Materials LettersPub Date : 2025-09-27DOI: 10.1016/j.matlet.2025.139583
Huifang Lan, Siyu Liu, Pengli Xu, Shuai Tang, Linxiu Du
{"title":"Tailoring bainitic transformation and mechanical properties in high-strength steel via Mn-induced chemical heterogeneity","authors":"Huifang Lan, Siyu Liu, Pengli Xu, Shuai Tang, Linxiu Du","doi":"10.1016/j.matlet.2025.139583","DOIUrl":"10.1016/j.matlet.2025.139583","url":null,"abstract":"<div><div>A composition-independent strategy was developed to modulate bainitic transformation and optimize mechanical properties in high-strength steel via engineered Mn chemical heterogeneity. Mn-depleted and Mn-enriched regions were introduced in fine-grained austenite through intercritical annealing and retained by rapid austenitization. This spatial heterogeneity accelerated initial bainite formation in Mn-depleted zones, while Mn-enriched regions stabilized austenite through Mn and C enrichment. The resulting microstructure exhibited refined bainitic laths, a higher volume fraction of film-like retained austenite, and suppressed formation of blocky martensite/austenite constituents along prior austenite grain boundaries. These features led to enhanced strength-ductility synergy through a sustained transformation-induced plasticity effect and delayed plastic instability. The results demonstrate that spatial control of chemical heterogeneity provides a practical and efficient route for tailoring transformation pathways and mechanical performance in bainitic steels without altering overall alloy composition.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"404 ","pages":"Article 139583"},"PeriodicalIF":2.7,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145264481","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials LettersPub Date : 2025-09-27DOI: 10.1016/j.matlet.2025.139577
Peng Wang , Wei Yu , Jiawen Li , Mai Zhang , Yu Bai , Endian Liu , Hai Hao
{"title":"Mechanical enhancement of fly ash syntactic foams via synergistic effects in lattice-reinforced three-phase composites","authors":"Peng Wang , Wei Yu , Jiawen Li , Mai Zhang , Yu Bai , Endian Liu , Hai Hao","doi":"10.1016/j.matlet.2025.139577","DOIUrl":"10.1016/j.matlet.2025.139577","url":null,"abstract":"<div><div>Fly ash, a byproduct of coal combustion, can be utilized to fabricate metallic matrix syntactic foams (MMSFs) due to its hollow microstructure and low density. However, the relatively low strength of fly ash limits the overall energy absorption capacity of the MMSFs. This study employed a two-step process of stir casting followed by infiltration casting to fabricate lattice-reinforced three-phase interpenetrating porous composites (IPCs), which exhibit well-bonded mechanical interlocking. The system integrated the high strength of lattice structures with the energy-absorption capacity of porous material. Quasi-static compression tests reveal that the synergistic effect of structural reinforcement from lattice architectures and interfacial bonding significantly enhanced mechanical performance. The IPCs demonstrate a maximum compressive strength of 106.3 MPa and specific energy absorption of 23.7 kJ·kg<sup>−1</sup>, representing improvements of 410.8 % and 59.1 %, respectively, compared to those of the baseline syntactic foam.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"404 ","pages":"Article 139577"},"PeriodicalIF":2.7,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145264016","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials LettersPub Date : 2025-09-26DOI: 10.1016/j.matlet.2025.139572
T.V.M. Sreekanth , Taeyong Shin , B. Naresh , Juliano C. Denardin , J. Kim , K. Yoo
{"title":"Selenium nanostructures grown on copper oxide nanoneedle for oxygen evolution reaction","authors":"T.V.M. Sreekanth , Taeyong Shin , B. Naresh , Juliano C. Denardin , J. Kim , K. Yoo","doi":"10.1016/j.matlet.2025.139572","DOIUrl":"10.1016/j.matlet.2025.139572","url":null,"abstract":"<div><div>In this study, copper selenium nanostructures (Cu<sub>2</sub>Se Ns) were successfully grown and integrated onto a nanoneedle like structured oxidized copper (Cu) mesh via a simple hydrothermal approach. The nanoneedles were formed on the Cu mesh annealing at 400 °C in an air atmosphere. The Cu₂Se electrocatalyst exhibited excellent oxygen evolution reaction (OER) activity, with a low overpotential, enhanced charge transfer kinetics, and long-term operational stability.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"404 ","pages":"Article 139572"},"PeriodicalIF":2.7,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145264118","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials LettersPub Date : 2025-09-26DOI: 10.1016/j.matlet.2025.139562
S.J. Meza-Gómez , R.V. Silva , H. Colmenares-Cano , J. Ortiz-Palacios , T.E. González-Robles , D.E. Ramírez-Arreola
{"title":"CO2 curing influence in alkali-activated Metakaolin/waste glass rejects systems","authors":"S.J. Meza-Gómez , R.V. Silva , H. Colmenares-Cano , J. Ortiz-Palacios , T.E. González-Robles , D.E. Ramírez-Arreola","doi":"10.1016/j.matlet.2025.139562","DOIUrl":"10.1016/j.matlet.2025.139562","url":null,"abstract":"<div><div>This study analyses the performance of alkali-activated metakaolin/waste glass rejects at mass ratios of 100:0, 90:10, and 80:20, to increase internal Si/Al ratios of the precursor, using NaOH and Na<sub>2</sub>SiO<sub>3</sub>∙5H<sub>2</sub>O-based alkaline solutions. The specimens underwent a performance-enhancing accelerated carbonation-based curing regimen and were compared to specimens left uncarbonated. X-ray diffraction results showed that metakaolin and waste glass were highly amorphous, which led to essentially non-crystalline aluminosilicate gels. Exposure to CO<sub>2</sub> enhanced compressive strength by ∼40 % partly due to densification from additional CaCO<sub>3</sub> precipitation. The materials' mechanical performance was negatively affected by glass addition, whereas minimal changes were observed from the use of Na<sub>2</sub>SiO<sub>3</sub>∙5H<sub>2</sub>O-containing activators. Low dimensional stability was observed due to extremely high water demand of metakaolin, leading to high shrinkage strains and mitigated by glass addition.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"404 ","pages":"Article 139562"},"PeriodicalIF":2.7,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145227831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials LettersPub Date : 2025-09-26DOI: 10.1016/j.matlet.2025.139536
Yu Fu , Renhong Song , Kun Zhang , Yujun Chen , Lijun Chen , Qianqiu Tian , Wenbin Hu
{"title":"Synergistic effects of confinement structure and expanded interlayer spacing on MoS2/C towards high-efficient rate and cycle performance","authors":"Yu Fu , Renhong Song , Kun Zhang , Yujun Chen , Lijun Chen , Qianqiu Tian , Wenbin Hu","doi":"10.1016/j.matlet.2025.139536","DOIUrl":"10.1016/j.matlet.2025.139536","url":null,"abstract":"<div><div>Transition-metal sulfides (TMSs) are promising cathode materials for all-solid-state lithium batteries (ASSLBs) but suffer from poor electronic conductivity and severe volume expansion. We developed MoS<sub>2</sub>/C nanospheres featuring expanded interlayer spacing (0.71 nm) through facile hydrothermal synthesis. The radially arranged nanosheet architecture maximizes electrochemically active edge sites, while the expanded interlayers enhance Li<sup>+</sup> diffusion kinetics. The in-situ formed carbon layer provides dual benefits: structural confinement to suppress volume changes and improved electronic conductivity. The MoS<sub>2</sub>/C nanospheres deliver exceptional capacity of 385.1 mAh g<sup>−1</sup> after 250 cycles at 1C, substantially outperforming bulk MoS<sub>2</sub> and MoS<sub>2</sub> nanosheets. This synergistic design combining interlayer expansion, hierarchical morphology, and carbon confinement establishes an effective strategy for high-performance ASSLBs cathodes.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"404 ","pages":"Article 139536"},"PeriodicalIF":2.7,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145227822","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials LettersPub Date : 2025-09-25DOI: 10.1016/j.matlet.2025.139540
Dohun Kim , Jimin Kwon , Wonjun Ahn , Jae-Seong Yeo , Yusong Choi , Sangbaek Park
{"title":"Encapsulating sulfur with a turbostatic carbon matrix and carbon nanotubes for enhanced capacity and operating voltage in thermal batteries","authors":"Dohun Kim , Jimin Kwon , Wonjun Ahn , Jae-Seong Yeo , Yusong Choi , Sangbaek Park","doi":"10.1016/j.matlet.2025.139540","DOIUrl":"10.1016/j.matlet.2025.139540","url":null,"abstract":"<div><div>The demand for higher energy and power densities in thermal batteries necessitates the development of advanced cathode materials. Although sulfur offers a high theoretical capacity, its low electrical conductivity and thermal instability limit its practical use. Herein, we present a SPAN-CNT composite cathode, comprising sulfur embedded in a turbostratic carbon matrix derived from polyacrylonitrile (SPAN) and uniformly wrapped with carbon nanotubes (CNTs). The composite achieves high conductivity (0.39 S cm<sup>−1</sup>) through a percolating CNT network and exhibits thermal stability up to 500 °C due to strong covalent S<img>C bonding. In thermal battery tests, SPAN-CNT cathode exhibits an open-circuit voltage of 2.0 V, higher than that of conventional FeS<sub>2</sub> (1.9 V). It delivers a high capacity of 5972 As g<sup>−1</sup>, significantly surpassing FeS<sub>2</sub> (2006 As g<sup>−1</sup>). These results underscore the potential of SPAN-CNT as a next-generation cathode for high-performance thermal batteries.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"404 ","pages":"Article 139540"},"PeriodicalIF":2.7,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145227824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials LettersPub Date : 2025-09-25DOI: 10.1016/j.matlet.2025.139468
Jin-Tao Zou , Yong-Dong He , Xu Yue
{"title":"Investigation of Cu segregation in cast Ti-5Cu alloys","authors":"Jin-Tao Zou , Yong-Dong He , Xu Yue","doi":"10.1016/j.matlet.2025.139468","DOIUrl":"10.1016/j.matlet.2025.139468","url":null,"abstract":"<div><div>To investigate the compositional segregation behavior of Cu during the solidification of Ti-5Cu alloy and its influence on microstructural evolution under thermal deformation, this study employed ICP-OES and SEM-EDS techniques to analyze the compositional distribution in the initial, intermediate, and final solidification zones of the as-cast ingot. The macro- and micro-scale distribution characteristics of Cu were revealed. Results show that Cu segregation occurs in the ingot, with significant enrichment along grain boundaries. In addition, the Ti<sub>2</sub>Cu precipitates are dispersed along grain boundaries, effectively hindering grain growth. These findings provide critical theoretical guidance for optimizing homogenization treatments and hot-working parameters of Ti-Cu alloy ingots.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"404 ","pages":"Article 139468"},"PeriodicalIF":2.7,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145264023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials LettersPub Date : 2025-09-25DOI: 10.1016/j.matlet.2025.139485
Suyoung Jang, Mayur A. Gaikwad, Dhanaji B. Malavekar, Fang Zheng, Zhenhua Fang, Youngrog Kim, Suin Jeong, Jin Hyeok Kim
{"title":"Interfacial Engineering of FTO/TiO2 Bilayer for Improved charge separation in BiVO4 photoanodes","authors":"Suyoung Jang, Mayur A. Gaikwad, Dhanaji B. Malavekar, Fang Zheng, Zhenhua Fang, Youngrog Kim, Suin Jeong, Jin Hyeok Kim","doi":"10.1016/j.matlet.2025.139485","DOIUrl":"10.1016/j.matlet.2025.139485","url":null,"abstract":"<div><div>To advance next-generation photoanodes for solar-driven water splitting, innovative strategies to enhance surface catalysis and charge transport are essential. Among various photoanode materials, bismuth vanadate (BiVO<sub>4</sub>) stands out as a promising candidate not only for enhanced photoelectrochemical (PEC) performance but also for being eco-friendly. Herein, a TiO<sub>2</sub> underlayer was deposited on fluorine-doped tin oxide (FTO) substrates to fabricate FTO/TiO<sub>2</sub>/BiVO<sub>4</sub> heterojunctions, thereby enhancing the electrical properties of the photoanode. Additionally, the simplest Fenton-like deposition method was employed to deposit NiFeOOH overlayer on BiVO<sub>4</sub>. As a result, the FTO/TiO<sub>2</sub>/BiVO<sub>4</sub>/NiFeOOH photoanode achieved the remarkable photocurrent density of 1.73 mA/cm<sup>2</sup> and ABPE(%) of 0.432 %. These findings demonstrate that the TiO<sub>2</sub> underlayer significantly increases the charge transport by suppressing surface recombination, thereby advancing the PEC performance of BiVO<sub>4</sub>-based photoanode.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"404 ","pages":"Article 139485"},"PeriodicalIF":2.7,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145263915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials LettersPub Date : 2025-09-22DOI: 10.1016/j.matlet.2025.139557
Min Xie , Lihua Zhan , Bolin Ma , Zheng Cao , Ruitong Yu
{"title":"Improved interfacial and electrochemical properties of CFRP via nano-Fe2O3 coated carbon fibers","authors":"Min Xie , Lihua Zhan , Bolin Ma , Zheng Cao , Ruitong Yu","doi":"10.1016/j.matlet.2025.139557","DOIUrl":"10.1016/j.matlet.2025.139557","url":null,"abstract":"<div><div>This study employed hydrothermal synthesis to deposit nano-Fe<sub>2</sub>O<sub>3</sub> particles on carbon fibers (CFs) by varying mass ratio of FeCl<sub>3</sub> to CF (0–1). The presence of γ-Fe<sub>2</sub>O<sub>3</sub> was verified through XRD and XPS analyses. When the mass ratio is 0.75, surface energy of CFs increased by 57.5 %, leading to a 15.3 % enhancement in interlaminar shear strength (ILSS) and a 153.1 % rise in electrical resistivity of carbon fiber reinforced polymer (CFRP). Moreover, the composite exhibited significantly improved electrochemical performance, with a −58.2 mV shift in corrosion potential and a reduction in corrosion current density by2–3 orders of magnitude.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"404 ","pages":"Article 139557"},"PeriodicalIF":2.7,"publicationDate":"2025-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145227828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials LettersPub Date : 2025-09-18DOI: 10.1016/j.matlet.2025.139529
Chaofu Zhang , Liji Su , Changyun Li , Lei Xu , Heliang Fan , Hanzhuo Zhang
{"title":"Zinc orthostannate nanorods assembled into coral-like clusters with improved acetone gas sensitivity and selectivity","authors":"Chaofu Zhang , Liji Su , Changyun Li , Lei Xu , Heliang Fan , Hanzhuo Zhang","doi":"10.1016/j.matlet.2025.139529","DOIUrl":"10.1016/j.matlet.2025.139529","url":null,"abstract":"<div><div>As an n-type semiconductor, zinc orthostannate (Zn<sub>2</sub>SnO<sub>4</sub>) has been studied for years while its morphology modulation and semiconductor characteristics need further exploring. In this paper, Zn<sub>2</sub>SnO<sub>4</sub> nanorods with random orientations and self-assembly into coral-like clusters were synthesized by hydrothermal processes for gas sensing investigations. High response values of 58.9, rapid response time of 11 s and improved sensitivity to 100 ppm acetone were revealed at optimal working temperature of 200 °C, which might be related with oordination effects between carbonyl oxygen in acetone and more Sn<sup>4+</sup>/Zn<sup>2+</sup> active centers in as-prepared Zn<sub>2</sub>SnO<sub>4</sub>.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"403 ","pages":"Article 139529"},"PeriodicalIF":2.7,"publicationDate":"2025-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145262789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}