Corrosion Science最新文献

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High-temperature oxidation resistance of alumina-forming ferritic alloys in a steam-containing atmosphere 含蒸汽气氛中铝形成铁素体合金的高温抗氧化性
IF 7.4 1区 材料科学
Corrosion Science Pub Date : 2025-10-12 DOI: 10.1016/j.corsci.2025.113363
Sang Hun Shim , Sang-Hwa Lee , Heoun Jun Kwon , Dae Won Yun , Jae-Gil Jung , Ka Ram Lim
{"title":"High-temperature oxidation resistance of alumina-forming ferritic alloys in a steam-containing atmosphere","authors":"Sang Hun Shim ,&nbsp;Sang-Hwa Lee ,&nbsp;Heoun Jun Kwon ,&nbsp;Dae Won Yun ,&nbsp;Jae-Gil Jung ,&nbsp;Ka Ram Lim","doi":"10.1016/j.corsci.2025.113363","DOIUrl":"10.1016/j.corsci.2025.113363","url":null,"abstract":"<div><div>In this study, the high-temperature steam oxidation resistance of alumina-forming ferritic alloys (AFF) alloys was investigated. A dense α-Al<sub>2</sub>O<sub>3</sub> film, heterogeneously nucleated beneath pre-formed Fe<sub>2</sub>O<sub>3</sub>/Cr<sub>2</sub>O<sub>3</sub> oxides, effectively suppressed oxygen diffusion into the substrate, resulting in significantly enhanced oxidation resistance compared to commercial austenitic stainless steels (ASS). Upon prolonged exposure at 700 °C in an air-10 % H<sub>2</sub>O atmosphere, AFF alloys exhibited minimal weight change and no surface degradation, unlike conventional ASS alloys. These findings offer valuable insights into the design of cost-effective structural materials that require both high corrosion resistance and mechanical performance. Notably, the AFF alloys demonstrate a favorable balance between these physical properties, positioning them as strong candidates for commercialization in advanced energy systems.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"258 ","pages":"Article 113363"},"PeriodicalIF":7.4,"publicationDate":"2025-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145325998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Achieving robust long-term corrosion resistance and high strength of wrought Mg-Al-Y alloy via introducing continuous precipitates 通过引入连续析出物,实现锻造Mg-Al-Y合金的长期耐腐蚀性和高强度
IF 7.4 1区 材料科学
Corrosion Science Pub Date : 2025-10-11 DOI: 10.1016/j.corsci.2025.113407
Haiyang Wang , Yao Yang , Jie Wang , Yuyang Chen , Xingpeng Liao , Yue Yang , Zhansheng Chen , Tao Ying , Xiaoqin Zeng
{"title":"Achieving robust long-term corrosion resistance and high strength of wrought Mg-Al-Y alloy via introducing continuous precipitates","authors":"Haiyang Wang ,&nbsp;Yao Yang ,&nbsp;Jie Wang ,&nbsp;Yuyang Chen ,&nbsp;Xingpeng Liao ,&nbsp;Yue Yang ,&nbsp;Zhansheng Chen ,&nbsp;Tao Ying ,&nbsp;Xiaoqin Zeng","doi":"10.1016/j.corsci.2025.113407","DOIUrl":"10.1016/j.corsci.2025.113407","url":null,"abstract":"<div><div>The corrosion resistance and strength of the extruded Mg-9Al-0.2Y (wt%) alloy were significantly improved by simple rolling and aging treatment. Compared with the as-extruded alloy, the rolled alloy containing high-density dislocations also exhibits superior corrosion resistance due to the formation of a more compact passive film. Owing to the introduction of dense Mg<sub>17</sub>Al<sub>12</sub> continuous precipitates (CPs), the aged alloy exhibits excellent long-term corrosion resistance and high strength, with a corrosion rate (<em>P</em><sub>w</sub>) of 0.18 mm/y and a yield strength of 284 MPa. The stronger barrier effect of dense CPs on localized corrosion propagation and the formation of a stable Mg-Al LDH passive film are the primary reasons for the superior long-term corrosion resistance of the aged alloy.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"258 ","pages":"Article 113407"},"PeriodicalIF":7.4,"publicationDate":"2025-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145326000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrogen trapping and embrittlement of a high-carbon steel after quenching and high-temperature tempering 高碳钢淬火和高温回火后的氢捕获和脆化
IF 7.4 1区 材料科学
Corrosion Science Pub Date : 2025-10-11 DOI: 10.1016/j.corsci.2025.113408
Jiahao Zhu, Xiaoyuan Li, Wenchao Yu, Xiaofei He, Yongming Yan, Jie Shi, Maoqiu Wang
{"title":"Hydrogen trapping and embrittlement of a high-carbon steel after quenching and high-temperature tempering","authors":"Jiahao Zhu,&nbsp;Xiaoyuan Li,&nbsp;Wenchao Yu,&nbsp;Xiaofei He,&nbsp;Yongming Yan,&nbsp;Jie Shi,&nbsp;Maoqiu Wang","doi":"10.1016/j.corsci.2025.113408","DOIUrl":"10.1016/j.corsci.2025.113408","url":null,"abstract":"<div><div>High-carbon steels after quenching and tempering face hydrogen embrittlement (HE) risk due to their high strength and low ductility. This study investigates hydrogen trapping behavior and HE susceptibility in a quenched and tempered high-carbon steel by means of thermal desorption spectroscopy (TDS), hydrogen microprinting technique (HMT), and slow strain rate tensile (SSRT) tests. Results demonstrate that dislocations act as the primary reversible hydrogen trapping sites, and hydrogen uptake decreases with the decrease of dislocation density from 3.26 × 10<sup>12</sup> cm<sup>−2</sup> in the as-quenched specimen to 4.74 × 10<sup>8</sup> cm<sup>−2</sup> in the specimen tempered at 600 ℃. Cementite/matrix interfaces act as irreversible hydrogen trapping sites, where hydrogen adsorption is governed by heterogeneous strain fields near the interfaces. SSRT results reveal that the specimen tempered at 540 ℃ exhibits high HE susceptibility, with elongation decreasing from 8.9 % to 3.6 % after hydrogen charging. In contrast, the specimen tempered at 600 ℃ retains superior ductility under identical charging conditions, with elongation decreasing from 15.4 % to 12.9 %. HE susceptibility of the experimental steel shows an exponential dependence on hydrogen content, with the fracture mode transitions driven by synergistic hydrogen-enhanced localized plasticity (HELP) and hydrogen-enhanced decohesion (HEDE) mechanisms. This work indicates that optimizing dislocation density and interfacial strain states can effectively mitigate HE risk of high-carbon steels.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"258 ","pages":"Article 113408"},"PeriodicalIF":7.4,"publicationDate":"2025-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145325993","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In situ 2D visualization of hydrogen entry into Zn-coated steels in NaCl solutions: Roles of Zn dissolution and potential distribution 氢在NaCl溶液中进入镀锌钢的原位二维可视化:锌溶解和电位分布的作用
IF 7.4 1区 材料科学
Corrosion Science Pub Date : 2025-10-10 DOI: 10.1016/j.corsci.2025.113386
Hiroshi Kakinuma , Saya Ajito , Koki Okumura , Makoto Akahoshi , Yu Takabatake , Tomohiko Omura , Motomichi Koyama , Eiji Akiyama
{"title":"In situ 2D visualization of hydrogen entry into Zn-coated steels in NaCl solutions: Roles of Zn dissolution and potential distribution","authors":"Hiroshi Kakinuma ,&nbsp;Saya Ajito ,&nbsp;Koki Okumura ,&nbsp;Makoto Akahoshi ,&nbsp;Yu Takabatake ,&nbsp;Tomohiko Omura ,&nbsp;Motomichi Koyama ,&nbsp;Eiji Akiyama","doi":"10.1016/j.corsci.2025.113386","DOIUrl":"10.1016/j.corsci.2025.113386","url":null,"abstract":"<div><div>The hydrogen entry behavior of a partially Zn-coated steel sheet in NaCl solutions was investigated employing a polyaniline-based hydrogenochromic sensor, electrochemical hydrogen permeation tests, and potential measurements using a scanning Kelvin probe. While the Zn coating mitigated corrosion of the steel substrate, it simultaneously accelerated the hydrogen entry. The hydrogen entry occurred at the bare steel surface regions exposed to the NaCl solution, with the hydrogen flux exhibiting non-uniform distribution: higher near the dissolving Zn coating. While no significant differences in Zn dissolution behavior or galvanic current were observed between 0.1 and 0.01 M NaCl solutions, the total hydrogen flux decreased with decreasing Cl<sup>−</sup> concentration. This reduction was attributed to a potential gradient induced by differences in electrolyte conductivity. The results demonstrate that potential distribution, rather than galvanic current, is a dominant factor influencing hydrogen entry under the investigated conditions.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"258 ","pages":"Article 113386"},"PeriodicalIF":7.4,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145325980","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Temperature-dependent micro-mechanisms in thermomechanical fatigue of thermal barrier coating/single-crystal superalloy systems 热障涂层/单晶高温合金热机械疲劳的温度依赖微观机制
IF 7.4 1区 材料科学
Corrosion Science Pub Date : 2025-10-10 DOI: 10.1016/j.corsci.2025.113406
Liyin Zhang , Luqing Cui , Xiaofeng Dang , Zhenyang Cao , Hao Su , Qihu Wang , Sihai Luo , Xiaoqing Liang , Weifeng He , Yinghong Li
{"title":"Temperature-dependent micro-mechanisms in thermomechanical fatigue of thermal barrier coating/single-crystal superalloy systems","authors":"Liyin Zhang ,&nbsp;Luqing Cui ,&nbsp;Xiaofeng Dang ,&nbsp;Zhenyang Cao ,&nbsp;Hao Su ,&nbsp;Qihu Wang ,&nbsp;Sihai Luo ,&nbsp;Xiaoqing Liang ,&nbsp;Weifeng He ,&nbsp;Yinghong Li","doi":"10.1016/j.corsci.2025.113406","DOIUrl":"10.1016/j.corsci.2025.113406","url":null,"abstract":"<div><div>Thermal barrier coating (TBC) is crucial for the performance of single-crystal superalloys (SXs), which are prone to thermomechanical fatigue (TMF) failure under combined thermal and mechanical stresses. Despite this, the underlying mechanisms associated with oxidation-assisted crack propagation and interdiffusion-driven phase transformation in TBC/SX systems have not yet been fully elucidated, particularly regarding temperature effects. In this study, through integrated experimental efforts and state-of-the-art characterization techniques, the fatigue performance and relevant enhancement mechanisms of TBC/SX systems under representative conditions (520°C–900 °C and 600°C–980 °C) were comprehensively investigated. Results demonstrated that the TMF lifespan of SXs was substantially prolonged under all conditions with TBC application, exhibiting distinct temperature dependence, and primarily extending lifespan by prolonging the crack propagation stage. The exceptional oxidation resistance of the TBC layer played a crucial role in performance improvement by altering crack-front plasticity and mitigating oxidation-driven shear strain. Furthermore, the reduced coefficient of thermal expansion (CTE) mismatch between coating and substrate due to γ'-to-γ transformation, the enhanced capacity to release thermal stress resulting from α-Cr dissolution, and the uniform deformation across microstructures facilitated by the cross-slip of screw dislocations were considered as the main contributors to the more pronounced performance enhancement under high-temperature conditions. These findings provide a comprehensive understanding of the temperature-dependent TMF behavior and microstructural evolution mechanisms of TBC/SX systems, which gives new insights to excavate the design potential for multilayered coatings.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"258 ","pages":"Article 113406"},"PeriodicalIF":7.4,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145263760","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Prism-plane-textured Cr2AlC MAX-phase coatings with superior resistance to coupled thermal–salt–steam corrosion 棱柱平面织构的Cr2AlC max相涂层具有优异的耐热-盐-蒸汽耦合腐蚀性能
IF 7.4 1区 材料科学
Corrosion Science Pub Date : 2025-10-09 DOI: 10.1016/j.corsci.2025.113395
Kaixuan Xu , Shenghao Zhou , Zhenyu Wang , Xiaoyu Sun , Kaiwei Yang , Kaihang Wang , Aiying Wang , Peiling Ke
{"title":"Prism-plane-textured Cr2AlC MAX-phase coatings with superior resistance to coupled thermal–salt–steam corrosion","authors":"Kaixuan Xu ,&nbsp;Shenghao Zhou ,&nbsp;Zhenyu Wang ,&nbsp;Xiaoyu Sun ,&nbsp;Kaiwei Yang ,&nbsp;Kaihang Wang ,&nbsp;Aiying Wang ,&nbsp;Peiling Ke","doi":"10.1016/j.corsci.2025.113395","DOIUrl":"10.1016/j.corsci.2025.113395","url":null,"abstract":"<div><div>Conventional protective coatings tend to fail prematurely under the extreme thermal–salt–steam coupled conditions typical of marine and aero-engine operating environments. Here, we present a strategy to enhance corrosion resistance by fabricating Cr<sub>2</sub>AlC MAX-phase coatings with a strong (11<span><math><mover><mrow><mn>2</mn></mrow><mo>¯</mo></mover></math></span>0) prism plane texture, achieved via synchronized pulsed HiPIMS deposition. As a control, a texture-free, equiaxed Cr<sub>2</sub>AlC coating was also prepared. Following a 5 h exposure to a simulated thermal–salt–steam environment at 600 °C, the textured coating demonstrated exceptional corrosion resistance, forming a corrosion scale that was only one-third the thickness of its equiaxed counterpart. Mechanistic investigations revealed that the Prism-plane coating orientation accelerates the formation of a dense, uniform amorphous Al<sub>2</sub>O<sub>3</sub> scale, which acts as an effective barrier against corrosive species. These findings underscore the pivotal role of crystallographic orientation in environmental durability, offering a pathway to design high-performance MAX-phase coatings for extreme service conditions.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"258 ","pages":"Article 113395"},"PeriodicalIF":7.4,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145325999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Gaseous hydrogen permeation behavior of the base metal and weld metal of X42 and X52 pipeline steels under different hydrogen pressure 不同氢气压力下X42和X52管线钢母材和焊缝金属的气体氢渗透行为
IF 7.4 1区 材料科学
Corrosion Science Pub Date : 2025-10-09 DOI: 10.1016/j.corsci.2025.113394
Huiling Wang , Hongliang Ming , Jianqiu Wang , En-Hou Han
{"title":"Gaseous hydrogen permeation behavior of the base metal and weld metal of X42 and X52 pipeline steels under different hydrogen pressure","authors":"Huiling Wang ,&nbsp;Hongliang Ming ,&nbsp;Jianqiu Wang ,&nbsp;En-Hou Han","doi":"10.1016/j.corsci.2025.113394","DOIUrl":"10.1016/j.corsci.2025.113394","url":null,"abstract":"<div><div>The effect of different hydrogen blending ratios in CH<sub>4</sub>+H<sub>2</sub> environment and varying hydrogen pressures in pure H<sub>2</sub> environment on the gaseous hydrogen permeation behavior of base metal (BM) and weld metal (WM) of X42 and X52 pipeline steels were investigated in this study. The appropriate sample thickness for the gaseous hydrogen permeation tests was determined through preliminary experiments. Under the experimental conditions involved in this research, the hydrogen permeation process in all four materials is controlled by bulk diffusion and exhibited thermodynamic non-ideality. The steady-state hydrogen permeation current density is found to be proportional to the 0.5–0.75 power of hydrogen pressure (<span><math><msub><mrow><mi>P</mi></mrow><mrow><msub><mrow><mi>H</mi></mrow><mrow><mn>2</mn></mrow></msub></mrow></msub></math></span>), while the effective hydrogen diffusion coefficient is proportional to approximately the 0.3 power of <span><math><msub><mrow><mi>P</mi></mrow><mrow><msub><mrow><mi>H</mi></mrow><mrow><mn>2</mn></mrow></msub></mrow></msub></math></span>. Furthermore, the microstructure of four materials was analyzed, and their influence on hydrogen permeation behavior was evaluated. X42 WM contains a large amount of acicular ferrite and numerous large-angle grain boundaries, which impose the greatest resistance to hydrogen diffusion. X52 BM has banded F/P structure, where adjacent ferrite bands provide shorter diffusion paths for hydrogen, resulting in the highest effective hydrogen diffusion coefficient. Besides, the hydrogen permeation parameters of X42 BM and X52 WM are comparable.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"258 ","pages":"Article 113394"},"PeriodicalIF":7.4,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145264105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correlation mechanism between corrosion product film evolution and corrosion resistance for 70/30 Cu-Ni alloy combining DFT calculation and experiments 结合DFT计算和实验研究了70/30 Cu-Ni合金腐蚀产物膜演化与耐蚀性的相关机理
IF 7.4 1区 材料科学
Corrosion Science Pub Date : 2025-10-09 DOI: 10.1016/j.corsci.2025.113405
Xiuqi Hu , Ke Gong , Fei Xue , Mingsi Yang , Guoqing Sun , Jiamu Wang , Feixiong Mao , Liping Wang
{"title":"Correlation mechanism between corrosion product film evolution and corrosion resistance for 70/30 Cu-Ni alloy combining DFT calculation and experiments","authors":"Xiuqi Hu ,&nbsp;Ke Gong ,&nbsp;Fei Xue ,&nbsp;Mingsi Yang ,&nbsp;Guoqing Sun ,&nbsp;Jiamu Wang ,&nbsp;Feixiong Mao ,&nbsp;Liping Wang","doi":"10.1016/j.corsci.2025.113405","DOIUrl":"10.1016/j.corsci.2025.113405","url":null,"abstract":"<div><div>The structural evolution of corrosion product films and the associated mechanism of corrosion resistance change in a 70/30 Cu-Ni alloy were investigated using a combination of multi-scale characterization and in situ electrochemical analysis. The results show that the increase in corrosion resistance during the growth of the corrosion product film is attributed to the synergistic effect of Cu and Ni. First, the transformation of the outer Cu<sub>2</sub>O layer from crystalline to amorphous/nanocrystalline structure enhances the resistance of the film to the penetration of aggressive ions. Second, Ni diffuse from the inner layer to the outer layer, doping into the Cu<sub>2</sub>O lattice and substituting Cu in Cu<sub>2</sub>(OH)<sub>3</sub>Cl. This reduces electrical conductivity and enhances the stability of the lattice structure, with DFT calculations providing validation for these effects. These processes enhance the corrosion resistance and stability of the film. The final mature corrosion product film in the static immersion state consists of three layers: the outermost layer of Cu<sub>2</sub>(OH)<sub>3</sub>Cl, the intermediate Cu-rich layer containing Ni-doped Cu<sub>2</sub>O, Cu<sub>2</sub>(OH)<sub>3</sub>Cl and (Cu, Ni)<sub>2</sub>(OH)<sub>3</sub>Cl, the inner Ni-rich layer comprising amorphous and nanocrystalline NiO/Ni(OH)<sub>2</sub>, Cu<sub>2</sub>O, and minor iron oxides.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"258 ","pages":"Article 113405"},"PeriodicalIF":7.4,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145263753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of welding processes on hydrogen embrittlement susceptibility of pipeline steel welded joints 焊接工艺对管道钢焊接接头氢脆敏感性的影响
IF 7.4 1区 材料科学
Corrosion Science Pub Date : 2025-10-08 DOI: 10.1016/j.corsci.2025.113396
Rui Zhang , Cailin Wang , Tianyu Zhang , Huimin Zhang , Cuiwei Liu , Mengze Zhu , Jun Zhang , Yuanxing Ning , Zaiyu Xia , Yuxing Li
{"title":"Effect of welding processes on hydrogen embrittlement susceptibility of pipeline steel welded joints","authors":"Rui Zhang ,&nbsp;Cailin Wang ,&nbsp;Tianyu Zhang ,&nbsp;Huimin Zhang ,&nbsp;Cuiwei Liu ,&nbsp;Mengze Zhu ,&nbsp;Jun Zhang ,&nbsp;Yuanxing Ning ,&nbsp;Zaiyu Xia ,&nbsp;Yuxing Li","doi":"10.1016/j.corsci.2025.113396","DOIUrl":"10.1016/j.corsci.2025.113396","url":null,"abstract":"<div><div>Welds of hydrogen transportation pipelines exhibit high hydrogen embrittlement (HE) susceptibility. To obtain the optimum welding process, the hydrogen compatibility of the 20# steel welds with different welding processes was tested by in-situ gaseous hydrogen permeation and slow strain rate tensile (SSRT) tests. The fracture surface analysis of the welds was also presented. The welding process with the best HE resistance was selected. Moreover, the mechanism between the HE susceptibility and microstructure of the welds was discussed. This study provides a reference for the selection of welding process for long-distance hydrogen pipelines.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"258 ","pages":"Article 113396"},"PeriodicalIF":7.4,"publicationDate":"2025-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145264103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanistic insight into the ferritization of austenite in Pb via a discontinuous reaction governed by a migrating liquid film 由迁移液膜控制的不连续反应对铅中奥氏体铁素化的机理研究
IF 7.4 1区 材料科学
Corrosion Science Pub Date : 2025-10-08 DOI: 10.1016/j.corsci.2025.113398
Kin Wing Wong, Peter Szakálos, Christopher Petersson, Dmitry Grishchenko, Pavel Kudinov
{"title":"Mechanistic insight into the ferritization of austenite in Pb via a discontinuous reaction governed by a migrating liquid film","authors":"Kin Wing Wong,&nbsp;Peter Szakálos,&nbsp;Christopher Petersson,&nbsp;Dmitry Grishchenko,&nbsp;Pavel Kudinov","doi":"10.1016/j.corsci.2025.113398","DOIUrl":"10.1016/j.corsci.2025.113398","url":null,"abstract":"<div><div>The dissolution of austenitic steel in liquid lead-based alloys can induce a phase transformation characterized by a sharp dissolution front separating ferrite and austenite grains, a process commonly referred to as ferritization. Although widely reported, the mechanism driving this transformation remains under debate. This study re-examines ferritization as a discontinuous reaction via a migrating liquid film and proposes a thermodynamically consistent model for the initiation and propagation of the dissolution front. The proposed mechanism is supported by experiments at 500–550°C, literature evidence, and diffusion calculations. Under low oxygen conditions, Cr transport through liquid Pb channels is identified as the rate-limiting step, setting the theoretical corrosion rate in stagnant environments. High-speed erosion-corrosion tests show enhanced corrosion rates, driven by erosion-limited channel lengths that locally boost mass transport. In contrast, under moderate oxygen concentrations relevant for lead-cooled fast reactor (LFR) operation, the rate-limiting step shifts to metal transport across a nanometer-scale amorphous oxide layer at the reaction front. Other Ni-containing austenitic steels, including alumina-forming austenitic (AFA) alloys and Ni-based high-entropy alloys (HEAs) can also be susceptible to discontinuous reactions under direct contact with liquid Pb-based alloys, lacking the self-healing oxide protection as observed in alumina-forming ferritic steels. This limitation may present a concern for the long-term use of bare austenitic steel in liquid Pb environments.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"258 ","pages":"Article 113398"},"PeriodicalIF":7.4,"publicationDate":"2025-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145325994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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