{"title":"Luminescence properties of Sr2Ga2GeO7:Bi3+ phosphors and temperature sensing characteristics of co-doped Sm3+","authors":"Jiangyun Wan, Haoyi Wu, Yanmei Li, Yonglin Chen, Chaoyue Peng, Geng Chen, Yihua Hu","doi":"10.1002/bio.4907","DOIUrl":"10.1002/bio.4907","url":null,"abstract":"<p>As one of the fundamental physical quantities, temperature is extremely important in various fields. In order to study the temperature sensing characteristics of dual-emitting center phosphors, Bi<sup>3+</sup>-doped and Bi<sup>3+</sup>/Sm<sup>3+</sup>-doped Sr<sub>2</sub>Ga<sub>2</sub>GeO<sub>7</sub> phosphors were synthesized by high-temperature solid-phase method. Under 312 nm excitation, the Sr<sub>2</sub>Ga<sub>2</sub>GeO<sub>7</sub>:Bi<sup>3+</sup> phosphor exhibits a blue broadband emission corresponding to the <sup>3</sup>P<sub>1</sub> → <sup>1</sup>S<sub>0</sub> transition of Bi<sup>3+</sup> ions. By testing the temperature change spectrum of phosphors, it was found that Bi<sup>3+</sup> exhibited strong thermal sensitivity. However, due to the fact that single ion doped phosphors are easily affected by other factors when applied to the field of temperature sensing, based on the thermal sensitivity of Bi<sup>3+</sup>, Sm<sup>3+</sup> with low temperature sensitivity was selected as the co-doped ion, and it was found that the two ions had different thermal quenching characteristics when the temperature change spectrum was tested. Using the temperature detection method based on the fluorescence intensity ratio (FIR) of the dual emission centers, it was found that the best absolute sensitivity S<sub>a</sub> was 3.125% K<sup>−1</sup> and the maximum relative sensitivity S<sub>r</sub> was 1.275% K<sup>−1</sup> in the range of 303–423 K. These results show that Sr<sub>2</sub>Ga<sub>2</sub>GeO<sub>7</sub>:Bi<sup>3+</sup>/Sm<sup>3+</sup> phosphors have broad application prospects in the field of optical temperature sensing.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 10","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142331243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A mixed Ce/Eu metal–organic framework for ratiometric detection of Al3+ ion","authors":"Dong Chen, Yating Wan, Yanping Li, Bowen Qin, Bing Zhang, Mengyao Wang, Yarui Cai, Yanxia Li, Weidong Li, Zhenling Wang","doi":"10.1002/bio.4909","DOIUrl":"10.1002/bio.4909","url":null,"abstract":"<p>As a heavy metal ion, excessive aluminum ions pose a serious threat to human health and the ecological environment. Developing a simple, efficient, and fast detection method to detect the content of aluminum ions is of great significance, especially for ensuring human health and ecological safety. Herein, the mixed rare earth metal–organic framework (Ce<sub>0.74</sub>Eu<sub>0.26</sub>TPTC and Ce<sub>0.62</sub>Eu<sub>0.38</sub>TPTC) were prepared based on simple ligand 1,1′:4′,1″-Terphenyl-2′,4,4″,5′-tetracarboxylic acid (H<sub>4</sub>TPTC). The Ce<sub>0.74</sub>Eu<sub>0.26</sub>TPTC and Ce<sub>0.62</sub>Eu<sub>0.38</sub>TPTC have dual luminescence centers, which can be used as ratio fluorescent probes to detect Al<sup>3+</sup> ions, making the detection results more accurate and reliable. Therefore, this work can promote the further development of rare earth-based MOFs in the detection of heavy metal ions.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 10","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142331242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LuminescencePub Date : 2024-09-25DOI: 10.1002/bio.4905
Machaba L. A. Letswalo, Leelakrishna Reddy, Avula Balakrishna, Hendrik C. Swart, Odireleng M. Ntwaeaborwa
{"title":"Investigation of red-emitting CaMoO4: Eu3+ phosphor by partitioning of substitutional PO43− ions via solid-state reaction method","authors":"Machaba L. A. Letswalo, Leelakrishna Reddy, Avula Balakrishna, Hendrik C. Swart, Odireleng M. Ntwaeaborwa","doi":"10.1002/bio.4905","DOIUrl":"https://doi.org/10.1002/bio.4905","url":null,"abstract":"<p>To investigate the impact of PO<sub>4</sub><sup>3−</sup> anionic groups, the trivalent europium ion-doped calcium molybdate (CaMoO<sub>3</sub>-PO<sub>4</sub>:<i>x</i>Eu<sup>3+</sup>, where <i>x</i> = 0.5, 1.0, 1.5, 2.0, and 2.5 mol%) phosphors were synthesized using the solid-state reaction method. The detailed study of the phosphor materials was carried out by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), optical diffuse reflectance spectroscopy (DRS), and photoluminescence (PL) spectroscopy. The XRD results indicate that the substitution of PO<sub>4</sub><sup>3−</sup> anion and Eu<sup>3+</sup> dopant ion did not affect the crystal structures of the CaMoO<sub>4</sub> phosphors. Ultraviolet–visible (UV–vis) absorption analysis revealed the change of absorption edge of both un-doped and Eu<sup>3+</sup>-doped CaMoO<sub>4</sub>-PO<sub>4</sub> phosphors. Under the 394 nm UV-excitation, the recorded PL spectra showed an intense peak at 615 nm corresponding to the Eu<sup>3+</sup>: <sup>5</sup>D<sub>0</sub> → <sup>7</sup>F<sub>2</sub> transition. The results of the Commission Internationale de l'Eclairage (CIE) diagram reported that the color of the emissions lies in the red color zone and there is no change in the CIE coordinates of the overall emission for Eu<sup>3+</sup>-doped CaMoO<sub>4</sub>-PO<sub>4</sub> as Eu concentration changes. Thus, these observations led to finding the best red components for white light-emitting diode applications.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 9","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bio.4905","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142320761","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LuminescencePub Date : 2024-09-25DOI: 10.1002/bio.4898
Prathima R., Kanthesh M Basalingappa, Sai Kavya D., Arjun K. R., Girish Kanavi K., Suresh J., Karthikeyan Murugesan, Anjuna Radhakrishnan, Deepa Kandaswamy, Bedanta Roy, Selvankumar Thangaswamy, Bharath Selvaraj, Jaganathan R, Maghimaa M
{"title":"Fluorescence capturing behaviour of cyanobacterial resilience: Insights into UV-exposed ecosystems and its environmental applications","authors":"Prathima R., Kanthesh M Basalingappa, Sai Kavya D., Arjun K. R., Girish Kanavi K., Suresh J., Karthikeyan Murugesan, Anjuna Radhakrishnan, Deepa Kandaswamy, Bedanta Roy, Selvankumar Thangaswamy, Bharath Selvaraj, Jaganathan R, Maghimaa M","doi":"10.1002/bio.4898","DOIUrl":"https://doi.org/10.1002/bio.4898","url":null,"abstract":"<p>Cyanobacteria are resilient microorganisms and thrive in environments exposed to UV radiation, ranging from ocean surfaces to scorching hot springs and dry expanses. ‘Cyanobacterial Resilience’ refers to their ability to withstand UV radiation, revealing intricate genomic secrets and adaptive mechanisms ensuring survival. These mechanisms include metabolic adaptations, robust DNA repair systems and UV-protective compounds such as Scytonemin and Mycosporine, vital for shielding against UV radiation survival. Cyanobacteria are crucial pioneers in UV-exposed ecosystems, highlighting their resilience and adaptability. Some cyanobacteria exhibit luminescence, emitting blue-green light due to phycobiliproteins, while bioluminescence in cyanobacteria, if it occurs, involves different compounds rather than luciferins and luciferase enzymes. This luminescence holds promise for various biotechnological applications, such as biosensors, imaging probes and carbon sequestration, for participating in photocatalytic processes for water purification and CO<sub>2</sub> conversion, and contributes to solar simulation studies to advance photosynthesis and renewable energy technologies. The versatile applications of these materials highlight their ecological importance and potential in addressing global challenges. In conclusion, ‘Cyanobacterial Resilience’ highlights the remarkable adaptation strategies of cyanobacteria in UV-exposed environments. It emphasises their role as pioneers and innovators in biological and technological domains, providing insights into their enduring impact on ecosystems and scientific advancement.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 9","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142320692","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LuminescencePub Date : 2024-09-25DOI: 10.1002/bio.4906
Johnrose Arul Hency Sheela, Chaitanya Kumar Kunapalli, P. Saravanan, Kothalam Radhakrishnan, Ayyar Dinesh, Mohammad Ahmad Wadaan, L. Praburaman, M. Sherlin Nivetha
{"title":"Visible-light enhanced tetracycline degradation via SnO2/TiO2-Ni@rGO ternary heterostructures","authors":"Johnrose Arul Hency Sheela, Chaitanya Kumar Kunapalli, P. Saravanan, Kothalam Radhakrishnan, Ayyar Dinesh, Mohammad Ahmad Wadaan, L. Praburaman, M. Sherlin Nivetha","doi":"10.1002/bio.4906","DOIUrl":"https://doi.org/10.1002/bio.4906","url":null,"abstract":"<p>This study explores the synthesis, characterization, and photocatalytic performance of a SnO<sub>2</sub>/TiO<sub>2</sub>-Ni@rGO nanocomposite for tetracycline (TC) degradation under visible light irradiation. The nanocomposite was precisely designed to enhance structural stability, charge transfer efficiency, and catalytic activity. X-ray diffraction (XRD) analysis confirmed the structural integrity of the SnO<sub>2</sub>/TiO<sub>2</sub>-Ni@rGO composite, demonstrating excellent reusability and resistance to photo-corrosion after multiple cycles. Photocatalytic experiments revealed that the SnO<sub>2</sub>/TiO<sub>2</sub>-Ni@rGO nanocomposite significantly outperformed individual SnO<sub>2</sub>/TiO<sub>2</sub>-Ni and rGO catalysts, achieving a remarkable 94.6% degradation of TC within 60 min. The degradation process followed pseudo-first-order kinetics, with a rate constant (<i>k</i>) of 0.046 min<sup>−1</sup>. The <i>Z</i>-scheme charge transfer mechanism facilitated efficient separation and migration of photogenerated charge carriers, generating reactive oxygen species such as superoxide (•O<sub>2</sub><sup>−</sup>) and hydroxyl (•OH) radicals crucial for the oxidation of TC. Radical scavenger studies confirmed that superoxide and hydroxyl radicals were the primary active species. The SnO<sub>2</sub>/TiO<sub>2</sub>-Ni@rGO composite also exhibited excellent reusability, maintaining high catalytic performance over four consecutive cycles. These findings suggest that the SnO<sub>2</sub>/TiO<sub>2</sub>-Ni@rGO nanocomposite is a promising candidate for the efficient and sustainable photocatalytic degradation of persistent organic pollutants like TC, offering significant potential for environmental remediation applications.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 9","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142316925","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LuminescencePub Date : 2024-09-24DOI: 10.1002/bio.4908
Zhong Luo, Changchun Yuan, Zhichun Li, Wenbing Ma
{"title":"A novel coumarin–naphthalimide-based ratiometric fluorescent probe for efficiently monitoring of hydrazine in environmental water","authors":"Zhong Luo, Changchun Yuan, Zhichun Li, Wenbing Ma","doi":"10.1002/bio.4908","DOIUrl":"10.1002/bio.4908","url":null,"abstract":"<p>A novel coumarin–naphthalimide-based ratiometric fluorescent probe, called XPT, was synthesized with the aim of achieving high sensitivity and anti-interference for N<sub>2</sub>H<sub>4</sub> detection. The probe XPT consists of coumarin species and naphthalimide species, which act as the energy donor and acceptor, respectively. The phthalimide group functions as the recognition unit for N<sub>2</sub>H<sub>4</sub>. Without the presence of hydrazine, the naphthalimide remains in a non-fluorogenic phthalimide mode, disrupting the FRET signal. However, the phthalimide group undergoes the Gabriel reaction to an amine, which induces FRET and consequently causes a shift in the emitted fluorescence from 468 to 528 nm when N<sub>2</sub>H<sub>4</sub> was added. The results of the study demonstrated that XPT exhibits high sensitivity with a limit of detection 2.2 μM, as well as selectivity. Furthermore, it is remarkable that the distribution of N<sub>2</sub>H<sub>4</sub> in real water samples can be monitored by XPT.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 9","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142308933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LuminescencePub Date : 2024-09-24DOI: 10.1002/bio.4901
Jayachandhiran Arumugam, Amal George, P. Saravanan, Subramani Rahul, Alphonse Dhayal Raj, Mohammed F. Albeshr, Savarenathan Johnsundaram, Thangaswamy Selvankumar, Duraisamy Karthika, Jothi Vinoth Kumar
{"title":"Fabrication of one-dimensional Zn-doped Bi2S3 nanorods for photodiode applications","authors":"Jayachandhiran Arumugam, Amal George, P. Saravanan, Subramani Rahul, Alphonse Dhayal Raj, Mohammed F. Albeshr, Savarenathan Johnsundaram, Thangaswamy Selvankumar, Duraisamy Karthika, Jothi Vinoth Kumar","doi":"10.1002/bio.4901","DOIUrl":"10.1002/bio.4901","url":null,"abstract":"<p>In this research, the impact of the different zinc (Zn) concentrations on the physical and optoelectronic properties of Bi<sub>2</sub>S<sub>3</sub> nanorods as self-powered and photodiode applications was investigated. The performance of P-N junction photodiodes has been for decades since they are crucial in energy applications. The structure, degree of crystallinity, and shape of Zn<span>-</span>doped Bi<sub>2</sub>S<sub>3</sub> nanorods of various doping percentages formed onto the indium tin oxide (ITO) substrates by the dip coating technique are investigated using X-ray powder diffraction (XRD) and SEM. With increasing illumination time, the current–voltage (I–V) graphs demonstrate a rise in photocurrent. The diode's idealist factor was estimated using the I–V technique under 30 min of light illumination.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 9","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142308934","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LuminescencePub Date : 2024-09-17DOI: 10.1002/bio.4902
Zongsu Yu, Dayu Wu
{"title":"An imidazole-copper(I) metallacycle complex exhibiting thermochromic fluorescence","authors":"Zongsu Yu, Dayu Wu","doi":"10.1002/bio.4902","DOIUrl":"https://doi.org/10.1002/bio.4902","url":null,"abstract":"<p>In this paper, we firstly report the synthesis and structural characterization of a discrete coordination metallacycle complex, [CuI (bipy)]<sub>2</sub> (1). The x-ray diffraction structure, temperature-dependent electronic absorption, and photoluminescence spectra have been investigated. The solid-state fluorescence at variable temperatures shows that complex 1 exhibits an obvious thermochromic fluorescence. At low temperature, the dual fluorescence with peaks at 590 and 694 nm was observed. The emission color significantly changes from red at 77 K to yellow at 200 K and blue-green at 330 K. The thermochromic fluorescent molecular materials show great potential as temperature sensing.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 9","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142244545","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
LuminescencePub Date : 2024-09-16DOI: 10.1002/bio.4880
Qi Qi, Li Junfeng, Sun Yueming
{"title":"Sandwiched naphthyl carbazole: Inversion Circularly Polarized Luminescence based on a pull-push electron valve strategy","authors":"Qi Qi, Li Junfeng, Sun Yueming","doi":"10.1002/bio.4880","DOIUrl":"https://doi.org/10.1002/bio.4880","url":null,"abstract":"<p>Inspired by circularly polarized luminescence (CPL), artificial CPL assembly has attracted intense attention. However, precise manipulation of chiral transfer from achiral and luminescent materials remains a formidable challenge. Two sandwiched carbazole and binaphthol derivatives composed of pyridine or trifluoride methyl benzene have been synthesized. Among R-1 and R-2, their spectra were found in the violet region, both in the solution and the film state. They exhibit the photoluminescence dissymmetry factors up to 1.4 × 10<sup>−3</sup> for R-2 and an opposite value of −5.6 × 10<sup>−4</sup> for R-1. Theoretical CPL and circular dichroism (CD) studies were in good agreement with the experimental data and deciphered their opposite signals by the transition electric and magnetic moment. Our study offers a strategy for studying the charge and chiral transfer.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 9","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142244524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A highly specific red-emitting fluorescent probe for monitoring of Cu2+ in living cells and zebrafish","authors":"Shuai Kong, Yan Zhang, Lianke Xie, Guodong Qi, Yanping Li, Haitao Dai, Qiubo Qi, Yimin Chen","doi":"10.1002/bio.4886","DOIUrl":"https://doi.org/10.1002/bio.4886","url":null,"abstract":"<p>A novel seminaphthorhodafluor-based fluorescent probe was designed and prepared. It exhibited an outstanding off–on fluorescence response (about 45-fold enhancement) to Cu<sup>2+</sup> because the structure changed from a spirocyclic form to a ring-open state. It showed satisfactory detection performances for Cu<sup>2+</sup> with fast response speed, high selectivity and anti-interference, and a low detection limit (22.9 nM) due to its long emission wavelength and off–on fluorescence response mode. This probe was also satisfactorily applied for the monitoring of Cu<sup>2+</sup> in living cells and zebrafish.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 9","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142244518","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}