Journal of Organometallic Chemistry最新文献

{"title":"Insights into the catalytic activity and recyclability of Pt deposited on PDA encapsulated porous silica toward hydrosilylation reaction","authors":"Zhiqing Liu ,&nbsp;Zepan Sun ,&nbsp;Haifeng Zhang ,&nbsp;Yajing Pan ,&nbsp;Pei Liu ,&nbsp;Chonggang Wu ,&nbsp;Tao Hu","doi":"10.1016/j.jorganchem.2025.123703","DOIUrl":"10.1016/j.jorganchem.2025.123703","url":null,"abstract":"<div><div>Mussel inspired polydopamine (PDA) has been extensively applied as a linker in noble metal based heterogeneous catalysts to promote either metal dispersion or metal-support interaction. Herein, three heterogeneous Pt catalysts were first prepared by depositing Pt on PDA encapsulated porous silica (SiO₂-PDA-Pt) with different PDA coating degree and their catalytic activity toward two model hydrosilylation reactions between methyldichlorosilane and a non-polar 1-octene and a polar allyl cyanide were investigated. Meanwhile, stability and recyclability of these catalysts were also explored. Results show that PDA coating degree may directly influence both Pt loading and its oxidation state, which then resultantly tailor the activity of the supported catalysts. The SiO₂-PDA-Pt catalysts all showed excellent activity even after six catalytic rounds even though a gradual loss of Pt species were observed. Among them, the activity of the one with lowest PDA coating exhibited both higher activity and better recyclability, which is mainly ascribed to a higher content and retention of more active low valent Pt⁰ species that may be well stabilized by proper PDA coating.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1036 ","pages":"Article 123703"},"PeriodicalIF":2.1,"publicationDate":"2025-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143942627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Development of a recyclable GO-metformin-Pd(0) nanocatalyst for ecofriendly synthesis of quinoline-4(1H)-ones and flavones via multicomponent-carbonylation reactions","authors":"Mosstafa Kazemi ,&nbsp;Vicky Jain ,&nbsp;Suhas Ballal ,&nbsp;Munthar Kadhim Abosaoda ,&nbsp;Abhayveer Singh ,&nbsp;T. Krithiga ,&nbsp;Subhashree Ray ,&nbsp;Naveen Chandra Talniya ,&nbsp;Radwan Ali","doi":"10.1016/j.jorganchem.2025.123699","DOIUrl":"10.1016/j.jorganchem.2025.123699","url":null,"abstract":"<div><div>In this method, a sustainable and reusable nanocatalyst, GO/MNPs-Met-Pd(0), was developed by anchoring Pd(0) complexes onto metformin-functionalized graphene oxide-magnetic nanoparticles. Comprehensive characterization using FT-IR, XRD, VSM, SEM, TEM, TGA, BET, EDX, elemental mapping, and ICP-OES confirmed the catalyst’s structure and composition. The catalytic performance of GO/MNPs-Met-Pd(0) was evaluated in two multicomponent reactions for the efficient synthesis of quinoline-4(1H)-one and flavone derivatives. Conducted in ionic liquid media, the reactions yielded quinoline-4(1H)-ones (15 examples) with 88–99 % yields and flavones (12 examples) with 85–98 % yields. The catalyst demonstrated excellent reusability with minimal activity loss over multiple cycles. These results highlight GO/MNPs-Met-Pd(0) as a highly efficient, selective, and eco-friendly catalyst for the sustainable synthesis of valuable heterocyclic scaffolds. Compared to previously reported methods for preparing quinoline derivatives via carbonylation reactions, this method has prominent features such as the following: use of a green catalyst with high efficiency, recyclability, and stability, carrying out carbonylation reactions in an ionic liquid as a green solvent, and synthesis of products with very high yields in 1 h.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1036 ","pages":"Article 123699"},"PeriodicalIF":2.1,"publicationDate":"2025-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143937298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hyaluronic acid modified magnetic nanoparticles decorated silver nanoparticles: catalytic application in C-S coupling and investigation of its anti-inflammatory, analgesic and anaesthetic activities","authors":"Yuanyuan Zhang ,&nbsp;Lang Xiong ,&nbsp;Songchun Liu ,&nbsp;Attalla F. El-kott ,&nbsp;Mohammed A. AlShehri ,&nbsp;Wei Da","doi":"10.1016/j.jorganchem.2025.123700","DOIUrl":"10.1016/j.jorganchem.2025.123700","url":null,"abstract":"<div><div>The current research deals with the synthesis and characteristic depiction of Ag NPs withheld and hyaluronic acid (HA) adjusted Fe₃O₄ nanoparticles (Fe₃O₄@HA/Ag NPs) observing a bio-promoted by law requiring no involvement toxic and deleterious reducers or reactants. A variety of physicochemical methodological analysis, including FT-IR, FE-SEM, TEM, EDX, XRD, VSM, and ICP-OES, contributed to identify and investigate the conceptual and various functional dimensions.We also applied the Fe₃O₄@HA/Ag NPs as the efficient catalyst for C-S coupling reactions to achieve the related aromatic sulfides. The catalyst shown excellent recyclability for 8 runs without significant performance loss.The Fe₃O₄@HA/Ag NPs nanocomposite was subsequently explored towards the anaesthetic, analgesic and anti-inflammatory activities. The nanocomposite Fe₃O₄@HA/Ag NPs exhibited an IC₅₀ value of 56 µg/mL against DPPH free radicals.The local anesthetic effects were assessed in models of frogs and guinea pigs, revealing noteworthy efficacy in both animal species.The analgesic effects were evaluated in mice by administering various doses orally.Writhing episodes caused by acetic acid were notably decreased in a manner that depended on the dosage.Furthermore, an assessment was conducted to determine the anti-inflammatory effects of the identical dosage.After being administered orally, the inflammation in the paws of mice induced by carrageenin, a commonly used inflammatory agent, was noticeably reduced.The Fe₃O₄@HA/Ag NPs nanocomposite shows promise as a groundbreaking therapeutic medication in the future, demonstrating analgesic, antioxidant properties, anti-inflammatory effects, and local anesthetic qualities.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1036 ","pages":"Article 123700"},"PeriodicalIF":2.1,"publicationDate":"2025-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143931847","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Decorated silver nanoparticles over chitosan modified CNTs/Fe3O4 nanoparticles: A recyclable navel catalyst for solvent-free A3 coupling reactions and evaluation of its anti-breast cancer effects","authors":"Fahad M. Aldosari ,&nbsp;Attalla F. El-kott ,&nbsp;Mohammed A. AlShehri ,&nbsp;Sally Negm ,&nbsp;Hiba A. Alarousi ,&nbsp;Heba I. Ghamry ,&nbsp;Kareem Morsy ,&nbsp;Bikash Karmakar","doi":"10.1016/j.jorganchem.2025.123701","DOIUrl":"10.1016/j.jorganchem.2025.123701","url":null,"abstract":"<div><div>The present research illustrates a sustainable method for the in <em>situ</em>-immobilized Ag nanoparticles on the chitosan biopolymer functionalized Fe₃O₄ supported over high surface carbon nanotubes (CNT). Numerous amino and hydroxyl organofunctions over chitosan biopolymer facilitated the green synthesis of the Ag NPs from silver ions without toxic reagents. Physicochemical properties of the designed material were further assessed using a number of characterization techniques, including TEM, FE-SEM, EDX, VSM elemental mapping, and ICP analysis. The TEM analysis depicted the Ag NPs deposited on the inner and outer surfaces of the CNT within the size range of 25–30 nm. Map sum spectrum revealed the major component of the nanocomposite as C (76.1 %). VSM studies showed the magnetization saturation value as 18.7 emu/g. The CNTs/Fe₃O₄@CS/Ag NPs was subsequently employed in the one-pot three component A³ coupling of phenylacetylene, morpholine and diverse aldehydes under solvent-less conditions to afford excellent yields (85–95 %) of a range of propargylamine derivatives. Recyclability was studied for seven consecutive cycles with any discernible reduction in activity. Furthermore, hot filtration and leaching test was carried out to validate the durability of the catalyst. Additionally, cytotoxic properties of the bio-nanomaterial were assessed against human breast cancer cells over MCF-7 cell line. The % toxicity profile against the material load demonstrated a dose dependent increase graph. This outcome is anticipated due to excellent ROS generation ability along with the contribution from chitosan secondary metabolites. The related IC₅₀ value was determined to be 269 μg/mL and was benign to the normal cells. Importance of this research lies beneath the fact, this is the first report of Ag NP doped functionalized magnetic carbon nanotube towards the C<img>H activation type of reaction for the one-pot synthesis of diverse propargylamines and also showed significant anti-breast cancer potential against corresponding cell line, studied in vitro.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1036 ","pages":"Article 123701"},"PeriodicalIF":2.1,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143923515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A review of the application of fibrous nano-silica (KCC-1) as nanocatalysts in the preparation of heterocyclic ring frameworks","authors":"Sara Payamifar ,&nbsp;Majid Abdouss ,&nbsp;Ahmad Poursattar Marjani ,&nbsp;Hamideh Sarreshtehdar Aslaheh","doi":"10.1016/j.jorganchem.2025.123687","DOIUrl":"10.1016/j.jorganchem.2025.123687","url":null,"abstract":"<div><div>Fibrous nano-silica (KCC-1) has emerged as a superior nanocatalyst support due to its high surface area, fibrous morphology, and enhanced accessibility. Its unique structural properties enable the development of efficient, eco-friendly metal-based nanocatalysts, which are instrumental in synthesizing biologically critical heterocyclic compounds. Traditionally, the synthesis of heterocyclic compounds has relied heavily on homogeneous metal catalysts, such as palladium or copper salts, which often require harsh conditions and toxic solvents and are difficult to recover or reuse. These systems, while effective, suffer from several drawbacks, including catalyst deactivation, limited selectivity, environmental concerns due to metal waste, and high operational costs. Current research focuses on leveraging KCC-1-supported metal nanoparticles for green, cost-effective, and scalable methods, addressing catalytic efficiency, selectivity, and sustainability challenges. This review highlights recent advancements in KCC-1 applications for heterocyclic frameworks and outlines future directions in developing high-performance, reusable catalytic systems for pharmaceutical and organic synthesis demands.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1036 ","pages":"Article 123687"},"PeriodicalIF":2.1,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143948939","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sodium lignosulfonate capped silver nanoparticles: Synthesis, characterization and its catalytic application in the CN coupling reactions and study of its anti-gastric cancer effects","authors":"Fahad M. Aldosari ,&nbsp;Attalla F. El-kott ,&nbsp;Mohammed A. AlShehri ,&nbsp;Sally Negm ,&nbsp;Hiba A. Alarousi ,&nbsp;Heba I. Ghamry ,&nbsp;Kareem Morsy ,&nbsp;Bikash Karmakar","doi":"10.1016/j.jorganchem.2025.123686","DOIUrl":"10.1016/j.jorganchem.2025.123686","url":null,"abstract":"<div><div>In this study, a bio-inspired technique is used to synthesize and characterize an Ag NPs garlanded sodium lignosulphate (Ag NPs@NaLS) without the use of any hazardous or poisonous stabilizing or reducing chemicals. The morphological and structural characteristics were evaluated using a variety of physicochemical techniques, including elemental mapping, FT-IR, SEM, TEM, EDX, XRD, and ICP-OES. Under mild circumstances, the nanocomposite was catalytically investigated in the effective N-arylation of indole via Buchwald-Hartwig C<img>N coupling with various haloarenes. A relatively short reaction time was required to get an excellent yield. With minimal loss of catalytic activity, the nanocatalyst was readily recovered by centrifugation and recycled seven times. The cytotoxicity of the Ag NPs@NaLS bionanomaterial against stomach tumors was investigated further from a biological perspective. Following the MTT approach, the experiments were conducted against the typical gastric cancer cell lines AGS, and they showed notable in vitro actions to prevent their proliferation.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1035 ","pages":"Article 123686"},"PeriodicalIF":2.1,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143912687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Quince seed mucilage mediated biosynthesis of silver nanoparticles as a novel nanocatalyst for O-acetylation of alcohols","authors":"Ali B. M Ali ,&nbsp;Thanaa Amir Ahmed ,&nbsp;Shaxnoza Saydaxmetova ,&nbsp;Suranjana V. Mayani ,&nbsp;Suhas Ballal ,&nbsp;Harshit Gupta ,&nbsp;Subhashree Ray ,&nbsp;Aashna Sinha ,&nbsp;Sarfaraz Kamangar ,&nbsp;Saiful Islam","doi":"10.1016/j.jorganchem.2025.123683","DOIUrl":"10.1016/j.jorganchem.2025.123683","url":null,"abstract":"<div><div>In this study, we present an environmentally friendly procedure for the bio-inspired fabrication of Ag nanoparticles facilitated by macromolecules extracted from <em>Quince</em> (<em>Cydonia oblonga</em>) seed mucilage (QSM). The inherent phytochemicals in the mucilage acted as efficient reducing agents for silver ions under ultrasonic irradiation, while also providing stabilization to the Ag NPs through capping or encapsulation. The structural properties of the nanocomposite (Ag NPs@QSM) were analyzed using various advanced techniques, including UV-Vis spectroscopy, TEM, FE-SEM, EDX and ICP-OES. The fabricated nanocomposite proved to be an effective nanocatalyst for solvent-free <em>O</em>-acetylation of various alcohols using acetic anhydride under mild conditions. Furthermore, the material could be isolated and reused for nine consecutive cycles.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1036 ","pages":"Article 123683"},"PeriodicalIF":2.1,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143927734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High selective photo-oxidation of cyclohexanol into cyclohexanone by W18O49 - Graphene oxide composite","authors":"Dong He ,&nbsp;Jincheng Liu ,&nbsp;Zewei Liao ,&nbsp;Wei Cai ,&nbsp;Yijun Luo ,&nbsp;Yanxiong Fang","doi":"10.1016/j.jorganchem.2025.123679","DOIUrl":"10.1016/j.jorganchem.2025.123679","url":null,"abstract":"<div><div>The efficient photooxidation of cyclohexanol to cyclohexanone under mild conditions presents significant challenges due to its low efficiency and unwanted by-products. In this study, we present a simple and scalable method to prepare a graphene oxide (GO)-tungsten oxide (W₁₈O₄₉) composite that overcomes these limitations. By combining ultrathin oxygen-vacancy containing W₁₈O₄₉ nanowires with GO sheets, we create a type II photocatalyst that enhances light absorption, minimizes electron-hole recombination, and selectively converts cyclohexanol to cyclohexanone. This design leverages the distinct advantageous characteristics of both materials, avoiding the aggregation of W₁₈O₄₉ nanowires and GO sheets while enhancing the absorption of reactants. Under ambient conditions and simulated solar light irradiation, the composite with a mass ratio of W₁₈O₄₉ to GO being 8:1 achieved 99.5 % selectivity for cyclohexanone with a conversion rate of 2.56 %, which is 1.83 times greater than standalone W₁₈O₄₉. The investigation into the selective photocatalytic oxidation mechanism was conducted through photoelectric measurements, band energy spectrum analysis, and active radical trapping experiments. The findings of this study demonstrate improvements in cyclohexanol adsorption and the charge separation by utilizing GO-W₁₈O₄₉ materials, ultimately leading to a strong preference for cyclohexanone under gentle conditions. This groundbreaking method holds significant promise for the advancement of photocatalysis technology.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1035 ","pages":"Article 123679"},"PeriodicalIF":2.1,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143899005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Exploring Metal Complexes for Cancer Treatment: Mechanistic Insights and Therapeutic Potential","authors":"Pandey Priya Arun ,&nbsp;Ritu Raj Patel ,&nbsp;Sudhir Kumar Singh ,&nbsp;Kailash Parmar ,&nbsp;Meenakshi Singh","doi":"10.1016/j.jorganchem.2025.123682","DOIUrl":"10.1016/j.jorganchem.2025.123682","url":null,"abstract":"<div><div>Recent research in the field of cancer therapeutics has explored various potential drug treatments supported by metal- based scaffolds, following the investigation and clinical application of cisplatin, which has emerged as an active anti- cancer drug. Organometallic compounds have gained significant attention in cancer therapy due to their unique ability to interact with biomolecules, providing targeted and efficient anticancer activity. This has led to the development of metallodrugs, which encompass metal-based compounds with a wider range of functionalities and mechanisms of action compared to organic molecules. However, platinum-based metal complexes have limitations in their spectrum of anti-cancer activities, often resulting in side effects and resistance. To address these challenges, extensive research has been conducted to study and develop effective alternatives to platinum-based anticancer medications, encompassing metals such as ruthenium, vanadium, copper, iron, manganese, zinc, and cobalt. Metallodrugs represent a promising new category of potential cancer treatments, renewing interest in pursuing effective anti-cancer therapies. Nanomedicine strategies offer an efficient drug delivery platform to overcome the limitations of conventional chemotherapy and enhance therapeutic efficacy. Multifunctional nanomaterials have demonstrated the ability to improve drug delivery by increasing bioavailability and optimizing pharmacokinetics, thereby enhancing the effectiveness of chemotherapeutic agents in overcoming multidrug resistance (MDR). By gaining a deeper understanding of their distinct characteristics and mechanisms of action, there is potential to explore avenues for developing targeted and effective anti-cancer treatments. This review explores the intricate details of various metal complexes, highlighting their unique properties and modes of action in combating cancer while providing valuable insights into their potential as promising agents for developing effective and targeted anticancer therapies, paving the way for future advancements in the field.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1035 ","pages":"Article 123682"},"PeriodicalIF":2.1,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Boron Compounds as Key Drivers of Innovation: Exploring Their Role in Environmental Remediation, Sustainable Agriculture, Advanced Biomedical Applications, and Green Chemistry","authors":"Metin Yildirim ,&nbsp;Mehmet Ersatir ,&nbsp;Mohammed Saleh ,&nbsp;Burcu Demirbağ ,&nbsp;Erdal Yabalak ,&nbsp;Ahmet Kilic","doi":"10.1016/j.jorganchem.2025.123688","DOIUrl":"10.1016/j.jorganchem.2025.123688","url":null,"abstract":"<div><div>Boron compounds have attracted significant attention from researchers in recent years due to their exceptional electronic properties and wide applicability in therapeutic, biomedical, environmental, and agricultural fields. On the other hand, boron compounds, which are low-cost, easy to synthesize, and stable, have the potential to be used in many application areas due to the hydrophobic and electrostatic interactions they form with different molecules under mild reaction conditions, and thus they appear as promising molecules for a wide range of different applications in the future. This review consists of four main sections, covering boron's catalytic role; its therapeutic potential, including anti-cancer, anti-inflammatory, and antimicrobial properties; its role in biosensors; its applications in water and wastewater treatment, waste management, and recycling; and its significance in agriculture, specifically in soil health, fertilization, and plant physiology. Moreover, this review provides an in-depth examination of boron from multiple perspectives, offering comprehensive insights while carefully summarizing recent studies selected with meticulous attention and is very likely to play a greater active role in the future studies. Although boron compounds have made significant progress in areas such as environmental remediation, sustainable agriculture, advanced biomedical applications, and higher priority green chemistry, new studies are still needed to synthesize new boron-based compounds and elucidate their properties.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1035 ","pages":"Article 123688"},"PeriodicalIF":2.1,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143917928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}