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Regulation of parameters for phase inversion tape casting technology applied in solid oxide fuel cells 固体氧化物燃料电池相变带铸造工艺参数的调整
IF 5.1 2区 材料科学
Ceramics International Pub Date : 2025-04-01 DOI: 10.1016/j.ceramint.2024.12.327
Xiang Guo, Jinshuo Qiao, Zhenhua Wang, Wang Sun, Kening Sun
{"title":"Regulation of parameters for phase inversion tape casting technology applied in solid oxide fuel cells","authors":"Xiang Guo,&nbsp;Jinshuo Qiao,&nbsp;Zhenhua Wang,&nbsp;Wang Sun,&nbsp;Kening Sun","doi":"10.1016/j.ceramint.2024.12.327","DOIUrl":"10.1016/j.ceramint.2024.12.327","url":null,"abstract":"<div><div>This study investigated the effects of patameters of phase inversion tape casting process on the skin-layer and finger-like layer structures of anode of solid oxide fuel cells (SOFCs). The skin-layer structure of anode was studied by controlling the slurry immersion approach during the phase inversion process. Consequently, the anode body with a smooth surface could be obtained when the slurry was immersed in deionized water with a constant speed, via tilted approach. Furthermore, the effects of solid content and polymer concentration on the anode structure were comprehensively studied. With the increase in solid content, the porosity and the size of channels gradually decreased. By contrast, the wall thickness of channel gradually increasesed. The anode with finger-like structure, prepared with a solid content of 65 wt% and polymer concentration of 25 wt%, exhibited the best suitable structure for gas diffusion, which is conducive to developing SOFCs based on finger-like structure.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 9","pages":"Pages 10998-11005"},"PeriodicalIF":5.1,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143815348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multilayer scaffolds designed with bioinspired topography for bone regeneration 采用仿生地形设计的多层支架用于骨再生
IF 5.1 2区 材料科学
Ceramics International Pub Date : 2025-04-01 DOI: 10.1016/j.ceramint.2025.01.180
Paula M. Riosalido , Pablo Velásquez , Ángel Murciano , Piedad N. De Aza
{"title":"Multilayer scaffolds designed with bioinspired topography for bone regeneration","authors":"Paula M. Riosalido ,&nbsp;Pablo Velásquez ,&nbsp;Ángel Murciano ,&nbsp;Piedad N. De Aza","doi":"10.1016/j.ceramint.2025.01.180","DOIUrl":"10.1016/j.ceramint.2025.01.180","url":null,"abstract":"<div><div>In this investigation, three distinct multiphasic scaffolds, comprising primary crystalline phases of SiO₂, Ca₂P₂O₇, and Ca₃(PO₄)₂, were developed. These scaffolds feature surface coatings that have been functionalised with Na, K, and varying molar proportions of Mg (0–1%). The samples were extensively characterised to evaluate a number of key properties including microstructure, porosity, mechanical properties, biodegradation profile, biocompatibility and <em>in vitro</em> bioactivity. The scaffolds demonstrated a mechanical strength of 1.8 MPa, accompanied by a high macroporosity of over 85 % and micropores ranging from 200 to 6 μm. All scaffolds showed bioactivity. Notably, CS0.7 Mg exhibited a distinctive topography characterised by non-periodic, irregular lamellae at both the micro- and nanoscale. During the bioactivity assays, the lamellae were progressively covered by HA until they were completely obscured after 14 days in SBF. This bioactive behaviour was accompanied by gradual degradation in PBS, with a 15 % weight loss over 21 days, indicating suitability for bone regeneration. In addition, ICP-OES analysis demonstrated ionic exchange from the scaffolds into the culture medium at both concentrations of 15 mg/mL and 30 mg/mL, which promoted the proliferation of 3T3 fibroblasts. Cells seeded on the CS0.7 Mg scaffold also showed sustained cell proliferation over time. This proliferation was found to be influenced by the topography of the scaffold, with the greatest enhancement observed in the CS0.7 Mg-7D samples, which had HA-covered lamellae.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 10","pages":"Pages 13363-13373"},"PeriodicalIF":5.1,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143815559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biocompatibility and corrosion performance of HA-based LVOF sprayed and post-annealed coatings on SS 254 surgical-grade bio-implant material SS 254外科级生物植入材料上ha基LVOF喷涂和退火涂层的生物相容性和腐蚀性能
IF 5.1 2区 材料科学
Ceramics International Pub Date : 2025-04-01 DOI: 10.1016/j.ceramint.2025.01.166
Praveen Kumar Verma , Hitesh Vasudev , Vinod Kumar
{"title":"Biocompatibility and corrosion performance of HA-based LVOF sprayed and post-annealed coatings on SS 254 surgical-grade bio-implant material","authors":"Praveen Kumar Verma ,&nbsp;Hitesh Vasudev ,&nbsp;Vinod Kumar","doi":"10.1016/j.ceramint.2025.01.166","DOIUrl":"10.1016/j.ceramint.2025.01.166","url":null,"abstract":"<div><div>The UNS 31254 (SS 254) stainless steel has a wide range of medical applications. However, its low biomedical and corrosion resistance limits its use in the medical field. To address this challenge, the Low-Velocity Oxy-Fuel (LVOF) technique was used to apply coatings of hydroxyapatite (HA), (HA+10 wt% micrometric - Al₂O₃), and (HA+10 wt% nanometric-Al₂O<sub>3</sub>) to the SS 254 substrate. The reinforced HA coatings were annealed at 400 °C and 800 °C for 2 h. Field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), electrochemical corrosion tests, and in-vitro bioactivity investigations were used to evaluate the performance of coatings. The XRD analysis revealed the phases present and assessed the crystallinity of the coatings. Additionally, the sintering effect produced by annealing resulted in a notable decrease in porosity. The annealing of HALN at 800 °C for 2 h has minimized the undesired phases (α-TCP and β-TCP) developed during coating thereby leading to improved crystallinity and densification of the coatings. The enhancement in annealing temperature increased the coating's corrosion resistance and reduced the bioactivity of coatings.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 10","pages":"Pages 13207-13225"},"PeriodicalIF":5.1,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143815588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Data-driven optimized XGBoost and LightGBM for predicting the Judd-Ofelt parameters in rare-earth doped phosphate-based glasses 基于数据驱动优化的XGBoost和LightGBM预测稀土掺杂磷酸盐基玻璃中Judd-Ofelt参数
IF 5.1 2区 材料科学
Ceramics International Pub Date : 2025-04-01 DOI: 10.1016/j.ceramint.2025.01.177
Fahimeh Ahmadi , Mohsen Hajihassani , Stefanos Papanikolaou , Panagiotis G. Asteris
{"title":"Data-driven optimized XGBoost and LightGBM for predicting the Judd-Ofelt parameters in rare-earth doped phosphate-based glasses","authors":"Fahimeh Ahmadi ,&nbsp;Mohsen Hajihassani ,&nbsp;Stefanos Papanikolaou ,&nbsp;Panagiotis G. Asteris","doi":"10.1016/j.ceramint.2025.01.177","DOIUrl":"10.1016/j.ceramint.2025.01.177","url":null,"abstract":"<div><div>Advanced machine learning models, and more specifically the XGBoost and LightGBM models with Grey Wolf Optimization (GWO), can be utilized towards the prediction of the Judd-Ofelt (JO) parameters in rare-earth doped phosphate-based glasses. The JO parameters (<span><math><mrow><msub><mi>Ω</mi><mn>2</mn></msub></mrow></math></span>, <span><math><mrow><msub><mi>Ω</mi><mn>4</mn></msub></mrow></math></span>, and <span><math><mrow><msub><mi>Ω</mi><mn>6</mn></msub></mrow></math></span>) are critical for evaluating optical properties of rare-earth-doped materials, which are essential in applications, such as solid-state lasers, optical amplifiers, and three-dimensional displays. Traditional methods for estimating JO parameters involve complex methodologies that are particularly challenging for nanomaterials and powders. The use of the GWO-optimized XGBoost and LightGBM models promotes a novel and efficient approach to predict these parameters with high accuracy. The results of this study demonstrate that the combined GWO-LightGBM model outperforms others, achieving the lowest Mean Absolute Error (MAE) of 0.640 and the highest R<sup>2</sup> of 0.972 for predicting <span><math><mrow><msub><mi>Ω</mi><mn>2</mn></msub></mrow></math></span>, with comparable performance for <span><math><mrow><msub><mi>Ω</mi><mn>4</mn></msub></mrow></math></span> and <span><math><mrow><msub><mi>Ω</mi><mn>6</mn></msub></mrow></math></span>. This innovative approach simplifies the parameter estimation methodology and significantly enhances predictive accuracy, offering a valuable tool for the development of advanced optical materials.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 10","pages":"Pages 13330-13344"},"PeriodicalIF":5.1,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143815668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High adsorption capacities of rhodamine B dye by activated carbon synthesized from cotton stalks agricultural waste by chemical activation 以农业废棉秸秆为原料化学活化合成的活性炭对罗丹明B染料具有较高的吸附性能
IF 5.1 2区 材料科学
Ceramics International Pub Date : 2025-04-01 DOI: 10.1016/j.ceramint.2025.01.178
A. Venkatesan , B. Srividhya , Abdalrahman Alajmi , Abdellatif M. Sadeq , Rama Krishna Chava , Mohamed A. Habila , D. Senthil Kumar , L. Guganathan , S. Ragupathy
{"title":"High adsorption capacities of rhodamine B dye by activated carbon synthesized from cotton stalks agricultural waste by chemical activation","authors":"A. Venkatesan ,&nbsp;B. Srividhya ,&nbsp;Abdalrahman Alajmi ,&nbsp;Abdellatif M. Sadeq ,&nbsp;Rama Krishna Chava ,&nbsp;Mohamed A. Habila ,&nbsp;D. Senthil Kumar ,&nbsp;L. Guganathan ,&nbsp;S. Ragupathy","doi":"10.1016/j.ceramint.2025.01.178","DOIUrl":"10.1016/j.ceramint.2025.01.178","url":null,"abstract":"<div><div>The worldwide water issue had been made worse by water contamination. The development of sustainable techniques to reduce water pollution was urgently needed because dye effluents constituted a major hazard to both the environment and human health. This paper described a simple process for producing cotton stalk-activated carbon (CSAC) using H<sub>3</sub>PO<sub>4</sub> activation and agricultural waste (cotton stalks). The CS impregnation ratios of 1:1 and 1:2 were prepared, and they were named CSAC1 and CSAC2, respectively. Using a range of analytical methods, the produced materials' physical-chemical characteristics were examined. The prepared CSAC2 had a BET specific surface area of 461 m<sup>2</sup>g<sup>−1</sup>. Additionally, CSAC2 material was employed for the adsorption of Rhodamine B (RhB) dye from aqueous solutions. However, the parameters of time, pH, dose, and dye concentration on the removal efficiency of dye were assessed. The isotherm modeling of the adsorption data over the concentration range (20–100 mg/L) was performed using non-linear regression analysis. In addition, it was shown to have &gt;99.5 % removal efficiency and the adsorption isotherms of dye were significantly described by the Langmuir model with maximum adsorption capacities of 144.36 mgg<sup>−1</sup> for RhB. The kinetic modeling revealed that the experimental data followed the pseudo-first order and pseudo-second order rate equations for CSAC2. The negative ΔG° and positive ΔH° values indicated spontaneous and endothermic adsorption process. The work's findings demonstrate that CSAC2, which can be produced quickly, is a great environmentally friendly adsorbent for removing dye from contaminated water.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 10","pages":"Pages 13345-13354"},"PeriodicalIF":5.1,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143815669","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Large low-field cryogenic magnetocaloric effect in ferromagnetic NaNd1-xEuxO2 (x=0, 0.05 and 0.1) compounds 铁磁性 NaNd1-xEuxO2(x=0、0.05 和 0.1)化合物中的大型低磁场低温磁致效应
IF 5.1 2区 材料科学
Ceramics International Pub Date : 2025-04-01 DOI: 10.1016/j.ceramint.2025.01.108
Yingwei Wu , Naikun Sun , Meiling Li , Xinguo Zhao , Juan Cheng , Jiaohong Huang
{"title":"Large low-field cryogenic magnetocaloric effect in ferromagnetic NaNd1-xEuxO2 (x=0, 0.05 and 0.1) compounds","authors":"Yingwei Wu ,&nbsp;Naikun Sun ,&nbsp;Meiling Li ,&nbsp;Xinguo Zhao ,&nbsp;Juan Cheng ,&nbsp;Jiaohong Huang","doi":"10.1016/j.ceramint.2025.01.108","DOIUrl":"10.1016/j.ceramint.2025.01.108","url":null,"abstract":"<div><div>Heavy rare-earth (<em>RE</em>)-based oxides possessing large magnetocaloric effect (MCE) have great application prospects in ultra-low-temperature magnetocaloric cooling. However, their large MCE based on the antiferromagnetic (AFM) ordering of heavy <em>RE</em> ions were generally obtained under high magnetic field changes. In this work, light <em>RE</em>-based tetragonal NaNd<sub>1-x</sub>Eu<sub>x</sub>O<sub>2</sub> (x = 0, 0.05, 0.1) compounds (<em>I</em>4<sub>1</sub>/<em>amd</em> space group) were prepared by a facile ball-milling assisted sintering method. These oxides exhibit a second-order ferromagnetic (FM) to paramagnetic transition (PM) transition at the Curie temperature (<em>T</em><sub>C</sub>) of 2.4 K to below 2 K, which is accompanied by an excellent low-field magnetocaloric cooling performance. In 0–1 T, a large magnetic entropy change Δ<em>S</em><sub>M</sub> of 7.7, 7.6 and 7 J kg<sup>−1</sup> K<sup>−1</sup> was obtained at 2.5 K in NaNd<sub>1-x</sub>Eu<sub>x</sub>O<sub>2</sub> for x = 0, 0.05 and 0.1, respectively. These values are approximately twice as much as that for the commercial gallium gadolinium garnet (GGG) material (3.9 J kg<sup>−1</sup> K<sup>−1</sup>, at 2 K). More favorably, these compounds show negligible coercivity and hysteretic loss, indicating reversibility of the large MCE. Eu<sup>3+</sup> doping leads to a decrease of both the lattice constants and lengths of the Nd-O and Na-O bonds, accompanied by a lowering of <em>T</em><sub>C</sub> and a decrease of effective magnetic moments of the <em>RE</em><sup>3+</sup>. The excellent low-field MCE in the light <em>RE</em>-based FM oxides provides a novel insight for exploring suitable cryogenic magnetic refrigeration materials.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 10","pages":"Pages 12682-12690"},"PeriodicalIF":5.1,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143815094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Visible-light-assisted hydrogen generation over silver oxide supported zinc tungstate nanostructured photocatalysts 以氧化银为支撑的钨酸锌纳米结构光催化剂在可见光辅助下制氢
IF 5.1 2区 材料科学
Ceramics International Pub Date : 2025-04-01 DOI: 10.1016/j.ceramint.2024.12.552
Ibraheem A. Mkhalid
{"title":"Visible-light-assisted hydrogen generation over silver oxide supported zinc tungstate nanostructured photocatalysts","authors":"Ibraheem A. Mkhalid","doi":"10.1016/j.ceramint.2024.12.552","DOIUrl":"10.1016/j.ceramint.2024.12.552","url":null,"abstract":"<div><div>Significant efforts are being made to find alternative energy resources due to the extensive consumption of fossil fuels, in addition to their pollution issues. Hydrogen (H<sub>2</sub>) signifies the future alternative energy source due to its lightweight and ecological nature. Lately, hydrogen has been produced over semiconductor photocatalysts under light irradiation. Regarding this, zinc tungstate (ZnWO<sub>4</sub>) nanorods have been prepared by a modified sol-gel route in the presence of polymeric surfactant. The visible light harvesting is boosted by supporting ZnWO<sub>4</sub> with trace amounts (0.5–2.0 wt%) of silver oxide (Ag<sub>2</sub>O) nanoparticles. Diverse depiction apparatuses appraised the prepared nanomaterials. The outcomes exposed the synergetic influence of supporting ZnWO<sub>4</sub> with Ag<sub>2</sub>O in charge recombination suppression and separation. The Ag<sub>2</sub>O/ZnWO<sub>4</sub> was utilized for the generation of H<sub>2</sub> under visible-light irradiation from the water/glycerol mixture. The 1.5 wt% Ag<sub>2</sub>O/ZnWO<sub>4</sub> revealed the narrowest calculated bandgap of 2.29 eV and the highest photoactivity. The specific surface area also recorded 115 m<sup>2</sup> g<sup>−1</sup>. The evolution rate of H<sub>2</sub> is enhanced up to ∼90 times (2.425 mmol g<sup>−1</sup>h<sup>−1</sup>) employing 1.5 wt% Ag<sub>2</sub>O/ZnWO<sub>4</sub> relative to pure ZnWO<sub>4</sub>. Furthermore, the optimized dose of 2.0 mg mL<sup>−1</sup> has promoted the photocatalytic evolution of H<sub>2</sub> up to 3.155 mmol g<sup>−1</sup>h<sup>−1</sup> with a recyclable applicability of 94.1 %.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 9","pages":"Pages 11338-11345"},"PeriodicalIF":5.1,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143815065","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Narrow gap semiconductor to metal transition in GdNiSb under pressure 压力下钆镍锑窄隙半导体到金属的转变 P-18
IF 5.1 2区 材料科学
Ceramics International Pub Date : 2025-04-01 DOI: 10.1016/j.ceramint.2024.09.251
Roman D. Mukhachev , Semyon T. Baidak , Alexey V. Lukoyanov
{"title":"Narrow gap semiconductor to metal transition in GdNiSb under pressure","authors":"Roman D. Mukhachev ,&nbsp;Semyon T. Baidak ,&nbsp;Alexey V. Lukoyanov","doi":"10.1016/j.ceramint.2024.09.251","DOIUrl":"10.1016/j.ceramint.2024.09.251","url":null,"abstract":"<div><div>The electronic structure of the GdNiSb compound under pressure has been investigated in the course of first-principles calculations accounting for spin-orbit coupling. At ambient conditions this compound is found to be a narrow gap semiconductor with an indirect band gap of 0.38 eV. Decreasing in the cell volume leads to a gradual redistribution of the density of states caused by band broadening and partial delocalization of the electronic states, in particular the 3d Ni states are strongly modified. The band gap is closed when the volume of the lattice decreases by 35 % or more with a slight metallization at the Fermi energy with the appearance of the Fermi surfaces. For the smaller volumes, the metallic states with non-trivial topological features are calculated for GdNiSb.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 10","pages":"Pages 12330-12336"},"PeriodicalIF":5.1,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142262611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-temperature evolution of microstructure, electrical properties and transverse thermoelectric performance in La1-xCaxMnO3 thin films La1-xCaxMnO3薄膜微观结构、电学性能和横向热电性能的高温演化
IF 5.1 2区 材料科学
Ceramics International Pub Date : 2025-04-01 DOI: 10.1016/j.ceramint.2025.01.153
Xi Chen , Bowan Tao , Ruipeng Zhao , Kai Yang , Zhenzhe Li , Tian Xie , Mingyuan Zhao , Guoliang Ming , Yuhang Yu , Hongbo Tian , Chang Wei , Hongxu Zhu , Yudong Xia
{"title":"High-temperature evolution of microstructure, electrical properties and transverse thermoelectric performance in La1-xCaxMnO3 thin films","authors":"Xi Chen ,&nbsp;Bowan Tao ,&nbsp;Ruipeng Zhao ,&nbsp;Kai Yang ,&nbsp;Zhenzhe Li ,&nbsp;Tian Xie ,&nbsp;Mingyuan Zhao ,&nbsp;Guoliang Ming ,&nbsp;Yuhang Yu ,&nbsp;Hongbo Tian ,&nbsp;Chang Wei ,&nbsp;Hongxu Zhu ,&nbsp;Yudong Xia","doi":"10.1016/j.ceramint.2025.01.153","DOIUrl":"10.1016/j.ceramint.2025.01.153","url":null,"abstract":"<div><div>High-frequency heat flux measurement is vital for the design of the hypersonic vehicle thermal protection system. La<sub>1-x</sub>Ca<sub>x</sub>MnO<sub>3</sub> (LCMO) thin-film heat flux sensor based on the transverse thermoelectric effect has significant advantages due to its high-frequency response characteristics. Aiming at extremely high-temperature environments, the high-temperature evolution of microstructure and transverse thermoelectric performance of LCMO thin film are revealed. With the heat treatment temperature not beyond 1300 °C, LCMO can maintain stable electrical properties and transverse thermoelectric properties, with a sensitivity of ∼8 μV/(kW/m<sup>2</sup>) and response frequency of ∼220 kHz. With the increase in temperature, the electrical properties of LCMO thin films gradually deteriorate due to atom diffusion, aggregation and escape, so the response speed slows. But LCMO still maintains normal transverse thermoelectric properties after heat treatment with 1450 °C for 1 h, showing strong survivability. This work lays a foundation for developing and applying high-temperature LCMO thin-film heat flux sensors.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 10","pages":"Pages 13069-13076"},"PeriodicalIF":5.1,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143815159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The mechanical and biological performance of zinc-containing micro-arc oxidation film on titanium implant 含锌微弧氧化膜在钛种植体上的力学和生物学性能
IF 5.1 2区 材料科学
Ceramics International Pub Date : 2025-04-01 DOI: 10.1016/j.ceramint.2025.01.155
Jianghui Zhao , Lei Liu , Fengcang Ma , Ping Liu , Shengcai Qi , Wei Li , Ke Zhang , Xiaohong Chen
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