D. Bradley, M. Grell, K. L. Brandon, M. Turner, P. Bentley, D. Dunmur, E. Woo, M. Inbasekaran
{"title":"Liquid Crystalline Polymers for Electroluminescence","authors":"D. Bradley, M. Grell, K. L. Brandon, M. Turner, P. Bentley, D. Dunmur, E. Woo, M. Inbasekaran","doi":"10.1364/otfa.1997.wd.3","DOIUrl":"https://doi.org/10.1364/otfa.1997.wd.3","url":null,"abstract":"Organic electroluminescence is attracting strong interest for applications in lighting and displays. Polymer devices offer some advantages for low cost processing over large areas and with extended molecular architectures there is the possibility of polarised emission. This is attractive for backlighting liquid crystal displays and also for development of sources for optoelectronics. In order to achieve polarised emission there is a need to obtain highly oriented samples. Further, to allow construction of efficient electrolumiescent diodes it is necessary to achieve this orientation in thin films deposited on suitable electrode surfaces. We believe that mesophase formation is an attractive approach to achieve these dual goals and we have thus undertaken a programme of work to produce liquid crystalline polymers with the dual attributes of charge transport and light emission capability that can allow application in electroluminescence devices. This paper reports on recent progress in materials preparation, processing and device fabrication.","PeriodicalId":378320,"journal":{"name":"Organic Thin Films for Photonics Applications","volume":"32 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115256864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Antao Chen, S. Garner, A. Yacoubian, W. Steier, Jinghong Chen, A. Harper, Jingsong Zhu, M. He, Shajing Sun, Fang Wang, Younsoo Ra, S. Mao, Cheng H. Zhang, L. Dalton, Datong Chen, H. Fetterman
{"title":"Characterization of electrooptic polymers with high µβ chromophores for photonic device applications","authors":"Antao Chen, S. Garner, A. Yacoubian, W. Steier, Jinghong Chen, A. Harper, Jingsong Zhu, M. He, Shajing Sun, Fang Wang, Younsoo Ra, S. Mao, Cheng H. Zhang, L. Dalton, Datong Chen, H. Fetterman","doi":"10.1364/otfa.1997.the.23","DOIUrl":"https://doi.org/10.1364/otfa.1997.the.23","url":null,"abstract":"For electrooptic (EO) polymer devices to be accepted in high speed fiber communication systems, the operation voltage of these devices must be reduced to a level compatible with the high speed electronics that drives the polymer devices. A low operation voltage, or Vπ in the case of modulators, requires EO polymers with high electrooptic coefficients. The electrooptic effect comes from the nonlinear chromophores in the polymer and the alignment of these chromophores by poling. High electrooptic coefficients calls for chromophores with large nonlinearity, i.e., high µβ. The synthesis and characterization of EO polymers with high µβ chromophores1 have been the focus of recent research in the field of nonlinear optic polymers.","PeriodicalId":378320,"journal":{"name":"Organic Thin Films for Photonics Applications","volume":"39 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115562685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Passive alignment of optic fiber array using silicon V-grooves monolithically integrated with polymer waveguide devices","authors":"Antao Chen, M. Ziari, W. Steier","doi":"10.1364/otfa.1997.the.21","DOIUrl":"https://doi.org/10.1364/otfa.1997.the.21","url":null,"abstract":"Packaging is the crucial link between a laboratory demonstrated device and a reliable component in a practical system. To achieve and maintain the sub-micron alignment tolerances between fiber and waveguide is the major factor that makes the packaging of photonic devices labor intensive, time consuming, and costly[1, 2]. Fiber arrays are important in WDM multiplexers and demultiplexers where multiple fiber attachment is essential. To avoid the complexity of the active alignment and attachment of individual fiber to each waveguide, we experimented with the passive alignment of fiber arrays with silicon V-grooves. The V-grooves are made on the same substrate that the polymer device is built on. The waveguide channels aligned to the center of the V-grooves are also processed together with the V-grooves using the same photolithography and etching technology. This technique is fundamentally different from the use of silicon V-grooves as fiber carrier for LiNbO3 and semiconductor devices, in which V-groove and devices are made on different substrate and bonded together later[3,4]. The width and the position of V-grooves can be fabricated in submicron precision with mature microelectronics technology. The fiber placed in the V-groove is entirely self-aligned in both vertical and lateral directions. The idea and some fabrication results of this approach have been presented earlier[5]. In this paper, our recent results of fiber coupling experiments are reported.","PeriodicalId":378320,"journal":{"name":"Organic Thin Films for Photonics Applications","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129564884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
W. Herman, J. Stenger-Smith, A. Chafin, R. Gratz, R. Hollins, R. Yee, G. Lindsay
{"title":"Accordion Polymers with Aromatic Donors","authors":"W. Herman, J. Stenger-Smith, A. Chafin, R. Gratz, R. Hollins, R. Yee, G. Lindsay","doi":"10.1364/otfa.1997.the.30","DOIUrl":"https://doi.org/10.1364/otfa.1997.the.30","url":null,"abstract":"Nonlinear optical (NLO) polymers are of considerable interest for photonics applications due to their fast NLO response time, low cost, ease of fabrication, favorable material characteristics for high-speed modulation, and potentially large nonlinear second-order susceptibility. These materials can readily be formed into thin films fabricated by standard microelectronic techniques. Photonic modulators with bandwidths as high as 110 GHz have recently been reported.1","PeriodicalId":378320,"journal":{"name":"Organic Thin Films for Photonics Applications","volume":"32 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130693260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
F. Hide, M. Díaz‐García, M. McGehee, B. J. Schwartz, A. Heeger
{"title":"Conjugated Polymers as Materials for Thin Film Solid State Lasers","authors":"F. Hide, M. Díaz‐García, M. McGehee, B. J. Schwartz, A. Heeger","doi":"10.1364/otfa.1997.wd.1","DOIUrl":"https://doi.org/10.1364/otfa.1997.wd.1","url":null,"abstract":"Optically pumped gain narrowing and lasing have been demonstrated in submicron thick films, neat and undiluted, of photoluminescent conjugated polymers. The dramatic collapse of the emission line width occurs at very low pump energy thresholds (~10 μJ/cm2). Gain narrowing is found in over a dozen different conjugated polymers representing a variety of molecular structures, including poly(p-phenylenevinylene), poly(p-phenylene) and polyfluorene derivatives; the emission wavelengths in these materials span the visible spectrum. The short gain lengths in conjugated polymers are attributed to the high density of chromophores, the large density of states associated with the interband (π-π*) transition in quasi-one-dimensional systems, and the Stokes shift which minimizes self-absorption and allows optical pumping to the excited state without simultaneously stimulating emission (thereby yielding population inversion). Lasing and gain narrowing are compared for a soluble poly(phenylene vinylene) derivative using two different resonant structures: planar waveguides and microcavities. In both cases, the gain narrowing threshold is at 0.05 - 0.1 μJ per 10 ns pulse focused to approximately 1.5 mm. Single mode microcavity lasers are obtained when a cavity resonance occurs at the wavelength where the gain of the polymer is a maximum. Low threshold lasing (threshold more than an order of magnitude below that observed in planar waveguides and microcavities) has also been demonstrated using distributed feedback in a planar chip film configuration.","PeriodicalId":378320,"journal":{"name":"Organic Thin Films for Photonics Applications","volume":"30 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129993343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Antao Chen, F. I. Marti-Carrera, V. Chuyanov, S. Garner, W. Steier, S. Mao, Younsoo Ra, L. Dalton, Yongqian Shi
{"title":"In situ trimming of polymer optical waveguides by rapid photobleaching for tuning device specifications","authors":"Antao Chen, F. I. Marti-Carrera, V. Chuyanov, S. Garner, W. Steier, S. Mao, Younsoo Ra, L. Dalton, Yongqian Shi","doi":"10.1364/otfa.1997.fb.2","DOIUrl":"https://doi.org/10.1364/otfa.1997.fb.2","url":null,"abstract":"Electrooptic (EO) polymer is very attractive for ultrahigh speed optical waveguide modulators and switches because of its good speed match between the traveling microwave and optical wave. High-speed EO polymer modulators that operate at frequencies as high as 113 GHz have been demonstrated(1). Besides such advantages as high frequency response, flexible processing capability, low cost, and ease of integration with VLSI circuitry, we will demonstrate an additional advantage of EO polymer - the ability of post-fabrication device trimming.","PeriodicalId":378320,"journal":{"name":"Organic Thin Films for Photonics Applications","volume":"90 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125531304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Antao Chen, V. Chuyanov, S. Garner, W. Steier, L. Dalton
{"title":"Modified attenuated total reflection for the fast and routine electrooptic measurements of nonlinear optical polymer thin films","authors":"Antao Chen, V. Chuyanov, S. Garner, W. Steier, L. Dalton","doi":"10.1364/otfa.1997.the.18","DOIUrl":"https://doi.org/10.1364/otfa.1997.the.18","url":null,"abstract":"In the course of developing EO polymers, a convenient and fast method to obtain the electrooptic (EO) coefficients, r33 and r13, is highly desirable. Some of the existing EO measurement techniques such as Fabry-Perot interferometry(1) and ellipsometry(2) require metal deposition and electrode processing for each test sample. Therefore, they are not suited for daily sample testing. Second harmonic generation (SHG) is an indirect method to measure the EO coefficients(3). It is usually performed with 1.064 Nd:YAG laser and encounters difficulties with polymers that contain high µβ chromophores because these chromophores usually have red-shifted absorption peaks that causes the Kleiman symmetry, a fundamental assumption of this technique, to break down. Attenuated total reflection (ATR) can directly measure the EO coefficients with no restriction on the wavelength of the absorption peak. One measurement scan provides the refractive index, the thickness, and an EO coefficient. Typically, the thin film electrode in contact with the test sample is made of Au or Ag in conventional ATR techniques(4). These metal thin films are soft and not durable for repeated measurements. The curve fitting algorithm for data processing(4, 5) is also inconvenient for fast sample evaluation. In this paper, a modified ATR technique for routine EO measurement is presented which does not require electrode preparation for each test sample and uses a simple algorithm for data processing.","PeriodicalId":378320,"journal":{"name":"Organic Thin Films for Photonics Applications","volume":"27 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121073793","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Bacteriorhodopsin Opto-Electronic Synapses","authors":"D. Shelton","doi":"10.1364/otfa.1997.the.11","DOIUrl":"https://doi.org/10.1364/otfa.1997.the.11","url":null,"abstract":"In recent years there has been a resurgence of interest in artificial neural networks, and several optical implementations have been investigated [1]. Neural networks are intrinsically parallel computers, and optics can provide the massive parallelism and interconnectivity they require. The key components of neural networks are the synapses between the neurons, which are the locus of signal processing, learning, and memory. Bacteriorhodopsin (BR) has photochromic properties which will enable one to construct functionally complete synapses in the form of a thin-film optically-addressed spatial light modulator. Here we present measurements of properties of bacteriorhodopsin relevant to synaptic functions.","PeriodicalId":378320,"journal":{"name":"Organic Thin Films for Photonics Applications","volume":"13 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126664419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. Blanco, R. Litrán, M. Ramírez-Del-Solar, F. Aranda, D. Rao, D. N. Rao, J. Akkara, M. Nakashima, S. Tripathy
{"title":"Nonlinear absorption in CuPc-SiO2 Composite","authors":"E. Blanco, R. Litrán, M. Ramírez-Del-Solar, F. Aranda, D. Rao, D. N. Rao, J. Akkara, M. Nakashima, S. Tripathy","doi":"10.1364/otfa.1997.the.2","DOIUrl":"https://doi.org/10.1364/otfa.1997.the.2","url":null,"abstract":"Recently macrocyclic organic dyes have attracted a lot of attention as possible candidates for applications in optical power limiters and pulse shaping devices. The fundamental requirement for power limiting is that the system must exhibit fluence dependent reverse saturable absorption. Copper Pthalocyanines possess a larger excited state absorption cross section than a ground state absorption cross section. They are thus suitable candidates for limiting applications. Most of the nonlinear optical studies have been done for solutions of the dyes1. For applications such as intracavity pulse shaping devices a solid material is more attractive than a solution2. In this paper we report nonlinear absorption studies of Copper Pthalocyanine, CuPc, in solution in sulfuric acid as well as incorporated in a Silica matrix host. The concentration of the solution was 5.75 x 10-4 Molar. The composite had a concentration of 1 x 10-4 Molar in the sol. Upon drying of the gel we estimate a similar concentration for the composite as in the solution given the reduction in volume. The thickness of the composite is of 4 mm. The solution was held in 1 mm thick spectroscopic grade glass cuvettes. The CuPc/silica composite was obtained by the Sol-gel method from the hydrolysis of tetramethoxysilane (TMOS). The reaction of TMOS with acidic water (pH=2) was promoted by means of 20 kHz ultrasound energy. The resulting gel was kept drying at room temperature for two weeks. We observe marked differences in the linear absorption spectrum of the solution and the composite. These changes are attributable to aggregation of the Copper Pthalocyanine molecules in the pores of the silica matrix as well as to the interaction between the dye molecules and the matrix. The linear absorption spectrum for both samples is shown in Fig. 1.","PeriodicalId":378320,"journal":{"name":"Organic Thin Films for Photonics Applications","volume":"75 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123088035","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
C. Spiegelberg, A. Schülzgen, M. Morrell, P. Allemand, B. Kippelen, N. Peyghambarian
{"title":"Origin of Optical Gain and Stimulated Emission in Conjugated Polymers","authors":"C. Spiegelberg, A. Schülzgen, M. Morrell, P. Allemand, B. Kippelen, N. Peyghambarian","doi":"10.1364/otfa.1997.wd.4","DOIUrl":"https://doi.org/10.1364/otfa.1997.wd.4","url":null,"abstract":"Recent reports on a spectrally narrow emission peak have generated a lot of excitement in the scientific community. Hide et al. [1] and Frolov et al. [2] reported dramatic photoluminescence (PL) line narrowing in a variety of PPV derivative films for exciton densities above 1017 cm-3, indicating stimulated emission (SE). The SE linewidth (7 to 9 nm) has been attributed to either amplified spontaneous emission [1] or superradiance [2].","PeriodicalId":378320,"journal":{"name":"Organic Thin Films for Photonics Applications","volume":"166 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124655994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}