LuminescencePub Date : 2024-12-01DOI: 10.1002/bio.70067
F M Aldosari, Fatmah O Sefrji, Abdulrhman M Alsharari, S A Al-Ghamdi, Sara A Alqarni, Muhammad Hadi, Wael M Alamoudi, Nashwa M El-Metwaly
{"title":"Optical, Opto-Mechanical, and Antimicrobial Characterization of TiO<sub>2</sub> and ZnO-Enhanced Polypropylene Fibers Using Interferometric Techniques and Fourier Transform Analysis.","authors":"F M Aldosari, Fatmah O Sefrji, Abdulrhman M Alsharari, S A Al-Ghamdi, Sara A Alqarni, Muhammad Hadi, Wael M Alamoudi, Nashwa M El-Metwaly","doi":"10.1002/bio.70067","DOIUrl":"https://doi.org/10.1002/bio.70067","url":null,"abstract":"<p><p>This study investigates the optical, mechanical, and antimicrobial properties of polypropylene (PP) fibers enhanced with titanium dioxide (TiO<sub>2</sub>) and zinc oxide (ZnO) nanoparticles. Using a Mach-Zehnder interferometric system, we examined the refractive indices, birefringence, and opto-mechanical behavior of blank PP, PP/TiO<sub>2</sub>, and PP/ZnO nanocomposite fibers under various conditions, including different polarization orientations and during cold drawing processes. The 2D Fourier transform algorithm is employed to analyze interferometric data, enabling precise measurements of refractive index profiles and birefringence. Results show that both TiO<sub>2</sub> and ZnO nanoparticles significantly enhance the optical and mechanical properties of PP fibers. PP/TiO<sub>2</sub> fibers exhibited the highest refractive index (1.530) and birefringence (0.0459), followed by PP/ZnO (1.522 and 0.040) and blank PP (1.520 and 0.031). The maximum draw ratios achieved were 4.2, 3.9, and 3.5 for PP/TiO<sub>2</sub>, PP/ZnO, and blank PP fibers, respectively, indicating improved mechanical properties in the nanocomposites. Antimicrobial efficacy was evaluated using the shaking flask method and optical density measurements against Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, and Candida albicans. PP/ZnO fibers demonstrated the highest antimicrobial activity, with growth reductions ranging from 64.8% to 80.4%, followed by PP/TiO2 fibers (56.0% to 70.3%).</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 12","pages":"e70067"},"PeriodicalIF":3.2,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142878420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LuminescencePub Date : 2024-11-27DOI: 10.1002/bio.70033
Yi Zhang, Yu-chen Wei, Na Zhang, Cong Wang, Xiao-ling Li, Zhen-tao Bian, Keying Zhang
{"title":"Blueberry Anthocyanin Functionalized CaMoO4:Tb3+ Nanophosphors for Dual-Mode pH Sensing","authors":"Yi Zhang, Yu-chen Wei, Na Zhang, Cong Wang, Xiao-ling Li, Zhen-tao Bian, Keying Zhang","doi":"10.1002/bio.70033","DOIUrl":"10.1002/bio.70033","url":null,"abstract":"<div>\u0000 \u0000 <p>A series of green phosphors, Ca<sub>1-y%</sub>MoO<sub>4</sub>:y%Tb<sup>3+</sup> (where y = 0.1, 0.5, 1, 2, 3, 4, and 5) were successfully prepared via hydrothermal synthesis. The pH levels were used to modulate the luminescent of CMO:Tb. To confirm the potential application of proposed phosphors, Blueberry anthocyanin (BBA) was loading onto CMO:Tb surface to form a luminescence probe. The synthesized phosphors and probes were characterized using X-ray diffraction (XRD), FT-IR spectra, transmission electron microscopy (TEM), and high-resolution TEM (HRTEM). As a proof-of-concept, the constructed probes were adopted to evaluate the acidity of solution. The results showed that luminescence emission intensity at 546 nm increased with pH value increasing in the range of 2–12. Meanwhile, the color of the sensor solution changed from bright red to pink, then to purple, and finally to yellow as the pH varies between 2 and 12. The above results indicated that the proposed probe could evaluate the acidity of solution via the dual-mode luminescence detecting and naked eye to obtain accurate results. This proposed strategy gives an insight to design the efficient probes to precisely and sensitively evaluate the acidity in complex samples.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 12","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142741168","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LuminescencePub Date : 2024-11-25DOI: 10.1002/bio.70040
Foziya Yusuf Vadia, Naved I. Malek, Tae Jung Park, Suresh Kumar Kailasa
{"title":"Fluorescence Turn-Off-On Sensing Strategy for the Detection of Pb2+ and Metalaxyl Fungicide Using Yellow Fluorescent Carbon Dots From Cordia dichotoma Fruits","authors":"Foziya Yusuf Vadia, Naved I. Malek, Tae Jung Park, Suresh Kumar Kailasa","doi":"10.1002/bio.70040","DOIUrl":"https://doi.org/10.1002/bio.70040","url":null,"abstract":"<div>\u0000 \u0000 <p>In this work, a facile and rapid fluorescence turn-off-on sensing method was developed for the detection of Pb<sup>2+</sup> and metalaxyl fungicide in environmental samples using yellow carbon dots (CDs) from <i>Cordia dichotoma</i> fruits. The prepared <i>C. dichotoma</i>-CDs showed the emission band (𝜆<sub>Em</sub>) at 535 nm under 448 nm of excitation wavelength. The fluorescence intensity of <i>C. dichotoma</i>-CDs quenches by Pb<sup>2+</sup> ion and then restores by metalaxyl fungicide, favoring to develop a fluorescence turn-off-on sensing strategy. The intensity ratios (<i>I</i><sub>0</sub>/<i>I</i> and <i>I</i>/<i>I</i><sub>0</sub>) are linear against Pb<sup>2+</sup> (0.01–50 μM) and metalaxyl fungicide (0.025–10 μM) concentrations, offering the detection limits of 0.0054 and 0.0087 μM for Pb<sup>2+</sup> and metalaxyl fungicide, respectively. Additionally, the potential application of <i>C. dichotoma</i>-CD-based fluorescence turn-off-on sensing approach was effectively demonstrated for Pb<sup>2+</sup> and metalaxyl fungicide assays in real samples, which confirms that <i>C. dichotoma</i>-CDs act as “turn-off-on” fluorescent probe for assaying of Pb<sup>2+</sup> and metalaxyl fungicide, respectively.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142708131","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LuminescencePub Date : 2024-11-24DOI: 10.1002/bio.70035
S. Varalakshmi, Arunachalam Lakshmanan, L. Sangeetha, V. Rathinamala
{"title":"Intense Red Fluorescence From Surface Traps in BaSO4:V5+, Eu3+ and Its Applications","authors":"S. Varalakshmi, Arunachalam Lakshmanan, L. Sangeetha, V. Rathinamala","doi":"10.1002/bio.70035","DOIUrl":"https://doi.org/10.1002/bio.70035","url":null,"abstract":"<div>\u0000 \u0000 <p>BaSO<sub>4</sub>:V<sup>5+</sup> synthesized at 1000°C in air exhibits an intense emission band peaking at 495 nm from surface traps assisted by atmospheric oxygen on excitation at 350 nm due to charge transfer from O<sup>2−</sup> to V<sup>5+</sup> in the (VO<sub>4</sub>)<sup>3−</sup> tetrahedral complex. BaSO<sub>4</sub>:Eu synthesized under similar conditions exhibits both Eu<sup>2+</sup> (375 nm) and Eu<sup>3+</sup> (619 nm) fluorescence. Vanadium codoping quenches the Eu<sup>2+</sup> fluorescence but enhances the Eu<sup>3+</sup> fluorescence in BaSO<sub>4</sub>:V, Eu due to charge compensation. However, Eu codoping quenches the vanadium fluorescence by diffusion of vanadium into the crystal, and V<sub>2</sub>O<sub>5</sub> also serves as a flux enhancing Eu<sup>3+</sup> doping efficiency in BaSO<sub>4</sub> lattice. The 619nm Eu<sup>3+</sup> PL emission intensity in BaSO<sub>4</sub>:V<sup>5+</sup>, Eu<sup>3+</sup> is comparable to 592nm emission from commercial (Y,Gd) BO<sub>3</sub>:Eu<sup>3+</sup>. However, V<sup>5+</sup> emission shows strong thermal quenching, while Eu<sup>3+</sup> emission shows little thermal quenching up to 210°C, making BaSO<sub>4</sub>:V<sup>5+</sup>, Eu<sup>3+</sup> a promising new red phosphor for improving the color rendering of blue light-based white LED. The ratio of Eu<sup>3+</sup> to V<sup>5+</sup> fluorescence increases with excitation temperature (30°C°C–180°C) enabling BaSO<sub>4</sub>:V<sup>5+</sup>, Eu<sup>3+</sup> to be used as a non-contact luminescence thermometer.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142708296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LuminescencePub Date : 2024-11-22DOI: 10.1002/bio.70009
M. Kanimozhi, R. Harikrishnan, M. Mani, S. Kumaresan, A. Rajasekar, N. Saradha Devi, Shankara G. Radhakrishnan, L. Sibali, K. Kaviyarasu
{"title":"Cyclic Voltammetry Study and Solar Light Assisted Photocatalytic Activity of the CeFeO3/CeO2/Fe2O3 Composite","authors":"M. Kanimozhi, R. Harikrishnan, M. Mani, S. Kumaresan, A. Rajasekar, N. Saradha Devi, Shankara G. Radhakrishnan, L. Sibali, K. Kaviyarasu","doi":"10.1002/bio.70009","DOIUrl":"https://doi.org/10.1002/bio.70009","url":null,"abstract":"<p>The semiconducting nature of CeFeO<sub>3</sub>/CeO<sub>2</sub>/Fe<sub>2</sub>O<sub>3</sub> nanocomposite has permitted the degradation of the organic toxic dye methylene blue under the irradiation of ultraviolet and visible light portions of solar radiation. Fullprof-assisted Rietveld refinement analysis, performed using the Match software, has revealed the orthorhombic nature of CeFeO<sub>3</sub>. In addition, in the synthesized material, the cubic phase byproduct CeO<sub>2</sub> was found due to the highly oxidizing nature of the cerium element. This occurred due to 6 min microwave irradiation because the microwave-assisted technique offered random distribution of heating during the supply of 800-W power for 30 s, followed by 12 cycles. Additionally, the presence of Fe<sub>2</sub>O<sub>3</sub> was also confirmed through Match software-assisted Rietveld refinement analysis through phase matching. During the synthesis, a certain portion of the synthesized CeFeO<sub>3</sub> experienced overheating, leading to phase transformation from CeFeO<sub>3</sub> into Fe<sub>2</sub>O<sub>3</sub> and CeO<sub>2</sub>. The unit cell compositions of CeFeO<sub>3</sub>, CeO<sub>2</sub>, and Fe<sub>2</sub>O<sub>3</sub> were found in the sample material with 35.54%, 52.43%, and 12.03%, respectively. The appearance of a fingerprint absorption region in the FTIR spectrum around 577.36 and 535.38 cm<sup>−1</sup> further confirmed the similarity of these values (577.36 and 535.38 cm<sup>−1</sup>) to those obtained from the calculated values obtained by substituting Rietveld refined bond length parameters. The fourth step process in the thermal analysis curve (TGA) revealed the oxidation process, which led to the destruction of the CeFeO<sub>3</sub> phase, causing the transformation of CeFeO<sub>3</sub> into two byproducts (CeO<sub>2</sub> and Fe<sub>2</sub>O<sub>3</sub>). This oxidation process permitted in an observable weight gain, which is observed in the thermal analysis curve (TGA). A cyclic voltammetry study (the experimentally measured current–voltage characteristic curve) revealed slightly distorted semirectangular CV curves, confirming the pseudo-capacitive behavior of the synthesized composite.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bio.70009","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142685287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"In Situ Study on Biodegradation Differences Between Dissolved Phenanthrene and Methylphenanthrene Using First Derivative Synchronous Fluorescence Spectrometry With Double Scans","authors":"Mengshuo Li, Jingjing Chen, Yaxian Zhu, Yong Zhang","doi":"10.1002/bio.70037","DOIUrl":"https://doi.org/10.1002/bio.70037","url":null,"abstract":"<div>\u0000 \u0000 <p>A rapid and highly sensitive first derivative synchronous fluorescence spectrometry with double scans was successfully optimized for the simultaneous determination of dissolved phenanthrene (Phe), 1-methylphenanthrene (1-MP), and 3-methylphenanthrene (3-MP) and their metabolites such as 1-hydroxy-2-naphthoic acid (1H2NA) and salicylic acid (SA) in the biodegradation processes of Phe, 1-MP, and 3-MP by <i>Novosphingobium pentaromativorans</i> US6-1. Δλ of 55 and 109 nm were selected for Phe, 1-MP, 3-MP, 1H2NA, and SA, respectively. The intensities of the first derivative synchronous fluorescence detected at λex of 289, 292, 291, 354, and 312 nm for Phe, 1-MP, 3-MP, 1H2NA, and SA varied linearly with the concentrations of them in the ranges of 0.20 × 10<sup>−7</sup>–44.89 × 10<sup>−7</sup>, 0.20 × 10<sup>−7</sup>–13.04 × 10<sup>−7</sup>, 0.20 × 10<sup>−7</sup>–13.04 × 10<sup>−7</sup>, 0.22 × 10<sup>−7</sup>–76.30 × 10<sup>−7</sup>, and 0.11 × 10<sup>−7</sup>–52.00 × 10<sup>−7</sup> mol/L. The limits of detection were 0.11 × 10<sup>−9</sup>, 0.30 × 10<sup>−9</sup>, 0.27 × 10<sup>−9</sup>, 0.33 × 10<sup>−9</sup>, and 2.90 × 10<sup>−9</sup> mol/L for Phe, 1-MP, 3-MP, 1H2NA, and SA, respectively, with RSD less than 2%. The method was successfully applied <i>in situ</i> to detect the instantaneous concentrations of the PAHs and their metabolites, especially SA, during their biodegradation processes under simulated conditions in the lab. The results demonstrated that the upper metabolic pathways of 1-MP and 3-MP by US6-1 were distinctly different from that of Phe owing to steric hindrance of the methyl group.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142685288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Quantitation of Vaporized γ-Aminobutyric Acid in Cigarette Smoke Extract From e-Cigarettes by the Combination of HPLC-Fluorescence Detection and Derivatization With DBD-F","authors":"Mitsuhiro Wada, Haruna Onodera, Makoto Takada, Suzuna Saruwatari, Junpei Mutoh, Ken Tachibana, Tadashi Hayama, Naoya Kishikawa, Naotaka Kuroda","doi":"10.1002/bio.70034","DOIUrl":"https://doi.org/10.1002/bio.70034","url":null,"abstract":"<p>Gamma-aminobutyric acid (GABA), which has attracted much attention as a bioactive ingredient, is used in functional foods. Recently, electronic cigarette (e-cigarette) products for inhaling vaporized GABA have become commercially available. In this study, we developed a high-performance liquid chromatography–fluorescence method for detecting GABA derivatized with 4-(<i>N,N</i>-dimethylaminosulfonyl)-7-fluoro-2,1,3-benzoxadiazole (DBD-F) in cigarette smoke extract (CSE). The vaporized GABA captured in CSE was derivatized with DBD-F under moderate conditions (80°C, 30 min). After chromatographic separation, the DBD-GABA derivative was detected at 437 and 558 nm. The calibration curve of GABA ranging from 10 to 20,000 ng/mL showed good linearity (more than 0.999). The limit of detection at a signal-to-noise ratio of 3 was 1.1 ng/mL. The method was applied to the detection of GABA in e-liquid and CSE for two kinds of e-cigarette products, and the estimated collection efficiency of GABA was approximately 25%. Furthermore, the detection of minor components, such as glutamine, glutamic acid, and arginine, in the e-liquid proved that the GABA used in the e-cigarette was prepared by microbial fermentation.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bio.70034","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142685359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Laser Characteristics of Er3+/Yb3+:K-BaF2-Al-Phosphate Glasses","authors":"Praveena Ravipati, Surendra Babu Sajja, Babu Palamandala, Jayasankar Chalicheemalpalli Kulala","doi":"10.1002/bio.70019","DOIUrl":"https://doi.org/10.1002/bio.70019","url":null,"abstract":"<div>\u0000 \u0000 <p>Er<sup>3+</sup> and Er<sup>3+</sup>/Yb<sup>3+</sup>-doped phosphate-based glasses have been synthesized by melt quenching technique and are characterized by absorption spectra, infrared emission, decay curves, Fourier transform infrared spectrum and up-conversion studies. From the absorption spectra, intensity parameters and radiative properties have been derived utilizing the Judd–Ofelt theory. Er<sup>3+</sup>-doped glass is found to have larger radiative lifetime for the laser originating from <sup>4</sup>I<sub>13/2</sub> level at 1537 nm. Infrared and visible characteristic emissions have been measured by exciting at 790 nm through down- and up-conversion, respectively. The up-conversion spectra consist of intense green emission at around 525 and 545 nm ascribed to the <sup>2</sup>H<sub>11/2</sub> → <sup>4</sup>I<sub>15/2</sub> and <sup>4</sup>S<sub>3/2</sub> → <sup>4</sup>I<sub>15/2</sub> transitions, respectively, and a weak red emission at around 656 nm due to the <sup>4</sup>F<sub>9/2</sub> → <sup>4</sup>I<sub>15/2</sub> transition of Er<sup>3+</sup> ions. Various spectroscopic and laser characteristics of these glasses have been calculated and compared with those of similar reported ones.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142674233","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LuminescencePub Date : 2024-11-19DOI: 10.1002/bio.70014
D. Harshitha., Anil Kumar, C. G. Renuka
{"title":"Light Harvesting Materials: A Study on Förster Resonance Energy Transfer and Optoelectronic Properties of Potential Nerium oleander Flowers","authors":"D. Harshitha., Anil Kumar, C. G. Renuka","doi":"10.1002/bio.70014","DOIUrl":"https://doi.org/10.1002/bio.70014","url":null,"abstract":"<div>\u0000 \u0000 <p>The present study focused on extracting the anthocyanin dyes in ethanol, acidic ethanol, methanol, and acidic methanol solvents from <i>Nerium oleander</i> flowers by a simple maceration extraction process. FTIR spectroscopy and vibrational studies have confirmed the existence of polyphenolic groups in 2-phenyl chromenylium (anthocyanin) dyes. The optoelectronic results show the least direct bandgap (2.89 eV), indirect bandgap (1.98 eV), Urbach energy (0.120 eV), high refractive index (1.654), dielectric constant (3.294) and high optical conductivity (1.813 10<sup>3</sup> S/m) for the anthocyanin dye extracted found in acidic ethanol solvent. The photoluminescence properties such as Stokes' shift, quantum yield, and lifetime results show that anthocyanin dyes are promising candidates for red-LEDs and optical materials. The excellent correspondence between the absorption and emission spectra reinforces that the anthocyanins are efficient (89%) FRET probes. Further, the donor and acceptor undergo redshift in excitation and emission spectra in all studied solvents. The photometric properties such as CIE, CRI, CCT and color purity results of anthocyanins in all studied solvents revealed that this material exhibits pink to red shades (x = 0.40 → 0.50 and y = 0.46 → 0.39) and is well suitable for have great potential in the manufacturing of Organic-LEDs and other optoelectronic device applications.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142674312","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LuminescencePub Date : 2024-11-16DOI: 10.1002/bio.70031
I. Koseva, P. Tzvetkov, P. Ivanov, M. Gancheva, V. Nikolov
{"title":"Dysprosium-Doped Glass-Ceramics From the System Na2O-Al2O3-SiO2-B2O3-Dy2O3","authors":"I. Koseva, P. Tzvetkov, P. Ivanov, M. Gancheva, V. Nikolov","doi":"10.1002/bio.70031","DOIUrl":"10.1002/bio.70031","url":null,"abstract":"<div>\u0000 \u0000 <p>Glasses from the system Na<sub>2</sub>O-Al<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub>-B<sub>2</sub>O<sub>3</sub>-Dy<sub>2</sub>O<sub>3</sub> are prepared with three different concentrations of the Dy<sup>3+</sup> ion—0.5, 1, and 2 at%. Glass-ceramics are obtained after thermal treatment of the parent glass at 580°С and 630°С during 2, 5, and 24 h. The crystallizing phases, the crystallinity degree, and the nano crystalline size are determined. The crystallizing phases after thermal treatment are NaAlSiO<sub>4</sub> in two different modifications and Na<sub>3</sub>B<sub>3</sub>O<sub>6</sub>. XRD analyses show the presence of third unknown phase in some samples. Emission and excitation spectra of the glass-ceramics show the characteristic peaks of Dy<sup>3+</sup> (<sup>4</sup>F<sub>9/2</sub> → <sup>6</sup>H<sub>15/2</sub>, <sup>4</sup>F<sub>9/2</sub> → <sup>6</sup>H<sub>13/2</sub> and <sup>4</sup>F<sub>9/2</sub> → <sup>6</sup>H<sub>11/2</sub> at 483, 575, and 668 nm, respectively). The yellow peak is dominating in all samples. The spectra show different intensity depending on the Dy<sup>3+</sup> concentration, temperature, and time of the thermal treatment. This result suggests that the emission color can be controlled by these three factors.</p>\u0000 </div>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645095","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}