{"title":"3-羟基哌啶氮α-碳负离子的形成及α-羟烷化反应","authors":"郑啸, 陈果, 阮源萍, 黄培强","doi":"10.1360/ZB2009-39-10-1175","DOIUrl":"https://doi.org/10.1360/ZB2009-39-10-1175","url":null,"abstract":"合成了( S )-3-羟基哌啶苯硫醚化合物6作为3-羟基哌啶氮α-碳负离子手性合成子(B)的合成等效体. 化合物6经羟基去质子现场保护、萘锂(LN)还原锂化形成手性哌啶醇双负离子中间体 B. 双负离子 B 可被质子淬灭得到还原产物 2a; 而与羰基化合物反应则得到α-羟烷化产物 12~17 和少量还原产物 2a. 该反应具有很高的环上2,3-位非对映立体选择性; 与非对称的羰基化合物反应产生新手性中心的立体选择性从50:50到77:23.","PeriodicalId":49128,"journal":{"name":"Science in China. Series B, Chemistry","volume":"42 1","pages":"1175-1183"},"PeriodicalIF":0.0,"publicationDate":"2009-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77274236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
陈军 马华冀伟强杨晓婧陶占良, Ji Wei-Jiang Yang Xiao-Jing Dao Tie-Liang Chen Jun Ma Hua
{"title":"CoV 2 O 6 纳米线/微米棒的制备及其在锂离子电池中的应用","authors":"陈军 马华冀伟强杨晓婧陶占良, Ji Wei-Jiang Yang Xiao-Jing Dao Tie-Liang Chen Jun Ma Hua","doi":"10.1360/ZB2009-39-9-918","DOIUrl":"https://doi.org/10.1360/ZB2009-39-9-918","url":null,"abstract":"采用水热法制备了纳米线/微米棒结构的CoV 2 O 6 电极材料, 并探讨了纳米线/微米棒的形成机理. 通过XRD、BET、SEM、TEM/HRTEM等测试手段对合成产物的结构、形貌、组成、表面性质进行了表征, 结果表明, 水热条件例如反应温度、反应时间对于产物的结构和形貌起关键作用. 在220℃, 水热反应1 h可以得到直径为60 nm的CoV 2 O 6 纳米线, 而在220℃, 水热反应6 h可以得到直径10 μm的CoV 2 O 6 微米棒. 研究了CoV 2 O 6 纳米线/微米棒作为锂离子电池负极材料的电化学性能, 结果显示, 与CoV 2 O 6 微米棒相比, CoV 2 O 6 纳米线具有高的初始放电容量(1235 mAh/g)和较好的循环稳定性, CoV 2 O 6 纳米线有希望作为锂离子电池的负极材料.","PeriodicalId":49128,"journal":{"name":"Science in China. Series B, Chemistry","volume":"296 1","pages":"918-925"},"PeriodicalIF":0.0,"publicationDate":"2009-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73162897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"4-PEG接枝苯乙烯-马来酸酐交替共聚物的合成及功能化","authors":"任丽霞, 陈永明","doi":"10.1360/ZB2009-39-9-950","DOIUrl":"https://doi.org/10.1360/ZB2009-39-9-950","url":null,"abstract":"采用普通自由基聚合和可逆加成-断裂链转移(RAFT)自由基聚合方法合成了对位PEG取代苯乙烯(PEG- g -St)和马来酸酐的交替共聚物(P((PEG-g-St)- alt -MA)), 13C NMR分析表明PEG-g-St和马来酸酐单元采取交替的序列结构. 利用反应性基团- 马来酸酐单元的水解以及胺解可以制备功能性的PEG聚合物. 以月桂胺为模型小分子研究了该聚合物的胺解, 得到4-PEG-苯乙烯与羧酸基团以及疏水烷烃的交替序列聚合物, 该双亲聚合物在水溶液中形成组装体.","PeriodicalId":49128,"journal":{"name":"Science in China. Series B, Chemistry","volume":"688 1","pages":"950-958"},"PeriodicalIF":0.0,"publicationDate":"2009-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77002113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}