International Journal of Hydrogen Energy最新文献_第9页

Improved catalytic activity of non-metallic elements doped two-dimensional Hittorf's violet phosphorene for the hydrogen evolution reaction: A DFT study 提高掺杂非金属元素的二维 Hittorf 紫磷烯在氢气进化反应中的催化活性：DFT 研究

IF 8.1 2区工程技术

International Journal of Hydrogen Energy Pub Date : 2025-02-03 DOI: 10.1016/j.ijhydene.2024.12.423

Yi-Lin Lu , Shengjie Dong , Fangchao Cui , Kaicheng Zhang , Chunmei Liu , Jiesen Li , Zhuo Mao

{"title":"Improved catalytic activity of non-metallic elements doped two-dimensional Hittorf's violet phosphorene for the hydrogen evolution reaction: A DFT study","authors":"Yi-Lin Lu , Shengjie Dong , Fangchao Cui , Kaicheng Zhang , Chunmei Liu , Jiesen Li , Zhuo Mao","doi":"10.1016/j.ijhydene.2024.12.423","DOIUrl":"10.1016/j.ijhydene.2024.12.423","url":null,"abstract":"<div><div>The search for high-efficiency and low-cost metal-free catalysts for the hydrogen evolution reaction (HER) is vital to promote the recycling of natural materials and sustainable development. With the aid of density functional theory, an evaluation of a series of non-metallic elements B-, C-, N-, O-, S-, and Si-doped Hittorf's violet phosphorene (HP) as HER catalysts are reported. Our results demonstrate that the incorporation of these non-metallic dopants can effectively improve the HER performance for the HP, implying that the doping can indeed break the inertia of the HP basal plane and enhance the interaction between the H atom and active sites. The improved HER activities are ascribed to suitable hydrogen adsorption abilities which are well correlated with the <em>p</em><sub>z</sub>-band center and charge transfer of the dopant. According to calculated exchange current density <em>i</em><sub>0</sub> and pH-dependent H adsorption Δ<em>G</em><sub>H∗</sub>, in an acidic environment, seven doped systems own high <em>i</em><sub>0</sub> (>0.1 mA/cm<sup>2</sup>) and the N/Si-codoping (configuration I, site N) has the best HER activity with 1.520 mA/cm<sup>2</sup>. Especially, combined with the high HER activity and experimental feasibility, the O-doped HP at site 2 is the most promising candidate as the electrocatalyst for HER. This work would pave the way for designing high-performance tunable metal-free catalysts for HER and also shed light on the catalytic application of HP-based materials.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"101 ","pages":"Pages 222-233"},"PeriodicalIF":8.1,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143180174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mathematical modeling of hydrogen diffusion in a medium with impurity and structural traps in the conditions of the formation and decomposition of hydrogen-containing complexes 含氢络合物形成和分解条件下氢在有杂质和结构陷阱介质中扩散的数学建模

IF 8.1 2区工程技术

International Journal of Hydrogen Energy Pub Date : 2025-02-03 DOI: 10.1016/j.ijhydene.2024.12.047

A.V. Zvyagintseva

{"title":"Mathematical modeling of hydrogen diffusion in a medium with impurity and structural traps in the conditions of the formation and decomposition of hydrogen-containing complexes","authors":"A.V. Zvyagintseva","doi":"10.1016/j.ijhydene.2024.12.047","DOIUrl":"10.1016/j.ijhydene.2024.12.047","url":null,"abstract":"<div><div>The process of creating a physical and mathematical model of the hydrogen permeability of a hollow cylinder, depending on the level, sign and nature of the distribution of internal stresses on the example of electrochemical alloys synthesized by electrolysis, is shown. For the concentration fields of hydrogen atoms, the corresponding analytical dependences are used, which are the basis for mathematical modeling of diffusion processes and demonstrate the possibility of controlling the hydrogen permeability of metals. It is shown that the hydrogen permeability of a hollow cylinder primarily depends on the level and nature of the distribution of internal stresses (tensile and compressive). Internal stresses with a logarithmic dependence on coordinates have a single mathematical description, and the use of the principle of superposition allows you to display a picture of the joint interactions of the fields of internal stresses of various origins. The mathematical interpretation of internal stresses in crystals is reduced to the introduction of some dimensionless parameters, which are easily calculated and algebraically summed. This allows the model to demonstrate the possibility of parametric control of internal stresses in alloys. The mathematical model of the diffusion process for a medium with the formation and decay of immovable metal-impurity-hydrogen complexes is presented taking into account the probabilities of their formation and decay.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"101 ","pages":"Pages 112-119"},"PeriodicalIF":8.1,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143180163","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Numerical modeling of the transport mechanism of NH3/H2 mixtures in nanoporous materials

IF 8.1 2区工程技术

International Journal of Hydrogen Energy Pub Date : 2025-02-03 DOI: 10.1016/j.ijhydene.2024.12.376

Ao Shen , Suresh K. Bhatia , Yufeng Duan , Yifan Xu

{"title":"Numerical modeling of the transport mechanism of NH3/H2 mixtures in nanoporous materials","authors":"Ao Shen , Suresh K. Bhatia , Yufeng Duan , Yifan Xu","doi":"10.1016/j.ijhydene.2024.12.376","DOIUrl":"10.1016/j.ijhydene.2024.12.376","url":null,"abstract":"<div><div>Understanding the nanotransport properties of NH<sub>3</sub> and H<sub>2</sub> is critical for designing adsorption and separation materials. In this work, we develop a novel numerical model at the molecular level by incorporating the M − S approach and effective medium theory, and provide a rigorous and analyzable simulation implementation for a binary transport system of NH<sub>3</sub> and H<sub>2</sub>. In addition, the effect of pore length nonuniformity is simultaneously incorporated. The results show that high temperatures and large radii are detrimental to adsorption but favorable for diffusion at the single-pore scale, while the greater conductance increase in large pores dominates the fluid transport property in the pore network. The existence of a pore length distribution can induce greater effective diffusivity and lower apparent tortuosity within the pore network. Moreover, we confirm that at 300 K, the equilibrium selectivity of NH<sub>3</sub> over H<sub>2</sub> reaches approximately 28 in a uniform pore network with a pore radius of 0.25 nm, indicating the feasibility of nanoporous silica materials for use in adsorption separation of NH<sub>3</sub> and H<sub>2</sub> mixtures.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"101 ","pages":"Pages 63-72"},"PeriodicalIF":8.1,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143181166","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Low-cost excellent-adhesion flexible poly(Catechol/Polyamine) semiconductor loaded on CdS photoanode for promoting photoelectrochemical water splitting 在 CdS 光阳极上负载低成本、高附着力的柔性聚（邻苯二酚/多胺）半导体，促进光电化学水分离

IF 8.1 2区工程技术

International Journal of Hydrogen Energy Pub Date : 2025-02-03 DOI: 10.1016/j.ijhydene.2024.12.461

Zhiling Huang, Di Liu, Yue Meng

{"title":"Low-cost excellent-adhesion flexible poly(Catechol/Polyamine) semiconductor loaded on CdS photoanode for promoting photoelectrochemical water splitting","authors":"Zhiling Huang, Di Liu, Yue Meng","doi":"10.1016/j.ijhydene.2024.12.461","DOIUrl":"10.1016/j.ijhydene.2024.12.461","url":null,"abstract":"<div><div>Organic semiconductor photoanodes have gained significant interest for use in photoelectrochemical (PEC) water splitting systems, enabling the conversion of solar energy into hydrogen. In this study, we utilized a cost-effective, highly adhesive flexible poly(Catechol/Polyamine) (PCPA) semiconductor, which forms strong coordinate bonds to enhance electron transfer and serves as a passivation layer. This PCPA was applied to the CdS photoanode surface using a simplified self-aggregation method at ambient temperature and pressure. At the same time, NiOOH was also used as a hole transport agent to mitigate the self-corrosion of CdS. The CdS/2PCPA/NiOOH photoanode achieved a peak photocurrent density of 3.61 mA/cm<sup>2</sup> at 1.23 V vs. RHE, exceeding the values of the CdS/2PCPA (1.75 mA/cm<sup>2</sup>) and CdS (0.75 mA/cm<sup>2</sup>) photoanodes by factors of 2 and 4.8, respectively. This research presents a novel approach for developing an economical, environmentally friendly, and stable photoanode for PEC water splitting.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"101 ","pages":"Pages 105-111"},"PeriodicalIF":8.1,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143181896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Impurities in hydrogen released from perhydro benzyltoluene - Assessment and adsorptive removal 全氢苄基甲苯释放的氢气中的杂质--评估和吸附去除

IF 8.1 2区工程技术

International Journal of Hydrogen Energy Pub Date : 2025-02-03 DOI: 10.1016/j.ijhydene.2024.12.204

Adrian Zilm , Florian Ortner , Felix Gackstatter , Stefan Köberlein , Julian Kadar , Michael Geißelbrecht , Andreas Bösmann , Peter Wasserscheid

{"title":"Impurities in hydrogen released from perhydro benzyltoluene - Assessment and adsorptive removal","authors":"Adrian Zilm , Florian Ortner , Felix Gackstatter , Stefan Köberlein , Julian Kadar , Michael Geißelbrecht , Andreas Bösmann , Peter Wasserscheid","doi":"10.1016/j.ijhydene.2024.12.204","DOIUrl":"10.1016/j.ijhydene.2024.12.204","url":null,"abstract":"<div><div>Liquid Organic Hydrogen Carriers (LOHC) technologies offer viable options to overcome most issues linked to the storage of elemental hydrogen. They involve the chemical binding of hydrogen to carrier molecules through reversible catalytic hydrogenation/dehydrogenation cycles. Hydrogen, released from LOHC systems should thereby meet high purity requirements. In this contribution, the quality of hydrogen released from the LOHC compound perhydro benzyltoluene (H12-BT) is assessed and a suitable adsorptive purification process is described. Our study considers volatile and semi-volatile organic compounds (VOCs and SVOCs), methane, CO, CO<sub>2</sub>, and water impurities found in the product stream of a continuous dehydrogenation rig operating at power levels between 1.4 and 4.3 kW<sub>H2-LHV</sub>. We determine the influence of dehydrogenation process parameters (e.g., temperature, pressure, LOHC flow rate, LOHC quality) on the hydrogen quality and demonstrate that a combination of silica- and carbon-based adsorbents is highly suitable for removing VOCs and SVOCs from the hydrogen product stream. Using optimized process and purification conditions the released hydrogen fulfills the requirements defined by ISO 14687 for fuel cell applications.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"101 ","pages":"Pages 469-481"},"PeriodicalIF":8.1,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143181165","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Breaking down the barrier: The progress and promise of seawater splitting

IF 8.1 2区工程技术

International Journal of Hydrogen Energy Pub Date : 2025-02-03 DOI: 10.1016/j.ijhydene.2025.01.447

Shanu Mishra, Mahesh M. Shanbhag, Bruno G. Pollet, Shankara S. Kalanur

{"title":"Breaking down the barrier: The progress and promise of seawater splitting","authors":"Shanu Mishra, Mahesh M. Shanbhag, Bruno G. Pollet, Shankara S. Kalanur","doi":"10.1016/j.ijhydene.2025.01.447","DOIUrl":"10.1016/j.ijhydene.2025.01.447","url":null,"abstract":"<div><div>Freshwater is crucial for green hydrogen production for future renewable energy infrastructure. However, freshwater scarcity has sparked interest in seawater electrolysis, especially in regions with abundant renewable energy. Despite its promise, seawater electrolysis faces challenges like electrode corrosion, membrane contamination, and electrolyzer degradation, raising concerns about its feasibility, commercialization, and cost-effectiveness. This review offers an analysis of using seawater for electrolysis by discussing the key thermodynamic parameters, reaction mechanisms, essential material optimization, and recent advances reported for increased efficiency and long-term stability. The advancements in materials and membrane systems utilized in different electrolysis methodologies are discussed with their feasibility towards the effective utilization in seawater electrolysis. Furthermore, the discussion highlights the advancements in electrolyser designs and their operational efficiencies and suitability for large-scale seawater electrolysis. Importantly, this review outlines a roadmap for designing and commercializing materials to address challenges in seawater splitting, proposing solutions to enhance catalytic performance and energy efficiency for sustainable green hydrogen production.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"106 ","pages":"Pages 334-352"},"PeriodicalIF":8.1,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143153746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Emerging perovskite-based catalysts for sustainable and green ammonia production: A promising hydrogen energy carrier

IF 8.1 2区工程技术

International Journal of Hydrogen Energy Pub Date : 2025-02-03 DOI: 10.1016/j.ijhydene.2025.01.283

Ali Salehabadi, Jonathan Perry, Jafar Zanganeh, Behdad Moghtaderi

{"title":"Emerging perovskite-based catalysts for sustainable and green ammonia production: A promising hydrogen energy carrier","authors":"Ali Salehabadi, Jonathan Perry, Jafar Zanganeh, Behdad Moghtaderi","doi":"10.1016/j.ijhydene.2025.01.283","DOIUrl":"10.1016/j.ijhydene.2025.01.283","url":null,"abstract":"<div><div>Ammonia (NH₃) presents a comprehensive energy storage solution for future energy demands. Its synthesis plays a pivotal role in the chemical industry, acting as a fundamental precursor for fertilizers, explosives, and a wide range of industrial applications. In recent years, there has been a growing interest in exploring novel catalyst materials to enhance the efficiency, selectivity, and sustainability of NH<sub>3</sub> production technologies. Among these materials, perovskite-based catalysts have emerged as promising candidates due to their unique properties. This review article aims to provide a sharp and short understanding of the role of perovskite-based catalysts in emerging NH<sub>3</sub> production technologies and to stimulate further research and innovation in this rapidly evolving field. It provides an overview of recent advances in the synthesis and characterisation of perovskite-based catalysts for NH<sub>3</sub> production in terms of structural properties, and catalytic performance of perovskite catalysts in NH<sub>3</sub> synthesis. The review also discusses the underlying mechanisms involved in NH<sub>3</sub> production on perovskite surfaces, highlighting the role of surface chemistry, and electronic structure. Furthermore, the review examines the potential applications and prospects of perovskite-based catalysts in NH<sub>3</sub> production technologies. It explores opportunities for integrating perovskite catalysts into existing NH<sub>3</sub> synthesis processes, as well as the development of process configurations to maximise the efficiency and sustainability of NH<sub>3</sub> production.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"106 ","pages":"Pages 243-260"},"PeriodicalIF":8.1,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143154294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Design and simulation of a Pd-functionalized cantilever for hydrogen detection

IF 8.1 2区工程技术

International Journal of Hydrogen Energy Pub Date : 2025-02-03 DOI: 10.1016/j.ijhydene.2025.01.009

Reza Hadjiaghaie Vafaie, Mahnaz Mehdipoor, Sayyad Nojavan

引用次数: 0

Fabrication of centimeter-scale MoTe2 layers with high chemical stability for hydrogen evolution application

IF 8.1 2区工程技术

International Journal of Hydrogen Energy Pub Date : 2025-02-03 DOI: 10.1016/j.ijhydene.2024.12.477

Yadu Chandran , Nitika Arya , Bhumit Luhar , Viswanath Balakrishnan

{"title":"Fabrication of centimeter-scale MoTe2 layers with high chemical stability for hydrogen evolution application","authors":"Yadu Chandran , Nitika Arya , Bhumit Luhar , Viswanath Balakrishnan","doi":"10.1016/j.ijhydene.2024.12.477","DOIUrl":"10.1016/j.ijhydene.2024.12.477","url":null,"abstract":"<div><div>Two-dimensional transition metal dichalcogenides (2D-TMDs) are suitable candidates for the hydrogen evolution reaction (HER) in water splitting. Among the different phases of TMDs, semi-metallic and metallic phases have shown greater efficiency for HER. However, achieving large-scale production of stable, semi-metallic or metallic phases of TMDs is challenging. We report large-scale growth of semi-metallic 1T′-MoTe<sub>2</sub> on three different substrates: sapphire, SiO<sub>2</sub>/Si, and fused quartz with an approach to transfer on flexible substrates with increased stability. Due to rapid oxidation of MoTe<sub>2</sub> flakes upon exposure to air, we explored a new transfer strategy using gold deposition to easily transfer flakes from the growth substrate to a flexible substrate. The gold coating ensures protective coverage and acts as a conducting medium after transfer. High activity was observed in MoTe<sub>2</sub> flakes transferred from sapphire, with an onset potential of 280 mV and a Tafel slope of 125 mV/dec. Additionally, the effectiveness of the transfer process in protecting the sample was demonstrated by the absence of oxide formations in the gold-coated MoTe<sub>2</sub> sample for up to one year. These results indicate that the gold-mediated transfer mechanism is suitable for creating flexible HER electrodes based on unstable 2D materials.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"101 ","pages":"Pages 983-989"},"PeriodicalIF":8.1,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143180769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cobalt/cobalt phosphide/nitrogen-doped carbon derived from zeolitic imidazolate framework-11@zeolitic imidazolate framework-12 core-shell structure as efficient electrocatalyst for oxygen evolution reaction

IF 8.1 2区工程技术

International Journal of Hydrogen Energy Pub Date : 2025-02-03 DOI: 10.1016/j.ijhydene.2025.01.014

Chen-Han Lin , Yin-Chen Lin , Chia-Lin Yeh , Lu-Yin Lin , Kuo-Chuan Ho

{"title":"Cobalt/cobalt phosphide/nitrogen-doped carbon derived from zeolitic imidazolate framework-11@zeolitic imidazolate framework-12 core-shell structure as efficient electrocatalyst for oxygen evolution reaction","authors":"Chen-Han Lin , Yin-Chen Lin , Chia-Lin Yeh , Lu-Yin Lin , Kuo-Chuan Ho","doi":"10.1016/j.ijhydene.2025.01.014","DOIUrl":"10.1016/j.ijhydene.2025.01.014","url":null,"abstract":"<div><div>Electrochemical water splitting is considered as a promising and efficient way to produce hydrogen and oxygen, which are regarded as sustainable energy. Zeolitic imidazolate frameworks (ZIFs) have been widely utilized as sacrificial templates for synthesizing efficient electrochemical active materials with porous structure and tunable pore properties. In this study, cobalt/cobalt phosphide on N-doped carbon matrix (CPZ11@12–150) derived from the novel core-shell structure of ZIF-11@ZIF-12 is reported as a highly efficient electrocatalyst for oxygen evolution reaction (OER). With the enhanced electrical conductivity from N-doped carbon and excellent electrocatalytic activity from cobalt phosphide, the CPZ11@12–150 possesses a low overpotential (274 mV) at 10 mA cm<sup>−2</sup> and a small Tafel slope of 76.2 mV·dec<sup>−1</sup> in 1 M KOH. The CPZ11@12–150 also shows superior long-term stability for at least 100 h, owing to good attachment of CoP on N-doped carbon matrix and its mesoporous structure for effective releases of O<sub>2</sub> bubbles.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"101 ","pages":"Pages 1279-1287"},"PeriodicalIF":8.1,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143179720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0