Energy Storage Materials最新文献_第9页

Multiscale characterizations boosting understanding of gassing behavior in rechargeable batteries: Progress and outlook 多尺度表征促进了对可充电电池气体行为的理解：进展与展望

IF 19.3 1区材料科学

Energy Storage Materials Pub Date : 2026-08-01 Epub Date: 2026-07-12 DOI: 10.1016/j.ensm.2026.105385

Yicheng Sun, Rui Wu, Shipeng Zhang, Nan Li, Keyu Xie

{"title":"Multiscale characterizations boosting understanding of gassing behavior in rechargeable batteries: Progress and outlook","authors":"Yicheng Sun, Rui Wu, Shipeng Zhang, Nan Li, Keyu Xie","doi":"10.1016/j.ensm.2026.105385","DOIUrl":"10.1016/j.ensm.2026.105385","url":null,"abstract":"<div><div>Gas evolution caused by parasitic reactions, together with the subsequent migration, consumption, and accumulation of gaseous products, severely affects the performance, lifetime, and safety of rechargeable lithium/sodium (Li/Na) batteries. Advanced characterization techniques allow for probing the mechanisms and impacts of these gas-related processes, thereby providing a substantive understanding of gassing behavior. As these techniques continue to develop, new insights will undoubtedly emerge. Herein, from the perspective of advanced characterization techniques, including both online gas analysis and gas visualization, gassing behavior in rechargeable Li/Na batteries is comprehensively reviewed. Gas analysis is presented according to the dominant driving force of gas evolution. For voltage-driven gas evolution, battery-level online gas analysis techniques are discussed, with emphasis on the mechanistic insights obtained from isotope labeling and the decoupling of gas evolution reactions at individual electrodes. For thermal-driven gas evolution, gas release and crosstalk mechanisms during thermal runaway are elucidated based on material-level gas analysis. In parallel, the principles of gas visualization at both the interface and battery scales are summarized, together with insights into the dynamic behavior of gaseous products. Finally, remaining challenges and future directions in gas-related characterizations are outlined. This review provides a comprehensive understanding of the overall gassing behavior in rechargeable Li/Na batteries, thereby advancing their safe and stable operation.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"90 ","pages":"Article 105385"},"PeriodicalIF":19.3,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148461385","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent advances in electrolyte additives for zinc flow batteries: Mechanisms, applications, and perspectives 锌液流电池电解液添加剂的研究进展：机理、应用与展望

IF 19.3 1区材料科学

Energy Storage Materials Pub Date : 2026-08-01 Epub Date: 2026-07-12 DOI: 10.1016/j.ensm.2026.105383

Dixian Wu, Jicheng Li, Qiang Zheng, Xingyi Shi

{"title":"Recent advances in electrolyte additives for zinc flow batteries: Mechanisms, applications, and perspectives","authors":"Dixian Wu, Jicheng Li, Qiang Zheng, Xingyi Shi","doi":"10.1016/j.ensm.2026.105383","DOIUrl":"10.1016/j.ensm.2026.105383","url":null,"abstract":"<div><div>Zinc flow batteries (ZFBs) are considered as a leading candidate for scalable electrochemical energy storage, combining high energy density, intrinsic safety, and cost-effectiveness. Nevertheless, their widespread commercialization progress is still being greatly hindered by persistent challenges, including active species crossover, metal-ion hydrolysis, and zinc dendrite formation. To address these limitations, extensive research has targeted advancements in key components, such as electrolytes, membranes, and electrodes. Among these strategies, electrolyte optimization via additive engineering has gained particular attraction, owing to its simplicity, low cost, and ease of implementation. This review critically outlines the fundamental challenges in various ZFB systems, provides a comprehensive summary of diverse electrolyte additives and their effects on battery performance enhancements, as well as elucidates the underlying mechanisms. Furthermore, evaluation and characterization techniques for these additives are systematically summarized. Finally, a forward-looking perspective on the additive development has been provided, with the aim of informing the rational design of next-generation ZFBs with enhanced stability and performance.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"90 ","pages":"Article 105383"},"PeriodicalIF":19.3,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148461390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Dualistic roles of water molecules in Mn-based oxide cathodes for sodium ion batteries 水分子在钠离子电池锰基氧化物阴极中的二元作用

IF 19.3 1区材料科学

Energy Storage Materials Pub Date : 2026-08-01 Epub Date: 2026-08-02 DOI: 10.1016/j.ensm.2026.105429

Yaping Yan, Xin-Bei Jia, Junlong Sun, Dan-Dan Wang, Rui-Zi Li, Lu-Lu Guo, Yan-Fang Zhu, Shilin Zhang, Yao Xiao

{"title":"Dualistic roles of water molecules in Mn-based oxide cathodes for sodium ion batteries","authors":"Yaping Yan, Xin-Bei Jia, Junlong Sun, Dan-Dan Wang, Rui-Zi Li, Lu-Lu Guo, Yan-Fang Zhu, Shilin Zhang, Yao Xiao","doi":"10.1016/j.ensm.2026.105429","DOIUrl":"10.1016/j.ensm.2026.105429","url":null,"abstract":"<div><div>Water molecules are traditionally regarded as detrimental impurities in sodium manganese (Mn)-based oxide cathodes, as they can trigger Na<sup>⁺</sup>/H<sup>⁺</sup> exchange, surface side reactions, transition-metal dissolution, and irreversible structural degradation. However, emerging studies reveal that judiciously incorporated into the crystal framework, water molecules can exert beneficial effects by functioning as electrostatic shields and structural pillars, thereby mitigating lattice strain, suppressing Mn dissolution, and facilitating Na<sup>+</sup> diffusion. In this review, we systematically evaluate the dualistic roles of water molecules in sodium Mn-based oxide cathodes. We begin by summarizing the widely reported degradation mechanisms induced by water, and then highlight recent advances showing that certain water species, particularly crystal/lattice water, can enhance structural robustness, ion-transport kinetics and electrochemical performance. Finally, we discuss the broader implications of water chemistry in rechargeable batteries and outline key challenges and future directions for state-selective water regulation, including multimodal characterization, theoretical modeling, and process-level control. This review establishes a balanced framework for understanding water-involved structural and electrochemical effects and provides guidance for future water regulation in next-generation Mn-based cathodes and related rechargeable battery systems.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"90 ","pages":"Article 105429"},"PeriodicalIF":19.3,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148692048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Physicochemical origins of interfacial ion transport in antiperovskite solid electrolytes 反钙钛矿固体电解质中界面离子传输的物理化学起源

IF 19.3 1区材料科学

Energy Storage Materials Pub Date : 2026-08-01 DOI: 10.1016/j.ensm.2026.105426

Mustafa Khan, Rizwana, Liyuan Qian, Zhiqian Lin, Haibin Lin, Xiaofei Wang, Songbai Han, Fayan Zhu, Jinlong Zhu, Yusheng Zhao

{"title":"Physicochemical origins of interfacial ion transport in antiperovskite solid electrolytes","authors":"Mustafa Khan, Rizwana, Liyuan Qian, Zhiqian Lin, Haibin Lin, Xiaofei Wang, Songbai Han, Fayan Zhu, Jinlong Zhu, Yusheng Zhao","doi":"10.1016/j.ensm.2026.105426","DOIUrl":"10.1016/j.ensm.2026.105426","url":null,"abstract":"<div><div>Antiperovskite solid electrolytes are promising candidates for next-generation solid-state batteries because of their high lithium-ion conductivity, tunable defect chemistry, and mechanically compliant lattices. Yet these favorable bulk properties do not directly translate into practical cell performance, which is often limited by interfacial chemical reactivity, transport heterogeneity, and chemo-mechanical degradation. In this review, we present an interface-centered mechanistic framework that links crystal chemistry, defect-mediated transport, lattice dynamics, and mesoscale mechanics to interfacial ion transport in antiperovskite electrolytes. We show that the same characteristics that promote fast bulk lithium transport, including lattice softness, defect distributions, and anion rotational dynamics, can also drive space-charge accumulation, stress localization, and interfacial transport bottlenecks under electrochemical operation. We further examine how grain boundaries, electrode contact evolution, and composite cathode architectures shape interfacial stability and full-cell behavior. Finally, we discuss emerging strategies, including artificial interphases, defect modulation, and coupled chemo-mechanical design, that can convert intrinsic transport advantages into stable and efficient battery operation. This perspective highlights the physicochemical origins of interfacial ion transport and establishes design principles for antiperovskite electrolytes in practical solid-state batteries.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"90 ","pages":"Article 105426"},"PeriodicalIF":19.3,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148736854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Vertically Aligned Interlayer-Nanoconfined Channels for Fast Lithium-Ion Transport in Solid-State Batteries 固态电池中锂离子快速输运的垂直排列层间纳米通道

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2026-07-16 DOI: 10.1016/j.ensm.2026.105395

Qiannan Zhang, Xiaokang Gu, Zhijie Zhang, Bixuan Li, Andrew Xiang, Weiyang Yang, Qian Chen, Yuying Jiao, Zhuohan Ma, Qingwei Zhai, Moxuan Wang, Zhou Zhou, Tong Liu, Qianqian He, Zhikun Zhao, Pengbo Zhai, Yongji Gong

引用次数: 0

Conformal Li3PO4-Coating Synergized Epitaxial Mn-Doping Consolidating Chemical and Structural Stability of Ni-Rich LiNi0.9Co0.1O2 Cathode 共形li3po4涂层协同外延mn掺杂强化富镍LiNi0.9Co0.1O2阴极的化学性质及结构稳定性

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2026-07-15 DOI: 10.1016/j.ensm.2026.105394

Mohan Yang, Danhua Li, Yue Yuan, Zenan Zhao, Jing Wang, Quan Li, Jingze Guo, Meng Wang, Chenglong Jiang, Weiyou Yang, Feng Wu, Fang Wang, Guoqiang Tan

引用次数: 0

Dual-Site Reinforcement Unlocks High-Energy O3-Type Layered Cathodes for Sodium-Ion Batteries 双位点强化解锁钠离子电池高能o3型层状阴极

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2026-07-14 DOI: 10.1016/j.ensm.2026.105393

Fang Zhang, Bijiao He, Yan Xin, Shiguo Zhang, Huajun Tian, Yongping Yang

引用次数: 0

The Electrical Double Layer and Autocatalytic NaF formation in Sodium Ion Batteries 钠离子电池中电双层及自催化形成NaF

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2026-07-14 DOI: 10.1016/j.ensm.2026.105392

Kie Hankins, Miftahussurur Hamidi Putra, Axel Gross, Ulrike Krewer

引用次数: 0

An Acidic Additive Eliminating Basic By-Products and Enabling Uniform Zn Deposition for Stable Aqueous Zn Batteries 一种消除碱性副产物的酸性添加剂，可使稳定的水锌电池均匀沉积锌

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2026-07-13 DOI: 10.1016/j.ensm.2026.105384

Hongtu Zhan, Kuo Wang, Qianrui Li, Jiaqi Shi, Yikai Hu, Zeyu Huang, Lichao Tan, Xiao-Xia Liu, Xiaoqi Sun

引用次数: 0

Stress-Adaptive Sodiation Enabled by a Sodiophilic Solid-Solution Interface for Long-Life Anode-Free Sodium Metal Batteries 长寿命无阳极钠金属电池的亲钠固溶界面实现应力自适应钠化

IF 20.4 1区材料科学

Energy Storage Materials Pub Date : 2026-07-13 DOI: 10.1016/j.ensm.2026.105388

Haiying Lu, Zewei Hu, Peng Xie, Yunqi Gao, Yuju Qi, Jiayao Wang, Siqi Zeng, Ningyan Cheng, Chao Han, Weijie Li

引用次数: 0