Progress in Polymer Science最新文献_第3页

Multi-mechanism polymerization as a promising tool for polymer synthesis 多机理聚合是一种有前途的聚合物合成方法

IF 26 1区化学

Progress in Polymer Science Pub Date : 2025-06-15 DOI: 10.1016/j.progpolymsci.2025.101988

Ning Ren , Xiangyi Wang , Pan Sun , Mengqi Ge , Wenwen Han , Xinyuan Zhu

{"title":"Multi-mechanism polymerization as a promising tool for polymer synthesis","authors":"Ning Ren , Xiangyi Wang , Pan Sun , Mengqi Ge , Wenwen Han , Xinyuan Zhu","doi":"10.1016/j.progpolymsci.2025.101988","DOIUrl":"10.1016/j.progpolymsci.2025.101988","url":null,"abstract":"<div><div>The properties and applications of polymeric materials are closely related to the composition and architecture of the polymer chain, which is primarily realized by the chemical bonds formed during the polymerization process. Due to the selectivity of typical polymerizations, constructing different types of chemical bonds usually requires different mechanisms. For this reason, multi-mechanism polymerization is a commonly used technique. However, due to the complex nature of chemical reactions, different mechanisms could affect each other. Incorporating multiple mechanisms in a single polymerization requires the elaborate design of the synthetic route and rational arrangement of the reaction sequence. Considering the importance of multi-mechanism polymerization for polymer synthesis, the scope of this review is to summarize the research progress on multi-mechanism polymerization. Because the number of publications using stepwise, sequential polymerizations is much more than those with simultaneous polymerizations, this review focuses primarily on the latter type with a brief summary of the former. Polymerization mechanisms and their combinations categorize multi-mechanism polymerizations. The mutual interactions between different mechanisms are discussed before summarizing and highlighting the published works during recent years. A perspective on the mechanistic and kinetic relationship between multi-mechanism polymerizations and their single-mechanism polymerization counterparts is also afforded in this review.</div></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"166 ","pages":"Article 101988"},"PeriodicalIF":26.0,"publicationDate":"2025-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144289984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Multimode anticounterfeiting materials based on polymers and supramolecular chemistry 基于聚合物和超分子化学的多模防伪材料

IF 26 1区化学

Progress in Polymer Science Pub Date : 2025-06-14 DOI: 10.1016/j.progpolymsci.2025.101986

Moein Mohammadi-Jorjafki , Milad Babazadeh-Mamaqani , Reza Khalilzadeh , Hossein Roghani-Mamaqani , Richard Hoogenboom , Feng Wang

{"title":"Multimode anticounterfeiting materials based on polymers and supramolecular chemistry","authors":"Moein Mohammadi-Jorjafki , Milad Babazadeh-Mamaqani , Reza Khalilzadeh , Hossein Roghani-Mamaqani , Richard Hoogenboom , Feng Wang","doi":"10.1016/j.progpolymsci.2025.101986","DOIUrl":"10.1016/j.progpolymsci.2025.101986","url":null,"abstract":"<div><div>The combination of polymer science and supramolecular chemistry has emerged as a promising exploration platform in developing dynamic and responsive materials. The synergy of non-covalent supramolecular chemistry with macromolecular covalent chemistry has opened up advanced applications in the sensing and anticounterfeiting fields. Such supramolecular interactions include hydrogen bonding, host-guest interactions, metal coordination and electrostatic interactions, donor-acceptor, and π-π stacking. Since many supramolecular self-assembling systems lead to a change in absorption or emission behavior of the involved supramolecular units, the combination of polymers with such supramolecular motifs provides a powerful platform for sensing, information storage, and anticounterfeiting applications. Considering that counterfeiting tactics continue to change, the need for multimode anticounterfeiting systems with diverse color and time dimensions as dynamic anticounterfeiting technology is indispensable. Due to the high need for multimode anticounterfeiting materials for nations, governments, suppliers, and customers, it is highly promising to use reversible, dynamic supramolecular structures in combination with polymers that provide good processability and materials properties. This review article provides an overview of the design and application of polymer materials with embedded supramolecular interactions as innovative multimodal anticounterfeiting materials.</div></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"166 ","pages":"Article 101986"},"PeriodicalIF":26.0,"publicationDate":"2025-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144279949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Polymeric chemistry design for battery electrode binders 电池电极粘合剂的聚合化学设计

IF 26 1区化学

Progress in Polymer Science Pub Date : 2025-06-04 DOI: 10.1016/j.progpolymsci.2025.101987

Soonho Jang , Myeong-Hwa Ryou , Ji-Youn Bae , Seung-Ho Yu , Sang-Young Lee , Joona Bang

{"title":"Polymeric chemistry design for battery electrode binders","authors":"Soonho Jang , Myeong-Hwa Ryou , Ji-Youn Bae , Seung-Ho Yu , Sang-Young Lee , Joona Bang","doi":"10.1016/j.progpolymsci.2025.101987","DOIUrl":"10.1016/j.progpolymsci.2025.101987","url":null,"abstract":"<div><div>Polymer binders are essential for battery electrode stability, ensuring adhesion and cohesion, facilitating active material dispersion, and providing mechanical resilience against cycling-induced stresses. However, conventional binders such as poly(vinylidene fluoride) and carboxymethyl cellulose/styrene-butadiene rubber, which are widely used in lithium-ion battery electrodes, struggle to meet these functional requirements, particularly in high-capacity and high-voltage electrodes. These limitations affect electrochemical performance, cycle life, and manufacturability, necessitating a new paradigm in battery design. Recent advances in polymer chemistry and molecular engineering have enabled the development of functional binders that offer improved mechanical properties, interfacial stability, and electrochemical compatibility. This review comprehensively examines binder design approaches, emphasizing quantitative structure–property relationships to provide a predictive framework for rational binder engineering. Key focus areas include adhesion and cohesion, dispersion stability, mechanical strength, and electrochemical stability, alongside emerging functionalities such as ionic/electrical conductivity, electrolyte compatibility, and flame retardance. By integrating multi-scale engineering approaches with case studies on silicon anodes, nickel-rich cathodes, dry-processed electrodes, and emerging electrodes, this review presents a strategic roadmap for the innovation of next-generation binder. The insights presented herein offer a scientifically grounded, application-driven framework for the development of scalable, high-performance, and sustainable binder technologies that will shape the future of advanced battery materials.</div></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"166 ","pages":"Article 101987"},"PeriodicalIF":26.0,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144219351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Emulsion templating: DIY versatility for the creative design of macroporous polymers 乳液模板：DIY多功能性，用于大孔聚合物的创意设计

IF 26 1区化学

Progress in Polymer Science Pub Date : 2025-05-16 DOI: 10.1016/j.progpolymsci.2025.101970

Samah Saied-Ahmad, Michael S. Silverstein

{"title":"Emulsion templating: DIY versatility for the creative design of macroporous polymers","authors":"Samah Saied-Ahmad, Michael S. Silverstein","doi":"10.1016/j.progpolymsci.2025.101970","DOIUrl":"10.1016/j.progpolymsci.2025.101970","url":null,"abstract":"<div><div>Porous polymers are of interest for a wide variety of applications including absorption, adsorption, tissue engineering, membranes, controlled release, reaction supports, and shape memory foams. Emulsion templating can be used to generate high-porosity, macroporous polymer monoliths with highly interconnected, micrometer-scale porous structures through polymerization in the external, continuous phase followed by removal of the internal, dispersed phase. Emulsion templating possesses, on one hand, the benefit of being seemly simple. This simplicity, however, belies its inherent versatility and considerable parameter space that enables creative design of innovative new materials in terms of their macromolecular structures, their porous structures, and their properties. As described here, approaching emulsion templating with a specific structure or application in mind can enable a do-it-yourself outlook to imaginatively selecting the most appropriate emulsion type, stabilization strategy, polymerization mechanism, crosslinking strategy, and post-synthesis modification. The research and development of emulsion-templated polymers has been blossoming, as reflected not only in the number of articles published, but also in the number of novel porous polymer materials synthesized and in the number of heretofore unexplored applications investigated. It is the hidden complexity of emulsion templating that enables a continuous stream of pioneering works stemming from breakthrough insights in connected and contiguous scientific fields. This appraisal, highlighting emulsion templating strategies, will serve as a guide for those involved in developing innovative polymers with unique macromolecular and porous structures that engender exceptional properties. Contemplating the future directions of emulsion templating, given the robust nature of its established foundation, suggests that innovative research and development will continue to flourish.</div></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"165 ","pages":"Article 101970"},"PeriodicalIF":26.0,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144067273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Baroplastics – The future of low temperature plastic processing 气压塑料-低温塑料加工的未来

IF 26 1区化学

Progress in Polymer Science Pub Date : 2025-05-11 DOI: 10.1016/j.progpolymsci.2025.101967

Daniel MacKinnon, Magdalena Godzina, C. Remzi Becer

{"title":"Baroplastics – The future of low temperature plastic processing","authors":"Daniel MacKinnon, Magdalena Godzina, C. Remzi Becer","doi":"10.1016/j.progpolymsci.2025.101967","DOIUrl":"10.1016/j.progpolymsci.2025.101967","url":null,"abstract":"<div><div>While global annual plastic production has surpassed 400 million tons, the rate of plastic recycling remains below 10 %. Recycling rates for conventional thermoplastics remain low, largely due to the harsh conditions required for high-temperature melt-molding. These conditions promote thermo-oxidative reactions and chain scission, causing significant deterioration of polymer chains and reducing the recyclability of these materials. Additionally, the sustainability of this process is compromised by its high energy demands and harmful environmental impacts. Baroplastics provide an alternative recycling pathway that involves the use of low-temperature processing under pressure; a novel class of sustainable polymers that leverages their unique pressure-responsive properties to enable recycling at markedly reduced energy consumption and CO<sub>2</sub> emissions. Baroplastics rely on order-to-disorder transitions (ODTs), typically of block copolymers (BCPs), that allow for a rheological transition from an ordered solid to a disordered liquid-like state that can flow and be molded. Once pressure is removed, the liquid-like state returns to its original solid form with no observed degradation of the polymeric chains. In this review, we introduce the concept of baroplastics and explore the mechanisms that underpin their distinctive ability to flow under pressure for sustainable recycling. We discuss the technological and environmental advantages of baromechanical recycling, the potential for future implementation within industry, and the use of baroplastics in nanocomposites and biological systems. Moreover, we have thoroughly reviewed the scope, modelling, and synthesis of baroplastic materials to produce a guide to this growing field.</div></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"165 ","pages":"Article 101967"},"PeriodicalIF":26.0,"publicationDate":"2025-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143933095","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Non-isocyanate polyurethanes at room temperature – a dream becoming reality 室温下的非异氰酸酯聚氨酯-梦想成为现实

IF 26 1区化学

Progress in Polymer Science Pub Date : 2025-05-10 DOI: 10.1016/j.progpolymsci.2025.101968

Thomas Habets , Bruno Grignard , Christophe Detrembleur

{"title":"Non-isocyanate polyurethanes at room temperature – a dream becoming reality","authors":"Thomas Habets , Bruno Grignard , Christophe Detrembleur","doi":"10.1016/j.progpolymsci.2025.101968","DOIUrl":"10.1016/j.progpolymsci.2025.101968","url":null,"abstract":"<div><div>Polyurethanes (PUs) are one of the most widely utilized classes of polymers worldwide. However, their conventional production relies on toxic and hazardous isocyanate compounds whose usage is being limited by recent regulations. This has driven the development of new chemical strategies to access non-isocyanate PUs, or NIPUs. While the traditional PU synthesis typically occurs at room temperature (r.T) due to the high reactivity of isocyanates, NIPU synthesis generally requires elevated temperatures to surpass the low reactivity of the precursors. Considering societal needs and regulatory changes, achieving NIPU synthesis at r.T could reduce the energy footprint of the process, facilitate transition to NIPUs within existing PU manufacturing facilities and in consumer-grade applications – a more seamless switch from PUs to NIPUs. Additionally, r.T reactions are desirable for minimizing side reactions and enabling a wider functional group tolerance. This review critically gathers unbridged data and recent strategies aimed at achieving NIPU synthesis at r.T. This includes advances in monomer design, catalysis, and the use of r.T-efficient hybrid chemistries. Various polymerization techniques from a wide diversity of precursors are discussed, along with the advantages and limitations of each approach.</div></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"165 ","pages":"Article 101968"},"PeriodicalIF":26.0,"publicationDate":"2025-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143931100","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Poly(1,2,4-triazolium)s as the rising generation of functional poly(ionic liquid)s 聚（1,2,4-三唑）是新一代功能化聚离子液体

IF 26 1区化学

Progress in Polymer Science Pub Date : 2025-05-09 DOI: 10.1016/j.progpolymsci.2025.101969

Xinghao Li , Eric Drockenmuller , Pierre Stiernet , Weiyi Zhang , Jiayin Yuan

引用次数: 0

Chemical depolymerization of polyethylene terephthalate and its blends: Enhanced strategies for efficient circularity 聚对苯二甲酸乙二醇酯及其共混物的化学解聚：提高循环效率的策略

IF 26 1区化学

Progress in Polymer Science Pub Date : 2025-05-01 DOI: 10.1016/j.progpolymsci.2025.101958

Shun Zhang , Xuan Zhao , Xuehui Liu , Lin Chen , Lan Bai , Shimei Xu , Yu-Zhong Wang

引用次数: 0

Recent trends in all-organic polymer dielectrics for high-temperature electrostatic energy storage capacitors 高温静电储能电容器用全有机聚合物电介质的最新发展趋势

IF 26 1区化学

Progress in Polymer Science Pub Date : 2025-05-01 DOI: 10.1016/j.progpolymsci.2025.101957

Zongliang Xie , Lu Fan , He Li , Zhaoyu Ran , Shiqi Lai , Xiaoyan Liu , Ashlin Deatherage , Yalin Wang , Qi Li , Yi Yin , Yi Liu

{"title":"Recent trends in all-organic polymer dielectrics for high-temperature electrostatic energy storage capacitors","authors":"Zongliang Xie , Lu Fan , He Li , Zhaoyu Ran , Shiqi Lai , Xiaoyan Liu , Ashlin Deatherage , Yalin Wang , Qi Li , Yi Yin , Yi Liu","doi":"10.1016/j.progpolymsci.2025.101957","DOIUrl":"10.1016/j.progpolymsci.2025.101957","url":null,"abstract":"<div><div>Electrostatic energy storage (EES) capacitors are critical for renewable energy and high-power systems, driving the search for dielectric materials that combine superior electrical insulation, mechanical flexibility, low density, cost-effectiveness, and processability. Polymer-based dielectrics have emerged as leading candidates, particularly for high electric field applications. However, conventional polymers often fail to meet the demands of high-temperature environments due to increased electrical conductivity and reduced discharged energy density at elevated temperatures, resulting in energy loss and reduced performance. High glass transition temperature (<em>T</em><sub>g</sub>) polymers show promise but require further optimization to enhance their energy storage capabilities under thermal and electrical stress. This review provides a comprehensive update on recent advancements in high-<em>T</em><sub>g</sub> polymer-based dielectrics for EES capacitors, focusing on both intrinsic polymers and all-organic composites. It outlines key design principles, critical performance parameters, and innovative strategies—such as nanofiller doping, layered architectures, physical blending, and chemical crosslinking—to improve electrical, thermal, and mechanical properties. The review also highlights emerging trends, including the integration of machine learning algorithms to explore novel polymer structures and expand the chemical design space. By bridging the gap between academic research and industrial application, this review aims to accelerate the development of next-generation dielectric materials capable of balancing multiple performance metrics for high-temperature EES capacitors.</div></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"164 ","pages":"Article 101957"},"PeriodicalIF":26.0,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872421","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Oil-infused silicone elastomers for barnacle and ice release: The current state of understanding 用于藤壶和冰释放的油注入有机硅弹性体：目前的了解状态

IF 26 1区化学

Progress in Polymer Science Pub Date : 2025-05-01 DOI: 10.1016/j.progpolymsci.2025.101966

David G.T. Boucher , Maryam Safaripour , Andrew B. Croll , Dean C. Webster

{"title":"Oil-infused silicone elastomers for barnacle and ice release: The current state of understanding","authors":"David G.T. Boucher , Maryam Safaripour , Andrew B. Croll , Dean C. Webster","doi":"10.1016/j.progpolymsci.2025.101966","DOIUrl":"10.1016/j.progpolymsci.2025.101966","url":null,"abstract":"<div><div>The adhesion of foulants and contaminants on surfaces is a well-known problem, particularly in the marine environment, which can potentially be solved by the use of an appropriate coating. Over the years, silicone elastomers have stood out for their release performance toward various foulants, allowing the cleaning of these surfaces using low stresses. The addition of non-reactive silicone fluids into silicone elastomers has often been presented as a way to further enhance their release properties. However, the mechanism behind this improvement remains quite unclear and the effect of fluids is largely unpredictable and always assessed experimentally. This review thus attempts to tackle this issue by identifying trends in experimental observations made on barnacle and ice release and proposing theoretical tools to explain and potentially model or predict them. With this objective in mind, this review is divided into three sections and will first describe the chemistry of silicone elastomers while highlighting the parameters that allow tuning the elastomer’s final properties. In the second section, the influence of the physical properties of the silicone elastomer (modulus, thickness, surface energy) on its barnacle and ice-release properties will be discussed. In this section and further, strong similarities will be highlighted between observations made for these foulants. Finally, reports of fluid-containing silicone elastomers will be scrutinized to examine the potential impact of parameters such as compatibility, molecular weight, surface tension, and crosslink density. During this discussion, the potential mechanisms behind the improvement of release properties will be highlighted and supported by theoretical considerations.</div></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"164 ","pages":"Article 101966"},"PeriodicalIF":26.0,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143889865","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0