Intermetallics最新文献

{"title":"Effect of gradient nanostructures on mechanical properties of Ti/AlCoCrFeNi composites","authors":"Qiping Zhou,&nbsp;Junming Luo,&nbsp;Shiyu Cui,&nbsp;Zhesong Wang","doi":"10.1016/j.intermet.2025.108855","DOIUrl":"10.1016/j.intermet.2025.108855","url":null,"abstract":"<div><div>Despite the challenges in engineering applications, the strength, plasticity, and wear resistance of metallic materials still exist, especially at room temperature, where these properties are critical to the performance of the materials. However, there is a certain gap in current research in revealing the mechanism of the effect of high entropy alloys (HEA) and fine grain structure (GNS) on room temperature properties. The aim of this study is to investigate the synergistic effect of HEA particles and GNS and their enhancement on the properties of titanium matrix composites under room temperature conditions. The experimental results showed that with the formation of GNS and the strengthening effect of HEA particles significantly increased the strength and wear resistance of the material. This study provides new insights into the interaction between HEA and GNS at room temperature and opens up new directions for the future development of highly wear-resistant metallic materials, with significant potential value especially in aerospace and other applications requiring high-performance components.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"184 ","pages":"Article 108855"},"PeriodicalIF":4.3,"publicationDate":"2025-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144123616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Cryogenic static and dynamic deformation behavior of Zr-based bulk metallic glasses","authors":"Zhenxiang Zhao ,&nbsp;Chunyan Li ,&nbsp;Tianyu Chen ,&nbsp;Jianhui Liu ,&nbsp;Xiaoqiang Fu ,&nbsp;Shengzhong Kou ,&nbsp;Xiaocheng Li ,&nbsp;Yudian Ouyang ,&nbsp;Jinfeng Kang","doi":"10.1016/j.intermet.2025.108851","DOIUrl":"10.1016/j.intermet.2025.108851","url":null,"abstract":"<div><div>Stable extension of metallic glass shear bands is crucial for achieving excellent macroscopic plasticity, yet quantitatively establishing the relationship between metallic glass shear band behavior and macroscopic plasticity remains a significant challenge. This study, based on a series of cryogenic quasi-static and dynamic compressive tests, reveals that optimal cryogenic compression plastic strain of up to 21.1 % is attained at 143 K. Combined with molecular dynamics simulations, the reasons can be attributed to the combination of the local temperature rise resulting from the adiabatic shear and the enhancement of interatomic forces under cryogenic conditions. Notably, the attenuation of the serrated flow behavior under cryogenic conditions. Additionally, during dynamic loading at cryogenic temperatures, negative strain rate sensitivity is exhibited as the temperature decreases. These findings could contribute to enhancing the understanding of the temperature-dependent characteristics of plasticity and aid in the design of plasticity/strength for metallic glass at cryogenic temperatures.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"184 ","pages":"Article 108851"},"PeriodicalIF":4.3,"publicationDate":"2025-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144131281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhance corrosion resistance via passivation treatment for CrMnFeCoNi high-entropy alloy prepared by hot isostatic pressing","authors":"Jiahao Liu ,&nbsp;Dianchun Ju ,&nbsp;Jing Zhang ,&nbsp;Yuji Cheng ,&nbsp;Zhanfang Wu ,&nbsp;Lida Che ,&nbsp;Xiangyang Li ,&nbsp;Zhoujin Lv","doi":"10.1016/j.intermet.2025.108846","DOIUrl":"10.1016/j.intermet.2025.108846","url":null,"abstract":"<div><div>CrMnFeCoNi high-entropy alloy (HEA) with equiatomic ratios was prepared through hot isostatic pressing, followed by a passivation treatment to enhance its corrosion resistance. The corrosion behavior and underlying mechanisms of the passivated alloy in 0.5M H₂SO₄ were systematically examined. The results demonstrated that passivation effectively removed harmful sulfide inclusions from the alloy surface and facilitated the formation of a protective passive film. Electrochemical tests revealed a decrease in corrosion current density (I_corr = 1.63 × 10⁻⁵A·cm⁻²) and an increase in corrosion potential (E_corr = -285 mV) following passivation. Grain boundary corrosion was identified as the dominant corrosion type. X-ray photoelectron spectroscopy (XPS) analysis showed that the passivation treatment enhanced the chromium content and reduced the manganese content in the passive film. Additionally, the oxide/hydroxide ratio in the film was increased, improving its protective properties and thereby enhancing the alloy's corrosion resistance.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"184 ","pages":"Article 108846"},"PeriodicalIF":4.3,"publicationDate":"2025-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144123780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synergistic effects of Mo and Cu on glass forming ability in mechanically alloyed FeCrNiSiWNbB complex metallic compound","authors":"E. Bahrami ,&nbsp;M. Khodaei","doi":"10.1016/j.intermet.2025.108856","DOIUrl":"10.1016/j.intermet.2025.108856","url":null,"abstract":"<div><div>Amorphous materials, due to their unique structure, have excellent thermal and magnetic properties. These materials are manufactured using different methods such as melt spinning and mechanical alloying. Among these methods, mechanical alloying is exceptionally suitable for large-scale production of amorphous materials. The purpose of this research is to assess the effect of Mo and Cu additions on the glass forming ability (GFA), magnetic properties and thermal stability of Fe-16Cr-3Ni-1.5Si-3W-1Nb-1.5B-xMo-yCu (x = 2.5, 5 and y = 0.5, 1, 1.5 wt%) amorphous mechanically alloyed ferroalloy powders for industrial application. The morphology and composition of the powders were measured by scanning electron microscopy armed with energy dispersive spectroscopy, respectively. Also, the phase changes were investigated using an x-ray diffraction technique. The GFA was exceedingly increased by adding Mo and Cu. Not only was the saturation magnetization (Ms) of the samples reduced, but the coercive force (Hc) also decreased with increasing Mo and Cu content. It was found that the optimal mechanically alloyed sample, containing 5 wt% Mo and 1 wt% Cu, exhibited a higher glass transition temperature (608 °C) compared to the Fe-based ferroalloy (587 °C). Ultimately, the saturation magnetization of the optimal sample decreased by 57.5 %, from 96 emu/g to 40 emu/g.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"184 ","pages":"Article 108856"},"PeriodicalIF":4.3,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144116000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unveiling the influence of grain refinement and crystallographic orientation on electrochemical behavior of cost-effective Fe40Ni25Cr25Mo5Al5 high-entropy alloy","authors":"Majid Naseri ,&nbsp;Omid Imantalab ,&nbsp;Svetlana Pratskova ,&nbsp;Davood Gholami ,&nbsp;Dmitry Mikhailov ,&nbsp;Milena Efimova ,&nbsp;Nataliya Shaburova ,&nbsp;Yong-Cheng Lin ,&nbsp;Abdel-Hamid I. Mourad ,&nbsp;Evgeny Trofimov","doi":"10.1016/j.intermet.2025.108854","DOIUrl":"10.1016/j.intermet.2025.108854","url":null,"abstract":"<div><div>This research has undoubtedly offered valuable insight into the correlation of grain refinement and crystallographic texture with the electrochemical properties of the cost-effective Fe₄₀Ni₂₅Cr₂₅Mo₅Al₅ high-entropy alloy in a 0.5 M H₂SO₄ solution, successfully processed through the cyclic closed-die forging (CCDF) technique for up to six passes. The findings revealed that the high strains imposed during CCDF processing, along with the uniform distribution of extremely fine grains, significantly decreased the corrosion current density of the alloy from 1.05 to 0.75 μA/cm². Moreover, the presence of high-intensity {011} orientations, such as the Brass {011}&lt;211&gt; and P {110}&lt;221&gt; components in the CCDF-processed alloy, provided ideal conditions for developing oxide passive films with superior protection properties compared to the as-homogenized alloy. Consequently, these findings open new avenues for the exploration of the crystallographic-orientation-dependent electrochemical properties in the corrosion performance of high-entropy alloys.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"184 ","pages":"Article 108854"},"PeriodicalIF":4.3,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144123618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"ZnO-decorated nanoporous Ag with Pt-like Tafel slopes as HER catalysts in alkaline electrolytes manipulated by cyclic square-wave potential sweeping dealloying","authors":"Zhangbin Wu ,&nbsp;Ketao Wang ,&nbsp;Hengtao Ge ,&nbsp;Zhenhua Dan","doi":"10.1016/j.intermet.2025.108847","DOIUrl":"10.1016/j.intermet.2025.108847","url":null,"abstract":"<div><div>Three cyclic square-wave potential sweeping dealloying (CSW) modes have been developed to manipulate the dealloying depth and nanoporosity of dual-phase Ag_35.5Zn_64.5 precursors with the ultimate aim of enhancing the performance of hydrogen evolution reactions. The evolution of the bimodal nanoporous structures is governed by two factors: the initial microstructure of the dual-phase Ag_35.5Zn_64.5 precursors and the cyclic frequency of the CSW dealloying. It is found that the pore sizes can be refined below 20 nm with an increase in the cyclic frequency of CSW as high as 21600 through the restricted diffusion in the single cycle with short cyclic time. Among the nanoporous Ag obtained through the modes of potentiostatic dealloying and CSW with varying cyclic frequencies (<em>f</em>: 1, 216 and 21600), the composites nanoarchitecture at CSW with a cyclic frequency of 21600 exhibits the superior HER catalytic performance in comparison to nanoporous Ag in the potentiostatic dealloying and bulk Ag plate. The nanoporous Ag nanoarchitectures decorated with ZnO nanograins with an average particle size of approximately 6.2 nm, possess an overpotential of 290 mV at 10 mA cm⁻² and a Pt-like low Tafel slope of 39.4 mV dec⁻¹. These properties are attributed to the rapid sweeping of square-wave potential in CSW with a frequency of 21600. The boosted catalytic performance of hydrogen evolution reactions, governed by the Volmer-Heyrovsky mechanism, is attributed to the enrichment of Ag (111) facets and the enlargement of the surface area of ultrafine nanoporosity of ZnO-decorated Ag porous nanoarchitectures.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"184 ","pages":"Article 108847"},"PeriodicalIF":4.3,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144123617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Influence of short-range order on precipitate orientation relationships in aluminum containing FCC high entropy alloys","authors":"Elaf A. Anber ,&nbsp;Daniel L. Foley ,&nbsp;James L. Hart ,&nbsp;Howie Joress ,&nbsp;Brian DeCost ,&nbsp;Roger Doherty ,&nbsp;Peter K. Liaw ,&nbsp;Diana Farkas ,&nbsp;Anatoly I. Frenkel ,&nbsp;Mitra L. Taheri","doi":"10.1016/j.intermet.2025.108832","DOIUrl":"10.1016/j.intermet.2025.108832","url":null,"abstract":"<div><div>High entropy alloy (HEA) phase evolution is governed by the competing roles of high configurational entropy and enthalpy of mixing, including severe lattice distortion, and local, or short range, atomic order. While HEAs have seen unprecedented interest over the last decade, many promising applications have not been realized due to limitations in secondary phase, or precipitate, control. Through high resolution microscopy and spectroscopy coupled with molecular dynamics simulations, we examine the role of chemical complexity on the evolution of precipitates, and specifically on their orientation relationships with their host matrices. Microstructural, chemical, and local order measurements are coupled with atomistic simulations of the structure and energy of the Face Center Cubic (FCC)/Body Center Cubic (BCC)B2 interface, in various possible orientations, using model interatomic potentials. Our local order measurements at the nanometer scale revealed that Cr-(Co/Ni/Fe) bonding becomes less favorable after aging. This finding aligns with our microstructural observations, which show lower Cr and Al content in the FCC phase post-aging. We experimentally observed a non-typical orientation relationship between B2-BCC and FCC matrices was stabilized, which we attribute to this chemical complexity. Our atomistic simulations reveal the significant effect of chemical complexity and local ordering on interface energies. Critically, we connect the local chemical order with the formation of high energy interfaces that lead to unusual orientation relationships. The relationship between local order and the orientation relationships landscape of precipitates within a microstructure presents an opportunity for tuning alloy properties at the level of atomic bonding.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"184 ","pages":"Article 108832"},"PeriodicalIF":4.3,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144116001","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High strain rate sensitivity and nanoscratch properties of the nano-sized crystalline/amorphous Ti-Zr-Hf-Co-Ni-Cu high-entropy metallic glass thin film fabricated by magnetron sputtering","authors":"Guanghua Zhou ,&nbsp;Huazhe Tang ,&nbsp;Ruochen Zhang ,&nbsp;Xuexi Zhang ,&nbsp;Mingfang Qian","doi":"10.1016/j.intermet.2025.108857","DOIUrl":"10.1016/j.intermet.2025.108857","url":null,"abstract":"<div><div>Catering for the development of microelectromechanical systems and micro actuators, the high-entropy conception is introduced into the metallic glass thin films to enhance the mechanical and thermal properties. Ti-Zr-Hf-Co-Ni-Cu high-entropy metallic glass thin films which exhibit promising application prospects are deposited at substrate bias voltages of 0 V, −50 V, and −100 V on the Si substrates coated with ∼150 μm SiO₂ by high-vacuum direct-current magnetron sputtering system in this work. The effects of substrate bias voltage on topographies, crystallinity, fracture behavior, mechanical properties, strain rate sensitivity, nanoscratch properties of thin films are investigated. With the substrate bias voltage increasing from 0 V to −100 V, the roughness of thin film decreases from 2.96 ± 0.03 nm to 0.63 ± 0.03 nm due to the densification and renucleation process. It is also the lowest roughness that has ever been reported in the Ti-Zr-Hf-Co-Ni-Cu high-entropy metallic glass thin films. All elements are distributed uniformly at the micrometer scale on the surfaces of all thin films, and the contents of each element are equal. All the thin films exhibit nanometer-sized crystalline/amorphous bi-phase nanostructures. With the increase of substrate bias voltage, the cross-sectional morphology changes from brittle cleavage character to plastic dimple structures, possibly related to the increased crystallinity. With the increasing substrate bias voltage, the elastic modulus and hardness both increase from 93.8 ± 0.2 GPa to 100.2 ± 0.2 GPa and from 6.4 ± 0.02 GPa to 7.0 ± 0.03 GPa, respectively. A significant strain rate sensitivity of ∼0.1 is discovered in all the thin films. Furthermore, the nanoscratch test shows that the largest critical stress to date for interface separation are discovered in these thin films, which show an enhancement from 5.7 N to 6.7 N with an increase of substrate bias from 0 V to −100 V, suggesting an improvement of bonding strength between the thin film and substrate.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"184 ","pages":"Article 108857"},"PeriodicalIF":4.3,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144123620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The effects of temperature and pressure on the hydrogen decrepitation and hydrogen desorption of Sm2TM17 sintered magnets","authors":"J. Griffiths ,&nbsp;O.P. Brooks ,&nbsp;G. Subramanian ,&nbsp;V. Kozak ,&nbsp;D. Brown ,&nbsp;A. Campbell ,&nbsp;A. Lambourne ,&nbsp;R.S. Sheridan","doi":"10.1016/j.intermet.2025.108831","DOIUrl":"10.1016/j.intermet.2025.108831","url":null,"abstract":"<div><div>This study investigated the impact of hydrogen pressure and processing temperature on the hydrogen decrepitation of Sm₂TM₁₇ sintered magnets (where TM = Co, Fe, Cu and Zr). Sm and Co are ‘critical elements’, hence there is interest in recycling these materials from end-of-life applications such as surface mounted permanent magnet motors and actuators. Hydrogen Decrepitation (HD) is a potential recycling technology, but the effect of different processing parameters has yet to be fully explored. Three commercial grades of Sm₂TM₁₇ sintered magnets with different compositions and microstructures were subjected to HD treatments over 72 h, at hydrogen pressures of 2 and 18 bar and temperatures between 25 and 300 °C. The resulting powders were characterised to assess their particle size and morphology, hydrogen content and degassing behaviour.</div><div>Thermal activation temperatures of 100–150 °C allowed for significant decrepitation to be observed across all Sm₂TM₁₇ compositions at both 2 and 18 bar pressures. Degassing analysis showed that all decrepitated powders examined released hydrogen in a single step, with peak hydrogen desorption occurring between 200 and 260 °C. At HD temperatures of 300 °C the reaction ceased as degassing took precedence over hydrogen absorption. Particle size analysis indicated that adjusting HD processing parameters altered powder size greatly, e.g. increasing temperature increased particle size whereas increasing pressure decreased particle size. The sample with the smallest cell size, greatest Cu and Zr and lowest Fe content absorbed the least amount of hydrogen. It also generated the coarsest powder and degassed at the lowest temperatures. This has been linked to this sample having less of the main interstitial hydride forming 2:17 rhombohedral phase found in the magnet nanostructure.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"184 ","pages":"Article 108831"},"PeriodicalIF":4.3,"publicationDate":"2025-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144107508","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The influence of chromium on the changes in phase constitution and electrical properties of amorphous Co73-xFe4CrxSi12B11 microwires during crystallization","authors":"Gennady N. Elmanov ,&nbsp;Ilya V. Kozlov ,&nbsp;Aida E. Sarakueva ,&nbsp;Vladimir I. Odintsov ,&nbsp;Margarita N. Churyukanova ,&nbsp;Sergey A. Gudoshnikov","doi":"10.1016/j.intermet.2025.108848","DOIUrl":"10.1016/j.intermet.2025.108848","url":null,"abstract":"<div><div>The influence of chromium on the crystallization processes (temperature and thermal effect of two crystallization stages, as well as the nature of phase composition change during crystallization) of amorphous Co_{73-<em>x</em>}Fe₄Cr_<em>x</em>Si₁₂B₁₁ (<em>x</em> = 0, 2, 4) alloys obtained in the form of microwires in a glass shell was studied. It was shown that if at the 1st crystallization stage of alloys with chromium there is a simultaneous precipitation of two crystalline phases (HCP phase of a solid solution based on cobalt and BCC-phase of Co₂Si) leading to the formation of a lamellar structure, then in the absence of chromium, only the BCC-phase is initially released. The influence of chromium on the increase in the activation energy of the 1st crystallization stage was determined. It was shown that at the 2nd crystallization stage the presence of chromium stabilizes the HCP-Co and Co₂₃B₆ phases. It is also shown that an increase in the Cr concentration from 0 to 4 at.% increases the specific electrical resistance ρ_25 °C of the alloys in the crystalline state from 0.68 ∙ 10⁻⁶ to 1.18 ∙ 10⁻⁶ Ohm ∙ m and simultaneously reduces the thermal coefficient of electrical resistance by 4 times. Based on the resistive measurement data, the Curie temperatures of the magnetic phases formed during crystallization were estimated. Comparison of the data obtained using the DSC and XRPD methods with the results of changes in electrical resistance during crystallization made it possible to interpret the results of resistive measurements and to demonstrate the efficiency of this simple method for studying the crystallization process of amorphous alloys.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"184 ","pages":"Article 108848"},"PeriodicalIF":4.3,"publicationDate":"2025-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144098537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}