Molecular Catalysis最新文献

{"title":"Nano UiO-66 and UiO-66-NH2 MOFs as Bifunctional Electrocatalysts for Water-Splitting: A Comparative Study","authors":"Batol Abbas,&nbsp;A.V. Ravindra","doi":"10.1016/j.mcat.2025.115025","DOIUrl":"10.1016/j.mcat.2025.115025","url":null,"abstract":"<div><div>This study focuses on the synthesis and comparative evaluation of nano UiO-66 (U) and UiO-66-NH₂ (U-N) MOFs as bifunctional electrocatalysts for water-splitting. The U and U-N MOFs are synthesized via a convection solvothermal method, and their structural, optical, and electrochemical properties, along with their performance in the Oxygen Evolution Reaction (OER) and Hydrogen Evolution Reaction (HER), are comprehensively characterized. The XRD patterns confirm the high crystallinity of both U and U-N, while FTIR spectra indicate the presence of typical functional groups in these MOFs. The UV-Vis absorbance spectra reveal a red shift in U-N compared to U, signifying a reduced band gap energy due to amino functional groups. TEM images display distinct particle sizes and morphologies with U-N exhibiting agglomerated particles and a narrower size distribution. BET analysis demonstrates the porous nature of both MOFs, with U exhibiting a greater surface area. Electrochemical studies reveal that U-N exhibits superior OER activity, characterized by lower overpotential, and a lower Tafel slope, as well as exceptional stability under prolonged electrochemical conditions. The amine (NH₂) groups in U-N are the primary factor contributing to its enhanced OER performance. Additionally, U-N displays a reduced band gap energy, promoting improved catalytic activity and sustained performance. On the other hand, the U MOF demonstrates promising HER activity, maintaining effective current density for a significant duration, albeit indicating the need for enhancements to ensure prolonged stability. The CV and Nyquist plots further reveal that the U-N MOF possesses a larger electrochemical surface area, higher sensitivity, and enhanced conductivity, attributed to the presence of amino (NH₂) groups, leading to more efficient charge transport within the material. Overall, this comparative study underscores the potential of U-N as a highly efficient electrocatalyst for water-splitting applications, offering valuable insights for the design and development of advanced MOF-based electrocatalysts.</div></div>","PeriodicalId":393,"journal":{"name":"Molecular Catalysis","volume":"578 ","pages":"Article 115025"},"PeriodicalIF":3.9,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143619479","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ethylene glycol partial oxidation on Co3O4 (001) surface: Interplay between solute’s surface coverage and aqueous solvation","authors":"F.B.S. Nkou,&nbsp;S. Kenmoe","doi":"10.1016/j.mcat.2025.114980","DOIUrl":"10.1016/j.mcat.2025.114980","url":null,"abstract":"<div><div>Using ab initio molecular dynamics simulations, we investigate the coverage dependent adsorption and decomposition of ethylene glycol (Egly), from the low coverage regime to surface saturation (0.13 ML to 0.44 ML) on the B-terminated Co₃O₄ (001) surface in dry and humid environments. We have analyzed the structure of Egly at the interface and identified the most probable binding mode and conformations. In dry conditions, Egly binds to the surface mostly via a bidendate mode and in a gauche conformation. Only single deprotonation events occur, leading to the formation of OHCH₂CH₂O species. A neutral aqueous solvent barely alters the situation. In the presence of a hydroxyl-rich aqueous solvent, OHCH₂CH₂O intermediates further decompose to form glycolaldehyde, which evolves to acetate and coexist together with OHCH₂CH₂O and OCH₂CH₂O species. This behavior holds from low coverage to half-saturation of the surface (up to 0.25 ML). Higher Egly population hinders oxidation and only hydrogen peroxide forms in favorable cases. Our work provides insight into the complex interplay between key factors governing the two-electron oxidation: the role of solvation, the relevant solute’s concentration range, the size of the active surface regions as well as the chemical state of interfacial water and its competition with Egly.</div></div>","PeriodicalId":393,"journal":{"name":"Molecular Catalysis","volume":"578 ","pages":"Article 114980"},"PeriodicalIF":3.9,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143619573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Environmentally friendly and recyclable Dawson-type polyoxometalate: A novel homogeneous catalytic system for degradation of dye pollutants","authors":"Mohammed Grabsi ,&nbsp;Nacéra Zabat ,&nbsp;Mohamed Djermane ,&nbsp;Abdeltif Amrane","doi":"10.1016/j.mcat.2025.114997","DOIUrl":"10.1016/j.mcat.2025.114997","url":null,"abstract":"<div><div>This research paper investigates the catalytic potential of a Dawson-type polyoxometalate-based metal complex (Co-POM) in the efficient degradation of Indigo Carmine (IC) and Methyl Orange (MO) dyes. The synthesized complex was characterized using a variety of characterization techniques, and its catalytic activity was evaluated during the degradation of these dyes under different experimental conditions. The results of the study reveal that this new environmental homogeneous catalytic system (H₂O₂/Co-POM/Dye) exhibits notable catalytic efficiency, leading to effective degradation of the dyes under consideration. The influence of various parameters on catalytic performance was systematically investigated.The cobalt-substituted complex (Co-POM) showed the best catalytic efficiency compared with other transition metal-substituted POMs {Ni(II), Cu(II), Mo(II)} and the parent POM, with a degradation of 87.4 % for IC and 94.3% for MO under the following optimized conditions: an initial hydrogen peroxide (H₂O₂) concentration of 0.02 M, a catalyst concentration of 0.2 mM, and an initial dye concentration of 5 mg/L at pH 3 and room temperature (25 °C). It revealed the oxidative role of hydroxyl radicals (OH<strong>^●</strong>), hydroperoxyl radicals (HO₂^●), and superoxydes (O₂•) as reactive species, on the basis of which a plausible degradation mechanism is proposed.The recyclability test indicated good catalyst stability over five consecutive cycles with a very low loss of catalytic efficiency (∼5 %). Their stability and robustness were verified by various characterization techniques such as UV–vis spectroscopy, FT-IR spectroscopy, single crystal X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FE-SEM), and Energy Dispersive X-ray analysis (EDX).</div></div>","PeriodicalId":393,"journal":{"name":"Molecular Catalysis","volume":"578 ","pages":"Article 114997"},"PeriodicalIF":3.9,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143619574","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Surface basicity induced Pd doped Cu/ZnO/ZrO2 for selective CO2 hydrogenation to Methanol","authors":"Vivek Kumar Shrivastaw ,&nbsp;Gaje Singh ,&nbsp;Satyajit Panda ,&nbsp;Jyotishman Kaishyop ,&nbsp;Subham Paul ,&nbsp;Ankur Bordoloi","doi":"10.1016/j.mcat.2025.114966","DOIUrl":"10.1016/j.mcat.2025.114966","url":null,"abstract":"<div><div>This study investigates the influence of palladium (Pd) doping on Cu/ZnO/ZrO₂ catalysts for selective CO₂ hydrogenation to CH₃OH, combining comprehensive experimental characterizations with theoretical insights. The catalysts, synthesized with varying Pd loadings (0–3 wt.%), were evaluated across 210–250 °C. Catalytic performance analysis revealed that 2 wt.% Pd (CZZPd2) demonstrated superior CO₂ conversion (22%) and methanol selectivity (64%) at 240 °C, achieving the highest methanol space-time yield (7.54 mmol/g.cat/hr). Characterization techniques, including XRD, XPS, TEM, CO₂-TPD, and H₂-TPR, highlighted the critical role of Pd in enhancing hydrogen spillover, stabilizing Cu active sites, and promoting optimal oxygen vacancy formation, which collectively facilitated intermediate stabilization and reduced the apparent activation energy (Ea = 52 kJ/mol) for methanol synthesis. In-situ DRIFTS validated the stabilization of key reaction intermediates (formate and methoxide) on CZZPd2, correlating with its superior catalytic performance. DFT calculations provided atomic-level insights, illustrating the synergistic electronic interaction between Pd, Cu, and ZnO, which optimally lowers the energy barrier for CO₂ activation and methanol formation. Excessive Pd loading (CZZPd3) led to particle agglomeration, disrupted metal-oxide interactions, and increased activation energy, reducing methanol selectivity. These findings highlight the important role of Pd in shaping the structure and electronic properties of the catalyst, making CZZPd2 as a benchmark catalyst for efficient and selective CO₂ hydrogenation to methanol.</div></div>","PeriodicalId":393,"journal":{"name":"Molecular Catalysis","volume":"578 ","pages":"Article 114966"},"PeriodicalIF":3.9,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143619571","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Zn supported on composite materials as catalysts for fine chemical applications","authors":"Luis Fernando Valencia ,&nbsp;Isabel Agudelo ,&nbsp;Juan Badano ,&nbsp;Mónica Quiroga ,&nbsp;Carolina Betti ,&nbsp;Cecilia Lederhos ,&nbsp;Aída Luz Villa","doi":"10.1016/j.mcat.2025.115012","DOIUrl":"10.1016/j.mcat.2025.115012","url":null,"abstract":"<div><div>In this work, zinc supported composite catalysts were evaluated in the isomerization of β-pinene epoxide, limonene oxidation, and one pot synthesis of campholenic aldehyde from α-pinene. The composites materials were synthesized using CaCO₃ and a mixture of aluminium and magnesium sources as the inorganic phases and the bisphenol A glycerolate dimethacrylate / triethylene glycol dimethacrylate polymerized mixture as the polymeric organic phases. The materials were characterized by NH₃-TPD, CO₂-TPD, XRD, Py-FTIR, XPS, ICP, TEM and SEM-EDX. Mainly Lewis acid sites were identified by Py-FTIR analysis of BTAlMg and Zn-BTAlMg. The basicity of BTCa and Zn-BTCa materials was identified by CO₂-TPD. Over Zn-BTCa, α-pinene conversion of 73 % and campholenic aldehyde selectivity of 90 % were obtained. The oxidation of limonene over Zn-BTCa yielded a conversion of 36 % with a selectivity of 92 % and 8 % towards 1,2-limonene epoxide and 8,9-limonene epoxide, respectively. The isomerization of β-pinene epoxide over Zn-BTAlMg with dimethyl carbonate, gave 89 % β-pinene epoxide conversion and 100 % selectivity to myrtanal. The synthesized catalysts did not show leaching under tested catalytic reactions. After four reuses, the product selectivity did not significantly changed and the conversion decreased 7 % and 11 % in the oxidation of α-pinene and isomerization of β-pinene epoxide, respectively.</div></div>","PeriodicalId":393,"journal":{"name":"Molecular Catalysis","volume":"578 ","pages":"Article 115012"},"PeriodicalIF":3.9,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143609968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Boosting the activity and selectivity for hydrogenation of benzoic acid to benzaldehyde by constructing Y-ZnO/Al2O3 catalyst","authors":"Qihui Ding ,&nbsp;Guoqiang Li ,&nbsp;Biao Li ,&nbsp;Qian Jia ,&nbsp;Xiaoyang Yang ,&nbsp;Feng Li ,&nbsp;Yanfeng Pu ,&nbsp;Lei Li","doi":"10.1016/j.mcat.2025.115024","DOIUrl":"10.1016/j.mcat.2025.115024","url":null,"abstract":"<div><div>Gas-phase benzoic acid hydrogenation is a promising strategy to produce benzaldehyde, but the formidable obstacle is the development of cost-effective and environmentally friendly catalysts. Herein, we carefully constructed the Y-ZnO/Al₂O₃ catalyst, which achieved 92.1 % benzoic acid conversion and 92.7 % benzaldehyde selectivity and maintaining stable performance for over 200 h at 350 °C under atmospheric pressure. The structure-activity relationship revealed that the smaller and electron-rich ZnO particles were formed by the addition of yttrium oxides (YO<em>_x</em>), which facilitating the hydrogen dissociation and the formation of oxygen vacancies, thus promoting the conversion of benzoic acid. Moreover, the YO<em>_x</em> also inhibited the overreduction of Zn²⁺ to Zn⁰ in ZnO, resulting in a significant reduction of the byproduct benzene to improve the selectivity of benzaldehyde. Finally, the reaction pathways of benzoic acid hydrogenation over Y-ZnO/Al₂O₃ were proposed based on experimental results in conjunction with characterization analysis. This work developed a cost-effective and environmentally friendly catalyst for the hydrogenation of benzoic acid to benzaldehyde and provided a theoretical insight of the structure-activity relationship.</div></div>","PeriodicalId":393,"journal":{"name":"Molecular Catalysis","volume":"578 ","pages":"Article 115024"},"PeriodicalIF":3.9,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143609967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Uniformly dispersed Bismuth nanoclusters anchored on reduced graphene oxide (rGO)&carbon black for high-efficiency electroreduction CO2 to formate","authors":"Guanghui Li ,&nbsp;Yuxuan Shi ,&nbsp;Xiduan Yang ,&nbsp;Changye Mang ,&nbsp;Jun Luo ,&nbsp;Mingjun Rao","doi":"10.1016/j.mcat.2025.115011","DOIUrl":"10.1016/j.mcat.2025.115011","url":null,"abstract":"<div><div>In this work, bismuth metal nanoclusters immobilized on reduced graphene oxide (rGO) and carbon black (Bi/rGO&amp;CB) were found to be highly efficient catalysts for the electrochemical reduction of carbon dioxide (CO₂) to formate (HCOO^-). During the CO₂ electroreduction process, Bi/rGO&amp;CB exhibited a Faradaic efficiency (FE) for HCOO^- of 94.16 % at -0.88 V versus the reversible hydrogen electrode (RHE). Additionally, at -1.18 V vs. RHE, the current density for HCOO^- production in the presence of Bi/rGO&amp;CB reached -16.0 mA·cm^-2, which is nearly three times higher than the -6.5 mA·cm^-2 observed with commercial Bi powder. The presence of nanocrystal clusters in Bi/rGO&amp;CB significantly enhances both the catalytic activity and Faraday efficiency of the catalyst. Mechanistic studies revealed that these nanocrystal clusters in Bi/rGO&amp;CB facilitate the Faradaic process and accelerate reaction kinetics compared to Bi/rGO and commercial Bi powder.</div></div>","PeriodicalId":393,"journal":{"name":"Molecular Catalysis","volume":"578 ","pages":"Article 115011"},"PeriodicalIF":3.9,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143593795","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Efficient plasma-assisted ammonia synthesis over a Ni catalyst supported on citrate-modified MgO-Al2O3","authors":"Chenlong Hu,&nbsp;Shijie Jiang,&nbsp;Linhan Yu,&nbsp;Xiaoqiang Shen,&nbsp;Tian Tang,&nbsp;Jinfei Chen,&nbsp;Yanrong Chen,&nbsp;Xuesen Du","doi":"10.1016/j.mcat.2025.115013","DOIUrl":"10.1016/j.mcat.2025.115013","url":null,"abstract":"<div><div>Non-thermal plasma-catalyzed ammonia synthesis has garnered significant attention due to its high efficiency under mild conditions. However, developing highly efficient catalysts remains a challenge, and substantial improvements in catalyst performance are still needed. In this study, we developed a novel Ni-MgAl-CA catalyst using a one-pot citrate modification method. Under conditions of 25 kJ/L energy input, the ammonia synthesis rate of the Ni-MgAl-CA catalyst reached 6510 µmol/g/h, with an energy yield of 0.89 g-NH₃/kWh. The catalyst's structure and surface properties were systematically characterized using various techniques. The results demonstrated that citrate modification significantly increased the concentration of oxygen vacancies on the catalyst surface, optimized the microstructure, and promoted the high dispersion of Ni. These oxygen vacancies played a critical role in enhancing the adsorption and activation of nitrogen molecules, as confirmed by experimental and characterization data. These findings confirm that citrate modification is an effective strategy for optimizing the structure and surface properties of catalysts, thereby significantly improving the efficiency of non-thermal plasma-catalyzed ammonia synthesis. This work offers valuable insights into the design and development of more efficient catalysts for ammonia production.</div></div>","PeriodicalId":393,"journal":{"name":"Molecular Catalysis","volume":"578 ","pages":"Article 115013"},"PeriodicalIF":3.9,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143601842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Wide spectral response enables efficient photochemistry-assisted selective hydrogenation of butadiene over Pd/N-TiO2","authors":"Bo Jiang ,&nbsp;Shu-Lin Liu ,&nbsp;Zhe-Yan Jin ,&nbsp;Zhao Wang ,&nbsp;Bin-Can Cheng ,&nbsp;Ze-Long Guan ,&nbsp;Ying Hong ,&nbsp;Zhao Wei ,&nbsp;Zhi Qiao ,&nbsp;Jian Tao ,&nbsp;Bao-Lian Su","doi":"10.1016/j.mcat.2025.115018","DOIUrl":"10.1016/j.mcat.2025.115018","url":null,"abstract":"<div><div>Selective hydrogenation driven by heat is a critical industrial process for purifying alkene feedstocks with serious problems of energy and H₂ consumption. Photochemistry-assisted strategy offers a sustainable alternative owing to its superiority of H₂-free reaction under ambient temperature, unfortunately, with a challenging demand on efficient catalysts. Herein, a wide-spectrum-responsive Pd/N-TiO₂ photo-thermal catalyst was developed by a solvothermal method for photochemistry-assisted selective hydrogenation of butadiene in propene. It shows an excellent catalytic performance, with 100 % alkenes selectivity and 100 % butadiene conversion under irradiation of full-light (i.e., 320 nm∼780 nm). Notably, over 53 % butadiene conversion with 100 % alkenes selectivity was successfully retained on Pd/N-TiO₂ after shortening the wavelength range to visible light, much superior to that on Pd-TiO₂ (i.e., &lt;1 % butadiene conversion). Further exploration reveals that the nitrogen doping extends the light-responsive wavelength of titanium oxide from ∼380 nm to above 500 nm owing to the formation of Ti³⁺ and oxygen vacancies, which later create a defect energy level (i.e., ∼-0.53 to -0.12 eV) between the valence-conduction band of TiO₂. The wide spectral response of N-TiO₂ enhances the water photolysis to produce intermediate hydrogen ([H]) that acts as the hydrogen source for the tandem butadiene hydrogenation over the Pd surface. The work indicates that developing a dual-functional catalyst with an expanded light-responsive wavelength is an efficient way to enhance the photochemistry-assisted selective hydrogenation.</div></div>","PeriodicalId":393,"journal":{"name":"Molecular Catalysis","volume":"578 ","pages":"Article 115018"},"PeriodicalIF":3.9,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143593781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Direct conversion of glucose into acetylfurans via C−C bond cleavage over Cs promoted Mo-based catalyst","authors":"Wei Wang ,&nbsp;Rui Zhang ,&nbsp;Jiaqing Li ,&nbsp;Huai Liu ,&nbsp;Wenlong Jia ,&nbsp;Junhua Zhang ,&nbsp;Dan Li ,&nbsp;Lincai Peng","doi":"10.1016/j.mcat.2025.115009","DOIUrl":"10.1016/j.mcat.2025.115009","url":null,"abstract":"<div><div>Furans are important scaffolds with applications in pharmaceuticals, polymers synthesis and biofuels. The direct production of new types of furans from glucose is therefore significant but remains a great challenge. Herein, we report a facile strategy to produce acetylfurans directly from glucose over MoCs-SiO₂, with an increase in yield from 35.8 % to 81.4 % compared with pristine Mo-SiO₂ due to the facilitated C−C bond cleavage of glucose. The incorporation of Cs improved the dispersion of Mo species, induced the formation of partially reduced Mo, increased the Lewis acidity and glucose adsorption of the catalyst, and thus shifting the reaction selectivity from C−C coupling to cleavage. Kinetic studies further demonstrated the positive contribution of Cs as a promoter in lowering the activation energy of C−C bond cleavage. This study provides a promising strategy to broaden the range of furanic compounds derived from glucose for product-oriented biorefineries.</div></div>","PeriodicalId":393,"journal":{"name":"Molecular Catalysis","volume":"578 ","pages":"Article 115009"},"PeriodicalIF":3.9,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143593794","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}