Advances in Colloid and Interface Science最新文献

{"title":"Recent development of metal-organic frameworks and their composites in electromagnetic wave absorption and shielding applications","authors":"Kexin Wei ,&nbsp;Yang Shi ,&nbsp;Xin Tan ,&nbsp;Marwan Shalash ,&nbsp;Juanna Ren ,&nbsp;Abeer A. Faheim ,&nbsp;Chong Jia ,&nbsp;Runzhou Huang ,&nbsp;Yequan Sheng ,&nbsp;Zhanhu Guo ,&nbsp;Shengbo Ge","doi":"10.1016/j.cis.2024.103271","DOIUrl":"10.1016/j.cis.2024.103271","url":null,"abstract":"<div><p>With the rapid development of information and communication industries, the usage of electromagnetic waves has caused the hazard of human health and misfunction of devices. The adsorption and shielding of electromagnetic waves have been achieved in various materials. The unique adjustable spatial structure makes metal-organic frameworks (MOFs) promising for electromagnetic shielding and adsorbing. As MOFs research advances, various large-scale MOF-based materials have been developed. For instance, MOFs spatial structure has been expanded from 2D to 3D to load more ligands. Progress in synthetic methods for MOFs and their derivatives is advancing, with priority on large-scale preparation and green synthesis. This review summarizes the methods for synthesizing MOFs and their derivatives, and explores the effects of MOFs spatial structure on electromagnetic interference (EMI) shielding and electromagnetic wave absorption capabilities. At the same time, detailed examples are used to focus on the applications of five different MOFs composites in electromagnetic shielding and electromagnetic wave absorption. Finally, the current challenges and prospects of MOFs in the electromagnetic field are introduced, providing a useful reference for the preparation and design of MOFs and their composites for electromagnetic wave processing applications.</p></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"332 ","pages":"Article 103271"},"PeriodicalIF":15.9,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141984862","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"3D printing of Pickering emulsions, Pickering foams and capillary suspensions – A review of stabilization, rheology and applications","authors":"Andrew T. Tyowua ,&nbsp;David Harbottle ,&nbsp;Bernard P. Binks","doi":"10.1016/j.cis.2024.103274","DOIUrl":"10.1016/j.cis.2024.103274","url":null,"abstract":"<div><p>Pickering emulsions and foams as well as capillary suspensions are becoming increasingly more popular as inks for 3D printing. However, a lack of understanding of the bulk rheological properties needed for their application in 3D printing is potentially stifling growth in the area, hence the timeliness of this review. Herein, we review the stability and bulk rheology of these materials as well as the applications of their 3D-printed products. By highlighting how the bulk rheology is tuned, and specifically the inks storage modulus, yield stress and critical balance between the two, we present a rheological performance map showing regions where good prints and slumps are observed thus providing clear guidance for future ink formulations. To further advance this field, we also suggest standard experimental protocols for characterizing the bulk rheology of the three types of ink: capillary suspension, Pickering emulsion and Pickering foam for 3D printing by direct ink writing.</p></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"332 ","pages":"Article 103274"},"PeriodicalIF":15.9,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142002109","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Defect and Heterostructure engineering assisted S-scheme Nb2O5 nanosystems-based solutions for environmental pollution and energy conversion","authors":"Karambir Singh ,&nbsp;Abhimanyu ,&nbsp;Sonu Sonu ,&nbsp;Vishal Chaudhary ,&nbsp;Pankaj Raizada ,&nbsp;Sarvesh Rustagi ,&nbsp;Pardeep Singh ,&nbsp;Pankaj Thakur ,&nbsp;Vinod Kumar ,&nbsp;Ajeet Kaushik","doi":"10.1016/j.cis.2024.103273","DOIUrl":"10.1016/j.cis.2024.103273","url":null,"abstract":"<div><p>This review explores the crystallographic versatility of niobium pentoxide (Nb₂O₅) at the nanoscale, showcasing enhanced catalytic efficiency for cutting-edge sustainable energy and environmental applications. The synthesis strategies explored encompass defect engineering, doping engineering, s-scheme formation, and heterojunction engineering to fine-tune the physicochemical attributes of diverse dimensional (0-D, 1-D, 2-D, and 3-D) Nb₂O₅ nanosystems as per targeted application. In addressing escalating environmental challenges, Nb₂O₅ emerges as a semiconductor photocatalyst with transformative potential, spanning applications from dye degradation to antibiotic and metal removal. Beyond its environmental impact, Nb₂O₅ is pivotal in sustainable energy applications, specifically in carbon dioxide and hydrogen conversion. However, challenges such as limited light absorption efficiency and scalability in production methods prompt the need for targeted research endeavors. The review details the state-of-the-art Nb₂O₅ nanosystems engineering, tuning their physicochemical properties employing material engineering, and their high catalytic performance in environment remediation and energy generation. It outlines challenges, potential mitigation strategies, and prospects, urging for developing greener synthesis routes, advanced charge transfer techniques, targeted optimization for specific pollutants, and application for micro/nano plastics photocatalytic reduction. As researchers and environmental stewards collaborate, Nb₂O₅ stands poised at the intersection of environmental remediation, energy harvesting, and nanomaterial advancements, offering a beacon of progress toward a cleaner, more sustainable future.</p></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"332 ","pages":"Article 103273"},"PeriodicalIF":15.9,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141914789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"On the temperature dependence of surface tension: Historical perspective on the Eötvös equation of capillarity, celebrating his 175th anniversary","authors":"George Kaptay","doi":"10.1016/j.cis.2024.103275","DOIUrl":"10.1016/j.cis.2024.103275","url":null,"abstract":"<div><p>The Hungarian baron Roland Eötvös (Eötvös Loránd, 1848–1919) lived in the difficult period between two revolutions in Hungary, but nevertheless he achieved revolutionary results in two fields of science: capillarity (1875–1886) and gravity (after 1886). This paper describes his famous capillary equation published in 1886 in the world-language of the time (German) and in one of the most famous scientific journals of the time (Annalen der Physik und Chemie). In his paper he showed a simple equation for the temperature dependence of surface tension of one-component liquids and more importantly he showed that this quantity approaches zero as temperature tends towards the critical temperature. This result was achieved by measuring the surface tension of 160 (!) different liquids along their boiling lines as function of temperature, in a home-made high-pressure high-temperature equipment, probably the first one of this kind. In this way he extended the meaning of the critical point previously introduced by van der Waals. In this paper, also a modern model of surface tension of one-component liquids is discussed, simplified and compared to the Eötvös equation. It is also shown, how the Avogadro number and the molecular sizes can be determined from the experimental results of Eötvös (note: the Avogadro number was estimated with reasonable accuracy for the first time by Einstein in 1905 from the kinetic theory of liquids). Apparently, it was not that easy to do back in 1886: this becomes obvious from the 1911-paper by Einstein, who gave a wrong estimate for the diameter of Hg atoms (5.19 nm) using the data of Eötvös (the correct value is around 0.3 nm). The Appendix to this paper contains the summary of 1543 handwritten pages on surface tension by Eötvös, including the on-line availability of all pdf files. Note also, that Eötvös used <em>g</em> = 10.0 m/s² for acceleration due gravity and so he over-estimated his surface tension values and also his Eötvös constant by about 2.0%. The corrected Eötvös constant using his measured values but the correct <em>g</em>-value would be “0.222” vs his published value of “0.227”. Probably this uncertainty in the value of <em>g</em> was one of the motives that pushed Eötvös to study gravity after 1886.</p></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"332 ","pages":"Article 103275"},"PeriodicalIF":15.9,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0001868624001982/pdfft?md5=c2306fe8920b520219adb5b87c97011a&pid=1-s2.0-S0001868624001982-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141979019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Single-cell encapsulation systems for probiotic delivery: Armor probiotics","authors":"Runan Zhao ,&nbsp;Ting Yu ,&nbsp;Jiaheng Li ,&nbsp;Ruihao Niu ,&nbsp;Donghong Liu ,&nbsp;Wenjun Wang","doi":"10.1016/j.cis.2024.103270","DOIUrl":"10.1016/j.cis.2024.103270","url":null,"abstract":"<div><p>Functional foods or drugs based on probiotics have gained unprecedented attention and development due to the increasingly clear relationship between probiotics and human health. Probiotics can regulate intestinal microbiota, dynamically participating in various physiological activities to directly affect human health. Some probiotic-based functional preparations have shown great potential in treating multiple refractory diseases. Currently, the survival and activity of probiotic cells in complex environments in vitro and in vivo have taken priority, and various encapsulation systems based on food-derived materials have been designed and constructed to protect and deliver probiotics. However, traditional encapsulation technology cannot achieve precise protection for a single probiotic, which makes it unable to have a significant effect after release. In this case, single-cell encapsulation systems can be assembled based on biological interfaces to protect and functionalize individual probiotic cells, maximizing their physiological activity. This review discussed the arduous challenges of probiotics in food processing, storage, human digestion, and the commonly used probiotic encapsulation system. Besides, a novel technology of probiotic encapsulation was introduced based on single-cell coating, namely, “armor probiotics”. We focused on the classification, structural design, and functional characteristics of armor coatings, and emphasized the essential functional characteristics of armor probiotics in human health regulation, including regulating intestinal health and targeted bioimaging and treatment of diseased tissues. Subsequently, the benefits, limitations, potential challenges, as well as future direction of armor probiotics were put forward. We hope this review may provide new insights and ideas for developing a single-cell probiotics encapsulating system.</p></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"332 ","pages":"Article 103270"},"PeriodicalIF":15.9,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141984104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Self-standing membranes for separation: Achievements and opportunities","authors":"Yunhao Liu ,&nbsp;Cailong Zhou ,&nbsp;Li Chen ,&nbsp;Jingcheng Du ,&nbsp;Qun Li ,&nbsp;Chenyang Lu ,&nbsp;Luxi Tan ,&nbsp;Xiaowei Huang ,&nbsp;Jiangtao Liu ,&nbsp;Lichun Dong","doi":"10.1016/j.cis.2024.103269","DOIUrl":"10.1016/j.cis.2024.103269","url":null,"abstract":"<div><p>Supported membranes and mixed matrix membranes have a limitation of harming the mass transfer due to the incompatibility between the support layer or the matrix and the active components of the membrane. Self-standing membranes, which could structurally abandon the support layer, altogether avoid the adverse effect, thus greatly facilitating the transmembrane mass transfer process. However, the abandonment of the support layer also reduces the membrane's mechanical properties and formability. In this review, our emphasis will be on self-standing membranes within the realm of materials and separation engineering. We will explore the materials employed in the fabrication of self-standing membranes, highlighting their ability to simultaneously enhance membrane performance and promote self-standing characteristics. Additionally, we will delve into the diverse techniques utilized for crafting self-standing membranes, encompassing interfacial polymerization, filtration, solvent casting, Langmuir-Blodgett &amp; layer-by-layer assembly, electrospinning, compression, etc. Throughout the discussion, the merits and drawbacks associated with each of these preparation methods were elucidated. We also provide a brief overview of the applications of self-standing membranes, including water purification, gas separation, organic solvent nanofiltration, electrochemistry, and membrane reactor, as well as a brief description of the general strategies for performance enhancement of self-standing membranes. Finally, the current status of self-standing membranes and the challenges they may encounter were discussed.</p></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"332 ","pages":"Article 103269"},"PeriodicalIF":15.9,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141918303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Flexible self-supporting photonic crystals: Fabrications and responsive structural colors","authors":"Zhipeng Meng ,&nbsp;Yukun Liu ,&nbsp;Haofei Huang ,&nbsp;Suli Wu","doi":"10.1016/j.cis.2024.103272","DOIUrl":"10.1016/j.cis.2024.103272","url":null,"abstract":"<div><p>Photonic crystals (PCs) play an increasingly significant role in anti-counterfeiting, sensors, displays, and other fields due to their tunable structural colors produced by light manipulation of photonic stop bands. Flexible self-supporting photonic crystals (FSPCs) eliminate the requirement for conventional structures to rely on the existence of hard substrates, as well as the problem of poor mechanical qualities caused by the stiffness of the building blocks. Meanwhile, diverse production techniques and materials provide FSPCs with varied stimulus-responsive color-changing capacities, thus they have received an abundance of focus. This review summarizes the preparation strategies and variable structural colors of FSPCs. First, a series of preparation strategies by integrating polymers with PCs are summarized, including assembly of colloidal spheres on flexible substrates, polymer packaging, polymer-based direct assembly, nanoimprinting, and 3D printing. Subsequently, variable structural colors of FSPCs with different stimulations, such as viewing angle, chemical stimulation (solvents, ions, pH, biomolecules, etc.), temperature, mechanical/magnetic stress, and light, are described in detail. Finally, the outlook and challenges regarding FSPCs are presented, and several potential directions for their fabrication and application are discussed. It's believed that FSPCs will be a valuable platform for advancing the practical implementation of optical metamaterials.</p></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"333 ","pages":"Article 103272"},"PeriodicalIF":15.9,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142095642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hybridization of metal-organic frameworks and MXenes: Expanding horizons in supercapacitor applications","authors":"Latisha Gaba ,&nbsp;Priya Siwach ,&nbsp;Kanika Aggarwal ,&nbsp;Sajjan Dahiya ,&nbsp;Rajesh Punia ,&nbsp;A.S. Maan ,&nbsp;Kuldeep Singh ,&nbsp;Anil Ohlan","doi":"10.1016/j.cis.2024.103268","DOIUrl":"10.1016/j.cis.2024.103268","url":null,"abstract":"<div><p>Metal-organic frameworks (MOFs) and MXenes have gained prominence in the queue of advanced material research. Both materials' outstanding physical and chemical characteristics prominently promote their utilization in diverse fields, especially the electrochemical energy storage (EES) domain. The collective contribution of extremely high specific surface area (SSA), customizable pores, and abundant active sites propose MOFs as integral materials for EES devices. However, conventional MOFs endure low conductivity, constraining their utility in practical applications. The development of hybrid materials via integrating MOFs with various conductive materials stands out as an effective approach to improvising MOF's conductivity. MXenes, formulated as two-dimensional (2D) carbides and nitrides of transition metals, fall in the category of the latest 2D materials. MXenes possess extensive structural diversity, impressive conductivity, and rich surface chemical characteristics. The electrochemical characteristics of MOF@MXene hybrids outperform MOFs and MXenes individually, credited to the synergistic effect of both components. Additionally, the MOF derivatives coupled with MXene, exhibiting unique morphologies, demonstrate outstanding electrochemical performance. The important attributes of MOF@MXene hybrids, including the various synthesis protocols, have been summarized in this review. This review delves into the architectural analysis of both MOFs and MXenes, along with their advanced hybrids. Furthermore, the comprehensive survey of the latest advancements in MOF@MXene hybrids as electroactive material for supercapacitors (SCs) is the prime objective of this review. The review concludes with an elaborate discussion of the current challenges faced and the future outlooks for optimizing MOF@MXene composites.</p></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"332 ","pages":"Article 103268"},"PeriodicalIF":15.9,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141914790","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Progress and challenges in bacterial infection theranostics based on functional metal nanoparticles","authors":"Zengchao Guo ,&nbsp;Hui Jiang ,&nbsp;Aiguo Song ,&nbsp;Xiaohui Liu ,&nbsp;Xuemei Wang","doi":"10.1016/j.cis.2024.103265","DOIUrl":"10.1016/j.cis.2024.103265","url":null,"abstract":"<div><p>The rapid proliferation and infection of bacteria, especially multidrug-resistant bacteria, have become a great threat to global public health. Focusing on the emergence of “super drug-resistant bacteria” caused by the abuse of antibiotics and the insufficient and delayed early diagnosis of bacterial diseases, it is of great research significance to develop new technologies and methods for early targeted detection and treatment of bacterial infection. The exceptional effects of metal nanoparticles based on their unique physical and chemical properties make such systems ideal for the detection and treatment of bacterial infection both in vitro and in vivo. Metal nanoparticles also have admirable clinical application prospects due to their broad antibacterial spectrum, various antibacterial mechanisms and excellent biocompatibility. Herein, we summarized the research progress concerning the mechanism of metal nanoparticles in terms of antibacterial activity together with the detection of bacterial. Representative achievements are selected to illustrate the proof-of-concept in vitro and in vivo applications. Based on these observations, we also give a brief discussion on the current problems and perspective outlook of metal nanoparticles in the diagnosis and treatment of bacterial infection.</p></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"332 ","pages":"Article 103265"},"PeriodicalIF":15.9,"publicationDate":"2024-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141914792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Locomotion behavior of air bubbles on solid surfaces","authors":"Jing Wang ,&nbsp;Zhiguang Guo ,&nbsp;Feiyan Fu","doi":"10.1016/j.cis.2024.103266","DOIUrl":"10.1016/j.cis.2024.103266","url":null,"abstract":"<div><p>Air bubbles are a common occurrence in both natural and industrial settings and are a significant topic in the fields of physics, chemistry, engineering, and medicine. The physical phenomena of the contact between bubbles and submerged solid surfaces, as well as the locomotion behavior of bubbles, are worth exploring. Bubbles are generated in an unbounded liquid environment and rise due to unbalanced external forces. Bubbles of different diameters follow different ascending paths, after which they approach, touch, collide, bounce, and finally adsorb to the solid surface, forming a stable three-phase contact line (TPCL). The bubbles are in an unstable state due to the unbalanced external forces on the solid surface and the effects generated by the two-phase contact surface, resulting in different locomotion behaviors on the solid surface. Studying the formation, transport, aggregation, and rupture behaviors of bubbles on solid surfaces can enable the controllable operation of bubbles. This, in turn, can effectively reduce the loss of mechanical apparatus in agro-industrial production activities and improve corresponding production efficiency. Recent research has shown that the degree of bubble wetting on a solid surface is a crucial factor in the locomotion behavior of bubbles on that surface. This has led to significant progress in the study of bubble wetting, which has in turn greatly advanced our understanding of bubble behavior. Based on this, exploring the manipulation process of the directional motion of bubbles is a promising research direction. The locomotion behavior of bubbles on solid surfaces can be controlled by changing external conditions, leading to the integration of bubble behavior in various scientific and technological fields. Studying the dynamics of bubbles in liquids with infinite boundaries is worthwhile. Additionally, the manipulation process and mode of these bubbles is a popular research direction.</p></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"332 ","pages":"Article 103266"},"PeriodicalIF":15.9,"publicationDate":"2024-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141993055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}