2006 25th International Conference on Thermoelectrics最新文献

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Investigation of the Magnesium Silicide -- Mg2Si Films 硅化镁—Mg2Si薄膜的研究
2006 25th International Conference on Thermoelectrics Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331316
T. Kamilov, D.K. Kabilov, R.Kh. Kamilova, M.E. Azimov, V. Klechkovskaya, A. Orekhov, E. Suvorova
{"title":"Investigation of the Magnesium Silicide -- Mg2Si Films","authors":"T. Kamilov, D.K. Kabilov, R.Kh. Kamilova, M.E. Azimov, V. Klechkovskaya, A. Orekhov, E. Suvorova","doi":"10.1109/ICT.2006.331316","DOIUrl":"https://doi.org/10.1109/ICT.2006.331316","url":null,"abstract":"The silicides are ecologically friendly materials and they have a mechanical stability to corrosion, oxidation, decay and aggressive environments. It is known that a bulk magnesium silicide - Mg2Si demonstrates semiconductor conductivity n-type character with energy band gap Eg=0.78 eV and solid solution based on the Mg2Si-Mg2Sn have figure of merit of ZT>1 [Samsonov, et. al. 1979]. Only small part of articles has devoted to thin Mg2Si films on silicon. In this work the magnesium silicide films have been grown on silicon substrate by reactive diffusion method and their thermoelectric properties were investigated","PeriodicalId":346555,"journal":{"name":"2006 25th International Conference on Thermoelectrics","volume":"9 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2006-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126513148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Fine Bi2Te3 wires fabricated by glass sealed melt spinning 用玻璃密封熔融纺丝制备Bi2Te3细丝
2006 25th International Conference on Thermoelectrics Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331361
Ichiro Shiota, H. Kohri, Munehiro Kato, I. J. Ohsugi
{"title":"Fine Bi2Te3 wires fabricated by glass sealed melt spinning","authors":"Ichiro Shiota, H. Kohri, Munehiro Kato, I. J. Ohsugi","doi":"10.1109/ICT.2006.331361","DOIUrl":"https://doi.org/10.1109/ICT.2006.331361","url":null,"abstract":"Applying a small size cooling system is essential to avoid thermal noise in the field of micro-electronics. Fine thermoelectric materials are required to construct the system. A glass sealed melt spinning process was attempted to fabricate the fine materials. Bi2Te 3 wires of 75 mum in diameter with oval cross section were successfully obtained. The original electrical resistivity and Seebeck coefficient of the wires were maintained after the process","PeriodicalId":346555,"journal":{"name":"2006 25th International Conference on Thermoelectrics","volume":"32 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2006-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115922180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Thermoelectric Properties of P-type Half-Heusler Compounds HfPtSn and ZrPtSn p型半heusler化合物HfPtSn和ZrPtSn的热电性能
2006 25th International Conference on Thermoelectrics Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331294
Y. Kimura, A. Zama, Y. Mishima
{"title":"Thermoelectric Properties of P-type Half-Heusler Compounds HfPtSn and ZrPtSn","authors":"Y. Kimura, A. Zama, Y. Mishima","doi":"10.1109/ICT.2006.331294","DOIUrl":"https://doi.org/10.1109/ICT.2006.331294","url":null,"abstract":"We focused on half-Heusler compounds MPtSn, where M is Hf, Zr and Ti, to seek for half-Heusler compounds which intrinsically show excellent p-type thermoelectric properties in a wide temperature range up to around 1000 K. Nearly single-phase MPtSn alloys were fabricated by directional solidification using optical floating zone melting method to evaluate thermoelectric properties as properly as possible. We have found that HfPtSn and ZrPtSn show p-type thermoelectric properties in a measured temperature range from 300 to 1100 K as it is expected from our previous work. It is interesting that HfNiSn and ZrNiSn with the same valence electrons count of 18 are well-known to show n-type thermolectric properties. HfPtSn shows quite high values of p-type thermoelectric power around 250 muV/K in low and intermediate temperature ranges, while ZrPtSn shows much smaller maximum value of about 70 muV/K. On the other hand, TiPtSn exhibits very large n-type thermoelectric power of around 500 muV/K at ambient temperatures though it decreases drastically at elevated temperatures. High electrical resistivity is a major drawback that all three MPtSn compounds have in common. HfPtSn has the lowest thermal conductivity among MPtSn though the values are relatively high. The lattice contribution is supposed to dominates the thermal conduction because of high electrical resistivity and low carrier concentration measured as 2.17 times 1025 m-3","PeriodicalId":346555,"journal":{"name":"2006 25th International Conference on Thermoelectrics","volume":"144 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2006-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122055339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Effective Electron Mass of ordered AgPbmSbTe2+m clarified by ab-initio calculations 用从头算法澄清了有序AgPbmSbTe2+m的有效电子质量
2006 25th International Conference on Thermoelectrics Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331352
W. Wunderlich
{"title":"Effective Electron Mass of ordered AgPbmSbTe2+m clarified by ab-initio calculations","authors":"W. Wunderlich","doi":"10.1109/ICT.2006.331352","DOIUrl":"https://doi.org/10.1109/ICT.2006.331352","url":null,"abstract":"Experimental data on PbTe2-AgSbTe2-solid solutions near the metal-insulator- transition (MIT) showed controversy resulting in high [Hsu, KF, et al., 2004] or low [Kosuga, A, et al., 2005] values of the Seebeck-coefficient and could partly be explained by specimen inhomogeneties and resulting measurement difficulties [Chen, N, et al., 2005] or different ordering states [Bilc, D, et al., 2004]. The goal of this investigation is to clarify which ordering state is expected to have the higher Seebeck coefficient by estimating the effective mass from ab-initio band structure calculations, as successfully applied for Nb-doped SrTiO3 [Wunderlich, W, et al., 2006] and metallic alloys. While the effective masses for the metallic and the semiconducting compositions were less than 0.5, the effective mass near the MIT was around m*/m0 = 9 for SrNb0.2Ti0.8O2.98 [Wunderlich, W, et al., 2006]. The effective mass depends on ordering, namely on the distance of the foreign atoms. These findings give important guidelines for further improvement of this advanced thermoelectric material","PeriodicalId":346555,"journal":{"name":"2006 25th International Conference on Thermoelectrics","volume":"46 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2006-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116841828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of oxide additive on thermoelectricity of FeSi2 氧化物添加剂对FeSi2热电性能的影响
2006 25th International Conference on Thermoelectrics Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331240
S. Sugihara, K. Morikawa, Y. Igarashi, K. Nishiyama
{"title":"Effects of oxide additive on thermoelectricity of FeSi2","authors":"S. Sugihara, K. Morikawa, Y. Igarashi, K. Nishiyama","doi":"10.1109/ICT.2006.331240","DOIUrl":"https://doi.org/10.1109/ICT.2006.331240","url":null,"abstract":"Thermoelectricity has been hot issue in these days, because of environmental problems and energy sources deficit. Moreover, material development for thermoelectricity is now busy in oxide and metal or alloy, basically. However, conclusive materials with good performance have not yet been found in application basis. We have studied oxide-added beta-FeSi2 for these years. Iron disilicide is well known and utilized in relatively higher temperature. In this report, we indicated our successful improvement of performance of beta-FeSi2 added with Ta2O5 showing the figure of merit almost 0.3 times 10-3/K This was obtained by reducing thermal conductivity and electrical resistivity (a half of standard FeSi2)","PeriodicalId":346555,"journal":{"name":"2006 25th International Conference on Thermoelectrics","volume":"198 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2006-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129766491","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermoelectric properties on n-type Si80Ge20 with different Dopants 不同掺杂剂对n型Si80Ge20热电性能的影响
2006 25th International Conference on Thermoelectrics Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331367
Guiying Xu, Huawei Jiang, Chunyan Zhang, Xiaofeng Wu, Sitong Niu
{"title":"Thermoelectric properties on n-type Si80Ge20 with different Dopants","authors":"Guiying Xu, Huawei Jiang, Chunyan Zhang, Xiaofeng Wu, Sitong Niu","doi":"10.1109/ICT.2006.331367","DOIUrl":"https://doi.org/10.1109/ICT.2006.331367","url":null,"abstract":"Si<sub>x</sub>Ge<sub>1-x</sub> is typical thermoelectric materials used for higher temperature as thermoelectric generator. Their property is dependent on their composition. Here different dopants, including P, Ga, B, GaP, In, Sb and InSb, were used to investigate their effect on the thermoelectric properties of n type Si<sub>80</sub>Ge<sub>20</sub> alloys. The results describe that GaP and InSb are good dopant for n type alloys. Especially p type dopants Ga and In are very good multiplex dopant as dopants GaP and InSb for n type Si<sub>80</sub>Ge<sub>20</sub> respectively by Seebeck coefficient of n type Si<sub>80</sub>Ge<sub>20 </sub> at same time","PeriodicalId":346555,"journal":{"name":"2006 25th International Conference on Thermoelectrics","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2006-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129790999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Development of flexible thermoelectric device: Improvement of device performance 柔性热电器件的发展:器件性能的提高
2006 25th International Conference on Thermoelectrics Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331376
Y. Iwasaki, M. Takeda
{"title":"Development of flexible thermoelectric device: Improvement of device performance","authors":"Y. Iwasaki, M. Takeda","doi":"10.1109/ICT.2006.331376","DOIUrl":"https://doi.org/10.1109/ICT.2006.331376","url":null,"abstract":"Thermoelectric (TE) device has some problems, such as low mechanical strength, high manufacturing cost, etc. We are developing flexible TE device using thin films and flexible substrates in order to overcome those problems. The purpose of this work is to fabricate and evaluate the flexible TE device. A flexible TE device consists of vapor-deposited thin films of n- and p-type TE materials between two flexible substrates. The flexible substrate is made up of a combination of polyimide and copper. This structure enables the device itself to convert temperature difference of outer surfaces (DeltaTout) into in-plane temperature difference (DeltaT in), and it can generate electricity by the p-n couples. We analyzed temperature distribution of the device by the finite element method (FEM). According to the analysis, a flexible substrate which has thinner polyimide layer (h1) and thicker copper layer (h1) is preferable to obtain larger temperature difference. We fabricated flexible TE devices containing 33 pairs of p-n couple, which is composed of chromel and constantan thin films. The device of h 1/h2 = 12 mum/70 mum generated 3.72 muW at DeltaTout = 22.7 K, while 2.40 muW was generated from the device of h1/h2 = 35 mum/25 mum at DeltaT out = 24.0 K. The performance of the flexible TE device was successfully improved as predicted by the analysis","PeriodicalId":346555,"journal":{"name":"2006 25th International Conference on Thermoelectrics","volume":"2 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2006-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128877219","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 10
Synthesis and Characterization of nanoscale Bi2Te3, Sb2Te3, PbTe and Ag2Te powders: activated Metals and soluble Tellurium sources as synthetic Tools 纳米Bi2Te3、Sb2Te3、PbTe和Ag2Te粉体的合成与表征:活性金属和可溶性碲源作为合成工具
2006 25th International Conference on Thermoelectrics Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331224
S. Schlecht, M. Yosef, S. Weimer
{"title":"Synthesis and Characterization of nanoscale Bi2Te3, Sb2Te3, PbTe and Ag2Te powders: activated Metals and soluble Tellurium sources as synthetic Tools","authors":"S. Schlecht, M. Yosef, S. Weimer","doi":"10.1109/ICT.2006.331224","DOIUrl":"https://doi.org/10.1109/ICT.2006.331224","url":null,"abstract":"Binary tellurides such as PbTe or Bi<sub>2</sub>Te<sub>3</sub> represent one of the fundamental classes of thermoelectrics. Thus, the development of new routes for the preparation of these compounds as nanoscale powders is an important challenge. In this context, we investigated the use of activated metals and soluble tellurium sources such as diphenyltelluride or the tellurolates of hard transition metal cations as versatile tool box system for the synthesis of these powders. Using solvochemically activated lead, bismuth or antimony, their respective tellurides PbTe, Bi<sub>2</sub>Te<sub>3</sub> and Sb<sub>2 </sub>Te<sub>3</sub> could be obtained in a reaction with Ph<sub>2</sub>Te<sub>2</sub> following the same experimental protocol in all cases. The preparation of an Ag<sub>2</sub>Te nanopowder required a different synthetic approach as elemental silver does not react with Ph <sub>2</sub>Te<sub>2</sub>. Following the principle of hard and soft acids and bases, silver acetate and zinc tellurolate Zn(TePh)<sub>2</sub>middotTMEDA [Jun, Y, 2001] were reacted to form nanoparticles of Ag<sub>2</sub>Te from intermediately formed silver tellurolate","PeriodicalId":346555,"journal":{"name":"2006 25th International Conference on Thermoelectrics","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2006-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128944019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Effect of the Yb substitutions on the thermoelectric properties of CaMnO3 Yb取代对CaMnO3热电性能的影响
2006 25th International Conference on Thermoelectrics Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331291
D. Flahaut, R. Funahashi, K. Lee, H. Ohta, K. Koumoto
{"title":"Effect of the Yb substitutions on the thermoelectric properties of CaMnO3","authors":"D. Flahaut, R. Funahashi, K. Lee, H. Ohta, K. Koumoto","doi":"10.1109/ICT.2006.331291","DOIUrl":"https://doi.org/10.1109/ICT.2006.331291","url":null,"abstract":"Ca1-xYbxMnO3 (x = 0-0.5) samples were prepared via solid state reaction in air. Electrical and thermoelectric properties have been investigated up to 1000 K. The measurements reveal that the resistivity values are strongly affected by the charge carrier content and the octahedral distortion. The lowest rho reaches 3 mOmegamiddotcm for x = 0.15. Whereas the Seebeck coefficient depends only on the charge carrier concentration, the thermal conductivity of Ca1-xYbxMnO3 is mainly governed by the mass difference between the Yb and Ca cations. The best ZT value, ZT = 0.2, is obtained for x = 0.05 at 1000 K and demonstrates the good potentialities of these oxides as high temperature thermoelectric material","PeriodicalId":346555,"journal":{"name":"2006 25th International Conference on Thermoelectrics","volume":"477 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2006-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130009824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
A new concept of reducing nitrogen oxides emissions in a combustion engine -- combination of ceramic oxygen conductors and thermoelectric materials 减少内燃机中氮氧化物排放的新概念——陶瓷氧导体和热电材料的结合
2006 25th International Conference on Thermoelectrics Pub Date : 2006-08-01 DOI: 10.1109/ICT.2006.331239
K. Wojciechowski, M. Bučko, J. Obła̧kowski, P. Fuć, J. Merkisz
{"title":"A new concept of reducing nitrogen oxides emissions in a combustion engine -- combination of ceramic oxygen conductors and thermoelectric materials","authors":"K. Wojciechowski, M. Bučko, J. Obła̧kowski, P. Fuć, J. Merkisz","doi":"10.1109/ICT.2006.331239","DOIUrl":"https://doi.org/10.1109/ICT.2006.331239","url":null,"abstract":"The subject of this work is to present a new concept of reducing NOx emissions in a combustion engine based on full elimination of nitrogen from a supply system. The use of the oxygen separator (oxygen pump), composed of the ceramic ionic conductor, together with an electrical supply system based on thermoelectric materials that utilizes exhaust heat is the main assumption of the proposed solution. The paper focuses on analyzing several possibilities for the practical application of the idea suggested","PeriodicalId":346555,"journal":{"name":"2006 25th International Conference on Thermoelectrics","volume":"46 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2006-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116778135","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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