) and (2) (10%, 20%, 30%, and 50%) were employed for the synthesis of Co-doped ReS<sub>2</sub>films. ICP-OES quantification revealed actual Co incorporation levels of 0.96%, 2.05%, 6.35%, and 8.19%, corresponding to the respective feed ratios. XRD analysis of the Co-doped films showed systematic shifts in the intensity and position of the (001) diffraction peaks with increasing Co content. A continuous shift was observed from 0.96 to 6.35% Co, while the disappearance of the (001) peak at 8.19% indicated a significant loss of crystallinity, suggesting a transition to an amorphous structure. The interplanar spacing <i>d</i>(001), calculated from XRD data, decreased from 6.119 Å in pure ReS₂ to 5.818 Å at 6.35% Co doping. XPS spectra confirmed the presence of both Co<sup>2</sup>⁺ and metallic Co⁰, indicating partial substitution of Re by Co in the ReS₂ lattice and the simultaneous formation of Co⁰ clusters. Moreover, the combination of bottom-up AACVD synthesis with top-down liquid-phase exfoliation (LPE) proved to be an effective strategy for producing both pristine and doped ReS₂ nanosheets, demonstrating their potential in biomedical applications. Antibacterial assays of ReS<sub>2</sub> and Co-doped ReS<sub>2</sub> extracts revealed variable efficacy. The undoped ReS<sub>2</sub> extract demonstrated moderate antibacterial activity, with inhibition zones of 8 mm against <i>Pseudomonas aeruginosa</i> and 8.5 mm against <i>Staphylococcus aureus</i>. Upon Co doping, a significant enhancement was observed, particularly at 6.35% Co content, resulting in maximum inhibition zones of 16 mm and 11.5 mm against <i>Pseudomonas aeruginosa</i> and <i>Staphylococcus aureus</i>, respectively.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 8","pages":"5157 - 5166"},"PeriodicalIF":2.5,"publicationDate":"2025-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171195","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comparative in silico study of noscapine, bosutinib, and the co-crystal ligand (DHHE) of 3B99 to investigate their interaction with prostacyclin synthase 诺斯卡平、博舒替尼和3B99共晶配体(DHHE)与前列环素合成酶相互作用的对比研究
IF 2.5 4区 化学
Chemical Papers Pub Date : 2025-05-30 DOI: 10.1007/s11696-025-04126-0
Mohd. Aslam, Vishnu Kumar Malakar, Bhaskara Nand, Snigdha Singh, Ramesh Chandra, Kamlesh Kumari, Garima Pandey, Prashant Singh
{"title":"A comparative in silico study of noscapine, bosutinib, and the co-crystal ligand (DHHE) of 3B99 to investigate their interaction with prostacyclin synthase","authors":"Mohd. Aslam,&nbsp;Vishnu Kumar Malakar,&nbsp;Bhaskara Nand,&nbsp;Snigdha Singh,&nbsp;Ramesh Chandra,&nbsp;Kamlesh Kumari,&nbsp;Garima Pandey,&nbsp;Prashant Singh","doi":"10.1007/s11696-025-04126-0","DOIUrl":"10.1007/s11696-025-04126-0","url":null,"abstract":"<div><p>Prostacyclin synthase (PGIS), a heme-containing cytochrome P450 enzyme located in the endoplasmic reticulum membrane, catalyzes the isomerization of prostaglandin H2 (PGH2) into prostacyclin, an essential mediator of vascular homeostasis. The present work investigates the interaction of prostacyclin synthase (PDB ID: 3B99) with noscapine (Nos), bosutinib (Bos), and the co-crystal ligand (DHHE) through molecular docking, density functional theory (DFT) calculations, and molecular dynamics (MD) simulations. Molecular docking revealed binding affinities of − 7.9, − 7.3, and − 6.2 kcal/mol for Nos, Bos, and DHHE, respectively, with Nos exhibiting the strongest interactions through hydrogen bonds and hydrophobic contacts involving residues such as Leu101, Ala335, and Leu336. DFT calculations indicated that DHHE displayed the highest stability with the largest HOMO–LUMO energy gap (− 0.18 Hartree), while Bos exhibited the highest chemical reactivity. MD simulations over 500 ns highlighted the dynamic stability of these complexes, with Bos showing minimal structural deviations (RMSD: 0.19–0.34 nm) and Nos demonstrating significant Van der Waals stabilization. Principal component analysis indicated that ligand binding induces conformational flexibility in PGIS, with Bos complexes demonstrating enhanced compactness and stability. The interaction energy analysis reveals that Bos exhibits the strongest binding affinity to the 3B99 target, with the most favorable Coulombic (− 47.86 ± 3.6 kJ/mol) and Lennard–Jones interactions (− 203.558 ± 4.9 kJ/mol), resulting in the lowest total interaction energy (− 251.418 kJ/mol), compared to 3B99-Nos and 3B99-DHHE.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 8","pages":"5301 - 5317"},"PeriodicalIF":2.5,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable fuel solutions: a comprehensive review of syngas in internal combustion engines 可持续燃料解决方案:内燃机合成气的全面回顾
IF 2.5 4区 化学
Chemical Papers Pub Date : 2025-05-29 DOI: 10.1007/s11696-025-04069-6
D. Christopher Selvam, Yuvarajan Devarajan, Beemkumar Nagappan, Arpit Arora, G. Madhan Kumar, Debabrata Pradhan
{"title":"Sustainable fuel solutions: a comprehensive review of syngas in internal combustion engines","authors":"D. Christopher Selvam,&nbsp;Yuvarajan Devarajan,&nbsp;Beemkumar Nagappan,&nbsp;Arpit Arora,&nbsp;G. Madhan Kumar,&nbsp;Debabrata Pradhan","doi":"10.1007/s11696-025-04069-6","DOIUrl":"10.1007/s11696-025-04069-6","url":null,"abstract":"<div><p>Syngas, a gaseous amalgamation predominantly constituted of carbon monoxide (CO) and hydrogen (H<sub>2</sub>), presents a promising alternative to traditional hydrocarbon fuels utilized in internal combustion (IC) engines. Derived from a diverse array of feedstocks—including biomass, coal, and natural gas—syngas exhibits the potential to mitigate detrimental emissions such as CO<sub>2</sub>, SOx, and particulate matter, thereby rendering it a more environmentally sustainable fuel choice. Its compatibility with extant infrastructure further augments its practicality for imminent adoption. Notwithstanding these benefits, challenges persist in enhancing the efficiency of syngas production and addressing the elevated nitrogen oxide (NOx) emissions that are associated with high-temperature combustion processes. This review meticulously scrutinizes the environmental advantages, feedstock adaptability, and integration of syngas within IC engines while underscoring the technical and operational constraints. Propelling syngas as a feasible low-emission fuel necessitates ongoing research into combustion optimization and emission control methodologies, thereby reinforcing its significance in prospective sustainable energy frameworks.</p></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 7","pages":"4019 - 4027"},"PeriodicalIF":2.5,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145145436","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption and desorption of lignans, flavonoids, phenolic acids by macroporous adsorbent resins during extraction of Astragali radix and stir-fried Arctii Fructus 大孔吸附树脂对黄芪和牛蒡子提取过程中木脂素、黄酮类和酚酸的吸附与解吸
IF 2.5 4区 化学
Chemical Papers Pub Date : 2025-05-29 DOI: 10.1007/s11696-025-04111-7
Yujie Zhu, Ling Meng, Yi Zhao, Chenfeng Zhang, Jinyang Shen, Kunming Qin
{"title":"Adsorption and desorption of lignans, flavonoids, phenolic acids by macroporous adsorbent resins during extraction of Astragali radix and stir-fried Arctii Fructus","authors":"Yujie Zhu,&nbsp;Ling Meng,&nbsp;Yi Zhao,&nbsp;Chenfeng Zhang,&nbsp;Jinyang Shen,&nbsp;Kunming Qin","doi":"10.1007/s11696-025-04111-7","DOIUrl":"10.1007/s11696-025-04111-7","url":null,"abstract":"<p>Astragali radix and Arctii Fructus are extensively utilized in traditional Chinese medicine and have demonstrated efficacy in mitigating renal damage associated with early diabetic nephropathy. To facilitate the comprehensive extraction and application, this study aimed to devise a streamlined and efficacious approach for the preparative purification of lignans, flavonoids, and phenolic acids from Astragali Radix, as well as stir-fried Arctii Fructus, using macroporous resin column chromatography. Initially, the adsorption and desorption characteristics of these compounds on six distinct macroporous resins were investigated, leading to the selection of XDA-8 resin. Subsequently, a combination of column chromatography, single factor testing, and orthogonal experimental design was employed to optimize the technological parameters for the purification process.The desorption rates achieved were notable: lignans at 80.61%, flavonoids at 73.79%, and phenolic acids at 58.96%. In addition, a comparative analysis was conducted on the extracts before and after purification using high-performance liquid chromatography with photodiode-array detection (HPLC-PAD). The results demonstrated that the purified product contained higher amounts of all seven constituents than prior to purification. Therefore, macroporous resin column chromatography utilizing XDA-8 resin, as established in this study, emerges as a promising method for the industrial-scale purification of Astragali Radix and stir-fried Arctii Fructus.</p>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 8","pages":"5125 - 5138"},"PeriodicalIF":2.5,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145170371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of the effect of flocculation and pulp parameters on the performance of vacuum filtration of Moroccan phosphate slurry using novel definitive screening design 采用新型确定筛分设计研究了絮凝剂和矿浆参数对摩洛哥磷酸盐料浆真空过滤性能的影响
IF 2.5 4区 化学
Chemical Papers Pub Date : 2025-05-29 DOI: 10.1007/s11696-025-04113-5
Ahmed Alalou, Zouhair Hafid, Bouali Ali, El Yazghi Ezzaher Amine, Mohammed El Asri, Ahmed Boulahna
{"title":"Investigation of the effect of flocculation and pulp parameters on the performance of vacuum filtration of Moroccan phosphate slurry using novel definitive screening design","authors":"Ahmed Alalou,&nbsp;Zouhair Hafid,&nbsp;Bouali Ali,&nbsp;El Yazghi Ezzaher Amine,&nbsp;Mohammed El Asri,&nbsp;Ahmed Boulahna","doi":"10.1007/s11696-025-04113-5","DOIUrl":"10.1007/s11696-025-04113-5","url":null,"abstract":"<div><p>For the Moroccan phosphate industry, the dewatering of phosphate slurry is significant challenge that has adverse effects on the cost-efficiency of the transportation of phosphate, and the depletion of the water resources. To overcome this challenge, the company is working on developing a flocculation-vacuum filtration system to enhance the dewatering of the phosphate slurry. In this regard, the objective of our study was to evaluate the effect of the flocculation and pulp parameters of the phosphate slurry on the efficiency of the vacuum filtration of the phosphate. The experiments were planned according to a definitive screening design (DSD), by varying the parameters of six input variables and investigating their impact on the humidity of the phosphate cake and the turbidity of the filtrate. The studied factors were the solids rate (<span>({{varvec{X}}}_{1})</span>), the specific consumption of the flocculant (<span>({{varvec{X}}}_{2})</span>), the mass concentration of the flocculant (<span>({{varvec{X}}}_{3})</span>), the viscosity of the flocculant (<span>({{varvec{X}}}_{4})</span>), the percentage of the fine particles (<span>({{varvec{X}}}_{5})</span>), and the duration of filtration (<span>({{varvec{X}}}_{6})</span>). The factors that affect the humidity of the phosphate the most were identified as the viscosity of the flocculant, followed by the duration of filtration and the specific consumption of the flocculant. Due to the useful features of the DSD, a quadratic model for the turbidity of the filtrate was developed and validated. The parameters of the significant factors that minimize the turbidity of the filtrate were defined, allowing for the determination of the conditions for the reduction in the turbidity to below 3 NTU. These findings show promising efficiency of the proposed separation and dewatering process.</p></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 8","pages":"5139 - 5155"},"PeriodicalIF":2.5,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental development of gold nanoparticle-based colorimetric sensor for simultaneous detection of triptan drugs in biological samples 同时检测生物样品中曲坦类药物的金纳米粒子比色传感器的实验研制
IF 2.5 4区 化学
Chemical Papers Pub Date : 2025-05-29 DOI: 10.1007/s11696-025-04118-0
Rafid Jihad Albadr, Waam Mohammedtaher, Mariem Alwan, Mahmood Jasem Jawad, Hiba Mushtaq, Monthar Kedhim, Aseel Smerat, Nadia Msarhan
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