CsCdBr3中三价稀土离子的电荷转移和4fn-4fn- 15d跃迁

Feofilov Symposium on Spectropscopy of Crystals Activated by Rare-Earth and Transition Metal Ions Pub Date : 2002-07-12 DOI:10.1117/12.475347

R. Demirbilek, J. Heber, S. I. Nikitin

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引用次数: 10

摘要

利用Jorgensen和Dorenbos方法分别估计了CsCdBr3中三价稀土离子的电荷转移(CT)和4f- 4fn-15d (fd)跃迁的位置。测量了CsCdBr3中Sm3+、Eu3+、Tm3+和Yb3+的CT谱和Pr3+的f-d跃迁。实验结果与理论结果进行了比较。

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Charge transfer and 4fn-4fn-1 5d transitions of trivalent rare-earth ions in CsCdBr3

The positions of the Charge Transfer (CT) and the 4f- 4fn-15d (fd) transitions of the trivalent rare-earth ions in CsCdBr3 are estimated using the Jorgensen and Dorenbos methods, respectively. The CT spectra of Sm3+, Eu3+, Tm3+ and Yb3+ and the f-d transitions of Pr3+ in CsCdBr3 were measured. Experimental and theoretical results are compared.

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Feofilov Symposium on Spectropscopy of Crystals Activated by Rare-Earth and Transition Metal Ions

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