Proceedings of the Combustion Institute最新文献

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Effect of cross-wind on firebrand flame: An experimental study and scaling analysis 横风对火焰的影响:实验研究和比例分析
IF 3.4 2区 工程技术
Proceedings of the Combustion Institute Pub Date : 2024-08-02 DOI: 10.1016/j.proci.2024.105621
Weidong Yan, Naian Liu, Hong Zhu, Haixiang Chen, Xiaodong Xie, Linhe Zhang
{"title":"Effect of cross-wind on firebrand flame: An experimental study and scaling analysis","authors":"Weidong Yan, Naian Liu, Hong Zhu, Haixiang Chen, Xiaodong Xie, Linhe Zhang","doi":"10.1016/j.proci.2024.105621","DOIUrl":"https://doi.org/10.1016/j.proci.2024.105621","url":null,"abstract":"Spot fire is an important ignition pathway in the rapid spread of wildland and wildland-urban interface (WUI) fires. Firebrand combustion regime (flaming or glowing) and flame characteristics (flame tilt angle, flame length, and flame duration) are critical in predicting firebrand burning rate, spotting distance, and ignition hazard. Experiments were conducted to study firebrand combustion with various firebrand diameters ( = 10 to 20 mm) and wind speeds ( = 0 to 6 m s). The effects of the cross-wind on the pyrolysis rate, flame tilt angle (), flame length, and flame duration are investigated before the transition from flaming to glowing combustion ( 5 m s in this work). The pyrolysis rate is derived, showing it is proportional to ( is pyrolysis diameter). Then, the tan, flame length, and flame duration models are proposed based on the pyrolysis rate model. The tan is determined by wind speed and flame uprising speed (a speed controlled by the pyrolysis rate). The wind speed has a noticeable effect on the flame tilt angle. The derived flame length positively correlates with the volatile combustion rate, which is related to the pyrolysis rate. The flame length is proportional to and inversely proportional to for < 90°. The flame duration model is also derived, showing that the flame duration is related to the reduction rate of and is thus also affected by the pyrolysis rate. The flame duration is proportional to and inversely proportional to . The model predictions in tan, flame length, and flame duration agree well with the experimental data. Finally, a correlation equation of flame extinction ( 5 m s in this work) is related to critical wind speed and firebrand diameter.","PeriodicalId":408,"journal":{"name":"Proceedings of the Combustion Institute","volume":"78 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141886571","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Identification of entropy waves in a partially premixed combustor 识别部分预混燃烧器中的熵波
IF 3.4 2区 工程技术
Proceedings of the Combustion Institute Pub Date : 2024-08-02 DOI: 10.1016/j.proci.2024.105609
Alexander J. Eder, Bayu Dharmaputra, Alex M. Garcia, Camilo F. Silva, Wolfgang Polifke
{"title":"Identification of entropy waves in a partially premixed combustor","authors":"Alexander J. Eder, Bayu Dharmaputra, Alex M. Garcia, Camilo F. Silva, Wolfgang Polifke","doi":"10.1016/j.proci.2024.105609","DOIUrl":"https://doi.org/10.1016/j.proci.2024.105609","url":null,"abstract":"Unsteady combustion generates not only acoustic waves, but also fluctuations of the burnt gas temperature — referred to as entropy waves. These waves are convected by the mean flow through the combustor and result in conversion to acoustic energy when accelerated in an exit nozzle. The upstream traveling acoustic wave can then couple with the unsteady heat release of the flame and cause self-excited thermoacoustic instability, particularly at low frequencies (“rumble”). In this work, large eddy simulation (LES) is combined with system identification (SI) to determine the entropy transfer function (ETF) of a partially premixed, swirl-stabilized flame with hydrogen enrichment. We compare the single-input single-output (SISO) entropy transfer function identified from a broadband-forced LES with air mass flow modulation to the one obtained experimentally through tunable diode laser absorption spectroscopy with wavelength modulation spectroscopy (TDLAS-WMS) to measure temperature fluctuations. Then, multiple-input single-output (MISO) identification is applied to time series data obtained from simultaneous modulation of air and fuel mass flow to estimate the individual contributions of perturbations in velocity and equivalence ratio to entropy response. Equivalence ratio fluctuations are found to be the dominant generation mechanism of entropy waves. Finally, the entropy transfer function is identified at various positions in the combustion chamber to analyze the decay of entropy waves governed by convective dispersion.","PeriodicalId":408,"journal":{"name":"Proceedings of the Combustion Institute","volume":"99 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141886572","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of two-component liquid fuel mixtures on the dynamics of a swirl-stabilized spray flames array subjected to a forced transverse acoustic mode 双组分液体燃料混合物对受迫横向声学模式影响的漩涡稳定喷雾火焰阵列动力学的影响
IF 3.4 2区 工程技术
Proceedings of the Combustion Institute Pub Date : 2024-08-01 DOI: 10.1016/j.proci.2024.105566
Abdallah Alhaffar, Clément Patat, Jean-Bernard Blaisot, Éric Domingues, Françoise Baillot
{"title":"Effect of two-component liquid fuel mixtures on the dynamics of a swirl-stabilized spray flames array subjected to a forced transverse acoustic mode","authors":"Abdallah Alhaffar, Clément Patat, Jean-Bernard Blaisot, Éric Domingues, Françoise Baillot","doi":"10.1016/j.proci.2024.105566","DOIUrl":"https://doi.org/10.1016/j.proci.2024.105566","url":null,"abstract":"Reducing the environmental impact of aircraft engines could be achieved in particular through the use of drop-in sustainable aviation fuels. However, changing the fuel composition could give rise to operating issues, among which are transverse/azimuthal thermoacoustic combustion instabilities. In this context, the paper aims at characterizing the effect of two-component liquid fuel mixtures of n-heptane and dodecane on the dynamics of swirl-stabilized spray flames in a forced transverse acoustic mode of the combustion chamber. This is done by using a linear array of three flames, TACC-Spray, in which the central flame is placed at a pressure antinode. Analyses of the flame dynamics through the downstream-pressure-based Flame Describing Function, and of the thermoacoustic coupling qualified by a Rayleigh index show that increasing the proportion of n-heptane favors the propensity to instabilities. Flame dynamics is typified by the propagation of longitudinal flame intensity waves, whose amplitude significantly increases with the proportion of n-heptane. The fuel spray dynamics participates in the flame dynamics through the presence of droplet number waves and the oscillations of the Sauter mean diameter. The propagation of droplet number waves correlates well with that of flame intensity waves, indicating that the former waves are a fundamental mechanism at the basis of the swirl-stabilized spray flames dynamics. The decrease of the evaporation rate as the proportion of dodecane is increased appears as an essential feature which induces a weaker flame dynamics.","PeriodicalId":408,"journal":{"name":"Proceedings of the Combustion Institute","volume":"220 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141886421","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Shock tube and modeling study on the ignition delay times of ammonia/ethylene mixtures at high temperatures 高温下氨/乙烯混合物点火延迟时间的冲击管和模型研究
IF 3.4 2区 工程技术
Proceedings of the Combustion Institute Pub Date : 2024-08-01 DOI: 10.1016/j.proci.2024.105610
Chao Peng, Chun Zou, Jiacheng Liu, Lingfeng Dai, Wenxiang Xia
{"title":"Shock tube and modeling study on the ignition delay times of ammonia/ethylene mixtures at high temperatures","authors":"Chao Peng, Chun Zou, Jiacheng Liu, Lingfeng Dai, Wenxiang Xia","doi":"10.1016/j.proci.2024.105610","DOIUrl":"https://doi.org/10.1016/j.proci.2024.105610","url":null,"abstract":"Ammonia is a promising alternative clean fuel due to its carbon-free, high energy density and well-established infrastructure of storage and distribution. The co-combustion with reactive fuels improves the NH combustion stability. Moreover, CH is an important intermediate product in the oxidation of many hydrocarbon fuels. Therefore, some researchers focused the fundamental study and soot formation of NH/CH combustion. A reliable combustion model of NH/CH advances the understanding of the interaction between NH and CH. The key to develop the model of NH /CH is the cross reactions between N-containing species and C-containing species. In this work, the ignition delay times of NH/CH mixtures were measured at three blending ratios (95 %, 90 %, 70 % NH) at 1.75atm and 10atm in a shock tube at the temperature range of 1247 K to 1786 K. A detailed chemical kinetic model was developed on the base of our previous optimizing NH model and the CC sub-model of NUIGMECH1.1, and some new cross reactions between N-containing species and hydrocarbon species were considered in the model. The NH-CH model is validated by the current experimental data, the laminar flame speeds of NH/CH mixtures and the species profiles of NH/CH mixtures oxidation. The cross reactions considered in this work significantly improve the prediction. The disproportionation reactions, CH + NH <=> CH + NH (R1466) and HCO + NH <=> CO + NH (R1465), significantly inhibit the ignition and the flame propagation, and cause the increase in the formation of HCO and HCCO with the increase of NH content, which facilitates the reduction of the soot formation.","PeriodicalId":408,"journal":{"name":"Proceedings of the Combustion Institute","volume":"30 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141886577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Quantitative evaluation of four oxygen carriers for natural gas chemical looping combustion 四种氧气载体在天然气化学循环燃烧中的定量评估
IF 3.4 2区 工程技术
Proceedings of the Combustion Institute Pub Date : 2024-08-01 DOI: 10.1016/j.proci.2024.105641
Xianyu Liu, Zhenshan Li, Laihong Shen, Jinchen Ma, Xinhe Liu, Diwen He, Haibo Zhao
{"title":"Quantitative evaluation of four oxygen carriers for natural gas chemical looping combustion","authors":"Xianyu Liu, Zhenshan Li, Laihong Shen, Jinchen Ma, Xinhe Liu, Diwen He, Haibo Zhao","doi":"10.1016/j.proci.2024.105641","DOIUrl":"https://doi.org/10.1016/j.proci.2024.105641","url":null,"abstract":"Chemical looping combustion (CLC) reactors have developed into megawatt units, calling for industrial-scale oxygen carriers (OCs). Four typical OCs with potential for industrial-scale applications are quantitatively evaluated in terms of reactivity and attrition, including ilmenite (labeled as Ilm-NO), Cu-Fe bi-ore OC through hydroforming (labeled as CuFe-Hy), perovskite through spray drying (labeled as Per-SD), and Cu-based OC through impregnation (labeled as CuAl-Im). The 20-cycle reactivity test is operated in a batch fluidized bed reactor, while the 5-hour attrition test is conducted in an air jet attrition reactor. With the determined reduction durations via breakthrough testing, all OCs show no decrease in methane combustion performance. CuAl-Im demonstrates the highest instantaneous oxygen transferring rate of ca. 19.5 × 10 wt.%/s and the second maximum accumulated oxygen transferring amount of 3.74 wt.%. The OC reactivity follows the order of CuAl-Im > Per-SD > CuFe-Im > Ilm-NO. The attrition test results indicate that the attrition indexes, inversely proportional to the lifetimes of OCs, are 0.04 wt.% for Ilm-NO, 0.32 wt.% for CuFe-Hy, 0.20 wt.% for Per-SD, and 0.04 wt.% for CuAl-Im. Characterization results demonstrate all OCs get developed in pore structures except CuAl-Im due to its severe sintering after the reactivity test, which suppresses the regeneration of minor CuAlO. Reduced crushing strengths of four OCs are observed. Additionally, their phases are relatively stable, except for the migration of iron in Ilm-NO and CuFe-Hy, and the copper migration in CuAl-Im. The proposed method can be a preliminary standard to screen appropriate OC for industrial CLC units. The cycle number can be further reduced to 10 according to the reactivity tests, while the benchmark test details such the concentration of testing gases, reaction temperature, and reduction duration may need further consideration. Anyway, the obtained results are beneficial to the selection of OC for CLC of methane.","PeriodicalId":408,"journal":{"name":"Proceedings of the Combustion Institute","volume":"82 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141886418","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring the influence of swirl intensity on stability, emissions, and flame structure in non-premixed NH3/CH4 swirling flames 探索漩涡强度对非预混 NH3/CH4 漩涡火焰的稳定性、排放和火焰结构的影响
IF 3.4 2区 工程技术
Proceedings of the Combustion Institute Pub Date : 2024-08-01 DOI: 10.1016/j.proci.2024.105644
Ayman M. Elbaz, Zubayr O. Hassan, William L. Roberts
{"title":"Exploring the influence of swirl intensity on stability, emissions, and flame structure in non-premixed NH3/CH4 swirling flames","authors":"Ayman M. Elbaz, Zubayr O. Hassan, William L. Roberts","doi":"10.1016/j.proci.2024.105644","DOIUrl":"https://doi.org/10.1016/j.proci.2024.105644","url":null,"abstract":"Ammonia's appeal as a clean, carbon-free fuel is marred by its low reactivity and high NOx emissions, limiting its practical use. Understanding swirl intensity's influence on ammonia flame stabilization and emissions remains a gap. This study endeavors to explore the impact of swirl intensity on stabilization, NO/NH emissions, and the spatial distribution of NO and OH radicals in non-premixed NH/CH swirling flames. The burner consists of a central fuel jet (with a fuel jet velocity, U) surrounded by swirling airflow (of an air velocity, U). A blend of NH/CH, with ammonia mole fraction (: 0 to 0.85), was supplied to the central jet. The stability map, comparing U versus U, revealed that at the same swirl number (S), as U increased, a higher U became necessary to extinguish the flame, while, the higher levels amplified the sensitivity of U to U. For ≤ 0.25, an increase in S elevated the U required for the flame to blowout. However, this impact of S diminishes as increases until it starts to adversely reduce the blowout limits at = 0.85. At ≥ 0.75, adjusting Φ (the global mixture equivalence ratio) towards stoichiometry alongside increased S effectively lowers NO emissions and limits NH slip into the exhaust. The OH/NO-PLIF measurements highlight conical OH/NO layers near the burner exit. This conical NO layer transforms into a broader and more uniformly downstream, where the intensity of NO within this area likely mirrors the NO levels measured in the exhaust. Increasing at low S flames elongates both the OH/NO structure and intensifies the NO gradient in downstream distances. Conversely, an increase in S enhances fuel/air mixing and diminishes the impact of increased and Φ on the flame structure. A reduced sensitivity of NO emissions to Φ is observed with increasing S.","PeriodicalId":408,"journal":{"name":"Proceedings of the Combustion Institute","volume":"75 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141886417","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical study of the wall effect on the mass burning rate of small-scale methanol pool fires 壁效应对小规模甲醇池火灾质量燃烧速率的数值研究
IF 3.4 2区 工程技术
Proceedings of the Combustion Institute Pub Date : 2024-08-01 DOI: 10.1016/j.proci.2024.105619
Chonglv Cheng, Conghui Shan, Baopeng Xu, Jennifer X. Wen
{"title":"Numerical study of the wall effect on the mass burning rate of small-scale methanol pool fires","authors":"Chonglv Cheng, Conghui Shan, Baopeng Xu, Jennifer X. Wen","doi":"10.1016/j.proci.2024.105619","DOIUrl":"https://doi.org/10.1016/j.proci.2024.105619","url":null,"abstract":"Dynamic predictions of the mass burning rate of pool fires under different burner conditions are essential to facilitate pool fire simulations without the need for artificially setting the inlet boundary conditions for the fuel surface. Such capability can remove the need for prescribed mass burning rates of pool fires in quantified assessment of the fire hazards. A fully coupled three-dimensional (3-D) model based on a multi-zone approach has been developed. In the gas-phase region, a compressible solver was employed. In the liquid-phase region, an incompressible solver with temperature-dependent thermophysical properties was utilized to directly solve fuel flow, accounting for the Marangoni effect, buoyancy effect, and incident radiation. In the solid-phase region, the 3-D heat transfer equation was resolved. The heat and mass transfer processes between different regions were simulated using conjugate heat transfer and an evaporation model based on \"film theory\". The proposed model has been validated through comparison with the 9 cm diameter methanol pool fire experiments. The predictions showed promising agreement with experimental measurements and empirical corrections, with the error in mass burn rate being within 3.1 %. Additionally, the predictions have captured a pair of vortices in sizes and directions closely resembling experimental observations. The sizes of the predicted vortices increased with the rising temperature at the base of the pool due to buoyancy and shear force. The analysis revealed that the wall effect not only leads to differences in the number of vortices and Marangoni velocity but also leads to a smaller mass burning rate in the burner with a high thermal conductivity than in the one with a poor thermal conductivity in the 9 cm diameter methanol pool fire. Neglecting the wall heat transfer would result in up to 18 % underprediction of the mass burning rate.","PeriodicalId":408,"journal":{"name":"Proceedings of the Combustion Institute","volume":"55 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141886419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fluidized bed chemical looping for CO2 capture and catalytic methanation using dual function materials 流化床化学循环利用双功能材料进行二氧化碳捕集和催化甲烷化
IF 3.4 2区 工程技术
Proceedings of the Combustion Institute Pub Date : 2024-08-01 DOI: 10.1016/j.proci.2024.105648
Fiorella Massa, Elisabetta Maria Cepollaro, Stefano Cimino, Antonio Coppola, Fabrizio Scala
{"title":"Fluidized bed chemical looping for CO2 capture and catalytic methanation using dual function materials","authors":"Fiorella Massa, Elisabetta Maria Cepollaro, Stefano Cimino, Antonio Coppola, Fabrizio Scala","doi":"10.1016/j.proci.2024.105648","DOIUrl":"https://doi.org/10.1016/j.proci.2024.105648","url":null,"abstract":"CO capture from combustion flue gas combined to its catalytic hydrogenation to synthetic methane is considered as a promising technology in the field of Carbon Capture and Utilization (CCU). In this work, the integrated CO capture and methanation process was investigated in an innovative chemical looping configuration using dual function materials (DFMs) recirculated alternately between two interconnected bubbling fluidized bed reactors. By physically separating the CO capture step and the catalytic hydrogenation reaction in two coupled fluidized bed reactors it is possible to effectively control and independently optimize the operating temperature of each half cycle while running the process continuously. A high-performing Lithium-Ruthenium/AlO was selected to investigate the effect of the specific temperature level for the CO capture and the methanation phases in the range 200 - 400 °C, checking the stability and repeatability of the CO sorption and catalytic performance over 5 repeated cycles for each operating condition. Subsequently, under the best conditions in terms of methanation performance, a similar Na-promoted dual function material was also tested. The DFMs performance appeared to be quite reproducible over the cycles, but it was subject to kinetic limitations, especially in the case of Na-Ru/AlO. Interestingly, the methane yield approached 100 % under the highest tested temperatures for the Li-based DFM. Despite some limitations due to the experimental purge phases of the lab-scale system, the study provides the proof-of-concept of the process which enables the possibility of decoupling the two steps with the aim of a large potential intensification.","PeriodicalId":408,"journal":{"name":"Proceedings of the Combustion Institute","volume":"36 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141886576","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemical insights into ethyl acetate flames from experiment and kinetic modeling: Laminar burning velocity, speciation and NOx emission 通过实验和动力学建模深入了解醋酸乙酯火焰的化学性质:层流燃烧的速度、种类和氮氧化物排放
IF 3.4 2区 工程技术
Proceedings of the Combustion Institute Pub Date : 2024-08-01 DOI: 10.1016/j.proci.2024.105487
Sven Eckart, Krishna P. Shrestha, Binod R. Giri, Qilong Fang, Chen Chen, Wei Li, Hartmut Krause, Fabian Mauss, Dong Liu, Yuyang Li
{"title":"Chemical insights into ethyl acetate flames from experiment and kinetic modeling: Laminar burning velocity, speciation and NOx emission","authors":"Sven Eckart, Krishna P. Shrestha, Binod R. Giri, Qilong Fang, Chen Chen, Wei Li, Hartmut Krause, Fabian Mauss, Dong Liu, Yuyang Li","doi":"10.1016/j.proci.2024.105487","DOIUrl":"https://doi.org/10.1016/j.proci.2024.105487","url":null,"abstract":"Oxygenated fuels, such as alcohols, ethers, and esters, are promising alternatives to conventional fuels. These fuels can help reduce detrimental emissions like carbon monoxide and unburned hydrocarbons and enhance octane ratings. Among these oxygenates, ethyl acetate (EA), a small alkyl ester sourced from biomass, emerges as a clean, promising energy carrier. It serves as a surrogate fuel to facilitate investigations into the combustion behaviours of biodiesel. Despite its importance, the literature knowledge of EA combustion characteristics is limited. Therefore, this study aims to broaden the knowledge of the combustion behaviour of this type of oxygenated fuel compound. In this study, we measured the laminar burning velocities of EA by employing a heat flux burner and a closed combustion vessel over the equivalence ratios of 0.7 – 1.7, pressures of 1 – 10 bar and temperatures ranging from 353 – 423 K. Further, we also measured the NO emissions in exhaust gas of the premixed flames fueled by EA/air for the first time over the equivalence ratio of 0.8 – 1.2. Additionally, we employed a non-premixed counterflow flame setup for extensive characterisation of species and their concentration under diverse conditions encompassing various strain rates and oxygen concentrations. Finally, we utilized these newly measured data to construct and validate a detailed kinetic model developed as part of this work. The newly developed model will help characterize the combustion properties of EA.","PeriodicalId":408,"journal":{"name":"Proceedings of the Combustion Institute","volume":"34 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141886422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characteristics of liftoff, blowout and instability in nonpremixed jet flames with NH3/CH4 mixture fuels 使用 NH3/CH4 混合燃料的非预混合喷射火焰的升空、喷出和不稳定性特征
IF 3.4 2区 工程技术
Proceedings of the Combustion Institute Pub Date : 2024-08-01 DOI: 10.1016/j.proci.2024.105591
Jingru Zheng, Fei Tang, Suk Ho Chung, Longhua Hu
{"title":"Characteristics of liftoff, blowout and instability in nonpremixed jet flames with NH3/CH4 mixture fuels","authors":"Jingru Zheng, Fei Tang, Suk Ho Chung, Longhua Hu","doi":"10.1016/j.proci.2024.105591","DOIUrl":"https://doi.org/10.1016/j.proci.2024.105591","url":null,"abstract":"The effect of ammonia addition on the characteristics of liftoff, blowout, and instability is investigated experimentally in nonpremixed jet flames with NH/CH mixture fuels by the varying mole fraction of ammonia (). Both laminar and turbulent lifted flames are observed and the lifted flame for = 0.3 has a transition from laminar to turbulent lifted flame, when the jet flow is in the laminar-to-turbulent transition regime. The results demonstrate that, for ≤ 0.3, only turbulent lifted flame exists and the liftoff height increases linearly with the fuel jet velocity , as well as the ammonia mole fraction. A satisfactory linear relationship between nondimensional turbulent lifted flame height and nondimensional flow velocity can be obtained, based on the turbulent intensity theory. For > 0.3, only laminar lifted flame exists and the liftoff height increases reasonably linearly with , which is stabilized in the jet developing region. Both the critical liftoff () and blowout () velocities decrease with the increase in . When is scaled with laminar burning velocity , / is insensitive to for ≤ 0.3, having / ≈ 50, while it decreases linearly for > 0.3. While / decreases linearly with the increase in . These critical velocities show that no flame can be stabilized for > 0.5. The oscillation frequency of laminar nozzle-attached flame for CH/NH mixture fuel slightly increases with , while the critical Froude number (Fr) for the transition from sinuous to varicose modes of oscillation increases with ammonia addition. The flame oscillation frequency can be characterized by the Strouhal number St having a power law relationship of St ∝ (1/Fr).","PeriodicalId":408,"journal":{"name":"Proceedings of the Combustion Institute","volume":"34 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141886420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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