{"title":"Excitonic-type polaron states: photoluminescence in SBN and in other ferroelectric oxides","authors":"V. Vikhnin, I. Kislova, A. Kutsenko, S. Kapphan","doi":"10.1117/12.475343","DOIUrl":"https://doi.org/10.1117/12.475343","url":null,"abstract":"A theoretical model for two characteristic photoluminescence (PL) bands in SBN, 'green luminescence' and 'red luminescence' is proposed on the basis of the extended photoluminescence experiments in SBN:Cr, and also in SBN:Ce and in nominally pure SBN systems under different conditions. While the RL-band is suggested to be connected with charge transfer vibronic exciton (CTVE) clusters induced by Cr3+ impurities in the Nb-sites, the GL- band is connected with Nb4+ electronic polarons in a new, charge transfer excited states. Here Nb4+ centers are the cores of the CTVE clusters induced by these charged scores. The PL mechanism is the in-cluster CTVE recombination for both bands under discussion. But the CTVE states are quasi-resonantly mixed here with 4T2 states of the Cr3+ core in the RL-band case, and with 5s-states of the Nb4+ core in the GL-band case. The role of excitonic polarons of CTVE nature is also discussed in connection with 'green' luminescence origin in KTaO3 and KNbO3 crystals.","PeriodicalId":312884,"journal":{"name":"Feofilov Symposium on Spectropscopy of Crystals Activated by Rare-Earth and Transition Metal Ions","volume":"19 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123097713","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"S.A. Altshuler and spectroscopy: from nuclear physics to quantum electronics","authors":"N. Altshuler, A. L. Larionov","doi":"10.1117/12.475315","DOIUrl":"https://doi.org/10.1117/12.475315","url":null,"abstract":"The paper deals with the main stages of scientific and organizing activities in spectroscopy of member- correspondent of USSR Academy of Sciences, Professor SA Altashuler, as theorist, worked in the fields of magnetic and spectroscopic phenomena and nuclear magnetism. His name is known with the prediction of neutron magnetic moment, acoustic paramagnetic resonance phenomenon discovery, and a series of fundamental publications on paramagnetic resonance.","PeriodicalId":312884,"journal":{"name":"Feofilov Symposium on Spectropscopy of Crystals Activated by Rare-Earth and Transition Metal Ions","volume":"49 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115037818","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
P. Rodnyi, C. V. van Eijk, A. N. Mishin, S. B. Mikhrin, A. G. Avanesov, A. Potapov
{"title":"Interconfiguration and intraconfiguration transitions of Pr3+ in some oxides and flourides","authors":"P. Rodnyi, C. V. van Eijk, A. N. Mishin, S. B. Mikhrin, A. G. Avanesov, A. Potapov","doi":"10.1117/12.475331","DOIUrl":"https://doi.org/10.1117/12.475331","url":null,"abstract":"There is a very great interest to obtain luminophors with a large quantum efficiency. One way to realize this is the employment of photon cascade emission. We present result of a search for new materials with cascade emission in Pr3+ intraconfiguration f-f transitions. The influence of host lattices, temperature, Pr concentration of f-f and d-f transitions has been studied.","PeriodicalId":312884,"journal":{"name":"Feofilov Symposium on Spectropscopy of Crystals Activated by Rare-Earth and Transition Metal Ions","volume":"4 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125727139","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Charge transfer and 4fn-4fn-1 5d transitions of trivalent rare-earth ions in CsCdBr3","authors":"R. Demirbilek, J. Heber, S. I. Nikitin","doi":"10.1117/12.475347","DOIUrl":"https://doi.org/10.1117/12.475347","url":null,"abstract":"The positions of the Charge Transfer (CT) and the 4f- 4fn-15d (fd) transitions of the trivalent rare-earth ions in CsCdBr3 are estimated using the Jorgensen and Dorenbos methods, respectively. The CT spectra of Sm3+, Eu3+, Tm3+ and Yb3+ and the f-d transitions of Pr3+ in CsCdBr3 were measured. Experimental and theoretical results are compared.","PeriodicalId":312884,"journal":{"name":"Feofilov Symposium on Spectropscopy of Crystals Activated by Rare-Earth and Transition Metal Ions","volume":"16 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129890996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Spectroscopic properties of Cr3+ ions in KTP single crystals","authors":"E. Pestryakov, V. Petrov, A. Volkov, V. Maslov","doi":"10.1117/12.475316","DOIUrl":"https://doi.org/10.1117/12.475316","url":null,"abstract":"The possibility of creation of self-frequency doubling laser crystal based on crystal KTP doped with chromium ions is investigated. The spectral properties of Cr3+ ions are researched. The magnitude of emission cross-section at the wavelength of 833 nm corresponding to the maximum of vibronic transition 4T2-4A2 of Cr3+ ion is estimated. The excited state lifetimes at room and liquid nitrogen temperatures are determined. The spectroscopic investigations show that impurity Cr3+ ions in KTP crystal are placed in positions with weak crystal field: Dq equals 1507 cm-1, B equals 652 cm-1, C equals 2800 cm-1. The configuration diagram model with one excited state is discussed. The main features of fluorescence spectra and the expected laser emission in the near IR range form 700 to 1000 nm are considered.","PeriodicalId":312884,"journal":{"name":"Feofilov Symposium on Spectropscopy of Crystals Activated by Rare-Earth and Transition Metal Ions","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123116640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Up-conversion in rare-earth-doped systems: past, present and future","authors":"F. Auzel","doi":"10.1117/12.475333","DOIUrl":"https://doi.org/10.1117/12.475333","url":null,"abstract":"As for other fluorescence light emitters, rare-earth (RE)- doped solids usually follow the well known principle of the Stokes law which simply states that excitation photons are at higher energy than emitted ones or in other words that out-put photon energy is weaker than input photon energy. Such principle is valid of course only when one ion system is considered.","PeriodicalId":312884,"journal":{"name":"Feofilov Symposium on Spectropscopy of Crystals Activated by Rare-Earth and Transition Metal Ions","volume":"11 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126764026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. Khaidukov, N. Kirikova, M. Kirm, J. Krupa, V. Makhov, E. Negodin, G. Zimmerer
{"title":"Inter and intraconfigurational luminescence of LiYF4:Er3+ under selective VUV excitation","authors":"N. Khaidukov, N. Kirikova, M. Kirm, J. Krupa, V. Makhov, E. Negodin, G. Zimmerer","doi":"10.1117/12.475330","DOIUrl":"https://doi.org/10.1117/12.475330","url":null,"abstract":"Electronic relaxation of selectivity excited LiYF4:Er3+ was investigated by means of time-integrated and time-resolved photoluminescence spectroscopy, using synchrotron radiation for excitation purposes. The range of excitation covered both Er3+ and host excitation up to 200 eV. Following Er3+ excitation, radiative cascades and cross relaxation were established. Under soft x-ray excitation, inelastic scattering of photoelectrons contributes to electronic relaxation.","PeriodicalId":312884,"journal":{"name":"Feofilov Symposium on Spectropscopy of Crystals Activated by Rare-Earth and Transition Metal Ions","volume":"11 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126112407","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Some experimental peculiarities of photon echo in ruby","authors":"V. Samartsev, A. Kalachev, R. Usmanov","doi":"10.1117/12.475338","DOIUrl":"https://doi.org/10.1117/12.475338","url":null,"abstract":"Photon-echo measurements have been performed in gamma- irradiated ruby and in ruby with 53Cr3+.","PeriodicalId":312884,"journal":{"name":"Feofilov Symposium on Spectropscopy of Crystals Activated by Rare-Earth and Transition Metal Ions","volume":"15 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130385834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Spectroscopy and laser action of the disordered calcium-niobium and calcium-lithium-niobium-gallium garnets doped with rare earth ions","authors":"Y. Voronko, A. Sobol, S. Ushakov, V. Shukshin","doi":"10.1117/12.475324","DOIUrl":"https://doi.org/10.1117/12.475324","url":null,"abstract":"The results of spectroscopy and laser action of disordered calcium niobium gallium and calcium lithium niobium gallium garnets doped with Nd3+, Er3+, Eu3+, Ho3+ and Tm3+ are displayed.","PeriodicalId":312884,"journal":{"name":"Feofilov Symposium on Spectropscopy of Crystals Activated by Rare-Earth and Transition Metal Ions","volume":"04 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123638862","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Dotsenko, P. V. Pirogenko, I. Berezovskaya, E. Zhikhareva, E. V. Shabanov
{"title":"Luminescent properties of ytterbium ions in strontium haloborates","authors":"V. Dotsenko, P. V. Pirogenko, I. Berezovskaya, E. Zhikhareva, E. V. Shabanov","doi":"10.1117/12.475327","DOIUrl":"https://doi.org/10.1117/12.475327","url":null,"abstract":"The luminescence e properit4se of ytterbium ions in strongtium haloborates were studied under optical, x-ray and synchrotron excitation. The emission spectra of Sr2(1-x)Yb5O9R consists of a blue and a UV band. The former is due to 4f135d yields 4f14 transtions on the Yb2+ ions. The latter is tentatively assigned to charge transfer luminescence of Yb3+ ions. The influence of the structural features of Sr2B5O9R and some preparative conditions on the luminescent behavior of Yb ions is discussed.","PeriodicalId":312884,"journal":{"name":"Feofilov Symposium on Spectropscopy of Crystals Activated by Rare-Earth and Transition Metal Ions","volume":"412 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133974422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}