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A novel approach for expeditiously assessing residual carbon recovery from coal gasification slag 一种快速评估煤气化渣残碳回收的新方法
IF 6.7 1区 工程技术
Fuel Pub Date : 2025-06-08 DOI: 10.1016/j.fuel.2025.135923
Baolin Zhang, Qian Zhang, Le Li, Yufei Liu, Chenming Gao, Bin Xue, Peng Zhi, Wei Huang
{"title":"A novel approach for expeditiously assessing residual carbon recovery from coal gasification slag","authors":"Baolin Zhang,&nbsp;Qian Zhang,&nbsp;Le Li,&nbsp;Yufei Liu,&nbsp;Chenming Gao,&nbsp;Bin Xue,&nbsp;Peng Zhi,&nbsp;Wei Huang","doi":"10.1016/j.fuel.2025.135923","DOIUrl":"10.1016/j.fuel.2025.135923","url":null,"abstract":"<div><div>Residual carbon recovery from coal gasification slag (CGS) is a promising approach for the cascade utilization of CGS, while the inherent complexity and multistep processes in different separation techniques to achieve high-efficiency extraction hampered the rapid assessment of the residual carbon recovery potential. In this study, a self-designed simple water flow classifier was employed to extract the residual carbon from CGS by adjusting the superficial water flow velocities (SWFV). The results revealed the non-uniform carbon and ash distribution in CGS was the basis of residual carbon recovery, while the fine particles with lower carbon content significantly affected the separation efficiency of residual carbon in the water flow classifier. Based on this, a rapid and efficient method for assessing the residual carbon recovery was proposed by combining screening with water flow classification. Particles coarser than 0.075 mm after screening were subjected to water flow classification for carbon extraction. When the SWFV was 36 × 10<sup>−3</sup> m/s, the carbon content of the floating slag increased to 78.78 %, the recovery rate of combustible reached 76.69 %, and the carbon content of tailings reduced to 8.57 % simultaneously. This method holds the capacity to evaluate the feasibility of the carbon extraction process from CGS, presenting significant potential for the process optimization and large-scale implementation.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"401 ","pages":"Article 135923"},"PeriodicalIF":6.7,"publicationDate":"2025-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144242144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multiscale Elucidation of kerogen heterogeneity in Lucaogou Formation based on experiment and simulation: Structural Determinants of reactivity and stability for shale oil conversion 基于实验和模拟的芦草沟组干酪根非均质性多尺度解析:页岩油转化反应性和稳定性的结构决定因素
IF 6.7 1区 工程技术
Fuel Pub Date : 2025-06-07 DOI: 10.1016/j.fuel.2025.135898
Youjie Li , Huifei Tao , Zhuanhong Lu , Qian Wang , Ming Yan , Zaibo Xie , Zhongping Li
{"title":"Multiscale Elucidation of kerogen heterogeneity in Lucaogou Formation based on experiment and simulation: Structural Determinants of reactivity and stability for shale oil conversion","authors":"Youjie Li ,&nbsp;Huifei Tao ,&nbsp;Zhuanhong Lu ,&nbsp;Qian Wang ,&nbsp;Ming Yan ,&nbsp;Zaibo Xie ,&nbsp;Zhongping Li","doi":"10.1016/j.fuel.2025.135898","DOIUrl":"10.1016/j.fuel.2025.135898","url":null,"abstract":"<div><div>Despite breakthroughs in continental shale oil exploitation within the Lucaogou Formation of the Junggar Basin in Xinjiang, China, divergent structural and molecular characteristics between the kerogens of the upper and lower sub-members remain poorly understood. This study bridged this knowledge gap by integrating multiscale experimental characterizations—solid-state <sup>13</sup>C NMR, XPS, Py-GC/MS, FT-IR, and XRD—with computational simulations and revealed the influence of kerogen structure on shale oil conversion. Variations in aliphatic carbon distributions and degree of aromatic polymerization within Lucaogou kerogens directly account for differences in produced shale oil properties. Specifically, upper-section kerogen contains predominantly linear methylene chains, while lower-section kerogen features highly branched aliphatic chains and abundant aliphatic rings. Elevated aromatic substitution in upper kerogen promotes hydrocarbon generation through dealkylation, while higher condensation in lower kerogen suppresses thermal cracking. Nitrogen and sulfur species in kerogen primarily exist as aromatic heterocycles, which may inhibit free radical reactions at lower temperatures. Quantum chemical analysis was performed on molecular models constructed from experimental data. This analysis shows that oxygen atoms bonded to aromatic rings create potential electrophilic substitution sites on specific aromatic carbon atoms. Furthermore, alicyclic rings demonstrate higher susceptibility to ring-opening reactions. This is attributed to their lower bond dissociation energy compared to other C<img>C bonds structures. The HOMO-LUMO (highest occupied molecular orbital/lowest unoccupied molecular orbital) distribution enhances site-specific reactivity, governed by substituent electronic effects and conjugation. These findings elucidate critical structure–function relationships, offering theoretical guidance for Lucaogou shale oil exploration and conversion processes.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"401 ","pages":"Article 135898"},"PeriodicalIF":6.7,"publicationDate":"2025-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144229687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pore structure evolution of anthracite modified by CO2 foam fracturing fluid under different temperature and pressure conditions 不同温度和压力条件下CO2泡沫压裂液改性无烟煤孔隙结构演化
IF 6.7 1区 工程技术
Fuel Pub Date : 2025-06-07 DOI: 10.1016/j.fuel.2025.135929
Yangfeng Zheng , Cheng Zhai , Shuxun Sang , Aikun Chen , Jizhao Xu , Yong Sun , Hexiang Xu , Hongyang Xu , Yongshuai Lai
{"title":"Pore structure evolution of anthracite modified by CO2 foam fracturing fluid under different temperature and pressure conditions","authors":"Yangfeng Zheng ,&nbsp;Cheng Zhai ,&nbsp;Shuxun Sang ,&nbsp;Aikun Chen ,&nbsp;Jizhao Xu ,&nbsp;Yong Sun ,&nbsp;Hexiang Xu ,&nbsp;Hongyang Xu ,&nbsp;Yongshuai Lai","doi":"10.1016/j.fuel.2025.135929","DOIUrl":"10.1016/j.fuel.2025.135929","url":null,"abstract":"<div><div>CO<sub>2</sub> foam fracturing technology has significant potential for enhancing coalbed methane (CBM) recovery. Intrusion of the CO<sub>2</sub> foam fracturing fluid into coal seams alters coal pore and fracture structures, thereby influencing CBM recovery. However, coal pore structural evolution modified by CO<sub>2</sub> foam fracturing fluid under varying reservoir temperatures and injection pressures remains unclear. To address this, a self-constructed high-temperature and high-pressure reactor was used to modify anthracite under different temperature (30–60℃) and pressure (3–6 MPa) conditions for 15 h. The pore structure and mineral composition of the modified anthracite were subsequently analyzed using low-temperature nitrogen adsorption, low-field nuclear magnetic resonance, environmental scanning electron microscopy, and X-ray diffraction. The results showed that temperature and CO<sub>2</sub> pressure significantly affected the modified coal-pore structure. Specifically, as the temperature decreased or the CO<sub>2</sub> pressure increased, the average pore diameter, total and effective porosities, NMR permeability, proportion of free fluid, and adsorption pore fractal dimension <em>D</em><sub>2</sub> showed increasing trends, whereas the Brunauer–Emmett–Teller (BET)-specific surface area, and fractal dimensions <em>D</em><sub>1</sub>, and <em>D</em><sub>S</sub> decreased. Moreover, the combined effects of carbonic acid and sodium dodecyl sulfate in the CO<sub>2</sub> foam promoted the dissolution of clay and carbonate minerals, resulting in an increase in the number of surface fractures, pore enlargement, and the transformation of isolated pores into interconnected fractures. Pore structure evolution is primarily driven by mineral, and organic matter dissolution and fracturing, and CO<sub>2</sub> adsorption-induced matrix swelling. After performing CO<sub>2</sub> foam fracturing in deep high-temperature coal seams, implementing higher shut-in pressures can further enhance CBM recovery. These findings provide a fundamental theoretical basis for engineering applications of CO<sub>2</sub> foam fracturing technology to enhance CBM recovery.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"401 ","pages":"Article 135929"},"PeriodicalIF":6.7,"publicationDate":"2025-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144229689","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Laser direct writing of graphene-encapsulated MoNi4 nanoparticles on carbon cloth as a self-supporting electrode for enhanced electrochemical urea oxidation 石墨烯包封的mon4纳米粒子在碳布上的激光直写作为自支撑电极用于增强电化学尿素氧化
IF 6.7 1区 工程技术
Fuel Pub Date : 2025-06-07 DOI: 10.1016/j.fuel.2025.135913
Xiaobing Liu, Yuzhou Sun, Zizheng Xing, Luhan Hou, Yi Nie, Tielong Li, Haitao Wang
{"title":"Laser direct writing of graphene-encapsulated MoNi4 nanoparticles on carbon cloth as a self-supporting electrode for enhanced electrochemical urea oxidation","authors":"Xiaobing Liu,&nbsp;Yuzhou Sun,&nbsp;Zizheng Xing,&nbsp;Luhan Hou,&nbsp;Yi Nie,&nbsp;Tielong Li,&nbsp;Haitao Wang","doi":"10.1016/j.fuel.2025.135913","DOIUrl":"10.1016/j.fuel.2025.135913","url":null,"abstract":"<div><div>Nickel-based catalysts have garnered significant attention for the urea oxidation reaction (UOR), primarily due to the pivotal role of NiOOH as the active phase. However, practical applications are often hindered by poor electrical conductivity and sluggish Ni2<sup>+</sup>/Ni3<sup>+</sup> redox transitions. In this work, we present a self-supporting electrode composed of graphene encapsulated Mo-doped nickel nanoparticles grown on carbon cloth (NiMo/G/CC). The strategic Mo doping not only enhances the formation of NiOOH by accelerating the Ni2<sup>+</sup>→Ni3<sup>+</sup> transition but also modulates the electronic structure in synergy with graphene’s high conductivity. Consequently, the optimized electrode achieves an impressive current density of 100 mA cm<sup>−</sup>2 at 1.38 V vs. RHE, outperforming many state-of-the-art UOR catalysts. Furthermore, the protective graphene encapsulation greatly improves electrode stability under prolonged operation.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"401 ","pages":"Article 135913"},"PeriodicalIF":6.7,"publicationDate":"2025-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144241598","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Utilization of machine learning algorithms in estimation of syngas fractions and exergy values for gasification of biomass-lignite mixtures in fixed and fluidized bed gasifiers 利用机器学习算法估计合成气馏分和火用值在固定床和流化床气化生物质-褐煤混合物
IF 6.7 1区 工程技术
Fuel Pub Date : 2025-06-07 DOI: 10.1016/j.fuel.2025.135883
Mislina Cakar , Mert Akin Insel , Hasan Sadikoglu , Ozgun Yucel
{"title":"Utilization of machine learning algorithms in estimation of syngas fractions and exergy values for gasification of biomass-lignite mixtures in fixed and fluidized bed gasifiers","authors":"Mislina Cakar ,&nbsp;Mert Akin Insel ,&nbsp;Hasan Sadikoglu ,&nbsp;Ozgun Yucel","doi":"10.1016/j.fuel.2025.135883","DOIUrl":"10.1016/j.fuel.2025.135883","url":null,"abstract":"<div><div>Earth’s environmental challenges, such as climate change and pollution, require urgent emission reductions. A thermochemical method that transforms carbon-rich substances into syngas, biomass gasification produces clean hydrogen as a sustainable energy carrier. This process ensures high carbon conversion efficiency while minimizing greenhouse gas emissions. This study examines the gasification of nine biomass-lignite blends using fluidized-bed and fixed-bed gasifiers. A wide range of biomass samples blended with lignite enabled the analysis of different sample characteristics and their impact on the gasification technique. ASPEN Plus® simulations assess the effects of biomass-to-lignite ratio, equivalence ratio (ER), steam to biomass ratio (SBR), and reactor temperature on syngas fraction and system efficiency. Machine learning models gaussian process regression (GPR), random forest (RF), support vector machine (SVM), and decision tree (DT) predict syngas and product gas exergy values, providing a data-driven optimization approach. For hazelnut shell validation, R2 values were 0.98 for the fixed-bed model and 0.96 for the fluidized-bed model. The Random Forest algorithm demonstrated the highest accuracy (R2 = 0.93), outperforming other models. The study also analysed the amount of data required and demonstrated robust models capable of learning with limited data. Since a significant portion of the machine learning process involves dataset creation, the ability to learn from small datasets is crucial. This highlights the significance of data-efficient learning in machine learning applications. Findings contribute to advancing biomass gasification for cleaner hydrogen production.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"401 ","pages":"Article 135883"},"PeriodicalIF":6.7,"publicationDate":"2025-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144242143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative numerical study of Fe2O3 reduction using CO and H2 for direct iron production CO和H2直接制铁还原Fe2O3的数值对比研究
IF 6.7 1区 工程技术
Fuel Pub Date : 2025-06-07 DOI: 10.1016/j.fuel.2025.135885
Kavin Ravichandran , Natalia Ramos Goncalves , Pasquale Daniele Cavaliere
{"title":"Comparative numerical study of Fe2O3 reduction using CO and H2 for direct iron production","authors":"Kavin Ravichandran ,&nbsp;Natalia Ramos Goncalves ,&nbsp;Pasquale Daniele Cavaliere","doi":"10.1016/j.fuel.2025.135885","DOIUrl":"10.1016/j.fuel.2025.135885","url":null,"abstract":"<div><div>This study presents a comparative analysis of Direct Reduced Iron (DRI) production using carbon monoxide (CO) and hydrogen (H<sub>2</sub>) as reducing agents, modelled through Ansys Twin Builder. The simulations evaluate conversion efficiency, gas utilization, energy demand, and environmental performance under industrial-scale conditions. A simplified and idealized system is adopted, where iron ore pellets are assumed to be composed entirely of hematite (Fe<sub>2</sub>O<sub>3</sub>), with complete reduction to metallic iron (Fe) and negligible dust formation.</div><div>The model simulates the reduction of 300 tons of pellets per hour, corresponding to 206.25 tons of Fe<sub>2</sub>O<sub>3</sub>. Based on stoichiometric reactions (Fe<sub>2</sub>O<sub>3</sub> + 3CO → 2Fe + 3CO<sub>2</sub> and Fe<sub>2</sub>O<sub>3</sub> + 3H<sub>2</sub> → 2Fe + 3H<sub>2</sub>O), the simulation estimates the production of approximately 144.2 tons of metallic iron per hour. For the hydrogen-based route, ∼104,200 m<sup>3</sup>/h of H<sub>2</sub> is required (including 20 % excess), resulting in a gas utilization efficiency of 83.3 %. Under the same conditions, the CO-based route emits approximately 1.18 tons of CO<sub>2</sub> per ton of Fe, while the H<sub>2</sub>-based route achieves zero direct CO<sub>2</sub> emissions. Despite the higher total energy demand of the hydrogen route due to its endothermic nature and the positive enthalpy change, the significant reduction in carbon intensity positions hydrogen as a promising pathway for cleaner DRI production. These findings support the transition of the steel industry toward low-carbon technologies, contributing to compliance with future regulatory frameworks and international decarbonization targets.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"401 ","pages":"Article 135885"},"PeriodicalIF":6.7,"publicationDate":"2025-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144229688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual-tuning SiO2 nanosphere size and hydrothermal reaction temperature toward urchin-like copper phyllosilicate hollow nanospheres catalyst in dimethyl oxalate hydrogenation 双调SiO2纳米球尺寸和水热反应温度对海胆状叶状硅酸铜空心纳米球催化草酸二甲酯加氢的影响
IF 6.7 1区 工程技术
Fuel Pub Date : 2025-06-07 DOI: 10.1016/j.fuel.2025.135907
Yihua Wang , Jiyang Wei , Mingling Sun , Fei Li , Yishu Zhang , Ziyi Miao , Ling Lin , Yuangen Yao
{"title":"Dual-tuning SiO2 nanosphere size and hydrothermal reaction temperature toward urchin-like copper phyllosilicate hollow nanospheres catalyst in dimethyl oxalate hydrogenation","authors":"Yihua Wang ,&nbsp;Jiyang Wei ,&nbsp;Mingling Sun ,&nbsp;Fei Li ,&nbsp;Yishu Zhang ,&nbsp;Ziyi Miao ,&nbsp;Ling Lin ,&nbsp;Yuangen Yao","doi":"10.1016/j.fuel.2025.135907","DOIUrl":"10.1016/j.fuel.2025.135907","url":null,"abstract":"<div><div>In this work, the relationship between the size of SiO<sub>2</sub> nanospheres (SNS) and their surface hydroxyl concentration was investigated. Three types of SNS with diameters of 510  nm, 170  nm, and 100  nm were used as supports to synthesize a series of Cu/SNS-140 catalysts via a hydrothermal method at 140 °C. The influence of SNS size on the structure and relative amount of copper phyllosilicate was explored, identifying ∼ 170  nm as the optimal SNS size for forming urchin-like copper phyllosilicate hollow nanospheres. Subsequently, the effect of hydrothermal reaction temperature on the formation of these structures was studied. The results showed that both suitable SNS size and hydrothermal reaction temperature (140 °C) are critical for achieving the ideal morphology. Among the prepared catalysts, Cu/SNS-M−140 exhibited the best performance in the hydrogenation of dimethyl oxalate (DMO), achieving a DMO conversion of 99.9 % and ethylene glycol selectivity of 96.3 % at 190 °C, with a TOF of 27.9  h<sup>−1</sup>. The superior activity is attributed to its unique hollow structure, which enhances hydrogen enrichment and spatial restriction effects. This work offers valuable guidance for the rational design of copper phyllosilicate-based hollow nanostructured catalysts.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"401 ","pages":"Article 135907"},"PeriodicalIF":6.7,"publicationDate":"2025-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144241599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural and catalytic properties analysis of Ni-Ca-Al bi-functional materials derived from layered double hydroxide (LDH) precursors: Influence of Ca sources on performance of sorption enhanced steam methane reforming 层状双氢氧化物(LDH)前驱体衍生的Ni-Ca-Al双功能材料的结构和催化性能分析:Ca源对吸附强化蒸汽甲烷重整性能的影响
IF 6.7 1区 工程技术
Fuel Pub Date : 2025-06-07 DOI: 10.1016/j.fuel.2025.135895
Mengjin Xu , Xin Xiao , Hongwei Zhang , Jianjun Li
{"title":"Structural and catalytic properties analysis of Ni-Ca-Al bi-functional materials derived from layered double hydroxide (LDH) precursors: Influence of Ca sources on performance of sorption enhanced steam methane reforming","authors":"Mengjin Xu ,&nbsp;Xin Xiao ,&nbsp;Hongwei Zhang ,&nbsp;Jianjun Li","doi":"10.1016/j.fuel.2025.135895","DOIUrl":"10.1016/j.fuel.2025.135895","url":null,"abstract":"<div><div>The sorption-enhanced steam methane reforming (SESMR) technology holds significant potential as a medium-term solution to address energy shortages. For SESMR, highly effective bi-functional material is the key requirement for economic operation. In this study, layered double hydroxide (LDH) precursors with calcium nitrate tetrahydrate and calcium chloride anhydrous as calcium sources were proposed for SESMR. LDH precursor facilitates the construct of the porous structure of catalytic-sorption bi-functional materials. The characterization results indicated that the strong interactions between metallic elements in bi-functional material with calcium nitrate as calcium source (NCABNs) result in the smallest particle size of Ni and the highest element dispersion, which are beneficial for the catalytic performance and CO<sub>2</sub> sorption performance. Additionally, the hydrogen yield of 95.83% in the pre-breakthrough stage and the menthane conversion rate of 99.38% further indicated the excellent catalytic performance and CO<sub>2</sub> sorption performance of NCABNs. Based on the analysis of thermogravimetric data, NCABNs was applied to conduct the SESMR-regeneration cyclic tests. The CO<sub>2</sub> sorption process was obviously observed in 10 cyclic tests with the CO<sub>2</sub> volume concentration in the pre-breakthrough stage fluctuated around 3 %. Moreover, the textural properties of NCABNs were still retained after the cyclic tests. The low coke graphitization in NCABNs was demonstrated by Raman data with an I<sub>D</sub>/I<sub>G</sub> of 1.4, which represents the coke can be easily removed by CO<sub>2</sub>. The performance of the reported catalyst-sorbent system is encouraging for further studies for SESMR and other reforming techniques.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"401 ","pages":"Article 135895"},"PeriodicalIF":6.7,"publicationDate":"2025-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144241600","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrasonic-coupled ozone oxidation of Shengli lignite for efficient preparation of high-quality humic acid 胜利褐煤超声耦合臭氧氧化高效制备高品质腐植酸
IF 6.7 1区 工程技术
Fuel Pub Date : 2025-06-07 DOI: 10.1016/j.fuel.2025.135864
Chuang Zhang , Wei Jiang , Xiao-Yan Zhao , Chen Xu Chen , Wen Li , Jing-Pei Cao
{"title":"Ultrasonic-coupled ozone oxidation of Shengli lignite for efficient preparation of high-quality humic acid","authors":"Chuang Zhang ,&nbsp;Wei Jiang ,&nbsp;Xiao-Yan Zhao ,&nbsp;Chen Xu Chen ,&nbsp;Wen Li ,&nbsp;Jing-Pei Cao","doi":"10.1016/j.fuel.2025.135864","DOIUrl":"10.1016/j.fuel.2025.135864","url":null,"abstract":"<div><div>Humic acid (HA) is a natural organic substance with significant applications in modern agriculture, ecological restoration, and life sciences. However, the oxidative dissociation of organic matter fragments from lignite leads to polymerization, resulting in low soluble yields. The mechanical and cavitation effects of ultrasonic effectively reduces coal particle size, facilitating their oxidation in the presence of ozone. Additionally, the reactive free radicals generated by the ultrasonic-coupled ozone enhances the oxidizability of the reaction system. The organic matter conversion and HA yield without ash from Shengli lignite (SL) oxidized by ultrasonic-coupled ozone are 82.51% and 49.88%, respectively. The characterization results reveal that the oxidation process primarily breaks the C–O and C–C bridge bonds in SL, and HA has more polar functional groups (–COOH). This study provides a novel approach for efficiently preparing HA from lignite through ultrasonic-coupled ozone oxidation.</div></div>","PeriodicalId":325,"journal":{"name":"Fuel","volume":"401 ","pages":"Article 135864"},"PeriodicalIF":6.7,"publicationDate":"2025-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144229686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of exhaust heat recovery and hydrogen production by steam methane reforming under different operating conditions of the HCNG engine HCNG发动机不同工况下蒸汽甲烷重整余热回收及产氢分析
IF 6.7 1区 工程技术
Fuel Pub Date : 2025-06-06 DOI: 10.1016/j.fuel.2025.135853
Muhammad Ihsan Shahid , Muhammad Farhan , Anas Rao , Muhammad Saddam Hussain , Xianlei Zhu , Hamza Ahmad Salam , Tianhao Chen , Xin Li , Fanhua Ma
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