{"title":"A systematic literature review of environmental assessments of citrus processing systems, with a focus on the drying phase","authors":"Grazia Cinardi , Provvidenza Rita D'Urso , Claudia Arcidiacono , Magdalena Muradin , Carlo Ingrao","doi":"10.1016/j.scitotenv.2025.179219","DOIUrl":"10.1016/j.scitotenv.2025.179219","url":null,"abstract":"<div><div>Citrus processing results in a considerable quantity of citrus waste that must be treated in an environmentally friendly manner to minimise its overall impact and address the issue of resource circularity. The phase having the greatest environmental impact is the drying phase, since it requires a significant input of energy and time. This phase is essential for many valorisation strategies, as it facilitates the storage and transportation of citrus waste. To gain insight into the Life Cycle Assessment (LCA) of drying techniques, a Systematic Literature Review (SLR) was conducted in this study based on PRISMA statement. Eleven articles were reviewed, to understand the energy requirements and the environmental impacts associated with the process, along with the economical profitability. To that end, attention was focussed upon single- and multi-indicator LCAs. Results from the SLR showed that the drying phase makes citrus waste low valuable for energy valorisation employing gasification, with heat generation efficiency between 21 % and 25 %, or to produce biodiesel, with the impact greater than in conventional diesel usage for a vehicle. Sustainable practices in which the drying phase has a lesser impact include incineration and animal feed. In both cases, dehydration was performed with an industrial direct kiln, requiring the consumption of fossil fuels. Indeed, citrus waste has low thermal potential (low heating value<4 MJ*kg<sup>−1</sup>), and its use for thermal energy would result in lower environmental performance than natural gas. Moreover, using citrus waste as a feed additive for livestock is feasible, provided that the distance between the livestock and citrus processing facilities is assessed for sustainability.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"974 ","pages":"Article 179219"},"PeriodicalIF":8.2,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143704468","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Barbara Strojny-Cieślak , Michał Pruchniewski , Malwina Sosnowska , Jarosław Szczepaniak , Mateusz Wierzbicki
{"title":"Toxicological insights into graphene family materials: Cytochrome P450 modulation and cellular stress in liver cells","authors":"Barbara Strojny-Cieślak , Michał Pruchniewski , Malwina Sosnowska , Jarosław Szczepaniak , Mateusz Wierzbicki","doi":"10.1016/j.scitotenv.2025.179211","DOIUrl":"10.1016/j.scitotenv.2025.179211","url":null,"abstract":"<div><div>Graphene family materials (GFM), including pristine graphene (GN), graphene oxide (GO), and nano-sized graphene oxide (nGO), are increasingly utilized across industrial, environmental, and biomedical domains. Despite their potential benefits, the hazardous effects of GFM, particularly on liver xenobiotic-metabolizing enzymes and cellular functions, are not fully understood. Cytochrome P450 (CYP) are enzymes conserved across species, which play a crucial role in the metabolism of xenobiotics, drugs, environmental pollutants, and endogenous compounds, are key to understanding the biotransformation and detoxification processes impacted by GFM. This study investigates the effects of GFMs on CYP enzymes (CYP1A2, CYP2D6, CYP3A4) in a recombinant CYP system and HepG2 liver cells, alongside an assessment of cellular stress responses. In HepG2 cells, GFMs induced oxidative stress, mitochondrial depolarization, and cytotoxicity, with GN causing the most pronounced effects. GO exhibited the strongest inhibition of CYP enzymatic activity, particularly CYP1A2, in a dose-dependent manner in a recombinant CYP system. None of the tested nanomaterials significantly altered CYP expression, except for nGO, where a slight increase in CYP3A4 protein expression was observed. These findings highlight the significant influence of GFM physicochemical properties on their hazardous potential, especially their ability to disrupt metabolic processes and induce cellular stress. This study emphasizes the critical need for evaluating the safety of GFM in light of their widespread application and potential environmental and human health implications.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"974 ","pages":"Article 179211"},"PeriodicalIF":8.2,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143704467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Environmental risks of heavy metals in railway soils: Challenges to ecosystem management","authors":"Azadeh Safadoust, Shabnam Khaleghi, Zahra Kolahchi","doi":"10.1016/j.scitotenv.2025.179217","DOIUrl":"10.1016/j.scitotenv.2025.179217","url":null,"abstract":"<div><div>Heavy metal contamination near high-traffic railways presents serious risks to food safety, particularly in agricultural regions adjacent to rail transport corridors. This study investigated heavy metal in soils and wheat plants along the Arak-Tehran railway in Iran, focusing on how distance from the railway and soil depth influence contamination levels. Soil and plant samples were collected at intervals from 0 to 300 m away from the railway to assess the concentrations of nickel (Ni), cadmium (Cd), lead (Pb), and zinc (Zn). The findings indicated that heavy metal concentrations decreased with increasing distance from the railway, with surface soils showing higher contamination than subsurface soils. Soil parameters like Organic matter, calcium carbonate, and cation exchange capacity were positively correlated with the absorption of heavy metals. The Geoaccumulation Index (Igeo) classified the area as highly polluted, particularly by cadmium (Igeo = 6.39), nickel (Igeo = 6.72), and lead (Igeo = 4.01). Contamination factor (Cf) values for nickel (158.47), cadmium (125.67), and lead (24.23) along with the average Pollution Load Index (PLI) of 31.5, confirm severe soil contamination. The translocation factor analysis revealed that cadmium had the highest translocation rate from roots to shoots, followed by zinc, nickel, and lead. Both the aerial and root parts of wheat contained heavy metal concentrations exceeding FAO/WHO safety limits, posing a potential health risk to populations consuming crops from this area. Despite high soil contamination, heavy metals were efficiently transferred to the aerial parts of the wheat, particularly cadmium and lead. These findings underscore the health risks posed populations consuming wheat and other crops grown in agricultural zones near the Arak-Tehran railway, where heavy metal contamination from the railway infrastructure can impact food safety.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"974 ","pages":"Article 179217"},"PeriodicalIF":8.2,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143706148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Carolina Moreno-Perez , Dúber Mora-Motta , Fausto A. Ortiz-Morea , Jennifer Blesh , Adriana M. Silva-Olaya
{"title":"Transitioning from extensive pastures to silvopastoral systems improves multiple soil ecosystem services in Colombian Amazon","authors":"Carolina Moreno-Perez , Dúber Mora-Motta , Fausto A. Ortiz-Morea , Jennifer Blesh , Adriana M. Silva-Olaya","doi":"10.1016/j.scitotenv.2025.179185","DOIUrl":"10.1016/j.scitotenv.2025.179185","url":null,"abstract":"<div><div>Silvopastoral systems are gaining attention as a sustainable approach to address the environmental challenges caused by traditional livestock farming in the Amazon. This study examines the effects of transitioning from extensive pastures to silvopastoral systems on soil ecosystem services (SES) in the Colombian Amazon. We identified sensitive soil indicators to monitor SES changes in response to livestock management, and synergies and tradeoffs between them. Soil samples were collected from three locations to a depth of 30 cm across three land uses: traditional pastures, 15-years-old silvopastoral systems implemented on former pastures, and secondary vegetation. We assessed five critical soil-related ecosystem services: support for plant growth, carbon storage, nutrient cycling, erosion control, and water regulation and aeration. Our findings reveal significant enhancements in multiple soil ecosystem services in silvopastoral systems, with increases of 32 % in plant growth support, 34 % in nutrient cycling, and 16 % in erosion control compared to traditional pastures. Although soil carbon (C) storage showed no significant differences between pastures and silvopastoral systems, both systems exhibited values 16 % higher than secondary vegetation. A positive interconnection among carbon storage, nutrient cycling, and erosion control services was revealed, highlighting them as major drivers of synergies. Seven soil properties were identified as sensitive indicators of changes in land management, which may serve as key proxy for monitoring soil ecosystem services: i) soil organic carbon, ii) pH, iii) soil base saturation, iv) copper, v) magnesium, vi) zinc, and vii) aluminum. These results highlight the potential of silvopastoral systems to improve soil health and resilience, offering a sustainable alternative to traditional livestock management. This study underscores the importance of integrating trees into pastures to restore degraded lands and promote sustainable agricultural practices in tropical regions, contributing to global environmental conservation efforts.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"974 ","pages":"Article 179185"},"PeriodicalIF":8.2,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143697049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Modeling trace elements over Athabasca oil sands region in Alberta, Canada using WRF-Chem.","authors":"Jingliang Hao, Yongsheng Chen, Leiming Zhang","doi":"10.1016/j.scitotenv.2025.179144","DOIUrl":"https://doi.org/10.1016/j.scitotenv.2025.179144","url":null,"abstract":"<p><p>The Athabasca Oil Sands Region (AOSR) in northern Alberta, Canada is a significant source of particulate elements, which may cause negative effects on human and ecosystem health. This study simulates the transport and deposition of eight elements (Al, Ca, Fe, K, Mn, Si, Ti, and Zn) in the AOSR during 2016-2017 using WRF-Chem with a recently developed regional-scale emission database of elements as model input. Point and area emissions of the elements were gridded in the model domain, with stack emissions also considering the plume rise. The model-measurement differences in annual concentrations of the sum of the eight elements were 23 % at AMS1, 25 % at AMS17, and - 56 % at AMS18. Modeled annual average concentrations and atmospheric deposition of individual elements ranged from 0.016 to 2.67 μg m<sup>-3</sup> (the sum total of 5.98 μg m<sup>-3</sup>) and from 2.62 to 385 mg m<sup>-2</sup> yr<sup>-1</sup> (862 mg m<sup>-2</sup> yr<sup>-1</sup>), respectively, in the central industrial area of the AOSR. The concentration and deposition decreased rapidly with distance from the center industrial area, e.g., by three orders of magnitude in areas 150 km away. Adding the three sites together, modeled total concentrations of the eight elements were 110 % higher during the cold season and 29 % lower during the warm season than the measured values, noting that constant emission rates were used throughout the years of 2016-2017. Two model sensitivity tests were conducted, with the first one using seasonally varying emissions and the second one replacing the default dry and wet deposition schemes in WRF-Chem with different ones found in literature, to demonstrate the magnitudes of the uncertainties in the model simulated ambient concentrations and atmospheric deposition of particulate elements and major causing factors of the uncertainties.</p>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":" ","pages":"179144"},"PeriodicalIF":8.2,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143717698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kangho Bae , Chang-Keun Song , Michel Van Roozendael , Andreas Richter , Thomas Wagner , Alexis Merlaud , Gaia Pinardi , Martina M. Friedrich , Caroline Fayt , Ermioni Dimitropoulou , Kezia Lange , Tim Bösch , Bianca Zilker , Miriam Latsch , Lisa K. Behrens , Steffen Ziegler , Simona Ripperger-Lukosiunaite , Leon Kuhn , Bianca Lauster , Lucas Reischmann , Kwonho Jeon
{"title":"Validation of GEMS operational v2.0 total column NO2 and HCHO during the GMAP/SIJAQ campaign","authors":"Kangho Bae , Chang-Keun Song , Michel Van Roozendael , Andreas Richter , Thomas Wagner , Alexis Merlaud , Gaia Pinardi , Martina M. Friedrich , Caroline Fayt , Ermioni Dimitropoulou , Kezia Lange , Tim Bösch , Bianca Zilker , Miriam Latsch , Lisa K. Behrens , Steffen Ziegler , Simona Ripperger-Lukosiunaite , Leon Kuhn , Bianca Lauster , Lucas Reischmann , Kwonho Jeon","doi":"10.1016/j.scitotenv.2025.179190","DOIUrl":"10.1016/j.scitotenv.2025.179190","url":null,"abstract":"<div><div>The Geostationary Environmental Monitoring Spectrometer (GEMS), the first geostationary air quality instrument, onboard the GEO-KOMPSAT-2B (GK2B) satellite, produces hourly observations over Asia with 3.5 km <span><math><mo>×</mo></math></span> 8 km spatial resolution. To evaluate the GEMS L2 products, the National Institute of Environmental Research (NIER) organized the GEMS Map of Air Pollutants 2021 (GMAP2021) and the Satellite Integrated Joint monitoring of Air Quality 2022 (SIJAQ2022) campaigns during October 2021 to November 2021 and from June 2022 to July 2022, respectively. While GMAP2021 mainly targeted the SMA (Seoul Metropolitan Area), the SIJAQ2022 campaign extended to the southeastern area of South Korea. In this study, a comparison between Pandora and Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) products and an evaluation of the GEMS operational v2.0 total column NO<sub>2</sub> and HCHO products are conducted.</div><div>A comparative analysis between the Pandora (P189) and the IUP Bremen MAX-DOAS instrument at the Incheon NIER-ESC site was performed to analyze discrepancies between the retrieval processors (Pandora: PGN official processor, MAX-DOAS: MMF in FRM<sub>4</sub>DOAS framework). Aligning the viewing directions of both Pandora and MAX-DOAS leads to a significant increase in the slope and correlation coefficient from 0.87 to 0.96 and from 0.86 to 0.96, respectively, in the case of NO<sub>2</sub> tropospheric columns. Similarly, for HCHO tropospheric columns, slope and correlation coefficient change from 0.94 to 1.09 and from 0.81 to 0.90 when matching the viewing geometries of both instruments. In contrast to tropospheric columns, total HCHO columns derived from Pandora (P189) direct-sun measurements show significantly larger values than the MAX-DOAS ones, with a mean relative difference (MRD) of 126 %. This bias can however be reduced to 33 % after suitable adjustment of the direct-sun retrieval settings.</div><div>The GEMS v2.0 NO<sub>2</sub> total column product, evaluated over 6 official PGN sites in South Korea, shows good agreement with a correlation coefficient of 0.87 and similar seasonal and diurnal NO<sub>2</sub> variation. However, GEMS tends to report higher values than Pandora with a mean relative difference of +41 %. The magnitude of the GEMS overestimation is amplified in highly polluted conditions (i.e. during winter and at noontime).</div><div>Compared to 6 MAX-DOAS stations and 6 Pandora stations, the GEMS HCHO product captures well the seasonal and diurnal variation of HCHO and shows good agreement both with MAX-DOAS and Pandora with slopes of 0.84 and 0.79, respectively, and correlation coefficients of 0.86 for both. Large columns, however, tend to be systematically underestimated.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"974 ","pages":"Article 179190"},"PeriodicalIF":8.2,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143683453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Leticia E. Cruz-Escalante , S. Nandini , S.S.S. Sarma
{"title":"Combined effects of copper and temperature on the functional response of native (Mesocyclops longisetus and Microcyclops dubitabilis) and invasive (Mesocyclops pehpeiensis) copepods fed rotifers and cladocerans","authors":"Leticia E. Cruz-Escalante , S. Nandini , S.S.S. Sarma","doi":"10.1016/j.scitotenv.2025.179179","DOIUrl":"10.1016/j.scitotenv.2025.179179","url":null,"abstract":"<div><div>Environmental stressors such as temperature, heavy metal toxicity and the presence of exotic species may affect the sensitivity and feeding patterns of freshwater zooplankton. However, the combined effect of these stressors is not well studied. The cyclopoid copepod <em>Mesocyclops pehpeiensis</em>, was originally described from Asia but is now distributed in North America and Europe. The aim of this study was to determine the sensitivity and functional response of non-gravid and gravid females of two freshwater native copepods: <em>Mesocyclops longisetus</em> and <em>Microcyclops dubitabilis</em> and an invasive species <em>Mesocyclops pehpeiensis</em> fed on the cladoceran <em>Moina macrocopa</em> and the rotifer <em>Brachionus calyciflorus</em> exposed to copper at 18, 23 and 28 °C. We hypothesized that the adverse effect of the presence of Cu or non-optimal temperature would be greater on native than the exotic species. Our results showed that nauplii of all three copepod species were eight times more sensitive than adults. <em>Microcyclops dubitabilis</em> was the most sensitive compared to both species of <em>Mesocyclops</em>. Also, the sensitivity of all species in all developmental stages increased with increasing temperature. All three copepod species showed Type II functional response and there were differences in the feeding patterns among the three copepod species. Native <em>M. dubitabilis</em> consumed less prey than the invasive <em>M. pehpeiensis. M. longisetus</em> consumed more cladoceran prey than <em>M. pehpeiensis</em>, but <em>M. pehpeiensis</em> consumed more rotifer prey than <em>M. longisetus</em>. Generally, prey consumption decreased as copper concentration increased. Significant differences in prey consumption were observed between gravid and non-gravid females with regard to the test temperatures, Cu treatments and copepod species tested. <em>Mesocyclops longisetus</em>, especially the non-gravid females generally consumed more prey than <em>M. pehpeiensis</em>, especially at the highest temperature tested (28 °C). Studies on zooplankton can be conducted over a short period but providing insights into the combined effects of stressors on zooplankton communities.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"974 ","pages":"Article 179179"},"PeriodicalIF":8.2,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143697048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shahrokh Soltaninia , Mehrtash Eskandaripour , Mohammad H. Golmohammadi , Lobat Taghavi , Arvin Mehboodi
{"title":"Nitrate pollution in urban runoff: A comprehensive risk assessment for human and ecological health","authors":"Shahrokh Soltaninia , Mehrtash Eskandaripour , Mohammad H. Golmohammadi , Lobat Taghavi , Arvin Mehboodi","doi":"10.1016/j.scitotenv.2025.179184","DOIUrl":"10.1016/j.scitotenv.2025.179184","url":null,"abstract":"<div><div>Nitrate pollution in urban runoff poses significant environmental and public health risks, with its impact varying across different land use types. This study investigates nitrate concentrations in runoff from residential, commercial, industrial, and traffic zones in Tehran, Iran, using Event Mean Concentration (EMC) analysis and Monte Carlo simulations to assess both ecological and human health risks. The results indicate that industrial and traffic zones exhibit the highest nitrate concentrations, reaching 58.13 mg/L, significantly exceeding regulatory thresholds. Ecological risk assessments highlight the potential for aquatic system degradation, while health risk evaluations reveal hazard index (HI) values surpassing the safe limit (HI > 4), particularly in industrial and high-traffic areas. These findings underscore the need for targeted mitigation strategies, including the implementation of green infrastructure and stricter pollution control measures, to improve urban water quality and reduce associated risks.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"974 ","pages":"Article 179184"},"PeriodicalIF":8.2,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143683452","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiaoyu Cong , Carsten Ulrich Schwermer , Peter Krolla , Thomas Schwartz
{"title":"Inactivating facultative pathogen bacteria and antibiotic resistance genes in wastewater using blue light irradiation combined with a photosensitizer and hydrogen peroxide","authors":"Xiaoyu Cong , Carsten Ulrich Schwermer , Peter Krolla , Thomas Schwartz","doi":"10.1016/j.scitotenv.2025.179208","DOIUrl":"10.1016/j.scitotenv.2025.179208","url":null,"abstract":"<div><div>The effectiveness of antimicrobial blue light (aBL) irradiation in eliminating ten clinically significant antibiotic resistance genes (ARGs) and four taxonomic marker genes of the WHO-priority ESKAPE bacteria group from wastewater treatment plant (WWTP) effluent was examined. Experiments were conducted using an LED-driven continuous-flow photoreactor operating at wavelengths of 405 nm, 420 nm, and 460 nm. Irradiation with aBL alone was insufficient for effectively inactivating or eliminating ESKAPE bacteria and clinically relevant ARGs. The addition of the porphyrin-based photosensitizer TMPyP (10<sup>−6</sup> M) or the oxidative agent H₂O₂ (1 mM) resulted in several log<sub>10</sub> unit reductions of facultative pathogenic bacteria (FPB), their taxonomic gene markers, and target ARGs. However, the additional effects of TMPyP and H<sub>2</sub>O<sub>2</sub> were only noticeable in conjunction with aBL irradiation, as they were ineffective without it.</div><div>The reduction of the different FPB and ARGs in WWTP effluents was analyzed using culturing and qPCR together with living/dead discrimination. Different FPB and ARGs showed varying susceptibility to aBL-mediated irradiation. Among the FPB, enterococci were the most sensitive, while among the ARGs bacteria carrying <em>erm</em>B, <em>tet</em>M, <em>sul</em>1, and <em>bla</em><sub>VIM</sub> genes exhibited the strongest removal. This sensitivity may be due to the gene-carrying microorganism's response to aBL irradiation combined with TMPyP or H<sub>2</sub>O<sub>2</sub>. Additionally, molecular biology results revealed that aBL irradiation induced up to 13 lesions per 10 kb DNA, which is hypothesized to contribute to the acute inactivation effect and prevent regrowth by inhibiting DNA repair activities.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"974 ","pages":"Article 179208"},"PeriodicalIF":8.2,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143704466","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Olga Murujew , Andrea Wilson , Peter Vale , Yadira Bajón-Fernández , Bruce Jefferson , Marc Pidou
{"title":"Robustness and resilience of different solid-liquid separation technologies for tertiary phosphorus removal to low levels by coagulation","authors":"Olga Murujew , Andrea Wilson , Peter Vale , Yadira Bajón-Fernández , Bruce Jefferson , Marc Pidou","doi":"10.1016/j.scitotenv.2025.179170","DOIUrl":"10.1016/j.scitotenv.2025.179170","url":null,"abstract":"<div><div>In this study, three tertiary solid separation technologies were assessed on their robustness and resilience against an effluent phosphorus target of <0.3 mg P/L at steady state and dynamic conditions. The ballasted flocculation system was found to be very robust at delivering the low P target. Alternatively, cloth filtration provided a more sustainable option for less strict consents of sub 0.5 mg P/L. The effluent from the membrane system was more variable but it was shown to meet the low consents even with increased phosphorus and solids content in the feed. A molar ratio of 1.37 Fe: P was shown to be sufficient to meet the P target at short contact times as with the ballasted flocculation process. It was highlighted that optimisation of up-stream flocculation can be a considerable factor for consistent performance. Overall, the study determined key attributes of the different technologies tested providing valuable insights for technology selection at full scale.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"974 ","pages":"Article 179170"},"PeriodicalIF":8.2,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143695942","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}