Current Opinion in Chemical Engineering最新文献_第2页

Understanding synthesis and degradation of backbone deconstructable (co)polymers by radical ring-opening polymerization through theoretical calculation and numerical simulation 通过理论计算和数值模拟了解自由基开环聚合法合成和降解主干可解构（co）聚合物

IF 8 2区工程技术

Current Opinion in Chemical Engineering Pub Date : 2025-04-16 DOI: 10.1016/j.coche.2025.101131

Jin-Jin Li , Qi Luo , Yi-Xiang Lin , Zhenhao Xi , Ling Zhao

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Membrane synthesis via thermally induced phase separation: quantifying the shift to a more sustainable design 通过热诱导相分离的膜合成：量化转向更可持续的设计

IF 8 2区工程技术

Current Opinion in Chemical Engineering Pub Date : 2025-04-14 DOI: 10.1016/j.coche.2025.101130

Jason Stallings Jr, Endras Fadhilah, Malgorzata Chwatko

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Broadening the sonochemistry horizon: hurdles and challenges to address in cavitation 拓宽声化学视野：空化过程中需要解决的障碍和挑战

IF 8 2区工程技术

Current Opinion in Chemical Engineering Pub Date : 2025-04-10 DOI: 10.1016/j.coche.2025.101128

Davide Bernardo Preso , Ivan Smirnov , Mohamad Salimi , James Kwan

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Tantalum nitride photoanodes: a promising future for photoelectrochemical water splitting? 氮化钽光阳极：光电化学水分解的前景？

IF 8 2区工程技术

Current Opinion in Chemical Engineering Pub Date : 2025-04-09 DOI: 10.1016/j.coche.2025.101127

Mathieu Grandcolas , Annett Thøgersen , Ingeborg-Helene Svenum , Kevin Both , Athanasios Chatzitakis

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Applications and applicability of the cavitation technology 空化技术的应用与适用性

IF 8 2区工程技术

Current Opinion in Chemical Engineering Pub Date : 2025-04-09 DOI: 10.1016/j.coche.2025.101129

Melissa G Galloni , Vincenzo Fabbrizio , Roberto Giannantonio , Ermelinda Falletta , Claudia L Bianchi

{"title":"Applications and applicability of the cavitation technology","authors":"Melissa G Galloni , Vincenzo Fabbrizio , Roberto Giannantonio , Ermelinda Falletta , Claudia L Bianchi","doi":"10.1016/j.coche.2025.101129","DOIUrl":"10.1016/j.coche.2025.101129","url":null,"abstract":"<div><div>Cavitation technology, encompassing acoustic and hydrodynamic methods, represents a transformative approach to process intensification, enabling high-efficiency energy and mass transfer across diverse industrial applications. Acoustic cavitation exploits high-frequency ultrasonic waves to generate transient and stable bubbles, leading to localized high temperatures, pressures, and reactive species formation. Hydrodynamic cavitation, achieved through fluidic devices, such as Venturi tubes and vortex diodes, generates cavities under controlled low-pressure zones, providing scalable solutions for large-scale operations. This study critically examines the industrial viability of cavitation technologies, emphasizing their unique ability to combine mechanical, thermal, and chemical energy release. A detailed comparative analysis reveals the limitations of acoustic cavitation, including energy attenuation and equipment wear, against the superior scalability of hydrodynamic systems. Key challenges, such as enhancing hydroxyl radical yield, reducing operational costs, and improving system robustness, are explored alongside potential synergies with complementary technologies, like advanced oxidation processes and photocatalysis. Emerging industrial implementations, including biogas enhancement and chemical processing, underscore the evolving landscape of cavitation-based innovations. This work highlights the necessity for multidisciplinary strategies, integrating experimental, computational, and engineering perspectives to advance cavitation technology. By addressing scalability and cost-effectiveness, cavitation systems can unlock transformative opportunities for sustainable industrial applications, aligning with global environmental and economic imperatives.</div></div>","PeriodicalId":292,"journal":{"name":"Current Opinion in Chemical Engineering","volume":"48 ","pages":"Article 101129"},"PeriodicalIF":8.0,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143799289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Decoding the interactions between microplastics, polyfluoroalkyl substances, and endocrine disruptors: sorption kinetics and toxicity 解码微塑料、多氟烷基物质和内分泌干扰物之间的相互作用：吸附动力学和毒性

IF 8 2区工程技术

Current Opinion in Chemical Engineering Pub Date : 2025-04-09 DOI: 10.1016/j.coche.2025.101126

Kanika Dogra , Manish Kumar , Sanyogita Singh , Kanchan Deoli Bahukhandi

{"title":"Decoding the interactions between microplastics, polyfluoroalkyl substances, and endocrine disruptors: sorption kinetics and toxicity","authors":"Kanika Dogra , Manish Kumar , Sanyogita Singh , Kanchan Deoli Bahukhandi","doi":"10.1016/j.coche.2025.101126","DOIUrl":"10.1016/j.coche.2025.101126","url":null,"abstract":"<div><div>Microplastics (MPs) present a direct threat to aquatic organisms while functioning as vectors for the mobilization of organic contaminants within aquatic environments. Furthermore, due to their extensive usage, per- and polyfluoroalkyl substances (PFAS) and endocrine-disrupting chemicals (EDCs) have emerged as significant global concerns due to their pervasive presence and substantial accumulation in aquatic ecosystems. Research to date has primarily focused on these contaminants in isolation, leaving the interactions and cumulative effects among MPs, PFAS, and EDCs (trifecta) relatively unexamined. We elucidate the probable interaction mechanisms among these three categories of contaminants and to analyze their combined toxicity, as well as the existing regulatory frameworks and policies applicable to them. Our findings indicate that the sorption of EDCs and PFAS onto MPs is predominantly governed by hydrophobic and electrostatic forces and is sensitive to various environmental parameters, including pH, salinity, temperature, and dissolved organic matter. The interactions among these contaminants are intricate, encompassing mechanisms such as cation-π bonding and biofilm formation, all of which influence the dynamics of sorption. The synergistic effects of MPs in conjunction with co-contaminants, such as PFAS and EDCs, exacerbate toxicity, promote bioaccumulation, and elevate health risks for both aquatic organisms and mammals, typically contingent upon factors such as exposure duration, dosage, and environmental conditions. In conclusion, we underscore that while significant advancements have been achieved, considerable efforts are still required to address regulatory deficiencies and to advance legislation aimed at mitigating the impact of persistent pollutants.</div></div>","PeriodicalId":292,"journal":{"name":"Current Opinion in Chemical Engineering","volume":"48 ","pages":"Article 101126"},"PeriodicalIF":8.0,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143799288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Current status of chemical- or enzyme-assisted ultrasonic pre-treatment processes for lignocellulosic biomass to assess industrialization progress: A review 木质纤维素生物质化学或酶辅助超声预处理工艺的现状及产业化进展综述

IF 8 2区工程技术

Current Opinion in Chemical Engineering Pub Date : 2025-04-03 DOI: 10.1016/j.coche.2025.101124

Salla Kälkäjä , Katja Lappalainen , François Delattre , Jean-Marc Lévêque

{"title":"Current status of chemical- or enzyme-assisted ultrasonic pre-treatment processes for lignocellulosic biomass to assess industrialization progress: A review","authors":"Salla Kälkäjä , Katja Lappalainen , François Delattre , Jean-Marc Lévêque","doi":"10.1016/j.coche.2025.101124","DOIUrl":"10.1016/j.coche.2025.101124","url":null,"abstract":"<div><div>Global warming and rising pollution levels require a paradigm shift from fossil fuels to renewable feedstock. The valorization of lignocellulose, a virtually endless resource, implies the selective extraction of the three main components, cellulose, hemicellulose and lignin, to then treat them separately. Among the methods of pretreatment/preferential dissolution of biomass, low-frequency ultrasound (US) has shown to be a promising disruptive technology. Eager to be combined with physical technologies, chemical agents or enzymes, many examples under low-frequency US exist at the lab scale. However, examples of scaling-up of US-processing of biomass remain yet scarce. It appears quite challenging to design ultrasonic equipment that allows sufficient and homogeneous energy powers in large volumes, although recent pioneering work shows considerable progress. This review aims at highlighting the latest works on biomass pretreatment under chemically or enzymatically assisted ultrasonic irradiation on both lab and pilot/semi-industrial scales together with future directions to enable scale-up of ultrasonic processes for biomass valorization.</div></div>","PeriodicalId":292,"journal":{"name":"Current Opinion in Chemical Engineering","volume":"48 ","pages":"Article 101124"},"PeriodicalIF":8.0,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143768270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ferroelectric BiFeO3 and BaTiO3 photocatalysts for photoelectrochemical water splitting 用于光电化学水分解的铁电BiFeO3和BaTiO3光催化剂

IF 8 2区工程技术

Current Opinion in Chemical Engineering Pub Date : 2025-04-03 DOI: 10.1016/j.coche.2025.101123

Samutr Assavachin , Montree Sawangphruk , Frank E Osterloh

{"title":"Ferroelectric BiFeO3 and BaTiO3 photocatalysts for photoelectrochemical water splitting","authors":"Samutr Assavachin , Montree Sawangphruk , Frank E Osterloh","doi":"10.1016/j.coche.2025.101123","DOIUrl":"10.1016/j.coche.2025.101123","url":null,"abstract":"<div><div>Photocatalytic water splitting offers a sustainable route for hydrogen production but is often hindered by rapid charge carrier recombination and slow kinetics. Traditional strategies to enhance charge separation include solid–solid junctions, facet engineering, and cocatalyst addition. This review explores an alternative approach using ferroelectric materials to improve photoelectrochemical (PEC) water splitting efficiency. Ferroelectric materials exhibit spontaneous electric polarization, generating internal electric fields that modulate band bending at the solid–liquid interface. This intrinsic property enhances charge carrier separation and directs photogenerated electrons and holes toward specific redox sites or cocatalysts. We highlight key studies demonstrating the effectiveness of ferroelectric materials in PEC applications. Electric polarization of BiFeO<sub>3</sub> thin films resulted in controlled enhancement of water oxidation by directly influencing band bending and charge transfer processes. Similarly, BaTiO<sub>3</sub>–TiO<sub>2</sub> core–shell structures with Ni(OH)₂ cocatalysts exhibited improved PEC activity through polarization-mediated charge separation. BaTiO<sub>3</sub> particles also demonstrated enhanced PEC water oxidation and hydrogen evolution in both film and suspension systems due to ferroelectric effects. These findings underscore the potential of ferroelectric materials to optimize charge carrier dynamics in photocatalytic processes for better solar energy conversion.</div></div>","PeriodicalId":292,"journal":{"name":"Current Opinion in Chemical Engineering","volume":"48 ","pages":"Article 101123"},"PeriodicalIF":8.0,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143759124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Micro(nano)plastic and per- and polyfluoroalkyl substances in soil/sediment–water ecosystems: sources, transport, interactions, and challenges 土壤/沉积物-水生态系统中的微（纳米）塑料和全氟烷基和多氟烷基物质：来源、运输、相互作用和挑战

IF 8 2区工程技术

Current Opinion in Chemical Engineering Pub Date : 2025-04-03 DOI: 10.1016/j.coche.2025.101125

Rakesh Kumar , Pawan Kumar Rose , Pushpa Kumari Sharma , Jasmeet Lamba , Manish Kumar , Prosun Bhattacharya

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Perspective in the industrial applications of sonoelectrochemical hydrogen production 超声电化学制氢工业应用展望

IF 8 2区工程技术

Current Opinion in Chemical Engineering Pub Date : 2025-03-31 DOI: 10.1016/j.coche.2025.101122

Md Hujjatul Islam , Bruno G Pollet

{"title":"Perspective in the industrial applications of sonoelectrochemical hydrogen production","authors":"Md Hujjatul Islam , Bruno G Pollet","doi":"10.1016/j.coche.2025.101122","DOIUrl":"10.1016/j.coche.2025.101122","url":null,"abstract":"<div><div><em>Sonoelectrochemistry</em> is the incorporation of power ultrasound in electrochemistry. The use of ultrasound in electrochemical processes such as water electrolysis can lead to an energy efficiency enhancement in the range of 2–25% in low-temperature water electrolysers (LT-WE). However, this improvement greatly depends upon several factors such as the cell reactor design, the ultrasonic frequency, the transmitted acoustic power, and the distance between the ultrasonic transducer and the electrode. The main objectives of this review are to highlight recent advancements in using power ultrasound in water electrolysis and shed some light on possible commercial development by addressing the fundamental obstacles that lie in this technology. Several research works have highlighted that the efficiency improvement in ultrasound-aided water electrolysis is principally due to the gas bubble removal from the electrode surface, which ultimately reduces the ohmic resistance of the electrolytic cell. However, even with the observed higher efficiencies from the <em>sonoelectrolysers</em> for hydrogen production in R&D labs, this technology still faces challenges for further development due to the efficiency in competing with commercial LT-WEs, which are already in the range of 60–70%. If <em>sonoelectrolysers</em> are to succeed for commercial development and large-scale industrial applications, they would need to achieve overall efficiency much higher than current commercial LT-WEs.</div></div>","PeriodicalId":292,"journal":{"name":"Current Opinion in Chemical Engineering","volume":"48 ","pages":"Article 101122"},"PeriodicalIF":8.0,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143739240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0