Progress in Polymer Science最新文献

{"title":"Recent progress in non-photolithographic patterning of polymer thin films","authors":"Mingjun Qiu ,&nbsp;Weiwei Du ,&nbsp;Shangyu Zhou ,&nbsp;Pengzhe Cai ,&nbsp;Yingwu Luo ,&nbsp;Xiaoxue Wang ,&nbsp;Rong Yang ,&nbsp;Junjie Zhao","doi":"10.1016/j.progpolymsci.2023.101688","DOIUrl":"https://doi.org/10.1016/j.progpolymsci.2023.101688","url":null,"abstract":"<div><p><span><span><span>Patterned polymer thin films are essential components in many devices and applications owing to the multi-functionality, flexibility, lightweight and cost-efficiency. Unfortunately, conventional </span>photolithography needs the use of developers and strippers which contain solvents and reagents that may dissolve, swell or degrade the polymer thin film substrates. Alternatively, non-photolithographic strategies provide alternative options and avoid the complicated optical systems, offering versatile routes for fabricating polymeric micro- and </span>nanostructures<span>. In this review, we summarize the recent progress in non-photolithographic patterning methods including soft lithography<span>, nanoimprint lithography, direct writing, self-assembly of </span></span></span>block copolymers<span>, area-selective vapor phase deposition and instability induced patterning. These patterning approaches have been applied to various applications such as chromic devices, polymer light-emitting diodes, sensors, transistors, and protein and cellular engineering and many other scenarios. Finally, the subsisting challenges and future research directions of non-photolithographic patterning approaches are highlighted from the aspect of resolution, reliability and scalability.</span></p></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"142 ","pages":"Article 101688"},"PeriodicalIF":27.1,"publicationDate":"2023-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"3203138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Control of coordination polymerization behavior by counter-anionic effects","authors":"Ryo Tanaka,&nbsp;Oluwaseyi Aderemi Ajala,&nbsp;Yuushou Nakayama,&nbsp;Takeshi Shiono","doi":"10.1016/j.progpolymsci.2023.101690","DOIUrl":"https://doi.org/10.1016/j.progpolymsci.2023.101690","url":null,"abstract":"<div><p><span>In coordination polymerization<span> chemistry, the most active species are cationic transition metals which bear vacant sites for </span></span>monomer coordination. The steric and electronic properties around the metal center are strongly related to the polymerization behavior. Thus, the development of the catalyst system mainly represents the design of neutral metal complex precursors, especially the structure of the ligand. On the other hand, the choice of counteranions derived from the cocatalysts sometimes plays a crucial role in the controlled coordination polymerization. Some unusual polymerization behaviors on stereospecificity, activity, and monomer reactivity ratios have been reported by designing the structure of these cocatalysts.</p><p>The review summarizes these examples of polymerization controlled by cocatalysts. Various cocatalysts, such as methylaluminoxane (MAO), fluoroarylboranes, and borates with different activation mechanisms, are introduced based on their structural analysis and molecular design. Heterogeneous cocatalysts, important for industrial applications, are also mentioned with their various characterization methods. The application of these cocatalysts is discussed, along with the introduction of several techniques evaluating the relationship between cocatalysts and polymerization behavior. Moreover, the counter-anionic effect in the late-transition metal-catalyzed polymerization chemistry, which recently attracted many researchers for its versatile applicability for polar monomers, is reviewed.</p></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"142 ","pages":"Article 101690"},"PeriodicalIF":27.1,"publicationDate":"2023-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1623511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tellurium-containing polymers: Recent developments and trends","authors":"Yiheng Dai ,&nbsp;Jun Guan ,&nbsp;Shenghan Zhang ,&nbsp;Shuojiong Pan,&nbsp;Banruo Xianyu,&nbsp;Zhuoxin Ge,&nbsp;Jinyan Si,&nbsp;Chaowei He,&nbsp;Huaping Xu","doi":"10.1016/j.progpolymsci.2023.101678","DOIUrl":"https://doi.org/10.1016/j.progpolymsci.2023.101678","url":null,"abstract":"<div><p><span>Significant progresses have been made in tellurium-containing polymers over the past decades. Just like other heteroatom-containing polymers, tellurium-containing polymers exhibit several unique properties and promising applications. However, unlike elements such as boron, silicon<span>, sulfur and so on, tellurium<span> in polymers remains a fresh perspective for many researchers. In this review, we shall illustrate the diversification of tellurium-containing polymers and their respective synthetic methods. Besides, the properties of tellurium-containing polymers including redox-responsiveness, coordination properties, optoelectronic properties and so on will be discussed in detail. Furthermore, the performances of tellurium-containing polymers in biomedicine, optoelectronic materials and some recent advanced fields will be demonstrated. Overall, by reviewing the recent developments and trends of tellurium-containing polymers, we wish to popularize the concepts and it is anticipated that this review could function as an easy-to-read and comprehensive handbook to provide some inspirations and possible scientific supports for researchers in the field of </span></span></span>chemistry and materials.</p></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"141 ","pages":"Article 101678"},"PeriodicalIF":27.1,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1759879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Metallacycle/metallacage-cored supramolecular networks","authors":"Ruoqian Zhang ,&nbsp;Rongrong Li ,&nbsp;Feihe Huang ,&nbsp;Mingming Zhang","doi":"10.1016/j.progpolymsci.2023.101680","DOIUrl":"https://doi.org/10.1016/j.progpolymsci.2023.101680","url":null,"abstract":"<div><p>Supramolecular networks often possess good dynamic features but suffer from low mechanical properties<span>. Supramolecular coordination complexes including metallacycles<span><span> and metallacages have rigid chemical structures and tunable cavities but often lack processability. Therefore, the reasonable integration of these two types of </span>supramolecular structures into metallacycle/metallacage-cored supramolecular networks will reduce the shortcomings of both structures and offer intriguing properties for diverse applications. This review summarizes the progress of metallacycle/metallacage-cored networks according to the covalent or non-covalent interactions used to connect these metallacycles and metallacages. In each part, the structures, properties, functions and applications of such supramolecular networks are described in detail, in order to demonstrate the most exciting achievements in this emerging area. The remaining challenges and perspectives are also given at the end of this review. We hope this review can give our readers a snapshot on metallacycle/metallacage-cored supramolecular networks and attract more scientists to devote into this promising field.</span></span></p></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"141 ","pages":"Article 101680"},"PeriodicalIF":27.1,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1822388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Host defense peptide mimicking antimicrobial amino acid polymers and beyond: Design, synthesis and biomedical applications","authors":"Yueming Wu ,&nbsp;Kang Chen ,&nbsp;Jiangzhou Wang ,&nbsp;Minzhang Chen ,&nbsp;Yuan Chen ,&nbsp;Yunrui She ,&nbsp;Zi Yan ,&nbsp;Runhui Liu","doi":"10.1016/j.progpolymsci.2023.101679","DOIUrl":"https://doi.org/10.1016/j.progpolymsci.2023.101679","url":null,"abstract":"<div><p><span>Microbial infections endanger human health and life. Conventional antibiotics has saved countless human lives, however, is seriously challenged by the quick emergence of antibiotic-resistant pathogens. It is urgent to develop new types of antimicrobial agents to treat antibiotic-resistant microbial infections. Host defense peptides (HDPs) have broad-spectrum antimicrobial activity and low susceptibility to antimicrobial resistance, therefore, have been actively studied to develop promising antimicrobial agents. However, natural HDPs are structurally unstable due to their easy hydrolysis by proteases. Sequence-defined peptides have been explored as HDP mimics and have proven as promising candidates of antimicrobial drugs. Nevertheless, preparation of these HDP-mimicking peptides by solid-phase synthesis is time-consuming, expensive, and difficult for large scale synthesis. Assisted by the development of polymerization </span>chemistry<span><span><span>, polypeptides can be prepared in the form of </span>amino acid<span> polymers conveniently and at large scales using the polymerization strategy. Amino acid polymers, also known as poly(amino acid)s, have the same or similar backbone structure as natural peptides and have excellent biocompatibility. Several classes of such antimicrobial polymers have been explored as synthetic mimics of HDPs including α-amino acid polymers, β-amino acid polymers, peptoid polymers, amino acid hybrid polymers, and peptide mimicking polymers such as poly(2-oxazoline)s. To tune the biological activities and obtain the optimal antimicrobial polymers, key structure characteristics of HDPs are involved and investigated such as positive charges and the hydrophobic/hydrophilic amphiphilic structure. In this review, we provide an overview of research in the last decade about the design of HDP-mimicking antimicrobial amino acid polymers and beyond, including positive charge, amphiphilic structure, chain length, end group, </span></span>hydrophilicity<span>, stereochemistry<span>, secondary structure, topology, self-assembly and backbone structure, as well as the major applications of antimicrobial amino acid polymers. Finally, we provide a perspective on the comparison between antimicrobial peptides and antimicrobial amino acid polymers, as well as some key challenges that still need to be addressed for possible clinical application of HDP-mimicking antimicrobial amino acid polymers.</span></span></span></p></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"141 ","pages":"Article 101679"},"PeriodicalIF":27.1,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1822387","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Engineering precise sequence-defined polymers for advanced functions","authors":"Qiangqiang Shi ,&nbsp;Zhengyu Deng ,&nbsp;Mingxuan Hou ,&nbsp;Xianglong Hu ,&nbsp;Shiyong Liu","doi":"10.1016/j.progpolymsci.2023.101677","DOIUrl":"https://doi.org/10.1016/j.progpolymsci.2023.101677","url":null,"abstract":"<div><p><span>Unlike natural macromolecules<span><span><span> (e.g., nucleic acids and proteins) possessing precisely defined </span>molar mass<span>, chain sequence, chirality, and topology, </span></span>synthetic polymers<span> are typically featured with broad chain length distributions, inhomogeneous compositions, and undefined sequences. To bridge the wide gap between natural and synthetic polymers, sequence-defined polymers (SDPs) have gradually emerged and developed with precise chain length, sequence, tacticity, and topology, holding great promise to reach the same level of precision, complexity, and functionality of </span></span></span>biopolymers<span>. The emergence of SDPs confers an unparalleled opportunity to precisely regulate their primary structures, rational intrachain and interchain self-organization, and macroscopic properties, enabling the fundamental elucidation of structure-function relationships. This review aims to summarize recent progresses in the synthesis and advanced applications of emerging and booming SDPs. Some prospects are proposed towards future challenges and versatile promising developments of SDPs.</span></p></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"141 ","pages":"Article 101677"},"PeriodicalIF":27.1,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"3082044","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hemicellulose: Structure, chemical modification, and application","authors":"Jun Rao ,&nbsp;Ziwen Lv ,&nbsp;Gegu Chen ,&nbsp;Feng Peng","doi":"10.1016/j.progpolymsci.2023.101675","DOIUrl":"https://doi.org/10.1016/j.progpolymsci.2023.101675","url":null,"abstract":"<div><p><span>Lignocellulose has been extensively researched over the past decades in response to the growing global significance of renewable resources and environment-friendly materials. Hemicellulose<span> is a large family of polysaccharides<span> present in the primary and secondary cell walls of all land plants, fresh-water plants, and some seaweeds. It has gained significant attention in the development of hemicellulose-based functional polymeric materials owing to its distinct features such as environment-friendliness, renewability, and biodegradability. Recent studies have focused on the isolation, structural characterization, and chemical modification of hemicellulose and the preparation of hemicellulose-based materials. This review, comprehensively elaborates the preparation of hemicellulose-based functional polymeric materials </span></span></span><em>via</em><span> chemical modification, including the structures and properties of hemicellulose; design strategies for harnessing hemicellulose; and various forms of hemicellulose-based functional polymeric materials such as nanoparticles<span>, films and coatings, hydrogels and aerogels<span>, carbon quantum dots<span>, porous carbons and catalysts. This review provides an update on hemicellulose-based functional materials, with a focus on their controlled-release, adsorption, biosensing, packaging, catalytic conversion, and electrode applications. Future perspectives on challenges and opportunities in the research field of hemicellulose are briefly highlighted.</span></span></span></span></p></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"140 ","pages":"Article 101675"},"PeriodicalIF":27.1,"publicationDate":"2023-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1822389","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nature-inspired strategies for the synthesis of hydrogel actuators and their applications","authors":"Weijun Li ,&nbsp;Qingwen Guan ,&nbsp;Ming Li ,&nbsp;Eduardo Saiz ,&nbsp;Xu Hou","doi":"10.1016/j.progpolymsci.2023.101665","DOIUrl":"https://doi.org/10.1016/j.progpolymsci.2023.101665","url":null,"abstract":"<div><p>Nature endows numerous organisms with the ability to realize their basic physiological activities through stimulus-responsive actuation. Inspired by these interesting biological structures, various biomimetic hydrogel actuators with excellent controllability, fast response, and toughness have been developed. Here, the principles of enabling stimulus-responsive behavior in polymer materials are first reviewed for the example of biological materials and subsequently recent progress in implementing stimuli-response behavior in bioinspired hydrogel actuators are being discussed. Particular emphasis is on the mechanisms underlying mechanical toughening of hydrogel actuators and its role in applications. The goal is to highlight recent progress, find the common threads, and discuss the fundamental differences to determine the current challenges and future directions for this field.</p></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"140 ","pages":"Article 101665"},"PeriodicalIF":27.1,"publicationDate":"2023-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2620154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Strain-induced multiscale structural evolutions of crystallized polymers: From fundamental studies to recent progresses","authors":"Shanshan Xu ,&nbsp;Jian Zhou ,&nbsp;Pengju Pan","doi":"10.1016/j.progpolymsci.2023.101676","DOIUrl":"https://doi.org/10.1016/j.progpolymsci.2023.101676","url":null,"abstract":"<div><p>Semicrystalline polymers products usually adopt a crystallized form in their end-use environment. These crystallized polymers undergo various deformations under different external fields (<em>e.g.</em><span>, stretching) from precursor processing, post treatment to final shape formation. Such deformation process is accompanied by multi-scale and multi-stage structural evolutions due to the complex hierarchical structures of crystallized polymers. These structural evolutions control over essential physical properties of semicrystalline polymers, which can be further developed towards high-performance industrial materials. A profound understanding of associated mechanisms is the critical key to interpret the complicated deformation process and to optimize the practical performances of polymer materials. The past reviews have more or less focused on one aspect of deformation while the multi-scale vision is lacking. Herein, this review brings a comprehensive presentation of strain-induced structural mechanics of crystallized polymers based on a multi-scale, multi-stage standpoint from the initiation of plasticity until failure. Important structural changes and associated mechanisms during the whole deformation process are systematically summarized, with particular attention paid to the crystal phase transition and crystal morphology evolution. Besides, the relationships between resulted microstructures and the essential end-use properties of crystallized polymers as well as their performances as common industrial materials are discussed. By summarizing the recent processes, this review is hoped to open up more aventunes for developing deformation-inspired sophisticated materials facing broader and interdisciplinary application fields.</span></p></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"140 ","pages":"Article 101676"},"PeriodicalIF":27.1,"publicationDate":"2023-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"3082045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Heteroatom-containing degradable polymers by ring-opening metathesis polymerization","authors":"Jiaxi Xu,&nbsp;Nikos Hadjichristidis","doi":"10.1016/j.progpolymsci.2023.101656","DOIUrl":"https://doi.org/10.1016/j.progpolymsci.2023.101656","url":null,"abstract":"<div><p>The incorporation of heteroatom-containing weak bonds along polymer backbones has become a popular tool to accelerate degradation. Many methods have already been reported for the synthesis of degradable heteroatom-containing polymers based mainly on conventional step-growth polymerization and chain-growth ring-opening polymerization (ROP). In recent years, ring-opening metathesis polymerization (ROMP) has evolved as an emerging approach for the synthesis of various types of degradable polymers, from carbocyclic norbornene derivatives to heterocyclic olefin monomers. Classic ruthenium (Ru)-based catalysts exhibit not only high reactivity to C=C double bonds but also high tolerance to polar functional groups. Hence, a rich range of functional groups can be incorporated into cyclic olefin monomers and then transferred to the polymer backbones. This review covers the synthesis of the various heteroatom-containing degradable (co)polymers via ROMP, including poly(thio)acetals/polyketals, polyorthoesters, polyesters, polycarbonates, polyphosphoesters/polyphosphoamidates, poly(enol ether)s, poly(silyl ether)s, polydisulfides, polyketones, polyacylsilanes, polyamides, and polyureas, as well as their degradable mechanisms under different conditions. The review also highlights applications in tissue engineering and medicine.</p></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"139 ","pages":"Article 101656"},"PeriodicalIF":27.1,"publicationDate":"2023-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1759880","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}