Edgar Berrezueta , Timea Kovacs , Gricelda Herrera-Franco , Carlos Mora-Frank , Jhon Caicedo-Potosí , Paúl Carrion-Mero , Júlio Carneiro
{"title":"Laboratory studies on CO2-brine-rock interaction: an analysis of research trends and current knowledge","authors":"Edgar Berrezueta , Timea Kovacs , Gricelda Herrera-Franco , Carlos Mora-Frank , Jhon Caicedo-Potosí , Paúl Carrion-Mero , Júlio Carneiro","doi":"10.1016/j.ijggc.2023.103842","DOIUrl":"https://doi.org/10.1016/j.ijggc.2023.103842","url":null,"abstract":"<div><p>Greenhouse gas emission<span><span> into the atmosphere is considered one of the major causes of the ongoing climate change and the global warming of the last decades. One of the possible tools to reduce this emission is </span>carbon capture and storage (CCS). This work aims to describe the research trends and main findings related to laboratory-scale experiments within the field of CCS and how that research has developed over time with perspectives for large-scale deployment.</span></p><p>The study was based on a bibliometric approach using the WoS and Scopus databases. 12,276 contributions were identified in relation to the general field of CO<sub>2</sub> geological storage, 4,369 of which addressed laboratory-scale experimentation. Between 2001 and 2012, scientific production incremented considerably both on CO<sub>2</sub><span> geological storage and on related experimental laboratory work. According to keyword analysis, the currently leading research tendencies are about pore structure (0.48%), residual trapping (0.62%) and hydrogen (0.27%). Sedimentary rocks are the most studied rock type in laboratory studies (22.07%), while basaltic rocks are the least frequent (1.09%) in these experiments, which reflects the dominant use of sedimentary reservoirs in pilot and commercial projects. Laboratory scale experimentation and numerical modelling were found to be of utmost importance to understand processes that take place during CO</span><sub>2</sub> geological storage.</p></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"123 ","pages":"Article 103842"},"PeriodicalIF":3.9,"publicationDate":"2023-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2618269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Commentary: Legacy wells–we need more case studies","authors":"Charles Jenkins","doi":"10.1016/j.ijggc.2023.103837","DOIUrl":"https://doi.org/10.1016/j.ijggc.2023.103837","url":null,"abstract":"","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"123 ","pages":"Article 103837"},"PeriodicalIF":3.9,"publicationDate":"2023-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1556207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Modeling of pre-combustion carbon capture with CO2-selective polymer membranes","authors":"Lie Meng, Teruhiko Kai, Shin-ichi Nakao, Katsunori Yogo","doi":"10.1016/j.ijggc.2022.103830","DOIUrl":"https://doi.org/10.1016/j.ijggc.2022.103830","url":null,"abstract":"<div><p>CO<sub>2</sub>-selective polymer membranes were recently applied to pilot-scale and bench-scale pre-combustion capture and the obtained CO<sub>2</sub> capture ratios were reported to be less than 90%, which limits their application in industrial processes such as IGCC plants. This work is aimed to explore the possibility of achieving a CO<sub>2</sub> capture ratio >95% and CO<sub>2</sub> purity >95% in a gas-separation unit equipped with currently-available CO<sub>2</sub>-selective polymer membranes. A mathematical model for single-stage membrane gas separation was developed, and the effect of membrane characteristics (permeance and selectivity), as well as the operating parameters such as feed and permeate pressure, and feed flow rate on the performance of CO<sub>2</sub> capture was investigated. The simulation results reveal the optimal conditions that are necessary for a high-performance CO<sub>2</sub> capture process using the real industrial syngas and highlight the potential of facilitated transport membranes for CO<sub>2</sub> removal in both the oxygen-blown and air-blown IGCC processes.</p></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"123 ","pages":"Article 103830"},"PeriodicalIF":3.9,"publicationDate":"2023-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2695818","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tongtong Yu , Raoof Gholami , Arshad Raza , Kim Andre Nesse Vorland , Mohamed Mahmoud
{"title":"CO2 storage in chalks: What are we afraid of?","authors":"Tongtong Yu , Raoof Gholami , Arshad Raza , Kim Andre Nesse Vorland , Mohamed Mahmoud","doi":"10.1016/j.ijggc.2023.103832","DOIUrl":"https://doi.org/10.1016/j.ijggc.2023.103832","url":null,"abstract":"<div><p>Carbon Capture and Storage (CCS) has been recognized as an effective strategy to limit the temperature rise to 1.5 °C by 2050 under the Paris Agreement. As a result, more than 50 CCS pilot or large-scale projects have been commissioned in recent decades, targeting mainly sandstone reservoirs for their favourable petrophysical properties. Although many discussions and practical procedures have been developed, large-scale CO<sub>2</sub> storage in carbonates has not been implemented due to practical risks associated with rapid geochemical interactions. This study attempts to evaluate the feasibility of CO<sub>2</sub> storage in carbonate chalk formations by focusing on changes in storage capacity (porosity) and injectivity (permeability) over time. A series of laboratory tests were carried out on Stevns Klint chalk from Denmark after exposure to CO<sub>2</sub> for 37 days at a fluid pressure of 15 MPa and a temperature of 50 °C. The results obtained indicated a large removal of Ca<sup>+2</sup> ions from CO<sub>2</sub> saturated water solution and strong precipitation of secondary calcite in the pore structure, which reduced the porosity and permeability of the samples. It seems that CO<sub>2</sub> injection into chalk should be done very carefully, as the progressive dissolution of calcite and saturation of the formation water will initiate large secondary calcite precipitation in the long term, leading to a reduction in injectivity and storage capacity over time.</p></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"123 ","pages":"Article 103832"},"PeriodicalIF":3.9,"publicationDate":"2023-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1618201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Exploration of optimal operating conditions for a natural gas combined-cycle power plant integrated with post-combustion CO2 capture using 2-amino-2-methyl-1-propanol/piperazine considering the propagation effect","authors":"Hirotaka Isogai, Takao Nakagaki","doi":"10.1016/j.ijggc.2022.103816","DOIUrl":"https://doi.org/10.1016/j.ijggc.2022.103816","url":null,"abstract":"<div><p>Integrating post-combustion CO<sub>2</sub> capture (PCC) into thermal power plants can reduce CO<sub>2</sub> emissions but results in a significant decrease in net thermal efficiency. Optimizing PCC operating conditions, such as the ratio of the liquid flow rate to the gas flow rate (<em>L/G</em>) and stripper bottom temperature, reduces the net efficiency penalty. However, previous studies partially neglected the propagation effects of altered operating conditions on process performance, such as the effect of altered <em>L/G</em> and resultant change in fluid velocity on the heat transfer and pressure drop in the rich and lean solution heat exchanger. This study simulated amine-based PCC integrated into a natural gas combined cycle and explored optimal operating conditions comprehensively considering the propagation effects. The net efficiency penalty was minimized to 6.02%-pts. at a stripper bottom temperature of 130 °C and <em>L/G</em> of 0.82 for PCC operation with CO<sub>2</sub> compression. Meanwhile, neglecting propagation effects of altered <em>L/G</em> led to underestimation of the efficiency penalty and erroneous determination of optimal operating conditions. The system evaluation methods suggested in this paper contribute to correctly optimizing PCC operating conditions and can be broadly applied to amine-based PCC studies employing novel amine solutions or process modifications.</p></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"122 ","pages":"Article 103816"},"PeriodicalIF":3.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1894057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A.L. Herring , C. Sun , R.T. Armstrong , M. Saadatfar
{"title":"Insights into wettability alteration during cyclic scCO2-brine injections in a layered Bentheimer sandstone","authors":"A.L. Herring , C. Sun , R.T. Armstrong , M. Saadatfar","doi":"10.1016/j.ijggc.2022.103803","DOIUrl":"https://doi.org/10.1016/j.ijggc.2022.103803","url":null,"abstract":"<div><p>Residual trapping of supercritical carbon dioxide (“scCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>”) is a key mechanism contributing to the safety and security of geologic sequestration operations. Recent experimental studies have suggested that cycles of scCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> and brine injections cause surface chemistry reactions that increase residual trapping. We present results of a new experiment, analyzed with X-ray microcomputed tomography, aimed at pinning down specifics of the alteration mechanism. Four cycles of scCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> and brine injections were conducted in a Bentheimer sandstone core with a prominent low permeability region at the base (inlet side) of the core. Multiple successive scCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> injections were performed within cycles, and scCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> injection flow rate was varied. Saturation profiles near the low permeability layer remain approximately constant, while downstream scCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> saturation profiles change shape and generally increase for successive injections. Residual trapping increases over the four cycles, but only in the upper region of the core. Microstructural analysis of the scCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> phase indicates increasing presence of relatively high contact angle (i.e. less water-wetting) surfaces as the experiment progresses. These results suggest that surface chemistry alteration occurs during drainage injections, and may also occur during imbibition. However, the effect is only evident in the relatively high permeability region of the core; in the low permeability region, capillary heterogeneity dominates flow patterns and wettability alteration effects are not evident. These results support previous work demonstrating sandstone wettability alteration due to scCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>/brine cycling, and provide new clarification as to the conditions under which this wettability alteration will cause shifts in scCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> flow and trapping.</p></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"122 ","pages":"Article 103803"},"PeriodicalIF":3.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1627018","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Bi-objective optimization of post-combustion CO2 capture using methyldiethanolamine","authors":"Nobuo Hara, Satoshi Taniguchi, Takehiro Yamaki, Thuy T.H. Nguyen, Sho Kataoka","doi":"10.1016/j.ijggc.2022.103815","DOIUrl":"https://doi.org/10.1016/j.ijggc.2022.103815","url":null,"abstract":"<div><p>Process simulation and analyzes based on multiple evaluation indexes are crucial for accelerating the practical use of the post-combustion CO<sub>2</sub> capture process. This study presents a bi-objective optimization of the post-combustion CO<sub>2</sub> absorption process using methyldiethanolamine (MDEA) via machine-learning and genetic algorithm to evaluate CO<sub>2</sub> emissions from the absorption process using life cycle assessment and cost from operating and capital expenditures. An initial dataset was generated by changing eight design variables, and machine-learning models were built using random forest classifier and Gaussian process regression. Pareto solutions were predicted using a genetic algorithm (NSGA-II) with the constraints of purity, recovery, and temperature, and were verified via process simulation. Verified data were added to the dataset, and model building, prediction, and verification were repeated. Eventually, 56 Pareto solutions were obtained after 11 iterations. In the final Pareto solutions, CO<sub>2</sub> emissions increased from 0.56 to 0.6 t-CO<sub>2</sub>/t-CO<sub>2</sub> with a decrease in cost from 74 to 66 USD/t-CO<sub>2</sub>. The trends and composition of each objective variable were examined, and the optimal structure of the equipment and operation conditions was clarified. The approach of bi-objective optimization in this study is promising for evaluating the CO<sub>2</sub> capture process and individual processes of carbon capture, utilization, and storage.</p></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"122 ","pages":"Article 103815"},"PeriodicalIF":3.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"3201854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Carbon negative geothermal: Theoretical efficiency and sequestration potential of geothermal-BECCS energy cycles","authors":"K.A. Titus, D.E. Dempsey, R.A.M. Peer","doi":"10.1016/j.ijggc.2022.103813","DOIUrl":"https://doi.org/10.1016/j.ijggc.2022.103813","url":null,"abstract":"<div><p>Geothermal systems are an attractive option for baseload electricity generation with low emissions intensity (average 122 gCO<sub>2</sub>/kWh). However, about 70% of geothermal systems are low or medium enthalpy (<160°C), which often renders them uneconomic to develop for electricity production. A solution to increase both power production and utilization efficiency of these systems is hybridization with a biomass fuel source. In this work, we introduce and verify the concept of biomass hybridization combined with in-line dissolution and reinjection of biomass flue CO<sub>2</sub>. This subclass of bioenergy and carbon capture and storage (BECCS), termed geothermal-BECCS, has improved power production and negative CO<sub>2</sub> emissions. This dual approach of using geothermal systems for power production and as carbon sinks can be a potential decarbonisation tool in areas with suitable geothermal and bioenergy resources.</p><p>Here, we quantify the thermodynamic and sequestration performance of four geothermal-BECCS configurations. Up to 100% of flue gas is dissolved and reinjected with the spent geofluid. Scaled to a 1 kg/s geofluid production rate, flash and binary benchmark plants generated 32 and 43 kWe at efficiencies of 6 and 8%, respectively. In comparison, four geothermal-BECCS designs yielded 64 kWe at 9% efficiency (flash plant), 76 kWe at 9% efficiency (ORC binary plant), 62 kWe at 7% efficiency (compound flash-binary plant), and 589 kWe at 20% efficiency (bioenergy based geothermal-preheat plant). Annual biogenic CO<sub>2</sub> sequestration rates ranged from 217 to 675 tonnes per kg/s with emissions intensities from -131 to -922 gCO<sub>2</sub>/kWh. By simultaneously boosting low-emissions energy and sequestering biogenic CO<sub>2</sub>, geothermal-BECCS promises to be an essential technology for meeting climate targets.</p></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"122 ","pages":"Article 103813"},"PeriodicalIF":3.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1894059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Assessing possibilities for coal continuance in India under climate constraints","authors":"Vineet Tiwari , Amit Garg , Manmohan Kapshe , Aashish Deshpande , Saritha Vishwanathan","doi":"10.1016/j.ijggc.2022.103811","DOIUrl":"https://doi.org/10.1016/j.ijggc.2022.103811","url":null,"abstract":"<div><p>Rapid shift from traditional energy intensive pathways is required to pace-up economic growth before exhausting remaining carbon budget under 2 °C global stabilization target. Within this larger context, in this paper we have used AIM/End-use, a bottom-up, techno-economic model to analyze India's energy security and greenhouse gas (GHG) emissions from the year 2000 to 2050 with a focus on possibilities of coal continuance in India. Our analysis shows that by adopting advanced coal technologies and carbon dioxide capture and sequestration (CCS) options, up to 45% CO<sub>2</sub> emission reduction can be achieved over business-as-usual scenario (BAU) by 2050. This is possible even when coal use would increase to nearly 2200 Mt in 2050 as against 870 Mt in 2017-18. Without CCS, coal use could peak at 1200 Mt with 22% CO<sub>2</sub> reduction over BAU in 2050 but in that case nuclear and renewable energy would become pivotal in meeting energy demand. The paper concludes that a win-win integration of energy security and deep GHG emission mitigation is possible through a large-scale integration of advanced coal technologies and CCS in Indian energy systems. We have also provided a brief PESTLE analysis for finding the enabling environment necessary for achieving the results discussed in various scenarios.</p></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"122 ","pages":"Article 103811"},"PeriodicalIF":3.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2618270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Fetch-trap Pairs: Exploring definition of carbon storage prospects to increase capacity and flexibility in areas with competing uses","authors":"Alexander P. Bump, Susan D. Hovorka","doi":"10.1016/j.ijggc.2022.103817","DOIUrl":"https://doi.org/10.1016/j.ijggc.2022.103817","url":null,"abstract":"<div><p>As CCS grows beyond isolated first-mover projects, the question of how to identify potential storage sites (prospects) is key to siting projects amidst the constraints of neighboring storage projects, hydrocarbon fields and other considerations. To date, prospects have been defined either by the extent of a buoyant trap or by the predicted maximum extent of the CO<sub>2</sub> or pressure plume. Both approaches have worked, but they may struggle in places like the Gulf of Mexico where complex geologic structure can invalidate simple assumptions of radial plume spread and buoyant traps are commonly unattractive due to numerous legacy well penetrations. We propose identifying prospective storage sites by fetch area (drainage cell) rather than by buoyant closure alone. Doing so offers 1) greater freedom in siting injectors to avoid surface and subsurface constraints, including legacy wells that tend to cluster on structural high; and 2) a coherent flow regime in which buoyancy drives all injected CO<sub>2</sub> toward a common high. This strategy gives space to dissipate injection pressure and minimize the number of legacy wells needing review. It may also offer 1) better injectivity by bringing synclines and associated channel axes into play; and 2) potentially improved capacity by tapping a larger rock volume and taking advantage of migration losses.</p></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"122 ","pages":"Article 103817"},"PeriodicalIF":3.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1627019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}