Microporous and Mesoporous Materials最新文献

{"title":"A novel physicochemical activation method to synthesize mesopores enriched bamboo porous carbon for high-efficient adsorption of methylene blue","authors":"Xune Fan ,&nbsp;Baiyang Qiu ,&nbsp;Xundong Tian ,&nbsp;Xi Yang","doi":"10.1016/j.micromeso.2025.113625","DOIUrl":"10.1016/j.micromeso.2025.113625","url":null,"abstract":"<div><div>Industrial waste water from the textile and printing industries contains high concentrations of dyes, demonstrating a negative impact on both water ecosystems and human health. Bio-activated carbon with advantages of large surface area, good stability, high practical and cost-effective features serve as promising materials to address this problem. In this study, a novel one-step physicochemical carbonization-activation method involving H₃PO₄ and CO₂ was employed to prepare highly adsorptive bamboo porous carbon for methylene blue (MB) removal from wastewater by utilizing bamboo waste as a raw material. The structure characterization, adsorption isotherms and kinetic analyses showed that the specific surface area of bamboo porous carbon and its adsorption capacity on MB followed a rise with activation temperature. Benefiting from the deep reaction between bamboo carbon and physicochemical activators, mesopores enriched porous structure was achieved and the maximum specific surface area reached 2250 m²/g. Adsorption by bamboo porous carbon was primarily involved pore filling, electrostatic attraction, π-π stacking, and hydrogen bonding, contributing to the adsorption capacity of MB as high as 759.15 mg/g. Adsorption kinetics and isotherms followed pseudo-first-order model and Langmuir isotherm model. This study provides a novel, facile approach to obtain mesopores enriched bamboo porous carbon for realizing value-added utilization of bamboo wastage and its application in dye wastewater treatment.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"394 ","pages":"Article 113625"},"PeriodicalIF":4.8,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143917329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhanced drug delivery using surface-roughened MgO@Silica nanoparticles loaded with doxorubicin","authors":"Manoj Kumar Sharma ,&nbsp;Nidhi Aggarwal ,&nbsp;Ravi Kumar ,&nbsp;Jiban Jyoti Panda ,&nbsp;Chengzhong Yu ,&nbsp;Ashok K. Ganguli","doi":"10.1016/j.micromeso.2025.113624","DOIUrl":"10.1016/j.micromeso.2025.113624","url":null,"abstract":"<div><div>Nanoparticle based drug carriers have attracted considerable interest in drug delivery applications. However, their low drug loading efficiency of certain chemotherapeutic agents, insufficient cellular uptake, and limited <em>in-vitro</em> efficacy remain a significant challenge. In this study, we have synthesized and characterized MgO@silica core-shell nanoparticles with distinct surface morphologies: MgO@silica-smooth(S) and MgO@silica-rough(R). The rough-surfaced MgO@silica-R exhibited a significantly higher surface area and drug encapsulation efficiency (∼97 %) for the anticancer drug doxorubicin (Dox), compared to the smooth MgO@silica-S counterpart (∼37 %). The rough morphology of MgO@silica-R resulted in sustained drug release and a 2.5-fold increase in cellular uptake inside C6 glioma cells as compared to free Dox. Dox-loaded MgO@silica-R showed superior anticancer efficacy, inducing ∼90 % cell death, surpassing both MgO@silica-S and free Dox. These findings underscore the potential of MgO@silica-based nanoparticles, particularly those with rough surface properties, as effective carriers for targeted drug delivery and cancer treatment.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"391 ","pages":"Article 113624"},"PeriodicalIF":4.8,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143783546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ligand-engineered copper-based triazolate MOFs: enhanced adsorption performance for methyl blue removal","authors":"Yujie Zhang ,&nbsp;Wenmei Zhang ,&nbsp;Guang Yang ,&nbsp;Zhihao Chen ,&nbsp;Wenhua Zhang","doi":"10.1016/j.micromeso.2025.113623","DOIUrl":"10.1016/j.micromeso.2025.113623","url":null,"abstract":"<div><div>A series of copper triazolate metal-organic frameworks (MOFs), denoted as CuTz-1_X (X = CH₂OH, Py, and FPh), were synthesized via doping functionalized triazole ligands (3,5-R₂-tzH where R = CH₂OH, Py, or FPh) into the reactant of parent CuTz-1 ([Cu₈(3,5-Ph₂-tz)₆](BF₄)₂(CH₃OH), where 3,5-Ph₂-tz = 3,5-diphenyl-1,2,4-trizolate). The synthesized MOFs were thoroughly characterized via PXRD, ¹H NMR, SEM-EDS, EA, TG, etc. It was observed that doping ligands featuring similar size and structure with 3,5-diphenyl-1,2,4-triazole in the parent MOF CuTz-1 resulted in a higher incorporation quantity. Furthermore, the introduction of functional ligands into the modified MOFs, CuTz-1_X, led to enhanced adsorption performance for the removal of methyl blue (MeB) in comparison with that observed over the parent MOF. Especially, CuTz-1_Py, in which 3,5-bis(4-pyridinyl)-1,2,4-triazole was doped, exhibited the highest MeB adsorption capacity of 352.3 mg·g⁻¹ at 293 K. Besides, the adsorption capacity of MeB over CuTz-1_X MOFs materials maintained stable even in the simulated real water systems. More importantly, the adsorption efficiency of MeB over CuTz-1_Py was still 87 % after four cycles of adsorption experiments while preserving the crystallinity and morphology of the adsorbent, indicating that the modified MOFs materials (i.e. CuTz-1_X) could be promising candidates for wastewater treatment.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"392 ","pages":"Article 113623"},"PeriodicalIF":4.8,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143792113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"3D-printed activated carbon monoliths for efficient CO2 capture","authors":"Henrry Ortega-Ortiz ,&nbsp;Laura M. Esteves ,&nbsp;Andreia F.M. Santos ,&nbsp;Jeniffer Carrillo ,&nbsp;Isabel M. Fonseca ,&nbsp;José P.B. Mota ,&nbsp;Inês Matos ,&nbsp;Rui P.P.L. Ribeiro","doi":"10.1016/j.micromeso.2025.113621","DOIUrl":"10.1016/j.micromeso.2025.113621","url":null,"abstract":"<div><div>In gas-phase adsorption processes, adsorbents are typically used as beads or pellets in a fixed bed. While these shapes permit their application in adsorption processes, they fall short of achieving optimal performance. This limitation can be greatly improved by employing structured materials, which offer reduced pressure drop and enhanced mass and energy transfer, thereby improving the overall process efficiency. Herein, resol-based activated carbons (ACs) are structured using 3D-printed sacrificial water-soluble templates to produce custom-designed monoliths for efficient carbon dioxide (CO₂) capture. The influence of activation conditions (time under CO₂ flow) on textural properties, CO₂ adsorption capacity, and CO₂/nitrogen (N₂) selectivity are investigated. Prolonging the activation time leads to a progressive increase in surface area and micropore volume, as more carbon is removed through gasification reactions with CO₂. The resulting enhancement in porosity improves the CO₂ adsorption capacity. However, the AC with the lowest burn-off has the highest selectivity for CO₂ over N₂ (considering a binary CO₂/N₂ mixture with 15 mol% of CO₂) due to its lower ability to adsorb N₂. Overall, this work highlights the potential of a modern 3D-printing fused deposition modeling technique to engineer structured adsorbents with applications in gas separation processes, such as CO₂ capture.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"392 ","pages":"Article 113621"},"PeriodicalIF":4.8,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143786000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A stable Al-MOF based on pore size control strategy for efficient SF6/N2 separation","authors":"Zi-Yue Liu ,&nbsp;Jiang-wen Yan ,&nbsp;Qianji Han ,&nbsp;Jin-Can Zhao ,&nbsp;Lei Liu ,&nbsp;Ruihan Wang ,&nbsp;Shan-Qing Yang ,&nbsp;Jian-Long Du","doi":"10.1016/j.micromeso.2025.113622","DOIUrl":"10.1016/j.micromeso.2025.113622","url":null,"abstract":"<div><div>SF₆ has been widely used as an insulating medium, but it can also cause serious greenhouse effect. The efficient separation of SF₆ appears very important and challenging. A stable and scalable synthesis of Al-MOF (MOF-303) is reported in the present work, which possesses an appropriate pore size (6.79 Å) that matches the dynamic diameter of SF₆ molecules (5.2 Å). MOF-303 shows a higher adsorption capacity of SF₆ (49.70 cm³/g) at low pressure (10 kPa) and ambient temperature, and the excellent adsorption selectivity of SF₆/N₂ (10:90) achieves 183.37 at ambient conditions. Meanwhile, breakthrough experiments exhibit that MOF-303 can efficiently separate high purify SF₆ form SF₆/N₂ mixtures at ambient conditions. The relevant experimental conclusions have been further verified by theoretical calculations. The stronger binding energy between MOF-303 and SF₆ molecule should be responsible for the efficient SF₆ adsorption and separation. More importantly, the adsorption capacity of SF₆ by the particle sample has decreased, but it still exhibits excellent gas separation ability. The results will contribute to the design efficient and practical gas separation materials.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"391 ","pages":"Article 113622"},"PeriodicalIF":4.8,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143783547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Chelating-agent-protected nickel incorporation into TS-1 framework for enhanced phenol hydroxylation catalysis with improved stability and efficiency","authors":"Zhitao Lv ,&nbsp;Siyu Zhang ,&nbsp;Yufei Zhou ,&nbsp;Jiebai Li ,&nbsp;Guangguang Guan ,&nbsp;Yilai Jiao","doi":"10.1016/j.micromeso.2025.113611","DOIUrl":"10.1016/j.micromeso.2025.113611","url":null,"abstract":"<div><div>The phenol hydroxylation reaction represents a promising green strategy for the sustainable production of dihydroxybenzene. However, the high cost and mass transfer limitations associated with traditional titanium silicalite-1 (TS-1) catalysts significantly hinder their industrial scalability. In this study, a novel chelating-agent-protected technique, combined with a tetrapropylammonium hydroxide (TPAOH) hydrothermal treatment strategy, was developed to achieve the uniform incorporation of nickel ions into the TS-1 framework. This dual approach effectively redistributed the charge density, modulated the surface acidity, and introduced hierarchical structures, thereby addressing the intrinsic diffusion and catalytic limitations of conventional microporous TS-1. Unlike conventional nickel modification methods, the chelating-agent-protected strategy successfully prevented nickel ion reduction or the formation of nickel oxide particles, ensuring highly dispersed and framework-integrated nickel species. The incorporation of nickel further enhanced the synergistic interaction with titanium, significantly reducing the binding energy of tetrahedral framework titanium (Ti⁴⁺) and enhancing the electrophilicity of active catalytic sites. These structural and electronic improvements translated into superior catalytic performance, with the framework-engineered nickel-modified catalyst (CSD(1.68)@HTS-1) achieving a phenol conversion rate of 31.0 %, compared to 25.3 % for unmodified HTS-1. Furthermore, the selectivity for hydroquinone increased from 57.8 % to 59.3 %. The CSD(1.68)@HTS-1 catalyst also demonstrated excellent structural stability and recyclability, maintaining consistent activity and selectivity over multiple reaction cycles. This innovative framework-engineering strategy provides a cost-effective and scalable approach for the design of high-performance nickel-modified zeolite catalysts, offering new insights into the development of sustainable and efficient catalytic systems for industrial applications.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"391 ","pages":"Article 113611"},"PeriodicalIF":4.8,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143739154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Adsorption dynamics of aromatic and polar volatile organic compounds on metal-organic frameworks","authors":"Sina Neshati,&nbsp;Zaher Hashisho","doi":"10.1016/j.micromeso.2025.113619","DOIUrl":"10.1016/j.micromeso.2025.113619","url":null,"abstract":"<div><div>The study explores the effectiveness of metal-organic frameworks (MOFs) in capturing volatile organic compounds (VOCs). Specifically, it investigates the effect of polarity and aromaticity of VOCs on their adsorption behavior on two MOFs, CuBTC and FeBTC. Cyclic adsorption breakthroughs and isotherms were completed using toluene, 2-methylpyridine, n-hexane, and 2-methyl-2-butanol as adsorbates to assess the frameworks' adsorption and regeneration capabilities. X-ray diffraction, X-ray photoelectron spectroscopy, thermogravimetry analysis, Fourier transform infrared spectroscopy and nitrogen adsorption/desorption isotherm were used to evaluate the MOFs' crystallinity, thermal stability, and surface properties. The results suggest that CuBTC demonstrates superior adsorption capabilities for all tested VOCs, due to its larger surface area and higher crystallinity. However, FeBTC has a broader pore sizes, allowing faster VOC mass transfer rates and accommodating larger molecules, albeit with slightly lower adsorption capacities. Notably, VOCs with polar and aromatic properties, such as 2-methylpyridine, exhibited higher adsorption levels due to increased π-π interactions within the frameworks. However, regeneration of 2-methylpyridine was challenging due to chemisorption, forming strong, irreversible metal–nitrogen coordination bonds. Toluene and 2-methyl-2-bustanol showed similar adsorption capacities and could be effectively regenerated, indicating physisorption mechanisms involving π–π interactions and polar interactions, respectively. N-hexane exhibited the lowest adsorption capacities, relying on weaker van der Waals forces. These results highlight the promising potential of CuBTC and FeBTC in mitigating air pollution. The research also offers valuable insights for tailoring MOFs to contaminants' molecular properties, and advances our understanding of MOF applications in air quality engineering.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"391 ","pages":"Article 113619"},"PeriodicalIF":4.8,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143739155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Conjugated microporous polymer containing pyrene and Dibenzo[g,p]chrysene moieties as a luminescent powerhouse for multi-target sensing and environmental safety","authors":"Mohamed Gamal Mohamed ,&nbsp;Abdul Basit ,&nbsp;Manivannan Madhu ,&nbsp;K. Aravinthkumar ,&nbsp;Awad I. Said ,&nbsp;Devaraj Manoj ,&nbsp;Wei-Lung Tseng ,&nbsp;Shiao-Wei Kuo","doi":"10.1016/j.micromeso.2025.113620","DOIUrl":"10.1016/j.micromeso.2025.113620","url":null,"abstract":"<div><div>Conjugated microporous polymers (CMPs) have emerged as highly versatile materials, garnering significant attention in recent years due to their unique structural and functional properties. This study presents the development and synthesis of a CMP based on Py-TBNBZ, achieved via a well-established [4 + 4] Schiff base reaction. The reaction involves two primary building blocks: 4,4′,4″,4‴-(pyrene-1,3,6,8-tetrayl)tetrabenzaldehyde (PyBZ-4CHO) and 4,4′,4″,4‴-(dibenzo[g,p]chrysene-2,7,10,15-tetrayl)tetraaniline (TBNBZ-4NH₂). The structural and morphological characteristics of the synthesized Py-TBNBZ CMP material were systematically analyzed using advanced experimental techniques, confirming the successful formation of a robust framework. The Py-TBNBZ CMP prepared in this study showed a BET surface area (S_BET) of 497 m² g⁻¹. Thermal analysis indicated a decomposition temperature (<em>T</em>_<em>d10</em>) of 476 °C and a notable char yield of 74 wt%, as confirmed through BET and TGA measurements. One of the most notable features of the Py-TBNBZ CMP is its strong fluorescence, which enabled its application in chemical sensing. The material exhibited exceptional sensitivity and selectivity, allowing for the detection of K⁺ and Fe²⁺ ions and precise pH monitoring over a broad pH range (pH 2–10). The underlying sensing mechanisms were investigated and elucidated. Additionally, the Py-TBNBZ CMP demonstrated remarkable adsorption capabilities for hazardous gas vapors, including ammonia (NH₃) and hydrogen chloride (HCl), underscoring its potential for environmental remediation. The flexibility of the Py-TBNBZ CMP distinguishes it from other CMPs and porous materials, enabling superior performance, enhanced applicability, and improved operational efficiency. This work highlights the advanced capabilities of Py-TBNBZ CMP and contributes to the ongoing development of innovative materials for adsorption, environmental protection, and next-generation sensing technologies.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"391 ","pages":"Article 113620"},"PeriodicalIF":4.8,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143734586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Design of hierarchical TS-1 zeolites using spray-drying for enhanced catalytic activity in cyclic carbonate formation","authors":"Svitlana Gryn ,&nbsp;Mykhailo Kurmach ,&nbsp;Pavlo Yaremov ,&nbsp;Oleksiy Shvets ,&nbsp;Sergei Alekseev ,&nbsp;Susanne Wintzheimer ,&nbsp;Karl Mandel","doi":"10.1016/j.micromeso.2025.113610","DOIUrl":"10.1016/j.micromeso.2025.113610","url":null,"abstract":"<div><div>Herein we report on the design of hierarchical zeolite supraparticles from hydrothermally-derived 100 nm TS-1 zeolite nanoparticles (NPs) by means of spray-drying. These supraparticles, with a large surface area (up to 678 m²/g), possess a biporous structure that is composed of zeolitic micropores (0.9–1.1 nm) and secondary mesopores. Depending on the synthesis conditions, it is possible to prepare supraparticles, formed by separate NPs and wide (50 nm) interparticular pores or by zeolitic NPs, tightly glued together by amorphous mesoporous titanosilicate. According to the UV–vis spectrometry data and FTIR studies of adsorbed pyridine, the active sites of “separated” supraparticles are presented mainly by Lewis sites associated with [TiO₄] species isolated in the zeolite matrix, while “glued” supraparticles possess a significant fraction of [TiO₅] and [TiO₆] species.</div><div>The supraparticles demonstrate sufficiently high catalytic activity in the industrially valuable two-stage synthesis of cyclic carbonate (4-phenyl-1,3-dioxolan-2-one) from styrene and carbon dioxide, in the presence of <em>tert</em>-butyl hydroperoxide as an oxidant and tetrabutylammonium iodide as a co-catalyst. We found that the selectivity to the target cyclic carbonate increased with an external specific surface area growth, probably due to the facilitated withdrawal of reaction products from the zeolite pores.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"391 ","pages":"Article 113610"},"PeriodicalIF":4.8,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143739150","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Metal-organic frameworks: An overview of a possible solution for modern agriculture","authors":"Roberta Albino dos Reis ,&nbsp;Martín A. Fernández-Baldo ,&nbsp;Renan S. Nunes ,&nbsp;Amedea B. Seabra","doi":"10.1016/j.micromeso.2025.113609","DOIUrl":"10.1016/j.micromeso.2025.113609","url":null,"abstract":"<div><div>Metal-Organic Frameworks (MOFs) have emerged as promising materials for addressing modern agricultural challenges due to their exceptional porosity, high surface area, and chemical versatility. These crystalline frameworks enable the controlled release of agrochemicals, such as fertilizers, pesticides, and herbicides, improving resource efficiency and reducing environmental contamination. MOFs also exhibit multifunctionality, including water retention, pollutant remediation, and soil monitoring, offering solutions to issues like nutrient leaching, water scarcity, and pest resistance. ni Moreover, MOFs have been used as platform for biomolecules immobilization in the development of biosensors applied to agricultural area. Despite their transformative potential, challenges related to cost, scalability, and regulatory frameworks remain significant barriers to widespread adoption. This review explores the properties, applications, and limitations of MOFs in agriculture, emphasizing their role in advancing sustainable farming practices and highlighting perspectives for their integration into precision agriculture.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"391 ","pages":"Article 113609"},"PeriodicalIF":4.8,"publicationDate":"2025-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143687693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}