Nano-Micro Letters最新文献_第10页

Chip-Based High-Dimensional Optical Neural Network 基于芯片的高维光神经网络

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2022-11-14 DOI: 10.1007/s40820-022-00957-8

Xinyu Wang, Peng Xie, Bohan Chen, Xingcai Zhang

引用次数: 0

Carbon-Nitride-Based Materials for Advanced Lithium–Sulfur Batteries 用于先进锂硫电池的氮化碳基材料。

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2022-11-14 DOI: 10.1007/s40820-022-00954-x

Wenhao Sun, Zihao Song, Zhenxing Feng, Yaqin Huang, Zhichuan J. Xu, Yi-Chun Lu, Qingli Zou

{"title":"Carbon-Nitride-Based Materials for Advanced Lithium–Sulfur Batteries","authors":"Wenhao Sun, Zihao Song, Zhenxing Feng, Yaqin Huang, Zhichuan J. Xu, Yi-Chun Lu, Qingli Zou","doi":"10.1007/s40820-022-00954-x","DOIUrl":"10.1007/s40820-022-00954-x","url":null,"abstract":"<div><p>Lithium–sulfur (Li–S) batteries are promising candidates for next-generation energy storage systems owing to their high energy density and low cost. However, critical challenges including severe shuttling of lithium polysulfides (LiPSs) and sluggish redox kinetics limit the practical application of Li–S batteries. Carbon nitrides (C<sub><i>x</i></sub>N<sub><i>y</i></sub>), represented by graphitic carbon nitride (g-C<sub>3</sub>N<sub>4</sub>), provide new opportunities for overcoming these challenges. With a graphene-like structure and high pyridinic-N content, g-C<sub>3</sub>N<sub>4</sub> can effectively immobilize LiPSs and enhance the redox kinetics of S species. In addition, its structure and properties including electronic conductivity and catalytic activity can be regulated by simple methods that facilitate its application in Li–S batteries. Here, the recent progress of applying C<sub>x</sub>N<sub>y</sub>-based materials including the optimized g-C<sub>3</sub>N<sub>4</sub>, g-C<sub>3</sub>N<sub>4</sub>-based composites, and other novel C<sub><i>x</i></sub>N<sub><i>y</i></sub> materials is systematically reviewed in Li–S batteries, with a focus on the structure–activity relationship. The limitations of existing C<sub><i>x</i></sub>N<sub><i>y</i></sub>-based materials are identified, and the perspectives on the rational design of advanced C<sub><i>x</i></sub>N<sub><i>y</i></sub>-based materials are provided for high-performance Li–S batteries.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":48779,"journal":{"name":"Nano-Micro Letters","volume":"14 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2022-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9663784/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10465034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electron-Deficient Zn-N6 Configuration Enabling Polymeric Carbon Nitride for Visible-Light Photocatalytic Overall Water Splitting 缺电子的 Zn-N6 构型可使聚合物氮化碳用于可见光光催化整体水分离

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2022-11-14 DOI: 10.1007/s40820-022-00962-x

Daming Zhao, Yiqing Wang, Chung-Li Dong, Fanqi Meng, Yu-Cheng Huang, Qinghua Zhang, Lin Gu, Lan Liu, Shaohua Shen

{"title":"Electron-Deficient Zn-N6 Configuration Enabling Polymeric Carbon Nitride for Visible-Light Photocatalytic Overall Water Splitting","authors":"Daming Zhao, Yiqing Wang, Chung-Li Dong, Fanqi Meng, Yu-Cheng Huang, Qinghua Zhang, Lin Gu, Lan Liu, Shaohua Shen","doi":"10.1007/s40820-022-00962-x","DOIUrl":"10.1007/s40820-022-00962-x","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 \u0000 <ul>\u0000 <li>\u0000 <p>Atomically dispersed Zn-anchored 3D sponge-like polymeric carbon nitride (Zn-PCN) characteristic of a unique Zn-N<sub>6</sub> electron-deficient configuration is synthesized via an intermediate coordination strategy.</p>\u0000 </li>\u0000 <li>\u0000 <p>The electron-deficient Zn-N<sub>6</sub> configuration contributes to enhanced electron excitation, accelerated charge separation and transfer as well as reduced overpotentials of water redox reactions.</p>\u0000 </li>\u0000 <li>\u0000 <p>The obtained Zn-PCN realizes photocatalytic overall water splitting to stoichiometrically produce H<sub>2</sub> and O<sub>2</sub> with good durability under visible light.</p>\u0000 </li>\u0000 </ul>\u0000 \u0000 </div></div>","PeriodicalId":48779,"journal":{"name":"Nano-Micro Letters","volume":"14 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2022-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9663795/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10469622","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Bacterial Metabolism-Initiated Nanocatalytic Tumor Immunotherapy 细菌代谢引发的纳米催化肿瘤免疫疗法

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2022-11-11 DOI: 10.1007/s40820-022-00951-0

Wencheng Wu, Yinying Pu, Shuang Gao, Yucui Shen, Min Zhou, Heliang Yao, Jianlin Shi

引用次数: 0

Interface Reversible Electric Field Regulated by Amphoteric Charged Protein-Based Coating Toward High-Rate and Robust Zn Anode 基于两性带电蛋白质涂层的界面可逆电场调控技术--迈向高倍率和稳健的锌阳极

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2022-11-10 DOI: 10.1007/s40820-022-00969-4

Meihua Zhu, Qing Ran, Houhou Huang, Yunfei Xie, Mengxiao Zhong, Geyu Lu, Fu-Quan Bai, Xing-You Lang, Xiaoteng Jia, Danming Chao

{"title":"Interface Reversible Electric Field Regulated by Amphoteric Charged Protein-Based Coating Toward High-Rate and Robust Zn Anode","authors":"Meihua Zhu, Qing Ran, Houhou Huang, Yunfei Xie, Mengxiao Zhong, Geyu Lu, Fu-Quan Bai, Xing-You Lang, Xiaoteng Jia, Danming Chao","doi":"10.1007/s40820-022-00969-4","DOIUrl":"10.1007/s40820-022-00969-4","url":null,"abstract":"<div><h2> Highlights</h2><div>\u0000 \u0000 \u0000 <ul>\u0000 <li>\u0000 <p>Alternating positively and negatively charged surface controlled by pH expedites and\u0000homogenizes Zn<sup>2+</sup> flux, endowing the Zn- silk fibroin (SF) anode with low polarization\u0000voltage and stable stripping/plating.</p>\u0000 </li>\u0000 <li>\u0000 <p>Experimental analyses with theoretical calculations suggest that SF coating facilitates the\u0000desolvation of [Zn(H<sub>2</sub>O)<sub>6</sub>]<sup>2+</sup> and provides nucleation sites for uniform deposition.</p>\u0000 </li>\u0000 <li>\u0000 <p>Symmetric battery of Zn–SF anodes delivers high-rate performance (up to 20 mA cm<sup>−2</sup>)\u0000and excellent stability (1500 h at 1 mA cm<sup>−2</sup>; 500 h at 10 mA cm<sup>−2</sup>) with cumulative\u0000capacity of 2.5 Ah cm<sup>−2</sup>.</p>\u0000 </li>\u0000 </ul>\u0000 \u0000 </div></div>","PeriodicalId":48779,"journal":{"name":"Nano-Micro Letters","volume":"14 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2022-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9649586/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10814140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Aqueous Two-Phase Interfacial Assembly of COF Membranes for Water Desalination 用于海水淡化的 COF 膜的水性两相界面组装

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2022-11-09 DOI: 10.1007/s40820-022-00968-5

Hongjian Wang, Jiashuai Zhao, Yang Li, Yu Cao, Ziting Zhu, Meidi Wang, Runnan Zhang, Fusheng Pan, Zhongyi Jiang

{"title":"Aqueous Two-Phase Interfacial Assembly of COF Membranes for Water Desalination","authors":"Hongjian Wang, Jiashuai Zhao, Yang Li, Yu Cao, Ziting Zhu, Meidi Wang, Runnan Zhang, Fusheng Pan, Zhongyi Jiang","doi":"10.1007/s40820-022-00968-5","DOIUrl":"10.1007/s40820-022-00968-5","url":null,"abstract":"<div><p>Aqueous two-phase system features with ultralow interfacial tension and thick interfacial region, affording unique confined space for membrane assembly. Here, for the first time, an aqueous two-phase interfacial assembly method is proposed to fabricate covalent organic framework (COF) membranes. The aqueous solution containing polyethylene glycol and dextran undergoes segregated phase separation into two water-rich phases. By respectively distributing aldehyde and amine monomers into two aqueous phases, a series of COF membranes are fabricated at water–water interface. The resultant membranes exhibit high NaCl rejection of 93.0–93.6% and water permeance reaching 1.7–3.7 L m<sup>−2</sup> h<sup>−1</sup> bar<sup>−1</sup>, superior to most water desalination membranes. Interestingly, the interfacial tension is found to have pronounced effect on membrane structures. The appropriate interfacial tension range (0.1–1.0 mN m<sup>−1</sup>) leads to the tight and intact COF membranes. Furthermore, the method is extended to the fabrication of other COF and metal–organic polymer membranes. This work is the first exploitation of fabricating membranes in all-aqueous system, confering a green and generic method for advanced membrane manufacturing.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":48779,"journal":{"name":"Nano-Micro Letters","volume":"14 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2022-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9646690/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10830987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Metal–Organic Frameworks Functionalized Separators for Robust Aqueous Zinc-Ion Batteries 用于稳健锌离子水电池的金属有机框架功能化分离器

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2022-11-09 DOI: 10.1007/s40820-022-00960-z

Yang Song, Pengchao Ruan, Caiwang Mao, Yuxin Chang, Ling Wang, Lei Dai, Peng Zhou, Bingan Lu, Jiang Zhou, Zhangxing He

{"title":"Metal–Organic Frameworks Functionalized Separators for Robust Aqueous Zinc-Ion Batteries","authors":"Yang Song, Pengchao Ruan, Caiwang Mao, Yuxin Chang, Ling Wang, Lei Dai, Peng Zhou, Bingan Lu, Jiang Zhou, Zhangxing He","doi":"10.1007/s40820-022-00960-z","DOIUrl":"10.1007/s40820-022-00960-z","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 \u0000 <ul>\u0000 <li>\u0000 <p>Metal-organic frameworks (UiO-66) functionalized glass fiber separator was constructed to accelerate the transport of charge carriers and provide a uniform electric field distribution on the surface of zinc anode.</p>\u0000 </li>\u0000 <li>\u0000 <p>Zinc anode demonstrates preferential orientation of (002) plane under the control of UiO-66-GF, which effectively inhibits dendrites.</p>\u0000 </li>\u0000 <li>\u0000 <p>Density functional theory calculation confirms that the adsorption effect of (002) plane on H is weaker, thus improving corrosion resistance and suppressing the hydrogen evolution reaction.</p>\u0000 </li>\u0000 <li>\u0000 <p>Symmetric cells exhibit highly reversible plating/stripping behavior with long cycle life over 1650 h and full cells demonstrate excellent long-term stability (85%) for 1000 cycles.</p>\u0000 </li>\u0000 </ul>\u0000 \u0000 </div></div>","PeriodicalId":48779,"journal":{"name":"Nano-Micro Letters","volume":"14 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2022-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9646683/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10830982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High-Entropy Perovskite Oxide: A New Opportunity for Developing Highly Active and Durable Air Electrode for Reversible Protonic Ceramic Electrochemical Cells 高熵过氧化物：为可逆质子陶瓷电化学电池开发高活性和耐用空气电极的新机遇

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2022-11-09 DOI: 10.1007/s40820-022-00967-6

Zuoqing Liu, Zhengjie Tang, Yufei Song, Guangming Yang, Wanru Qian, Meiting Yang, Yinlong Zhu, Ran Ran, Wei Wang, Wei Zhou, Zongping Shao

{"title":"High-Entropy Perovskite Oxide: A New Opportunity for Developing Highly Active and Durable Air Electrode for Reversible Protonic Ceramic Electrochemical Cells","authors":"Zuoqing Liu, Zhengjie Tang, Yufei Song, Guangming Yang, Wanru Qian, Meiting Yang, Yinlong Zhu, Ran Ran, Wei Wang, Wei Zhou, Zongping Shao","doi":"10.1007/s40820-022-00967-6","DOIUrl":"10.1007/s40820-022-00967-6","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 \u0000 <ul>\u0000 <li>\u0000 <p>Synthesis of high-entropy perovskite oxide for air electrode in reversible proton ceramic electrochemical cells.</p>\u0000 </li>\u0000 <li>\u0000 <p>Triple-conducting high-entropy air electrodes exhibit excellent structural stability and oxygen catalytic activity.</p>\u0000 </li>\u0000 <li>\u0000 <p>The peak power density and current density of the cell with high-entropy air electrode in the fuel cell and electrolysis modes are 1.21 W cm<sup>−2</sup> and − 1.95 A cm<sup>−2</sup> at 600 °C, respectively.</p>\u0000 </li>\u0000 </ul>\u0000 \u0000 </div></div>","PeriodicalId":48779,"journal":{"name":"Nano-Micro Letters","volume":"14 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2022-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9646682/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10830983","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Defect Passivation on Lead-Free CsSnI3 Perovskite Nanowires Enables High-Performance Photodetectors with Ultra-High Stability 无铅 CsSnI3 包晶石纳米线上的缺陷钝化实现了超高稳定性的高性能光电探测器

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2022-11-07 DOI: 10.1007/s40820-022-00964-9

Zheng Gao, Hai Zhou, Kailian Dong, Chen Wang, Jiayun Wei, Zhe Li, Jiashuai Li, Yongjie Liu, Jiang Zhao, Guojia Fang

{"title":"Defect Passivation on Lead-Free CsSnI3 Perovskite Nanowires Enables High-Performance Photodetectors with Ultra-High Stability","authors":"Zheng Gao, Hai Zhou, Kailian Dong, Chen Wang, Jiayun Wei, Zhe Li, Jiashuai Li, Yongjie Liu, Jiang Zhao, Guojia Fang","doi":"10.1007/s40820-022-00964-9","DOIUrl":"10.1007/s40820-022-00964-9","url":null,"abstract":"<div><p>In recent years, Pb-free CsSnI<sub>3</sub> perovskite materials with excellent photoelectric properties as well as low toxicity are attracting much attention in photoelectric devices. However, deep level defects in CsSnI<sub>3</sub>, such as high density of tin vacancies, structural deformation of SnI<sub>6</sub><sup>−</sup> octahedra and oxidation of Sn<sup>2+</sup> states, are the major challenge to achieve high-performance CsSnI<sub>3</sub>-based photoelectric devices with good stability. In this work, defect passivation method is adopted to solve the above issues, and the ultra-stable and high-performance CsSnI<sub>3</sub> nanowires (NWs) photodetectors (PDs) are fabricated via incorporating 1-butyl-2,3-dimethylimidazolium chloride salt (BMIMCl) into perovskites. Through materials analysis and theoretical calculations, BMIM<sup>+</sup> ions can effectively passivate the Sn-related defects and reduce the dark current of CsSnI<sub>3</sub> NW PDs. To further reduce the dark current of the devices, the polymethyl methacrylate is introduced, and finally, the dual passivated CsSnI<sub>3</sub> NWPDs show ultra-high performance with an ultra-low dark current of 2 × 10<sup>–11</sup> A, a responsivity of up to 0.237 A W<sup>−1</sup>, a high detectivity of 1.18 × 10<sup>12</sup> Jones and a linear dynamic range of 180 dB. Furthermore, the unpackaged devices exhibit ultra-high stability in device performance after 60 days of storage in air (25 °C, 50% humidity), with the device performance remaining above 90%.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":48779,"journal":{"name":"Nano-Micro Letters","volume":"14 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2022-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9640512/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10463298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Oxygen Functionalization-Induced Charging Effect on Boron Active Sites for High-Yield Electrocatalytic NH3 Production 氧官能化对硼活性位点的充电效应促进高产电催化 NH3 生产

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2022-11-05 DOI: 10.1007/s40820-022-00966-7

Ashmita Biswas, Samadhan Kapse, Ranjit Thapa, Ramendra Sundar Dey

引用次数: 0