Acta Metallurgica Sinica-English Letters最新文献

筛选
英文 中文
Effect of K2HPO4 Concentration on the Formation, Structure, Composition and Protectiveness of Conversion Coating Deposited on AZ31 Magnesium Alloy K2HPO4浓度对AZ31镁合金转化涂层形成、结构、组成及防护性能的影响
IF 2.9 2区 材料科学
Acta Metallurgica Sinica-English Letters Pub Date : 2025-01-22 DOI: 10.1007/s40195-025-01815-3
Liping Wu, Junhua Dong, Xianfei Zheng, Zhongying Wang, Xiaoying Sun, Xiuling Shang, Wei Ke, Changgang Wang
{"title":"Effect of K2HPO4 Concentration on the Formation, Structure, Composition and Protectiveness of Conversion Coating Deposited on AZ31 Magnesium Alloy","authors":"Liping Wu,&nbsp;Junhua Dong,&nbsp;Xianfei Zheng,&nbsp;Zhongying Wang,&nbsp;Xiaoying Sun,&nbsp;Xiuling Shang,&nbsp;Wei Ke,&nbsp;Changgang Wang","doi":"10.1007/s40195-025-01815-3","DOIUrl":"10.1007/s40195-025-01815-3","url":null,"abstract":"<div><p>In deaerated 0.05 M, 0.1 M, 0.2 M and 0.5 M K<sub>2</sub>HPO<sub>4</sub> solutions with pH 9.5, AZ31 magnesium (Mg) alloy was subjected to potentiostatic polarization at − 0.8 V<sub>SCE</sub> to deposit a phosphate conversion coating. The morphology, structure, chemical composition, and protective performance of the conversion coating during the formation process were characterized. The results showed that amorphous Mg(OH)<sub>2</sub> and MgHPO<sub>4</sub> and crystallized KMgPO<sub>4</sub>·6H<sub>2</sub>O (struvite–K) were successively deposited on the surface of AZ31 Mg alloy in the four solutions. MgHPO<sub>4</sub> was converted from Mg(OH)<sub>2</sub>, while struvite–K was transformed from MgHPO<sub>4</sub>. The distribution of Mg(OH)<sub>2</sub>, MgHPO<sub>4</sub> and struvite–K along the thickness of the coating differs with K<sub>2</sub>HPO<sub>4</sub> concentration. As the concentration of K<sub>2</sub>HPO<sub>4</sub> increased, the coating time was gradually shortened, and the coating was gradually thinned. Meanwhile, the ratio of the nucleation rate to the growth rate of struvite–K crystal nuclei increased, resulting in a decrease in the size of struvite–K crystal. When the concentration of K<sub>2</sub>HPO<sub>4</sub> increased from 0.05 to 0.1 M, the content of struvite–K increased, and the protective performance of the coating was enhanced. However, as the concentration of K<sub>2</sub>HPO<sub>4</sub> continued to increase to 0.5 M, the content of struvite–K and the protective performance of the coating decreased.</p></div>","PeriodicalId":457,"journal":{"name":"Acta Metallurgica Sinica-English Letters","volume":"38 3","pages":"481 - 496"},"PeriodicalIF":2.9,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143521669","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermoelectric Performance of Layered PbBi4Te7 Compound 层状PbBi4Te7化合物的热电性能
IF 2.9 2区 材料科学
Acta Metallurgica Sinica-English Letters Pub Date : 2025-01-22 DOI: 10.1007/s40195-024-01811-z
Hong Zeng, Liqing Xu, Wei Liu, Xinxiu Cheng, Wenke He, Yu Xiao
{"title":"Thermoelectric Performance of Layered PbBi4Te7 Compound","authors":"Hong Zeng,&nbsp;Liqing Xu,&nbsp;Wei Liu,&nbsp;Xinxiu Cheng,&nbsp;Wenke He,&nbsp;Yu Xiao","doi":"10.1007/s40195-024-01811-z","DOIUrl":"10.1007/s40195-024-01811-z","url":null,"abstract":"<div><p>The layered PbBi<sub>4</sub>Te<sub>7</sub> compound is considered a promising thermoelectric material due to its unusually high electrical transport properties in ternary compound systems. However, its high carrier concentration leads to relatively high thermal conductivity and low Seebeck coefficient, limiting the enhancement of its thermoelectric performance. In this work, we introduce Se alloying and Cu doping to synergistically regulate the thermoelectric transport properties of PbBi<sub>4</sub>Te<sub>7</sub>. Se alloying induces strong lattice contraction and increased interlayer electron scattering, significantly reducing lattice thermal conductivity while enhancing the Seebeck coefficient. Besides, Cu doping forms interlayer electron transport channels thus optimizing carrier mobility and electrical transport properties. Cu substitution also enhances point defect scattering further suppressing phonon transport. Ultimately, the strong anharmonic structure formed by Se alloying and Cu-induced phonon scattering results in a remarkably low lattice thermal conductivity of 0.27 W m<sup>−1</sup> K<sup>−1</sup> at 300 K in PbBi<sub>4</sub>Te<sub>5</sub>Se<sub>2</sub>-0.1% Cu samples. The maximum thermoelectric figure of merit (<i>ZT</i><sub>max</sub>) is increased to 0.68, with an average thermoelectric figure of merit (<i>ZT</i><sub>ave</sub>) of 0.56 in the near-room temperature range (300–573 K), outperforming other typical ternary Pb-Bi-based compounds.</p></div>","PeriodicalId":457,"journal":{"name":"Acta Metallurgica Sinica-English Letters","volume":"38 5","pages":"772 - 780"},"PeriodicalIF":2.9,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143892625","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Mineralization Induced by Shewanella algae on Passive Film of Stainless Steel via FIB-SEM/TEM and EELS Shewanella藻矿化对不锈钢钝化膜的影响(FIB-SEM/TEM和EELS
IF 3.9 2区 材料科学
Acta Metallurgica Sinica-English Letters Pub Date : 2025-01-22 DOI: 10.1007/s40195-025-01816-2
Li Zhao, Tian-Yu Cui, Wei-Wei Chang, Hong-Chang Qian, Yun-Tian Lou, Jing-Zhi Yang, Da-Wei Zhang
{"title":"Effect of Mineralization Induced by Shewanella algae on Passive Film of Stainless Steel via FIB-SEM/TEM and EELS","authors":"Li Zhao,&nbsp;Tian-Yu Cui,&nbsp;Wei-Wei Chang,&nbsp;Hong-Chang Qian,&nbsp;Yun-Tian Lou,&nbsp;Jing-Zhi Yang,&nbsp;Da-Wei Zhang","doi":"10.1007/s40195-025-01816-2","DOIUrl":"10.1007/s40195-025-01816-2","url":null,"abstract":"<div><p>The adhesion of <i>Shewanella algae</i> (<i>S. algae</i>) on the surface of stainless steel induced the formation and coverage of calcium carbonate minerals in the aerobic environment, and the effect of these minerals on the passive film of stainless steel was investigated by focused ion beam-scanning electron microscopy/transmission electron microscopy (FIB-SEM/TEM) and electron energy loss spectroscopy (EELS) techniques. The TEM and energy-dispersive X-ray spectroscopy (EDS) results revealed that the passive film in the region covered by mineralized particles underwent chelation between Fe and Cr compounds with CaCO<sub>3</sub>, forming an unstable amorphous layer, which accelerated the loss of Fe and Cr elements. EELS analysis showed that the loss of Fe element in the passive film was the most significant, with a transition from Fe<sup>3+</sup> to soluble Fe<sup>2+</sup> occurring, which caused by the iron-reducing property and metabolic activities of the adherent <i>S. algae</i>. The loss of the main metal elements caused the accelerated degradation of the passive film beneath the minerals.</p></div>","PeriodicalId":457,"journal":{"name":"Acta Metallurgica Sinica-English Letters","volume":"38 6","pages":"877 - 888"},"PeriodicalIF":3.9,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145168180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In-Depth Understanding the Retained Austenite Stability on the Susceptibility of Multi-Alloying Ultra-Strength Steel to Hydrogen-Induced Cracking 残留奥氏体稳定性对多合金化超强钢氢致开裂敏感性的深入研究
IF 2.9 2区 材料科学
Acta Metallurgica Sinica-English Letters Pub Date : 2025-01-22 DOI: 10.1007/s40195-024-01809-7
Chao Hai, Kang Huang, Cuiwei Du, Xiaogang Li
{"title":"In-Depth Understanding the Retained Austenite Stability on the Susceptibility of Multi-Alloying Ultra-Strength Steel to Hydrogen-Induced Cracking","authors":"Chao Hai,&nbsp;Kang Huang,&nbsp;Cuiwei Du,&nbsp;Xiaogang Li","doi":"10.1007/s40195-024-01809-7","DOIUrl":"10.1007/s40195-024-01809-7","url":null,"abstract":"<div><p>Hydrogen-induced cracking (HIC) is one of the most complex material problems that hydrogen can diffuse into and interact with microstructure, degrading their mechanical properties. Microstructural modification is an effective way to enhance the resistance to HIC. The present study focused on the relationship between the retained austenite (RA) and HIC behavior in NiCrMoV/Nb multi-alloying ultra-strength steel. Results demonstrated that the maximum volume fraction of RA of 9.31% was obtained for QL<sub>30</sub>T specimen. After the deep cryogenic pretreatment, the volume fraction of RA reduced to 8.8%. RA could reduce the effective diffusion coefficient, while deep cryogenic pretreatment increased the susceptibility of the steel to HIC by a maxim of 14.8%. This was mainly due to the transformation of retained austenite into martensite, degrading the mechanical properties under hydrogen-charged condition. In addition, the deep cryogenic pretreatment had a significant effect on the crack initiation and propagation, with the intergranular (IG) fracture becoming the dominant fracture mode where an increase in the number of secondary cracks in the section. The interfaces of RA and matrix, as well as the grain boundaries, were the preferred sites for cracks initiation.</p></div>","PeriodicalId":457,"journal":{"name":"Acta Metallurgica Sinica-English Letters","volume":"38 4","pages":"691 - 704"},"PeriodicalIF":2.9,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143830936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In Vitro Corrosion Behavior and Mechanical Property of Novel Mg–Sn–In–Ga Alloys for Orthopedic Applications 新型骨科用Mg-Sn-In-Ga合金的体外腐蚀行为和力学性能
IF 2.9 2区 材料科学
Acta Metallurgica Sinica-English Letters Pub Date : 2025-01-16 DOI: 10.1007/s40195-024-01800-2
Jing Wang, Xuejian Wang, Zongning Chen, Huijun Kang, Tongmin Wang, Enyu Guo
{"title":"In Vitro Corrosion Behavior and Mechanical Property of Novel Mg–Sn–In–Ga Alloys for Orthopedic Applications","authors":"Jing Wang,&nbsp;Xuejian Wang,&nbsp;Zongning Chen,&nbsp;Huijun Kang,&nbsp;Tongmin Wang,&nbsp;Enyu Guo","doi":"10.1007/s40195-024-01800-2","DOIUrl":"10.1007/s40195-024-01800-2","url":null,"abstract":"<div><p>This study develops novel Mg–Sn–In–Ga alloys as potential implant materials for orthopedic applications. The corrosion behavior of the Mg–Sn–In–Ga alloys was studied through mass loss measurements, hydrogen evolution measurements, electrochemical analysis, and corrosion morphology observations. The results show that the corrosion rate of the Mg–1Sn–1In–1Ga alloy was only 0.10 ± 0.003 mm/y after immersion in Hank’s solution for 15 days. This outstanding corrosion resistance was associated with the protective effect of the corrosion products. The increase in the Sn and Ga element content led to the precipitation of a large amount of Mg<sub>2</sub>Sn and Mg<sub>5</sub>Ga<sub>2</sub>, which had a dominant effect on the corrosion rate in the Mg–5Sn–1In–2Ga alloy. These precipitates increased the current density and detached from the alloy surface during the corrosion process. This can lead to a weakened protective effect of the corrosion layer, and thus generate localized corrosion and an increase in the corrosion rate. The strength of the Mg–5Sn–1In–2Ga alloy was enhanced due to fine-grain strengthening and precipitation strengthening. The ultimate tensile strength and yield strength of the Mg–5Sn–1In–2Ga alloy were ~ 309 MPa and ~ 253 MPa, respectively.</p></div>","PeriodicalId":457,"journal":{"name":"Acta Metallurgica Sinica-English Letters","volume":"38 3","pages":"353 - 366"},"PeriodicalIF":2.9,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143521700","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Copper Precipitation Behavior and Mechanical Properties of Cu-Bearing Ferritic Stainless Steel with Different Cr Addition 不同Cr添加量含cu铁素体不锈钢的铜析出行为及力学性能
IF 2.9 2区 材料科学
Acta Metallurgica Sinica-English Letters Pub Date : 2025-01-15 DOI: 10.1007/s40195-025-01814-4
Yifan Li, Shengyao Ma, Xinrui Zhang, Tong Xi, Chunguang Yang, Hanyu Zhao, Ke Yang
{"title":"Copper Precipitation Behavior and Mechanical Properties of Cu-Bearing Ferritic Stainless Steel with Different Cr Addition","authors":"Yifan Li,&nbsp;Shengyao Ma,&nbsp;Xinrui Zhang,&nbsp;Tong Xi,&nbsp;Chunguang Yang,&nbsp;Hanyu Zhao,&nbsp;Ke Yang","doi":"10.1007/s40195-025-01814-4","DOIUrl":"10.1007/s40195-025-01814-4","url":null,"abstract":"<div><p>The microstructure evolution and mechanical properties of Cu-bearing ferritic stainless steel with different Cr addition (Cr = 12, 15 and 17 wt%) were investigated. The phase transformation behavior under different cooling rate, Cu-rich precipitation behavior and its influence on the mechanical properties under different aging treatment are systematically characterized using dilatometry, differential scanning calorimeter (DSC) and transmission electron microscopy (TEM). The results indicated that the increase in Cr content narrowed the austenite phase region at high temperatures, affecting its microstructure under different cooling rates. The 12Cr-1.5Cu steel exhibited a fully austenitic phase region at high temperature and occurred apparent martensitic transformation after air cooling. Cooling rate significantly influenced the phase transition of the steels, and subsequently affected its mechanical properties. All three investigated steels showed higher strength and lower plasticity in air cooling condition compared to furnace cooling condition, due to the presence of martensite. After aging treatment, high number densities of Cu-rich precipitates were formed in steel matrix and the size of Cu-rich precipitates increased obviously with increasing aging temperature, while the tendency for number density was opposite. Fine and dispersed Cu-rich precipitates formed during low-temperature aging enhanced strength of the steels, while larger Cu-rich phases developed during high-temperature aging endowed greater ductility to the steels. Notably, the Cr content had no significant effect on the precipitation behavior of Cu-rich precipitation. These comprehensive results and analyses could provide a solid foundation for broader applications of Cu-bearing ferritic stainless steels.</p></div>","PeriodicalId":457,"journal":{"name":"Acta Metallurgica Sinica-English Letters","volume":"38 3","pages":"383 - 395"},"PeriodicalIF":2.9,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143521699","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Novel BCC/B2 Structural Nb38Ti35Al15V6Cr4(TaHfMoW)2 Refractory High-Entropy Alloy with Excellent Specific Yield Strength-Plasticity Synergy 新型BCC/B2结构Nb38Ti35Al15V6Cr4(TaHfMoW)2耐火高熵合金,具有优异的比屈服强度-塑性协同效应
IF 2.9 2区 材料科学
Acta Metallurgica Sinica-English Letters Pub Date : 2025-01-13 DOI: 10.1007/s40195-024-01805-x
Hongbin Liu, Zhenqiang Xing, Yitong Yang, Jingyu Pang, Wen Li, Zhengwang Zhu, Long Zhang, Aimin Wang, Haifeng Zhang, Hongwei Zhang
{"title":"A Novel BCC/B2 Structural Nb38Ti35Al15V6Cr4(TaHfMoW)2 Refractory High-Entropy Alloy with Excellent Specific Yield Strength-Plasticity Synergy","authors":"Hongbin Liu,&nbsp;Zhenqiang Xing,&nbsp;Yitong Yang,&nbsp;Jingyu Pang,&nbsp;Wen Li,&nbsp;Zhengwang Zhu,&nbsp;Long Zhang,&nbsp;Aimin Wang,&nbsp;Haifeng Zhang,&nbsp;Hongwei Zhang","doi":"10.1007/s40195-024-01805-x","DOIUrl":"10.1007/s40195-024-01805-x","url":null,"abstract":"<div><p>Refractory high-entropy alloys (RHEAs) stand as promising candidates for the development of a new generation of high-temperature materials due to their exceptional mechanical properties. However, the inherent low ductility and high density of RHEAs have hindered their widespread adoption in industrial applications. In this study, an Nb<sub>38</sub>Ti<sub>35</sub>Al<sub>15</sub>V<sub>6</sub>Cr<sub>4</sub>(TaHfMoW)<sub>2</sub> RHEA with a BCC/B2 dual-phase structure is successfully developed. The RHEA exhibits excellent specific yield strength of 162.4 MPa·g<sup>−1</sup>·cm<sup>3</sup> and 84.3 MPa·g<sup>−1</sup>·cm<sup>3</sup> at room temperature (RT) and 800 °C, respectively. It was found that the pinning effect of the B2 phase induces a gradual transition in dislocation slip mode from planar slip to cross slip, homogenizing the plastic flow and resulting in excellent compression plasticity (<i>ε</i> &gt; 50%). Additionally, the B2 phase endows the alloy with excellent yield strength at high temperatures by precipitation strengthening. Moreover, the dominated <i>a</i>/2 &lt; 111 &gt; type dislocation contributes to the alloy's superior plasticity at high temperatures.</p></div>","PeriodicalId":457,"journal":{"name":"Acta Metallurgica Sinica-English Letters","volume":"38 3","pages":"396 - 406"},"PeriodicalIF":2.9,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143521682","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Roles of Y2Zr2O7 Nano-Oxides in Helium Management in ODS Ferritic Alloys: A First-Principles Study 纳米氧化物Y2Zr2O7在ODS铁素体合金氦管理中的作用:第一性原理研究
IF 2.9 2区 材料科学
Acta Metallurgica Sinica-English Letters Pub Date : 2025-01-13 DOI: 10.1007/s40195-024-01813-x
Huajian Wu, Jieli Ma, Yong Jiang, Yiren Wang, Fuhua Cao
{"title":"Roles of Y2Zr2O7 Nano-Oxides in Helium Management in ODS Ferritic Alloys: A First-Principles Study","authors":"Huajian Wu,&nbsp;Jieli Ma,&nbsp;Yong Jiang,&nbsp;Yiren Wang,&nbsp;Fuhua Cao","doi":"10.1007/s40195-024-01813-x","DOIUrl":"10.1007/s40195-024-01813-x","url":null,"abstract":"<div><p>Y–Zr–O nano-oxide dispersion-strengthened (ODS) ferritic alloys have attracted increasing research efforts in recent years, for the enhanced nucleation and refinement of nano-oxides. Here, we report a first-principles exploration on the possible roles of Y<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub> in helium management in Y + Zr and Y + Ti + Zr co-alloyed ODS ferritic alloys. Bulk phase calculations suggested that similarly as Y<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub>, Y<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub> has a comparably strong capability for trapping helium at its interstitial sites. The equilibrium Fe/Y<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub> interface structure was further predicted as the top-coordinated O-rich at the temperature range of interest. Vacancy and helium both segregate to the Y<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub> interface, in preference to the Y<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> interface, the bulk interior of Y<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub> and the grain boundaries. In this regard, Y<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub> can be more effective than Y<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> in preventing vacancies and helium from reaching GBs. Based on these results, the profound implications for the helium tolerance of Zr-alloyed ODS ferritic alloys were discussed<b>.</b></p></div>","PeriodicalId":457,"journal":{"name":"Acta Metallurgica Sinica-English Letters","volume":"38 3","pages":"497 - 506"},"PeriodicalIF":2.9,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143521683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
One-Step Carrier Modulation and Nano-Composition Enhancing Thermoelectric and Mechanical Properties of p-Type SnSe Polycrystals by Introducing Ag9GaSe6 Compound 引入Ag9GaSe6化合物提高p型SnSe多晶热电性能和力学性能的一步载流子调制和纳米复合
IF 2.9 2区 材料科学
Acta Metallurgica Sinica-English Letters Pub Date : 2025-01-13 DOI: 10.1007/s40195-024-01810-0
Ze Li, Xing Yang, Tian-En Shi, Wang-Qi Bao, Jing Feng, Zhen-Hua Ge
{"title":"One-Step Carrier Modulation and Nano-Composition Enhancing Thermoelectric and Mechanical Properties of p-Type SnSe Polycrystals by Introducing Ag9GaSe6 Compound","authors":"Ze Li,&nbsp;Xing Yang,&nbsp;Tian-En Shi,&nbsp;Wang-Qi Bao,&nbsp;Jing Feng,&nbsp;Zhen-Hua Ge","doi":"10.1007/s40195-024-01810-0","DOIUrl":"10.1007/s40195-024-01810-0","url":null,"abstract":"<div><p>The group IV–VI semiconductor, SnSe, is abundant on the earth and is a promising thermoelectric (TE) material due to its low thermal conductivity. However, the p-type SnSe polycrystals have low electrical conductivities due to their low carrier concentration, significantly limiting their further applications. This study introduced the argyrodite-type Ag<sub>9</sub>GaSe<sub>6</sub> compound into the SnSe matrix to effectively increase the hole carrier concentration, increasing the electrical conductivity. A high electrical conductivity of 50.5 S cm<sup>−1</sup> was obtained for the SnSe + 0.5 wt% Ag<sub>9</sub>GaSe<sub>6</sub> sample at 323 K. Due to the increased electrical conductivity, the SnSe + 0.5 wt% Ag<sub>9</sub>GaSe<sub>6</sub> sample had an average power factor (<i>PF</i><sub>ave</sub>) value of ~ 410 μW m<sup>–1</sup> K<sup>–2</sup> in the 323–823 K temperature range, a nearly four times enhancement compared to the undoped SnSe sample. Additionally, the thermal conductivity slightly increased due to the introduction of the Ag<sub>9</sub>GaSe<sub>6</sub> compound. However, the electrical transport properties were significantly enhanced, making up for the improvement in thermal conductivity. Consequently, the SnSe + 0.5 wt% Ag<sub>9</sub>GaSe<sub>6</sub> sample obtained a peak thermoelectric figure of merit <i>ZT</i> value of ~1.2 at 823 K and a <i>ZT</i><sub>ave</sub> value of 0.58 in the 323–823 K temperature range. The proposed strategy improved the <i>ZT</i> and <i>ZT</i><sub>ave</sub> values of SnSe-based TE materials at room temperature and provided a systematic strategy for modifying SnSe-based TE materials. Moreover, the thermoelectric properties of SnSe can be effectively improved by introducing the Ag<sub>9</sub>GaSe<sub>6</sub> compound for doping, and waste heat power generation can be effectively carried out in the middle temperature region.</p></div>","PeriodicalId":457,"journal":{"name":"Acta Metallurgica Sinica-English Letters","volume":"38 5","pages":"781 - 792"},"PeriodicalIF":2.9,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143892722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction: Microstructure, Texture, Mechanical Properties, and Corrosion Behavior of Biodegradable Zn-0.2 Mg Alloy Processed by Multi-Directional Forging 修正:多向锻造可生物降解Zn-0.2 Mg合金的显微组织、织构、力学性能和腐蚀行为
IF 2.9 2区 材料科学
Acta Metallurgica Sinica-English Letters Pub Date : 2025-01-09 DOI: 10.1007/s40195-024-01801-1
Nafiseh Mollaei, Seyed Mahmood Fatemi, Mohammad Reza Aboutalebi, Seyed Hossein Razavi, Wiktor Bednarczyk
{"title":"Correction: Microstructure, Texture, Mechanical Properties, and Corrosion Behavior of Biodegradable Zn-0.2 Mg Alloy Processed by Multi-Directional Forging","authors":"Nafiseh Mollaei,&nbsp;Seyed Mahmood Fatemi,&nbsp;Mohammad Reza Aboutalebi,&nbsp;Seyed Hossein Razavi,&nbsp;Wiktor Bednarczyk","doi":"10.1007/s40195-024-01801-1","DOIUrl":"10.1007/s40195-024-01801-1","url":null,"abstract":"","PeriodicalId":457,"journal":{"name":"Acta Metallurgica Sinica-English Letters","volume":"38 3","pages":"526 - 528"},"PeriodicalIF":2.9,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143521573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信