Applied Magnetic Resonance最新文献

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Observing Solid–Solid Phase Transitions in Two Alkanes and Natural Wax with Multidimensional NMR Relaxometry 用多维核磁共振弛豫法观察两种烷烃和天然蜡的固固相变
IF 1.1 4区 物理与天体物理
Applied Magnetic Resonance Pub Date : 2025-02-12 DOI: 10.1007/s00723-025-01751-6
Madison L. Nelson, Linn W. Thrane, Sarah L. Codd, Jonathan L. Cape, Christopher D. Craig, Amanda Pluntze, Joseph D. Seymour
{"title":"Observing Solid–Solid Phase Transitions in Two Alkanes and Natural Wax with Multidimensional NMR Relaxometry","authors":"Madison L. Nelson,&nbsp;Linn W. Thrane,&nbsp;Sarah L. Codd,&nbsp;Jonathan L. Cape,&nbsp;Christopher D. Craig,&nbsp;Amanda Pluntze,&nbsp;Joseph D. Seymour","doi":"10.1007/s00723-025-01751-6","DOIUrl":"10.1007/s00723-025-01751-6","url":null,"abstract":"<div><p>Nuclear magnetic resonance (NMR) spin–spin <i>T</i><sub>2</sub> relaxation is applied to characterize structural rearrangements in solid–solid phase transitions of lipids. 1D <i>T</i><sub>2</sub> relaxation distributions as a function of temperature indicate solid–solid transitions not easily discernible by differential scanning calorimetry (DSC). <i>T</i><sub>2</sub>–<i>T</i><sub>2</sub> correlation exchange measurements are demonstrated to be sensitive to spin-diffusion, allowing measurement of morphological length scales related to solid–solid molecular structure rearrangement by NMR relaxometry. <i>T</i><sub>2</sub> dispersion distributions indicate radio frequency pulse separation time dependence which alters with morphology and temperature. The NMR relaxometry data are complementary to DSC and has potential for bench top low field NMR implementation.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"56 6","pages":"723 - 747"},"PeriodicalIF":1.1,"publicationDate":"2025-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00723-025-01751-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144073586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Copper (II) EPR in Amino Phosphonic Polyampholytes 氨基膦多两性电解质中的铜(II) EPR
IF 1.1 4区 物理与天体物理
Applied Magnetic Resonance Pub Date : 2025-02-03 DOI: 10.1007/s00723-025-01750-7
Vitaly I. Volkov, Irina A. Avilova
{"title":"Copper (II) EPR in Amino Phosphonic Polyampholytes","authors":"Vitaly I. Volkov,&nbsp;Irina A. Avilova","doi":"10.1007/s00723-025-01750-7","DOIUrl":"10.1007/s00723-025-01750-7","url":null,"abstract":"<div><p>Copper (II) interaction and ion-exchange kinetics with dimethylamine (PA-1), trimethylamine (PA-2), pyridine (PA-3), phosphonoamine (PA-4), ethylene diamine phosphonic (PA-5, PA-6, PA-7), diethylamine (PA-8) ampholytes and phosphonic acid cationite CMF were investigated. In PA-1, PA-2, PA-3, PA-4, and PA-8, ethylene diamine phosphonic ampholytes (PA-5, PA-6, PA-7) and phosphonic acid cationite CMF Cu(R-HPO<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub> (A) and aqua complexes [Cu (H<sub>2</sub>O)<sub>6</sub>]<sup>2+</sup>are forming. The ampholyte polymer matrix structure consists of two packaging density segments. In the first place copper, (II) occupy high density region with a low water content where complex structure is Cu(R-HPO<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>. The self-diffusion coefficient of Cu<sup>2+</sup> calculated on the basis of EPR spectra analysis is in agreement with self-diffusion coefficient measured by radioactive-tracer technique. In ethylene diamine phosphonic polyampholytes PA-5, PA-6, PA-7 copper (II) forms stable complexes with amino group nitrogen atoms containing 4 (D) or 2 nitrogen atoms (E). In PA-5, PA-7 complexes with 2 and 4 nitrogen atoms and Cu(R-HPO<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub> are formed. In PA-6, isotropic line F appeared, which belongs to E complexes where Cu<sup>2+</sup> is exchange coupled to each other. In PA-7, EPR spectra consist of line A, line E and isotropic line G of copper (II) aqua complexes. Such multiversity of copper (II) complexes is due to these polyampholytes’ chemical inhomogeneity. Copper (II) sorption and desorption kinetics depending on outer aqueous solution concentration (CuSO<sub>4</sub> or HCl) and ampholyte grain diameters were investigated. Desorption kinetic curves are approximated by external diffusion and diffusion with moving boundary mechanisms.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"56 5","pages":"649 - 667"},"PeriodicalIF":1.1,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877709","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
FAME: A Federated Adversarial Learning Framework for Privacy-Preserving MRI Reconstruction FAME:用于保护隐私的MRI重建的联邦对抗学习框架
IF 1.1 4区 物理与天体物理
Applied Magnetic Resonance Pub Date : 2025-01-25 DOI: 10.1007/s00723-025-01749-0
Shahzad Ahmed, Jinchao Feng, Javed Ferzund, Muhammad Yaqub, Muhammad Usman Ali, Malik Abdul Manan, Abdul Raheem
{"title":"FAME: A Federated Adversarial Learning Framework for Privacy-Preserving MRI Reconstruction","authors":"Shahzad Ahmed,&nbsp;Jinchao Feng,&nbsp;Javed Ferzund,&nbsp;Muhammad Yaqub,&nbsp;Muhammad Usman Ali,&nbsp;Malik Abdul Manan,&nbsp;Abdul Raheem","doi":"10.1007/s00723-025-01749-0","DOIUrl":"10.1007/s00723-025-01749-0","url":null,"abstract":"<div><p>Magnetic Resonance Imaging (MRI) is a crucial tool in medical diagnostics, yet reconstructing high-quality images from under-sampled k-space data poses significant challenges. This study introduces Federated Adversarial MRI Enhancement (FAME), a novel framework combining Federated Learning (FL) with Generative Adversarial Networks (GANs) to enhance MRI reconstruction while maintaining patient privacy. FAME utilizes a hybrid model aggregation strategy that dynamically weights updates from local generators, ensuring a balanced contribution based on dataset size and quality. Each local generator is trained on-site-specific data, while a global discriminator evaluates and refines the aggregated updates to improve image quality. FAME addresses key issues in medical imaging, including data privacy, model generalization, and robustness, by integrating advanced GAN architectures such as multi-scale convolutions, attention mechanisms, and Graph Neural Networks (GNNs). Differential privacy and secure aggregation protocols are implemented to protect sensitive data during training. Extensive experiments using the fastMRI Brain and Knee datasets, along with the BraTS 2020 and IXI dataset, show that FAME outperforms existing models, achieving superior PSNR and SSIM values. This decentralized framework offers scalable, privacy-preserving MRI reconstruction, making it a promising solution for diverse clinical applications.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"56 6","pages":"681 - 722"},"PeriodicalIF":1.1,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144073744","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electron Paramagnetic Resonance and Magnetization Insights into Size-Induced Charge Order ‘Melting’ in Nanoparticles of Sm0.42Ca0.58MnO3 Sm0.42Ca0.58MnO3纳米颗粒尺寸诱导电荷序“熔化”的电子顺磁共振和磁化研究
IF 1.1 4区 物理与天体物理
Applied Magnetic Resonance Pub Date : 2025-01-13 DOI: 10.1007/s00723-024-01746-9
Pratheek, Narmada Hegde, Balachandra G. Hegde, S. V. Bhat
{"title":"Electron Paramagnetic Resonance and Magnetization Insights into Size-Induced Charge Order ‘Melting’ in Nanoparticles of Sm0.42Ca0.58MnO3","authors":"Pratheek,&nbsp;Narmada Hegde,&nbsp;Balachandra G. Hegde,&nbsp;S. V. Bhat","doi":"10.1007/s00723-024-01746-9","DOIUrl":"10.1007/s00723-024-01746-9","url":null,"abstract":"<div><p>When cooled, some manganites of the general form RE<sub>1-x</sub>A<sub>x</sub>Mn<sup>3+</sup><sub>1-x</sub>Mn<sup>4+</sup><sub>x</sub>O<sub>3</sub> where RE is a trivalent rare earth or Bi<sup>3+</sup> ion and A is a divalent alkaline earth ion, undergo a ‘charge ordering’ (CO) transition resulting in a periodic ‘ordered’ arrangement of the Mn<sup>3+</sup> and Mn<sup>4+</sup> ions in the crystal lattice leading to an increase in the resistivity and antiferromagnetic ordering. Size reduction to nanoscale is an intrinsic way of destabilizing CO for achieving properties, such as room temperature colossal magnetoresistance, important for applications. Here, we address the still unsettled question in this context of whether this size induced ‘melting’ of CO in manganites is complete or if some charge order persists at short range, through comprehensive electron paramagnetic resonance (EPR) and magnetic studies of nanoparticles of Sm<sub>0.42</sub>Ca<sub>0.58</sub>MnO<sub>3</sub> and those of the bulk counterpart for comparison. The nanosized samples were prepared by microwave assisted reverse micelle method by optimizing the choice of the surfactant as well as the water to surfactant ratio to obtain particles of minimum size and polydispersity. The crystallite and particle sizes were estimated by X-ray diffraction and transmission electron microscopy. The valence states of the manganese ions on the surface of the particles were determined by X-ray photoemission spectroscopy. The near-total absence of the tell-tale signatures of CO viz. the peaks in magnetization and EPR intensity and the minimum in the EPR linewidth at the CO temperature T<sub>CO</sub> point towards a complete disappearance of charge order in sufficiently small and monodisperse nanomanganites.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"56 5","pages":"631 - 647"},"PeriodicalIF":1.1,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877708","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Direct Approach to Pulse Dipolar Spectroscopy Measurement of Mean Distance between Spins by Electron Paramagnetic Resonance 脉冲偶极光谱测量电子顺磁共振自旋平均距离的直接方法
IF 1.1 4区 物理与天体物理
Applied Magnetic Resonance Pub Date : 2025-01-09 DOI: 10.1007/s00723-024-01748-7
V. M. Nekrasov, A. G. Matveeva, V. N. Syryamina, S. A. Agarkin, M. K. Bowman
{"title":"Direct Approach to Pulse Dipolar Spectroscopy Measurement of Mean Distance between Spins by Electron Paramagnetic Resonance","authors":"V. M. Nekrasov,&nbsp;A. G. Matveeva,&nbsp;V. N. Syryamina,&nbsp;S. A. Agarkin,&nbsp;M. K. Bowman","doi":"10.1007/s00723-024-01748-7","DOIUrl":"10.1007/s00723-024-01748-7","url":null,"abstract":"<div><p>An analytical approach is demonstrated for the direct calculation of the mean distance between a pair of spins from pulse dipolar spectroscopy measurements by electron paramagnetic resonance. This direct approach uses the Mellin integral transform and does not measure the spectrum of distances between spins, offering substantial increases in sensitivity. The approach provides accurate a priori prediction of the uncertainty for a mean distance measurement, based only on experimental measurement parameters and the final signal-to-noise ratio. The feasibility of this approach is confirmed by comparison with the standard indirect approaches using a set of in silico measurements. The new approach demonstrates comparable accuracy and possibilities for enhancing sensitivity.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"56 6","pages":"669 - 680"},"PeriodicalIF":1.1,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144073912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing Generalization and Mitigating Overfitting in Deep Learning for Brain Cancer Diagnosis from MRI 在MRI脑癌诊断的深度学习中增强泛化和减轻过拟合
IF 1.1 4区 物理与天体物理
Applied Magnetic Resonance Pub Date : 2025-01-03 DOI: 10.1007/s00723-024-01743-y
Mohamad Abou Ali, Jinan Charafeddine, Fadi Dornaika, Ignacio Arganda-Carreras
{"title":"Enhancing Generalization and Mitigating Overfitting in Deep Learning for Brain Cancer Diagnosis from MRI","authors":"Mohamad Abou Ali,&nbsp;Jinan Charafeddine,&nbsp;Fadi Dornaika,&nbsp;Ignacio Arganda-Carreras","doi":"10.1007/s00723-024-01743-y","DOIUrl":"10.1007/s00723-024-01743-y","url":null,"abstract":"<div><p>Brain cancer represents a significant global health challenge with increasing incidence and mortality rates. Magnetic Resonance Imaging (MRI) plays a pivotal role in early detection and treatment planning. This study adopts a systematic approach across four phases: (1) Optimal Model Selection using the Adam optimizer, emphasizing accuracy metrics, weight computation, early stopping, and ReduceLROnPlateau techniques. (2) Real-world Scenario Simulation through synthetic perturbed datasets created by applying noise, blur (to simulate various magnetic field strengths: 1T, 1.5T, 3T), and patient motion artifacts (mimicking MRI scanning motion effects) to the testing data from the BT-MRI dataset, an online published brain tumor MRI dataset. (3) Optimization involving a range of optimizers (Adam, Adagrad, Nadam, RMSprop, SGD) and online augmentation techniques (AutoMix, CutMix, LGCOAMix, PatchUp). (4) Solution Exploration integrating Gaussian Noise and Blur as augmentation strategies during training to enhance model generalization under diverse conditions. Initial evaluations achieved strong performance, consistently reaching 99.45% accuracy on the BT-MRI dataset. However, testing against synthetic perturbed datasets mimicking real-world conditions revealed challenges in maintaining robust model performance. Despite employing diverse optimization methods and advanced augmentation techniques, this study identifies persistent challenges in ensuring model robustness with synthetic perturbed datasets. Notably, the integration of Gaussian Noise and Blur during training significantly improved model resilience. This research underscores the critical role of methodological rigor and innovative augmentation strategies in advancing deep learning applications for precise brain cancer diagnosis using MRI.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"56 3","pages":"359 - 394"},"PeriodicalIF":1.1,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143471857","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Robustness and Sensitivity of Gd(III)–Gd(III) Double Electron–Electron Resonance (DEER) Measurements: Comparative Study of High-Frequency EPR Spectrometer Designs and Spin Label Variants Gd(III) -Gd (III)双电子-电子共振(DEER)测量的鲁棒性和灵敏度:高频EPR光谱仪设计和自旋标签变体的比较研究
IF 1.1 4区 物理与天体物理
Applied Magnetic Resonance Pub Date : 2025-01-03 DOI: 10.1007/s00723-024-01741-0
Elena M. Mocanu, Yasmin Ben-Ishay, Lydia Topping, S. Ronan Fisher, Robert I. Hunter, Xun-Cheng Su, Stephen J. Butler, Graham M. Smith, Daniella Goldfarb, Janet E. Lovett
{"title":"Robustness and Sensitivity of Gd(III)–Gd(III) Double Electron–Electron Resonance (DEER) Measurements: Comparative Study of High-Frequency EPR Spectrometer Designs and Spin Label Variants","authors":"Elena M. Mocanu,&nbsp;Yasmin Ben-Ishay,&nbsp;Lydia Topping,&nbsp;S. Ronan Fisher,&nbsp;Robert I. Hunter,&nbsp;Xun-Cheng Su,&nbsp;Stephen J. Butler,&nbsp;Graham M. Smith,&nbsp;Daniella Goldfarb,&nbsp;Janet E. Lovett","doi":"10.1007/s00723-024-01741-0","DOIUrl":"10.1007/s00723-024-01741-0","url":null,"abstract":"<div><p>In this paper, we explore the robustness and sensitivity of Gd(III)-Gd(III) double electron–electron resonance (DEER) distance measurements in proteins for different spectrometer designs and three spin labels. To do this a protein was labeled at the same two positions with Gd(III) spin labels and measurements were performed on two home-built high-frequency (W-band, ~ 95 GHz) EPR spectrometers with different design approaches, and a commercial 150 W Q-band (34 GHz) spectrometer. The first W-band measurement approach uses a conventional, narrow band single mode cavity, while the second uses a broadband non-resonant induction mode sample holder. Both systems incorporate advanced arbitrary waveform generators (AWGs) that give flexibility over excitation bandwidth. We use three DOTA-like Gd(III) spin labels, Gd.C12, Gd.DO3A and Gd.L<sup>1</sup>, conjugated to the calmodulin protein. We compare measurements taken by including or excluding the Gd(III) central transition excitation. The advantages and disadvantages of the EPR spectrometers for the measurement of Gd(III)–Gd(III) DEER are discussed in terms of the robustness of the resulting distance distribution width, absolute and concentration sensitivity, sample handling, ease of use, and flexibility of measurement.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"56 5","pages":"591 - 611"},"PeriodicalIF":1.1,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00723-024-01741-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Cylindrical Surface Dielectric Resonator with Substantially High Sensitivity for Deep-Tissue EPR Oximetry 具有高灵敏度的圆柱形表面介电谐振器用于深层组织EPR氧饱和度测定
IF 1.1 4区 物理与天体物理
Applied Magnetic Resonance Pub Date : 2024-12-31 DOI: 10.1007/s00723-024-01747-8
Sergey V. Petryakov, Maciej M. Kmiec, Ryan C. O’Connell, Conner S. Ubert, Victor B. Kassey, Philip E. Schaner, Periannan Kuppusamy
{"title":"A Cylindrical Surface Dielectric Resonator with Substantially High Sensitivity for Deep-Tissue EPR Oximetry","authors":"Sergey V. Petryakov,&nbsp;Maciej M. Kmiec,&nbsp;Ryan C. O’Connell,&nbsp;Conner S. Ubert,&nbsp;Victor B. Kassey,&nbsp;Philip E. Schaner,&nbsp;Periannan Kuppusamy","doi":"10.1007/s00723-024-01747-8","DOIUrl":"10.1007/s00723-024-01747-8","url":null,"abstract":"<div><p>Electron paramagnetic resonance (EPR) has been established as a unique and reliable method for quantitative in vivo oximetry applicable to a variety of preclinical and clinical studies. A recent clinical study using EPR oximetry with OxyChip from our laboratory demonstrated the feasibility of tumor oxygen measurements in cancer patients (Schaner, et al. Front. Oncol. 2021). During this study, the need to improve oxygen measurement capability in tumors at depths greater than 10 mm became apparent. This prompted us to develop new designs of resonators (RF coils) with enhanced sensitivity for measuring deep-tissue oxygen levels. In this manuscript, we report the development of a new cylindrical surface dielectric resonator (c-SDR) designed with a ceramic dielectric material for substantially enhanced sensitivity and capability for deep-tissue oximetry. The c-SDR was constructed with a cylindrical dielectric material (<i>ϕ</i> 27.2 × 22.2 mm; <i>ε</i> = 160), 6-segmented coupling loop and copper shield to provide an active surface (aperture) of 25 mm with an operating frequency of 1.16 GHz (L-band) and an unloaded <i>Q</i> 600. The resonator could detect OxyChip (<i>ϕ</i> 0.6 × 5 mm) at a surface-to-sample depth of 50 mm in water or 30 mm in a tissue-emulating phantom with a signal-to-noise ratio of 5. Further evaluations of the c-SDR using OxyChip demonstrated its capability for oxygen measurements at depths of 27 mm for 1% oxygen and 15 mm for 5% oxygen in a tissue phantom. In conclusion, the new c-SDR is a significant upgrade to the currently used resonators for in vivo EPR oximetry including clinical oximetry.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"56 5","pages":"613 - 629"},"PeriodicalIF":1.1,"publicationDate":"2024-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877735","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Derivation of Multi-Exponential Magnetic Resonance Relaxation Equations in Simple Pore Geometries 简单孔隙几何中多指数磁共振弛豫方程的推导
IF 1.1 4区 物理与天体物理
Applied Magnetic Resonance Pub Date : 2024-12-24 DOI: 10.1007/s00723-024-01729-w
Armin Afrough
{"title":"Derivation of Multi-Exponential Magnetic Resonance Relaxation Equations in Simple Pore Geometries","authors":"Armin Afrough","doi":"10.1007/s00723-024-01729-w","DOIUrl":"10.1007/s00723-024-01729-w","url":null,"abstract":"<div><p>The common interpretation of magnetic resonance relaxation time distribution of liquids in porous media assumes a one-to-one relationship between the pore size and the relaxation time constants. This common conviction may not be correct in many microporous materials. Each pore size may be associated with more than one peak in the NMR relaxation time distributions: a single dominant peak and also possibly one or a few minor peaks. The appearance of minor peaks is due to the non-vanishing nonground eigenvalues of the diffusion–relaxation equation. Brownstein and Tarr (Phys Rev A 19:2446, 1979) described these features, but their solutions at conditions beyond the fast-diffusion regime are not widely adopted. We provide the derivation of Brownstein–Tarr equations for multi-exponential magnetic resonance relaxation decay for liquids in simple pore geometries. General solutions are presented for planar, cylindrical, and spherical pores—as well as two limiting cases of fast and slow diffusion for each geometry. Similar solutions are also relevant to first-order dilute reactions in porous media in heterogeneous reaction–diffusion systems. We hope that the availability of these derivations helps wider adoption of more realistic interpretation of magnetic resonance relaxation in porous media in the light of the multi-exponential Brownstein–Tarr model.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"56 3","pages":"313 - 358"},"PeriodicalIF":1.1,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00723-024-01729-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143471856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of Water-Soluble Tocopherol Compositions Based on N-Vinylpyrrolidone Polymers and Exploration of the Molecular Exchange Process in Aqueous Solutions Using High-Resolution and Pulsed Field Gradient NMR Techniques 基于n -乙烯基吡咯烷酮聚合物的水溶性生育酚组合物的制备及高分辨率和脉冲场梯度核磁共振技术在水溶液中的分子交换过程的探索
IF 1.1 4区 物理与天体物理
Applied Magnetic Resonance Pub Date : 2024-12-21 DOI: 10.1007/s00723-024-01744-x
Svetlana V. Kurmaz, Ksenia V. Panicheva, Irina A. Avilova, Sergey G. Vasil’ev
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