RecyclingPub Date : 2024-06-04DOI: 10.3390/recycling9030049
Ibtissam Ballou, Jamal Naja, Zineelabidine Bakher, S. Kholtei
{"title":"Adsorption of Eriochrome Black T on Pseudo Boehmite and Gamma Alumina Synthesized from Drinking Water Treatment Sludge: A Waste-to-Recycling Approach","authors":"Ibtissam Ballou, Jamal Naja, Zineelabidine Bakher, S. Kholtei","doi":"10.3390/recycling9030049","DOIUrl":"https://doi.org/10.3390/recycling9030049","url":null,"abstract":"Eriochrome black T is considered as one of the anionic dyes with potential harmful effects on human health and the environment. Among other processes, adsorption can contribute to the removal of these dyes. In the present study, two adsorbent materials, pseudo-boehmite (γ-AlOOH) and gamma alumina (γ-Al2O3), were synthesized and tested in the removal of the Eriochrome black T molecule (EBT). γ-AlOOH and γ-Al2O3 were obtained by precipitation from NaAlO2 solution at pH = 7, at a temperature of 80 °C, and by the thermal transformation of γ-AlOOH at 800 °C, respectively. In order to gain insights into the structural, chemical, thermal and morphological properties of these materials, numerous analytical techniques were involved, including X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), differential thermogravimetric–thermal analysis (TGA-DTA), scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), and specific surface area measurement using the Brunauer–Emmett–Teller (BET) method. Several adsorption parameters were studied, such as the adsorbent dose, initial concentration, pH, contact time and reaction temperature. The kinetic study showed that EBT adsorption follows the pseudo-second-order model. The Langmuir isotherm model revealed a maximum EBT adsorption capacity of 344.44 mg g−1 and 421.94 mg g−1 for γ-AlOOH and γ-Al2O3, respectively. A textural and structural analysis after adsorption highlighted the effective adsorption of the dye.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141386866","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-06-03DOI: 10.3390/recycling9030048
Lin Wang, Peter Rem, Francesco Di Maio, Max van Beek, G. Tomás
{"title":"An Innovative Magnetic Density Separation Process for Sorting Granular Solid Wastes","authors":"Lin Wang, Peter Rem, Francesco Di Maio, Max van Beek, G. Tomás","doi":"10.3390/recycling9030048","DOIUrl":"https://doi.org/10.3390/recycling9030048","url":null,"abstract":"Solid waste sorting is an important pre-treatment in recycling to improve the efficiency of material recovery and reduce costs. Motivated by the PEACOC project on metal recovery from solid wastes, an innovative magnetic density separation (MDS) process has been developed for solid waste sorting. It has intrinsic advantages over conventional gravity separation technologies and the previously industrialized MDS process. The new MDS process applies an inclined planar magnet and a horizontal basin containing a static magnetic fluid as the separation medium. A particle sliding phenomenon is identified as a feature that could help the separation. Experiments have been carried out to demonstrate the role of the MDS in concentrating valuable metals in shredded PCBAs and reducing metallic contaminants in plastic fractions of shredded wires. A pilot scale facility is introduced to show the design to achieve continuous production and to reduce the consumption of ferrofluid.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141269941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-06-01DOI: 10.3390/recycling9030047
Ranjitha B. Tangadagi, P. T. Ravichandran
{"title":"Performance Evaluation of Self-Compacting Concrete Prepared Using Waste Foundry Sand on Engineering Properties and Life Cycle Assessment","authors":"Ranjitha B. Tangadagi, P. T. Ravichandran","doi":"10.3390/recycling9030047","DOIUrl":"https://doi.org/10.3390/recycling9030047","url":null,"abstract":"The primary objective of this research is to utilize an industrial waste byproduct such as waste foundry sand (WFS) as an alternative for fine aggregate in self-compacting concrete (SCC). This research focuses on the use of WFS in SCC to enhance durability and mechanical properties, to find an alternative for fine aggregate in SCC, to reduce the disposal challenges of WFS, and to make SCC lightweight and environmentally friendly. Initially, WFS was treated with chemical (H2SO4), segregating, and sieving to remove the foreign matter and clay content. For this study, WFS is considered in varying percentages such as 0, 10, 20, 30, 40, and 50. For this investigation, M60 grade SCC is considered as per Indian standards and EFNARC guidelines. After that, this research focuses on tests on various fresh properties of SCC in each batch to find the flowability and passing ability of various mixes prepared using WFS. Similarly, the mechanical properties of SCC such as compressive, flexural, and split tensile strength tests were performed at 7, 28, and 90 day curing periods, respectively. Likewise, durability properties of SCC were found in all the mixes prepared using WFS such as water absorption, sorptivity, resistance to chemical attack, and chloride ion penetration; tests of these properties were performed at 28 and 90 day curing periods, respectively. Based on the experimental investigation of SCC, it was found that WFS can be used in M60 grade SCC as an alternative for fine aggregate up to 30% without compromising much on its properties. Finally, this establishes that using treated WFS in SCC helps in reducing the generation of waste and prevails as a meaningful utilization method. This research will also establish that the use of treated WFS will reduce the density and make SCC a lightweight, green, and sustainable material.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141277411","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-05-24DOI: 10.3390/recycling9030046
Julien Hubert, Sophie Grigoletto, Frédéric Michel, Zengfeng Zhao, Luc Courard
{"title":"Development and Properties of Recycled Biomass Fly Ashes Modified Mortars","authors":"Julien Hubert, Sophie Grigoletto, Frédéric Michel, Zengfeng Zhao, Luc Courard","doi":"10.3390/recycling9030046","DOIUrl":"https://doi.org/10.3390/recycling9030046","url":null,"abstract":"The production of biomass fly ash has been increasing every year in Europe, reaching 5.5 million tons in 2020. Fly ash produced by burning biomass is not yet accepted in the standards as a substitute material for cement in mortar and concrete. In a first approach, the substitution limit of biomass ash is determined by comparing the mechanical strengths (among others, compressive strength), fresh state properties and hardened properties of mortars produced with fly ash with those of mortars produced with coal fly ash (EN 450-1 and ASTM C618). Masonry and rendering mortars have been designed with different substitution rates of fly ashes from wood combustion in thermal power plants. Although there is an overall decrease in performance, mortars made with biomass ash retain properties that make them suitable for use in masonry (loss of 13% compressive strength for masonry mortars with 10% substitution rate after 90 days) or rendering (loss of 20% compressive strength for rendering mortars with 10% substitution rate after 90 days). Water absorption and porosity (24.1 and 23.7% for masonry and rendering mortars, respectively) are, however, not significantly modified, which potentially contributes to good durability properties.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141102455","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-05-24DOI: 10.3390/recycling9030045
Manjunath Maddikeari, B. B. Das, Ranjitha B. Tangadagi, Suman Roy, Priyanka Bangalore Nagaraj, Manjunatha Lokanahally Ramachandra
{"title":"A Comprehensive Review on Use of Wastewater in the Manufacturing of Concrete: Fostering Sustainability through Recycling","authors":"Manjunath Maddikeari, B. B. Das, Ranjitha B. Tangadagi, Suman Roy, Priyanka Bangalore Nagaraj, Manjunatha Lokanahally Ramachandra","doi":"10.3390/recycling9030045","DOIUrl":"https://doi.org/10.3390/recycling9030045","url":null,"abstract":"The primary aim of this review article is to find the influence of wastewater and its characteristics on recycling as an alternative to potable water for concrete preparation. On the other hand, scarcity, and the demand for freshwater for drinking are also increasing day by day around the globe. About a billion tons of freshwater is consumed daily for concrete preparation for various operations such as mixing and curing, to name a few. The rapid development of certain industries such as textile, casting, stone cutting, and concrete production has caused the water supply to be severely affected. Recycling wastewater in concrete offers various potential benefits like resource conservation, environmental protection, cost savings, and enhanced sustainability. This article reviews the effect of various types of wastewater on various physical and chemical properties of wastewater, rheological characteristics, strength, durability, and microstructure properties of concrete. It also explores the potential effects of decomposing agents on enhancing concrete properties. Currently, limited research is available on the use of various types of wastewater in concrete. Hence, there is a need to develop various methods and procedures to ensure that the utilization of wastewater and treated wastewater is carried out in the production of concrete in a sustainable manner. Although wastewater can reduce the workability of fresh concrete, it can also increase its strength and long-term performance of concrete. The use of various types of wastewater, such as reclaimed water and tertiary-treated wastewater, was found to be superior compared to those using industrial- or secondary-treated wastewater. Researchers around the globe agree that wastewater can cause various detrimental effects on the mechanical and physical properties of concrete, but the reductions were not significant. To overcome limited scientific contributions, this article reviews all the available methods of using various types of wastewater to make concrete economically and environmentally friendly. This research also addresses possible challenges with respect to the demand for freshwater and the water crisis.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141099966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-05-22DOI: 10.3390/recycling9030044
A. Ravlikovsky, M. N. C. Pinheiro, Lucian Dincă, V. Crişan, L. Symochko
{"title":"Valorization of Spent Mushroom Substrate: Establishing the Foundation for Waste-Free Production","authors":"A. Ravlikovsky, M. N. C. Pinheiro, Lucian Dincă, V. Crişan, L. Symochko","doi":"10.3390/recycling9030044","DOIUrl":"https://doi.org/10.3390/recycling9030044","url":null,"abstract":"Spent mushroom substrate (SMS), often disregarded as waste despite its abundance in organic matter and mineral micronutrients, has emerged as a valuable resource for diverse applications. While Europe and Asia have witnessed extensive research in this field over the past decade, Ukraine’s exploration remains limited. This study conducts a thorough investigation into SMS recycling and reutilization over a 4-year period. Employing experimental and comparative methods, this research unveils compelling insights into the potential of SMS for reintroduction into the primary production cycle and secondary activities. The main conclusions reveal the success of SMS valorization in the production of additives, fertilizers, and alternative fuels. Furthermore, the application of SMS in agroecosystems significantly enhances the soil biological activity. The integration of these methods into production chains not only yields economic benefits for companies but also fosters environmental stewardship, aligning with waste-free practices and the principles of bioeconomy and sustainability.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141108722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-05-21DOI: 10.3390/recycling9030043
Mandar Golvaskar, Sammy A. Ojo, Manigandan Kannan
{"title":"Recent Advancements in Material Waste Recycling: Conventional, Direct Conversion, and Additive Manufacturing Techniques","authors":"Mandar Golvaskar, Sammy A. Ojo, Manigandan Kannan","doi":"10.3390/recycling9030043","DOIUrl":"https://doi.org/10.3390/recycling9030043","url":null,"abstract":"To improve the microstructure and mechanical properties of fundamental materials including aluminum, stainless steel, superalloys, and titanium alloys, traditional manufacturing techniques have for years been utilized in critical sectors including the aerospace and nuclear industries. However, additive manufacturing has become an efficient and effective means for fabricating these materials with superior mechanical attributes, making it easier to develop complex parts with relative ease compared to conventional processes. The waste generated in additive manufacturing processes are usually in the form of powders, while that of conventional processes come in the form of chips. The current study focuses on the features and uses of various typical recycling methods for traditional and additive manufacturing that are presently utilized to recycle material waste from both processes. Additionally, the main factors impacting the microstructural features and density of the chip-unified components are discussed. Moreover, it recommends a novel approach for recycling chips, while improving the process of development, bonding quality of the chips, microstructure, overall mechanical properties, and fostering sustainable and environmentally friendly engineering.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141117735","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-05-20DOI: 10.3390/recycling9030042
Konstantinos Tsimnadis, Grigorios L. Kyriakopoulos
{"title":"Investigating the Role of Municipal Waste Treatment within the European Union through a Novel Created Common Sustainability Point System","authors":"Konstantinos Tsimnadis, Grigorios L. Kyriakopoulos","doi":"10.3390/recycling9030042","DOIUrl":"https://doi.org/10.3390/recycling9030042","url":null,"abstract":"Over the last several decades, the European Union (EU) has championed recycling and sustainable waste management through Directives 2008/98/EC and 2018/851, shaping practices across its member states. Currently, 30% of the EU’s municipal waste is recycled, 19% composted, 23% incinerated, and 23% landfilled. However, regional variations exist within the EU, with Greece and other Mediterranean/Balkan nations favoring landfilling, while Germany and other Western/Central EU nations prioritize recycling and composting, and Nordic countries lean toward incineration. To address these differences, a new sustainability point system was created in order to evaluate and compare all different municipal waste management strategies of EU members. Notably, countries like Germany, the Netherlands, and Sweden score the highest due to low municipal waste generation, high recycling rates (>35%), minimal landfilling (<1%), and significant incineration. In contrast, Cyprus, Malta, and Greece score lower due to landfill reliance and lower recycling rates. Therefore, this study introduces a novel sustainability point system to mitigate disparities, highlighting the need for targeted interventions and policy initiatives at the national and EU levels. By leveraging these insights, policymakers can allocate resources effectively, foster collaboration, and motivate citizens to achieve common environmental goals as well as the Sustainable Development Goals (SDGs).","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141119577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-05-18DOI: 10.3390/recycling9030041
H. Al-Bayati, Waleed Jadaa, Susan L. Tighe
{"title":"Effect of Recycled Concrete Aggregate Addition on the Asphalt Mixtures Performance: ITZ Area, Microstructure, and Chemical Analysis Perspectives","authors":"H. Al-Bayati, Waleed Jadaa, Susan L. Tighe","doi":"10.3390/recycling9030041","DOIUrl":"https://doi.org/10.3390/recycling9030041","url":null,"abstract":"The importance of environmental consciousness and sustainability is increasing among transportation governing bodies worldwide. Many government bodies are concerned with maximizing the usage of recycled substances in road construction. Therefore, assessing the effect of recycled materials consumption is essential, mainly when designing new ‘green’ pavement types. The primary objective of this study is to investigate the impact of different treatments on improving the interfacial transition zone (ITZ) of coarse recycled concrete aggregate (CRCA) and its application in asphalt mixes. Such an aim is accomplished by enhancing its physical and mechanical characteristics, as well as its microstructure. The surface morphology, chemical composition, and intermix phases of the ITZ area and calcium silicate hydrate (CSH) compounds for CRCA were evaluated using scanning electron microscopy (SEM), an energy-dispersive X-ray analyzer (EDAX), and X-ray diffraction analysis (XRD). The performance of asphalt mixtures that included treated and untreated CRCA was also examined using different tests. It was found that heat treatment is an effective technique for enhancing the ITZ. However, cracks were seen in the mortar of CRCA when exposed to high temperatures (500 °C), which adversely affects the characteristics of the mortar. Acid treatment appeared to be an effective approach for improving the ITZ area. Nevertheless, the treatment that used acetic acid, a weak acid, was more effective than HCl acid, a strong acid. The outcomes revealed that the ITZ microstructure is significantly enhanced under different treatment types; however, microstructure improvements mainly included increased surface homogeneity and CSH compounds and a reduced Ca/Si ratio. It was also found that the asphalt mixtures with different proportions of untreated CRCA exhibited enhanced resistance to rutting. Furthermore, their tensile strength ratio (TSR) values were above the minimal level requirements. Moreover, the asphalt mixture with 30% CRCA, which was treated with various treatment methods, demonstrated a significant improvement in the mixtures’ mechanical properties; therefore, its application is highly successful and an environmentally friendly solution.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141125233","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-05-17DOI: 10.3390/recycling9030040
G. Okuthe
{"title":"Valorizing Fruit and Vegetable Waste: The Untapped Potential for Entrepreneurship in Sub-Saharan Africa—A Systematic Review","authors":"G. Okuthe","doi":"10.3390/recycling9030040","DOIUrl":"https://doi.org/10.3390/recycling9030040","url":null,"abstract":"Valorizing food waste (FW) in sub-Saharan Africa (SSA) can enhance the efficiency of limited resources, make healthy diets more affordable, and foster the creation of innovative enterprises. The vast quantities of FW from the agri-food chain significantly threaten food security. To address this issue and maximize potential environmental and socio-economic benefits, valorizing waste, a value-adding process for waste materials, has emerged as a sustainable and efficient strategy. Valorizing FW reduces greenhouse gas emissions, mitigates climate change, enhances resource efficiency, and improves planetary health. As a pivotal player in the transition toward the circular economy, this study investigates the potential of converting FW into value-added products, offering entrepreneurial opportunities for SSA’s unemployed youth. A systematic literature review is conducted to identify and filter relevant articles over five years by applying inclusion and exclusion criteria. A total of 33 articles were included for in-depth analysis to address the study’s aim. The findings highlight a range of value-added products derived from FW, including renewable energy sources, nutraceuticals, and heavy metal adsorbents. These products present promising entrepreneurial prospects within SSA. Nonetheless, overcoming barriers to FW valorization adoption is crucial for fully realizing its potential as a profitable business avenue.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140963756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}