Journal of Photochemistry and Photobiology最新文献

筛选
英文 中文
Dedicated to Professor Kazuhiko Mizuno on the occasion of his 75th birthday celebration 在水野和彦教授 75 岁生日之际献给他
IF 3.261
Journal of Photochemistry and Photobiology Pub Date : 2024-08-08 DOI: 10.1016/j.jpap.2024.100248
Yasuharu Yoshimi , Hiroshi Ikeda , Shinsuke Takagi
{"title":"Dedicated to Professor Kazuhiko Mizuno on the occasion of his 75th birthday celebration","authors":"Yasuharu Yoshimi , Hiroshi Ikeda , Shinsuke Takagi","doi":"10.1016/j.jpap.2024.100248","DOIUrl":"10.1016/j.jpap.2024.100248","url":null,"abstract":"","PeriodicalId":375,"journal":{"name":"Journal of Photochemistry and Photobiology","volume":"23 ","pages":"Article 100248"},"PeriodicalIF":3.261,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S266646902400023X/pdfft?md5=bb25e5fab0e2bccbe6190ca3298952d4&pid=1-s2.0-S266646902400023X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142172036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Editorial: Special issue on optical spectroscopy of plants and algae 编辑植物和藻类的光学光谱特刊
IF 3.261
Journal of Photochemistry and Photobiology Pub Date : 2024-07-27 DOI: 10.1016/j.jpap.2024.100246
Giovanni Agati , M.Gabriela Lagorio
{"title":"Editorial: Special issue on optical spectroscopy of plants and algae","authors":"Giovanni Agati , M.Gabriela Lagorio","doi":"10.1016/j.jpap.2024.100246","DOIUrl":"10.1016/j.jpap.2024.100246","url":null,"abstract":"","PeriodicalId":375,"journal":{"name":"Journal of Photochemistry and Photobiology","volume":"23 ","pages":"Article 100246"},"PeriodicalIF":3.261,"publicationDate":"2024-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666469024000216/pdfft?md5=ce1674e08a4b6fdbdd2b4df415e1f0f5&pid=1-s2.0-S2666469024000216-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141844344","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Special issue "chromophores and opsins: Physiological processes elicited by visible, ultraviolet and infrared light" 特刊 "色素和蛋白:可见光、紫外线和红外线引发的生理过程"。
IF 3.261
Journal of Photochemistry and Photobiology Pub Date : 2024-07-25 DOI: 10.1016/j.jpap.2024.100247
Mario E. Guido
{"title":"Special issue \"chromophores and opsins: Physiological processes elicited by visible, ultraviolet and infrared light\"","authors":"Mario E. Guido","doi":"10.1016/j.jpap.2024.100247","DOIUrl":"10.1016/j.jpap.2024.100247","url":null,"abstract":"","PeriodicalId":375,"journal":{"name":"Journal of Photochemistry and Photobiology","volume":"23 ","pages":"Article 100247"},"PeriodicalIF":3.261,"publicationDate":"2024-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666469024000228/pdfft?md5=08aea0607e791991b7b3c34dd5c31840&pid=1-s2.0-S2666469024000228-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141854028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and applications of metal organic frameworks in photodynamic therapy 光动力疗法中金属有机框架的合成与应用
IF 3.261
Journal of Photochemistry and Photobiology Pub Date : 2024-07-11 DOI: 10.1016/j.jpap.2024.100245
Sandile Phinda Songca
{"title":"Synthesis and applications of metal organic frameworks in photodynamic therapy","authors":"Sandile Phinda Songca","doi":"10.1016/j.jpap.2024.100245","DOIUrl":"10.1016/j.jpap.2024.100245","url":null,"abstract":"<div><p>Metal organic frameworks (MOFs) consist of metal atoms or clusters, coordinated to organic ligands to form macromolecular super structures, with pores large enough to host free drug molecules, including photodynamic therapy (PDT) photosensitizers. This review presents examples of applications in PDT of various types of MOFs. To contextualize the discussions of their PDT applications, general procedures of MOF synthesis are considered. Applications of MOFs in PDT are described using examples of several combination therapy innovations developed for the purpose of solving some of the key challenges in the clinical translation value chain of PDT. The review presents evidence to show that the explosion of research in MOFs is due to their capability for applications as carriers and delivery systems for PDT photosensitizers. It also shows their unique applications as platforms for combination therapies, for stimulus responsive release of photosensitizer and drug molecules, for cancer cell targeting, and for auxiliary enhancement of efficacy. Published literature on MOFs has been on the rise since the eighties. In Scopus, the applications of MOFs in PDT increased from 1 article in 2010, to 169 articles in 2023, whereas published literature on MOFs generally, increased from 878 to 11644 during this period. Research on the applications of MOFs in PDT has therefore increased more than that of MOFs generally. Literature on the applications of MOFs in PDT increased by between 0.7% to 1.45% relative to published literature on MOFs generally. Clearly, MOFs are researched to overcome challenges of and improve PDT efficacy, more than they are generally.</p></div>","PeriodicalId":375,"journal":{"name":"Journal of Photochemistry and Photobiology","volume":"23 ","pages":"Article 100245"},"PeriodicalIF":3.261,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666469024000204/pdfft?md5=5481a5bf2bc14b52daee1f28af08d552&pid=1-s2.0-S2666469024000204-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141691981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High energy throughput using photogalvanic solar techniques and environmentally benign chemical system 利用光电镀太阳能技术和对环境无害的化学系统实现高能量生产
IF 3.261
Journal of Photochemistry and Photobiology Pub Date : 2024-06-30 DOI: 10.1016/j.jpap.2024.100244
Meenakshi Jonwal, Pooran Koli, Yashodhara Dayma, Ramesh Kumar Pareek
{"title":"High energy throughput using photogalvanic solar techniques and environmentally benign chemical system","authors":"Meenakshi Jonwal,&nbsp;Pooran Koli,&nbsp;Yashodhara Dayma,&nbsp;Ramesh Kumar Pareek","doi":"10.1016/j.jpap.2024.100244","DOIUrl":"https://doi.org/10.1016/j.jpap.2024.100244","url":null,"abstract":"<div><p>Solar energy is gradually becoming integrated into households, holding the potential to address energy requirements through technologies like PV cells. Ongoing research is actively exploring diverse methods of harnessing solar power, with Photogalvanic cells emerging as a particularly promising alternative to Photovoltaic cells. The advantage lies in the cost-effectiveness and simplified fabrication, coupled with the capability of power storage. The utilization of the economical Dioctyl sulfosuccinate sodium (DOSS) surfactant, widely employed in industry, has yielded impressive electrical performance. The present investigation presents a reliable photogalvanic system composed of the photosensitizer dye Quinoline Yellow, the reductant Cellobiose, and the surfactant Dioctyl sulfosuccinate sodium (DOSS), all in a highly alkaline solution with platinum and graphite electrodes. The platinum electrode employed is notably small, boasting a surface area of 0.03 cm<sup>2</sup>, which enhances the diffusion characteristics of the dye molecules, it is contributing to an enhanced electrical performance of the photogalvanic cell. The resulting photogalvanic cell demonstrates superior electrical performance, featuring a maximum potential of 870 mV, a maximum current of 8000 µA, power at PowerPoint of 695 µW, a fill factor of 0.11, and a conversion efficiency of 13.78 %. Spectrophotometric analysis has confirmed the stability of the dye within the electrolyte solution. Additionally, conductometric analysis has revealed that the surfactant Dioctyl sulfosuccinate sodium (DOSS) enhances the electrical conductivity of the electrolyte solution.</p></div>","PeriodicalId":375,"journal":{"name":"Journal of Photochemistry and Photobiology","volume":"22 ","pages":"Article 100244"},"PeriodicalIF":3.261,"publicationDate":"2024-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666469024000198/pdfft?md5=71469a0cca5e1218ae13bec4a41e077d&pid=1-s2.0-S2666469024000198-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141542505","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modulation of UVB-induced oxidative stress and inflammation in skin keratinocytes (HaCaT) utilising unfermented rooibos and honeybush aqueous extracts 利用发酵的路依保斯和蜜蜂草水提取物调节紫外线诱导的皮肤角质细胞(HaCaT)氧化应激和炎症反应
IF 3.261
Journal of Photochemistry and Photobiology Pub Date : 2024-06-03 DOI: 10.1016/j.jpap.2024.100242
Lana Keet , Tandeka Magcwebeba , Stefan Abel , Ann Louw , Wentzel Gelderblom , Mariska Lilly
{"title":"Modulation of UVB-induced oxidative stress and inflammation in skin keratinocytes (HaCaT) utilising unfermented rooibos and honeybush aqueous extracts","authors":"Lana Keet ,&nbsp;Tandeka Magcwebeba ,&nbsp;Stefan Abel ,&nbsp;Ann Louw ,&nbsp;Wentzel Gelderblom ,&nbsp;Mariska Lilly","doi":"10.1016/j.jpap.2024.100242","DOIUrl":"10.1016/j.jpap.2024.100242","url":null,"abstract":"<div><p>Exposure to Ultraviolet B (UVB) radiation can trigger a diverse array of biological responses that have the potential to contribute to the onset of skin cancer. Natural compounds, such as tea polyphenols, have been shown to protect against UVB-induced damage by modulating oxidative stress, inflammatory response, and cell proliferation. The chemopreventive and anti-inflammatory properties of South African rooibos (<em>Aspalathus linearis</em>) and honeybush (<em>Cyclopia spp</em>.) herbal teas have been shown to mainly target the early stages of cancer development through mechanisms that involve intracellular interleukin-1α (IL-1α) inhibition. Thus, the aim was to investigate the preventive effects of unfermented rooibos and honeybush aqueous extracts against UVB-induced oxidative stress and inflammation in HaCaTs. Honeybush was found to reduce the accumulation of UVB-induced IL-1α while maintaining cell viability and without affecting apoptosis. Furthermore, only honeybush extract was able to decrease the secretion of interleukin-6 (IL-6) caused by UVB exposure. Honeybush and rooibos extracts significantly decreased the secretion of UVB-induced interleukin-8 (IL-8). Except for rooibos extract at a concentration of 0.2 mg/mL, both extracts restored the expression of antioxidant genes to levels observed prior to UVB exposure. The anti-inflammatory effects of these herbal tea extracts are likely attributed to the antioxidant properties of their polyphenolic constituents, which modulate the oxidative stress-induced pathways governing inflammatory responses.</p></div>","PeriodicalId":375,"journal":{"name":"Journal of Photochemistry and Photobiology","volume":"22 ","pages":"Article 100242"},"PeriodicalIF":3.261,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666469024000174/pdfft?md5=5dcc7cbf4a6572f10748e8319e5fea35&pid=1-s2.0-S2666469024000174-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141276270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photoacoustic lifetime oxygen imaging of radiotherapy-induced tumor reoxygenation In Vivo 放疗诱导的肿瘤体内复氧的光声寿命氧成像
IF 3.261
Journal of Photochemistry and Photobiology Pub Date : 2024-04-27 DOI: 10.1016/j.jpap.2024.100241
Jeff Folz , Janggun Jo , Maria E. Gonzalez , Ahmad Eido , Tianqu Zhai , Roberta Caruso , Celina G. Kleer , Xueding Wang , Raoul Kopelman
{"title":"Photoacoustic lifetime oxygen imaging of radiotherapy-induced tumor reoxygenation In Vivo","authors":"Jeff Folz ,&nbsp;Janggun Jo ,&nbsp;Maria E. Gonzalez ,&nbsp;Ahmad Eido ,&nbsp;Tianqu Zhai ,&nbsp;Roberta Caruso ,&nbsp;Celina G. Kleer ,&nbsp;Xueding Wang ,&nbsp;Raoul Kopelman","doi":"10.1016/j.jpap.2024.100241","DOIUrl":"https://doi.org/10.1016/j.jpap.2024.100241","url":null,"abstract":"<div><h3>Purpose</h3><p>Early detection and diagnosis of cancer is critical for achieving positive therapeutic outcomes. Biomarkers that can provide clinicians with clues to the outcome of a given therapeutic course are highly desired. Oxygen is a small molecule that is nearly universally present in biological tissues and plays a critical role in the effectiveness of radiotherapies by reacting with DNA radicals and subsequently impairing cellular repair of double strand breaks.</p><p>Techniques for measuring oxygen in biological tissues often use blood oxygen saturation to approximate the oxygen partial pressure in surrounding tissues despite the complex, nonlinear, and dynamic relationship between these two separate oxygen populations.</p></div><div><h3>Methods and materials</h3><p>We combined a directly oxygen-sensitive, tumor-targeted, chemical contrast nanoelement with the photoacoustic lifetime-based (PALT) oxygen imaging technique to obtain image maps of oxygen in breast cancer tumors in vivo. The oxygen levels of patient-derived xenografts in a mouse model were characterized before and after a course of radiotherapy.</p></div><div><h3>Results</h3><p>We show that, independent of tumor size, radiotherapy induced an increase in the overall oxygenation levels of the tumor. Further, this increase in the oxygenation of the tumor significantly correlated with a positive response to radiotherapy, as demonstrated by a reduction in tumor volume over the twenty-day monitoring period following therapy and histological staining.</p></div><div><h3>Conclusion</h3><p>Our PALT imaging presented here is simple, fast, and non-invasive. Facilized by the PALT approach, imaging of tumor reoxygenation may be utilized as a simple, early indicator for evaluating cancer response to radiotherapy. Further characterization of the reoxygenation degree, temporal onset, and possible theragnostic implications are warranted.</p></div>","PeriodicalId":375,"journal":{"name":"Journal of Photochemistry and Photobiology","volume":"21 ","pages":"Article 100241"},"PeriodicalIF":3.261,"publicationDate":"2024-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666469024000162/pdfft?md5=7689613c44cf27f4a26f47fc73453186&pid=1-s2.0-S2666469024000162-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140822693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyaniline-supported g-C3N4/ZnO/Ag2CrO4 composite for photodegradation of methylene blue under visible light irradiation 聚苯胺支撑的 g-C3N4/ZnO/Ag2CrO4 复合材料在可见光照射下对亚甲基蓝的光降解作用
IF 3.261
Journal of Photochemistry and Photobiology Pub Date : 2024-04-23 DOI: 10.1016/j.jpap.2024.100239
Ziyad Abrahim, Abi M. Taddesse, Yiheyis Bogale, Zewdu Bezu, Endale Teju
{"title":"Polyaniline-supported g-C3N4/ZnO/Ag2CrO4 composite for photodegradation of methylene blue under visible light irradiation","authors":"Ziyad Abrahim,&nbsp;Abi M. Taddesse,&nbsp;Yiheyis Bogale,&nbsp;Zewdu Bezu,&nbsp;Endale Teju","doi":"10.1016/j.jpap.2024.100239","DOIUrl":"https://doi.org/10.1016/j.jpap.2024.100239","url":null,"abstract":"<div><p>Organic dyes are a major source of environmental pollution from different industries. To remove these recalcitrant, a novel ternary g-C<sub>3</sub>N<sub>4</sub>/ZnO/Ag<sub>2</sub>CrO<sub>4</sub> and its polyaniline-supported (PANI) composites were synthesized using an “in situ” oxidative polymerization approach. XRD, SEM, UV–Vis DRS, and PL techniques were utilized to characterize the as-prepared composites. The photocatalytic efficiency was evaluated using a model organic pollutant, methylene blue (MB), and samples of the effluent of the textile industry. The as-synthesized ternary g-C<sub>3</sub>N<sub>4</sub>/ZnO/Ag<sub>2</sub>CrO<sub>4</sub> (ZT3= 87.87 %) composite showed better photocatalytic performance than the single (5 %) and binaries (15–25 %) counterparts for MB degradation. The influence of various experimental settings on the photodegradation of MB dye was examined and these were an initial dye amount of 10 ppm, photocatalyst load of 0.15 g/L, and pH 10. Under optimized conditions, PANI-supported g-C<sub>3</sub>N<sub>4</sub>/ZnO/Ag<sub>2</sub>CrO<sub>4</sub> composite (PAST) demonstrated substantial degradation efficiency (97.5 %). The reusability study of the spent catalyst revealed a reduced efficiency from 97.5 to 78.5 % photodegradation of MB after four successive cycles, demonstrating the photocatalyst's stability and efficiency. According to the study on the effect of scavengers, h<sup>+</sup> plays a significant part in the discoloration of MB. The PAST photocatalyst outperformed the MB discoloration (97.5 %) and adequate degradation for real textile effluent samples (77.7 %) collected from Hawassa textile industries. The photodegradation efficiency result of this study demonstrated that PANI-supported g-C<sub>3</sub>N<sub>4</sub>/ZnO/Ag<sub>2</sub>CrO<sub>4</sub> might serve as an advantageous photocatalyst for the efficient removal of MB and other dyes under visible light irradiation at the optimum conditions. The total estimated cost analysis of synthesis and photocatalytic degradation using Polyaniline-supported g-C<sub>3</sub>N<sub>4</sub>/ZnO/Ag<sub>2</sub>CrO<sub>4</sub> composite found that it was quite affordable, costing around $5 per 1,000 L of wastewater treatment.</p></div>","PeriodicalId":375,"journal":{"name":"Journal of Photochemistry and Photobiology","volume":"21 ","pages":"Article 100239"},"PeriodicalIF":3.261,"publicationDate":"2024-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666469024000149/pdfft?md5=2978e4c825eab96c74deeb3f73fc0541&pid=1-s2.0-S2666469024000149-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140649720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Solution conductivity as a factor determining the photocatalytic reaction rate 溶液电导率是决定光催化反应速率的一个因素
IF 3.261
Journal of Photochemistry and Photobiology Pub Date : 2024-04-23 DOI: 10.1016/j.jpap.2024.100240
E. Lilov , S. Nedev , V. Lilova , S. Kozhukharov , Ch. Girginov
{"title":"Solution conductivity as a factor determining the photocatalytic reaction rate","authors":"E. Lilov ,&nbsp;S. Nedev ,&nbsp;V. Lilova ,&nbsp;S. Kozhukharov ,&nbsp;Ch. Girginov","doi":"10.1016/j.jpap.2024.100240","DOIUrl":"10.1016/j.jpap.2024.100240","url":null,"abstract":"<div><p>A rather simple model was developed, which predicted a hyperbolic relation between the photocatalytic reaction rate and solution conductivity. Experimental validation was performed using methyl orange as a model pollutant and titanium dioxide as a photocatalyst. The experiments, conducted with three different salts confirm the hyperbolic correlation between the photocatalytic degradation rate and solution conductivity. The results have evinced this correlation, albeit the model ignores crucial factors, such as the role of one of the two types of charges generated during light absorption and the chemical decomposition pathway. In addition, the experimentally derived hyperbolic function displays a positive shift along the ordinate.</p></div>","PeriodicalId":375,"journal":{"name":"Journal of Photochemistry and Photobiology","volume":"21 ","pages":"Article 100240"},"PeriodicalIF":3.261,"publicationDate":"2024-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666469024000150/pdfft?md5=bdf09587fc4c9eb075ea073df697e476&pid=1-s2.0-S2666469024000150-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140779839","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in exploration of photoinduced electron transfer reactions involving small molecules probed by magnetic field effect 利用磁场效应探测涉及小分子的光诱导电子转移反应的探索进展
IF 3.261
Journal of Photochemistry and Photobiology Pub Date : 2024-03-30 DOI: 10.1016/j.jpap.2024.100238
Brotati Chakraborty , Chaitrali Sengupta , Samita Basu
{"title":"Advances in exploration of photoinduced electron transfer reactions involving small molecules probed by magnetic field effect","authors":"Brotati Chakraborty ,&nbsp;Chaitrali Sengupta ,&nbsp;Samita Basu","doi":"10.1016/j.jpap.2024.100238","DOIUrl":"10.1016/j.jpap.2024.100238","url":null,"abstract":"<div><p>The review focuses on photoinduced electron transfer (PET) reactions between small molecules and various kinds of chemical and biological systems using a weak external magnetic field (MF). Laser flash photolysis is a competent tool to characterize the intermediates which are formed due to PET. A weak MF, very close to the hyperfine interaction of the system, has the potential to inhibit or enhance reaction channels for singlet and triplet states, which eventually effects the product distribution. At first, well-documented examples of PET involving small molecules like derivatives of phenazines, carbazoles and acridines with classical electron donors in varying homogeneous and heterogeneous media have been discussed and the influence of a weak MF on the dynamics of PET is highlighted. Secondly, utilization of magnetic field effect (MFE) to probe PET in protein pockets has been described. Thirdly, an extensive discussion on PET involving nucleobases, nucleosides, nucleotides and nucleic acids and subsequent MFE on such reactions has been reported. Next, MFE has been exploited to study PET involving nanomaterials. Finally, some very recent studies of MFE have been discussed. Thus, this review is an attempt to unravel various aspects of PET in a large number of systems of varying dimensions by means of several facets of MFE like B<sub>1/2</sub> parameter, its capability to authenticate the initial spin state and distance dependence property.</p></div>","PeriodicalId":375,"journal":{"name":"Journal of Photochemistry and Photobiology","volume":"21 ","pages":"Article 100238"},"PeriodicalIF":3.261,"publicationDate":"2024-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666469024000137/pdfft?md5=64e974a162239ce1d7c2c90bd89d0f50&pid=1-s2.0-S2666469024000137-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140406845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信