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Sustainable nanocellulose coating for EPS geofoam extracted from agricultural waste 从农业废弃物中提取的可持续纳米纤维素涂层用于发泡聚苯乙烯土工泡沫。
IF 7.1 2区 环境科学与生态学
Waste management Pub Date : 2024-11-11 DOI: 10.1016/j.wasman.2024.11.011
Rana Adel , Irene Samy Fahim , Emad S. Bakhoum , Ahmed M. Ahmed , Sherif S. AbdelSalam
{"title":"Sustainable nanocellulose coating for EPS geofoam extracted from agricultural waste","authors":"Rana Adel ,&nbsp;Irene Samy Fahim ,&nbsp;Emad S. Bakhoum ,&nbsp;Ahmed M. Ahmed ,&nbsp;Sherif S. AbdelSalam","doi":"10.1016/j.wasman.2024.11.011","DOIUrl":"10.1016/j.wasman.2024.11.011","url":null,"abstract":"<div><div>Expanded polystyrene (EPS) geofoam blocks are gaining acceptance across industries due to their low density, insulation properties, strength, compressibility, and shock absorption under dynamic loads. The effective application of EPS is impeded by restrictions imposed by using conventional polymer-based synthetic geomembrane insulation ought for protection. Meanwhile, the production process of the geomembrane has detrimental environmental impacts, incurs high costs, and limits the utilization of EPS blocks in various applications. This research aims to create an innovative nanocoating substance using nanocellulose derived from agricultural residues to provide an eco-friendly alternative to geomembranes. The nanocellulose was extracted from four agricultural waste materials; sugarcane bagasse, banana fibers, rice straw, and spent-ground coffee; where each had a local percentage yield of 35 %, 25 %, 19 %, and 10 %, respectively. Based upon a technical criterion provided by the transmission electron microscopy (TEM) micrographs, the TOPSIS multi-criteria decision-making method was used to rank the sustainability of waste materials. It was found that sugarcane bagasse (SCB) is the most sustainable type with the smallest nano particle size. Nanocellulose extracted from SCB was characterized using X-ray diffraction (XRD), energy dispersive X-ray (EDX), nuclear magnetic resonance (NMR), and Fourier transform infrared spectroscopy (FTIR). The innovative nanocellulose coating primarily consisted of a nanocellulose mixture (SCB + water), polyvinyl acetate (PVA), and zinc oxide. Fourteen distinct formulas were obtained to identify the optimal proportions suitable for application on EPS surface with respect to the nano particle size, purity, and binding energy between the elements. It was found that the optimum formula consists of 42 % SCB, 50 % PVA, and 8 % zinc oxide.</div></div>","PeriodicalId":23969,"journal":{"name":"Waste management","volume":"191 ","pages":"Pages 135-146"},"PeriodicalIF":7.1,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142629309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Valorization of organic waste through black soldier fly: On the way of a real circular bioeconomy process 通过黑兵蝇实现有机废物的价值化:迈向真正的循环生物经济进程。
IF 7.1 2区 环境科学与生态学
Waste management Pub Date : 2024-11-11 DOI: 10.1016/j.wasman.2024.10.030
Daniele Bruno , Marco Orlando , Edoardo Testa , Marco Carnevale Miino , Giulia Pesaro , Matteo Miceli , Loredano Pollegioni , Vincenzina Barbera , Elisa Fasoli , Lorenza Draghi , Alberto Pietro Damiano Baltrocchi , Navarro Ferronato , Raffaello Seri , Elena Maggi , Silvia Caccia , Morena Casartelli , Gianluca Molla , Maurizio Stefano Galimberti , Vincenzo Torretta , Andrea Vezzulli , Gianluca Tettamanti
{"title":"Valorization of organic waste through black soldier fly: On the way of a real circular bioeconomy process","authors":"Daniele Bruno ,&nbsp;Marco Orlando ,&nbsp;Edoardo Testa ,&nbsp;Marco Carnevale Miino ,&nbsp;Giulia Pesaro ,&nbsp;Matteo Miceli ,&nbsp;Loredano Pollegioni ,&nbsp;Vincenzina Barbera ,&nbsp;Elisa Fasoli ,&nbsp;Lorenza Draghi ,&nbsp;Alberto Pietro Damiano Baltrocchi ,&nbsp;Navarro Ferronato ,&nbsp;Raffaello Seri ,&nbsp;Elena Maggi ,&nbsp;Silvia Caccia ,&nbsp;Morena Casartelli ,&nbsp;Gianluca Molla ,&nbsp;Maurizio Stefano Galimberti ,&nbsp;Vincenzo Torretta ,&nbsp;Andrea Vezzulli ,&nbsp;Gianluca Tettamanti","doi":"10.1016/j.wasman.2024.10.030","DOIUrl":"10.1016/j.wasman.2024.10.030","url":null,"abstract":"<div><div>The transition from a linear to a circular production system involves transforming waste into valuable resources. Insect-mediated bioconversion, particularly using black soldier fly (BSF) larvae, can offer a promising opportunity to convert the organic fraction of municipal solid waste (OFMSW) into protein-rich biomass. However, current regulatory restrictions do not allow the use of this substrate to obtain insect proteins for animal feed, prompting the exploration of other applications, such as the production of bioplastics. Here, we explored at laboratory scale an innovative and integrated circular supply chain which aims to valorize the OFMSW through BSF larvae for the production of biobased materials with high technological value. BSF larvae reared on this organic waste showed excellent growth performance and bioconversion rate of the substrate. The use of well-suited extraction methods allowed the isolation of high-purity lipids, proteins, and chitin fractions, which are building blocks to produce biobased materials. In particular, the protein fraction was used to develop biodegradable plastic films which showed potential for replacing traditional petroleum-based materials, with the possibility to be fully recycled back to amino acids. Socioeconomic analysis highlighted values generated along the entire supply chain, and life cycle assessment pointed out that lipid extraction was the most challenging step: implementation of more sustainable methods is thus needed to reduce the overall environmental impact of the proposed chain. In conclusion, this study represents a proof of concept gathering evidence to support the feasibility of an alternative supply chain that can promote circular economy while valorising organic waste.</div></div>","PeriodicalId":23969,"journal":{"name":"Waste management","volume":"191 ","pages":"Pages 123-134"},"PeriodicalIF":7.1,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142629311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biodegradable waste does not always degrade faster than plastic 可生物降解的废物并不一定比塑料降解得快。
IF 7.1 2区 环境科学与生态学
Waste management Pub Date : 2024-11-11 DOI: 10.1016/j.wasman.2024.11.012
Frederik Dalgaard Kjaer , François-Xavier Joly
{"title":"Biodegradable waste does not always degrade faster than plastic","authors":"Frederik Dalgaard Kjaer ,&nbsp;François-Xavier Joly","doi":"10.1016/j.wasman.2024.11.012","DOIUrl":"10.1016/j.wasman.2024.11.012","url":null,"abstract":"<div><div>Plastic pollution has become a global environmental issue, with between 22 and 48 millions of tons of plastic waste accumulating in the environment annually. Transitioning from conventional plastics to biodegradable materials for single-use items could limit this accumulation, but the degradation advantage of biodegradable material over plastic lacks empirical evidence from <em>in situ</em> experiments. Here, we compared the short-term degradation of seven single-use items (e.g., shopping bags, take-away boxes), made from plastic and biodegradable materials, in both marine and terrestrial environments. Biodegradable items tended to degrade faster than their plastic counterparts, but this advantage occurred in less than half of the situations tested (6 out of 14 situations). Notably, biodegradable items degraded faster than plastic counterparts more often in the terrestrial (5 out of 7 items) compared to the marine (1 out of 7 items). Interestingly, biodegradable items made of plant-based materials, such as bagasse and cellulose, generally degraded more rapidly than plastic, while those made of polylactic acid rarely degraded faster than plastic. We conclude that biodegradable single-use items should not be disposed of in the environment and require adequate waste management, and we encourage future research on the long-term degradation of biodegradable items in a range of environments.</div></div>","PeriodicalId":23969,"journal":{"name":"Waste management","volume":"191 ","pages":"Pages 117-122"},"PeriodicalIF":7.1,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142629291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Life cycle optimization oriented to sustainable waste management and circular economy: A review 以可持续废物管理和循环经济为导向的生命周期优化:综述。
IF 7.1 2区 环境科学与生态学
Waste management Pub Date : 2024-11-09 DOI: 10.1016/j.wasman.2024.11.001
Dandan Zhao , Yong Chen , Haoran Yuan , Dezhen Chen
{"title":"Life cycle optimization oriented to sustainable waste management and circular economy: A review","authors":"Dandan Zhao ,&nbsp;Yong Chen ,&nbsp;Haoran Yuan ,&nbsp;Dezhen Chen","doi":"10.1016/j.wasman.2024.11.001","DOIUrl":"10.1016/j.wasman.2024.11.001","url":null,"abstract":"<div><div>Life cycle optimization (LCO) is an effective decision-making method combining life cycle assessment and optimization, which is capable of adjusting system configurations to meet specified sustainability goals. This study analyzed the status quo of LCO studies related to sustainable waste management and the circular economy. Most studies have focused on simultaneously optimizing environmental and economic objectives, whereas few have considered social impacts. Greenhouse gas emissions is the most commonly used environmental indicator in optimization, followed by the endpoint single-score indicator. A static deterministic model is often employed to formulate an LCO problem, while uncertainty and dynamic models are less frequently applied but cause concerns. To deal with multi-objective optimization, the ε-constraint method and non-dominated sorting genetic algorithm are popular. Waste LCO has been mainly applied to macro system planning, such as integrated municipal solid waste management systems, biowaste supply chains, waste-to-energy systems, and waste-to-resource networks, aiming to determine optimal waste allocation, facility capacity/location, technology choice, etc. It is occasionally used in optimizing process structure, operating conditions, blending ratio of feedstocks, and product development. Future research should focus on exploring the integration of more environmental and social indicators into multi-objective optimization, modeling under uncertainty, dynamic LCO, process and product optimization, and addressing the lack of multi-scale studies.</div></div>","PeriodicalId":23969,"journal":{"name":"Waste management","volume":"191 ","pages":"Pages 89-106"},"PeriodicalIF":7.1,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142629300","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mitigation of zinc leaching from waste ground tire rubbers through polymer encapsulation 通过聚合物封装减轻废旧轮胎橡胶中的锌浸出。
IF 7.1 2区 环境科学与生态学
Waste management Pub Date : 2024-11-09 DOI: 10.1016/j.wasman.2024.11.008
Muhammad Adeel , Yanou Fishel , Johan Blom , Freddy Dardenne , Bart Michielsen , Jef Bergmans , Lorenz Van Nueten , Cedric Vuye , Christophe M.L. Vande Velde , Pieter Billen
{"title":"Mitigation of zinc leaching from waste ground tire rubbers through polymer encapsulation","authors":"Muhammad Adeel ,&nbsp;Yanou Fishel ,&nbsp;Johan Blom ,&nbsp;Freddy Dardenne ,&nbsp;Bart Michielsen ,&nbsp;Jef Bergmans ,&nbsp;Lorenz Van Nueten ,&nbsp;Cedric Vuye ,&nbsp;Christophe M.L. Vande Velde ,&nbsp;Pieter Billen","doi":"10.1016/j.wasman.2024.11.008","DOIUrl":"10.1016/j.wasman.2024.11.008","url":null,"abstract":"<div><div>The increasing disposal of waste tires is a growing environmental challenge requiring innovative recycling and reuse approaches. Crumb rubber, derived from end-of-life tires, has potential for various applications where resilience and elasticity are required. However, as highlighted by the upcoming ban on using crumb rubber granulate as infill for artificial turf in the EU, one of the most prominent issues, zinc leaching, urgently requires an effective solution. We studied a range of commercial polymer coatings as a zinc leaching barrier through batch and column leaching tests. This study demonstrates that coatings can reduce the leaching down to 1 % of that of uncoated rubber, reducing environmental risks while improving the prospects for continued use of crumb rubber in various applications. The physico-chemical relation between the coating structure and zinc leaching is elucidated for the most promising coatings by comparing the leaching results with FTIR, GPC and <sup>1</sup>H NMR analyses. The use of certain additives shows a cumulative effect to further reduce zinc leaching, while improving UV- and moisture stability. Thermal stability is controlled by the stability of the polymer base. These findings allow us to tailor the mechanical properties to various applications requiring specific elasticity and durability, while retaining the versatility and adaptability of crumb rubber in a range of scenarios. Additionally, the use of additives, typically cheaper than the polymer matrix, enhances the economic viability. By effectively controlling zinc leaching and tailoring mechanical properties through coatings, this study offers a way to extend the life and utility of waste rubbers.</div></div>","PeriodicalId":23969,"journal":{"name":"Waste management","volume":"191 ","pages":"Pages 107-116"},"PeriodicalIF":7.1,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142629303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Insights into sulfur migration and transformation during the magnetization roasting of iron tailings and textile dyeing sludge 铁尾矿和纺织印染污泥磁化焙烧过程中硫迁移和转化的启示。
IF 7.1 2区 环境科学与生态学
Waste management Pub Date : 2024-11-08 DOI: 10.1016/j.wasman.2024.11.005
Xiqing Cui, Xunan Ning, Jianyi Zhang, Dingyuan Zhang, Guoqiang Qiu, Yi Wang
{"title":"Insights into sulfur migration and transformation during the magnetization roasting of iron tailings and textile dyeing sludge","authors":"Xiqing Cui,&nbsp;Xunan Ning,&nbsp;Jianyi Zhang,&nbsp;Dingyuan Zhang,&nbsp;Guoqiang Qiu,&nbsp;Yi Wang","doi":"10.1016/j.wasman.2024.11.005","DOIUrl":"10.1016/j.wasman.2024.11.005","url":null,"abstract":"<div><div>Magnetization roasting of iron tailings (IT) is an effective method to recovery fine iron concentrate (IC) from refractory IT. However, the migration and transformation of sulfur during the roasting process remain unclear, impacting iron quality if sulfur content exceeds the allowable limit value. This study investigates the sulfur release and fixation during magnetization roasting of textile dyeing sludge (TDS) and IT, elucidating the sulfur migration and transformation processes. Results indicate that 31.7 % of sulfur migrates to the gas phase due to the thermal decomposition of organic-S and the reduction of high-valent sulfur to SO<sub>2</sub> by H<sub>2</sub> and CO. The total sulfur (TS) content in tailing slag (TSL) (1.96 %) is significantly higher than that in the roasted product (RP) (0.84 %), suggesting a tendency for sulfur migration into TSL. This migration is attributed to reactions between H<sub>2</sub>S/COS and Fe<sub>2</sub>O<sub>3</sub>/Fe<sub>3</sub>O<sub>4</sub>, resulting in the formation of non-magnetic byproduct FeS. Additionally, due to the symbiosis of hematite and sulfate, sulfur in the IC primarily exists as sulfate sulfur (76.98 %). This research is crucial for quality control in iron ore processing and provides theoretical guidance for sulfur regulation in practical production processes.</div></div>","PeriodicalId":23969,"journal":{"name":"Waste management","volume":"191 ","pages":"Pages 81-88"},"PeriodicalIF":7.1,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142629298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Low-carbon and high-value utilization of hazardous industrial organic waste: From molecular mechanism to application 危险工业有机废物的低碳和高价值利用:从分子机制到应用。
IF 7.1 2区 环境科学与生态学
Waste management Pub Date : 2024-11-07 DOI: 10.1016/j.wasman.2024.11.007
Ying Tian , Sichao Cai , Yuansen Li , Lin He , Hong Sui
{"title":"Low-carbon and high-value utilization of hazardous industrial organic waste: From molecular mechanism to application","authors":"Ying Tian ,&nbsp;Sichao Cai ,&nbsp;Yuansen Li ,&nbsp;Lin He ,&nbsp;Hong Sui","doi":"10.1016/j.wasman.2024.11.007","DOIUrl":"10.1016/j.wasman.2024.11.007","url":null,"abstract":"<div><div>The management of large volumes of hazardous organic waste poses remarkable challenges due to costs and environmental pollution in industrial processes. Developing a universal strategy for recycling such waste is crucial for environmental protection. Herein, a reaction-based strategy has been proposed to recover and recycle the heavy phenolic slag wastes (HPSW) in a high-valued way. After analyzing the chemical structure of HPSW, the polycondensation method has been used to convert HPSW into an activated carbon adhesive (ACA) through reaction between phenolic hydroxyl groups and formaldehyde. The newly prepared activated carbon sample (AC-12, at optimal conditions) exhibited a high iodine value of 1320.80 mg·g<sup>−1</sup> and a specific surface area of 1368.8 m<sup>2</sup>·g<sup>−1</sup>. It demonstrates high efficiency in adsorbing organic pollutants from both gaseous (<em>p</em>-xylene vapor) and liquid phases (methylene blue), with an equilibration time under 15 min, achieving the standard of high-end commercial ACs. This environmentally friendly and cost-effective method offers innovative approaches for the resourceful recycling and treatment of various types of organic waste, facilitating the efficient utilization and disposal of hazardous organic solid wastes in industries.</div></div>","PeriodicalId":23969,"journal":{"name":"Waste management","volume":"191 ","pages":"Pages 56-69"},"PeriodicalIF":7.1,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142606128","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Data-centric approach for instance segmentation in optical waste sorting 以数据为中心的光学垃圾分类实例分割方法。
IF 7.1 2区 环境科学与生态学
Waste management Pub Date : 2024-11-07 DOI: 10.1016/j.wasman.2024.11.002
Anna Iliushina , Gleb Mazanov , Sergey Nesteruk , Andrey Pimenov , Anton Stepanov , Nadezhda Mikhaylova , Anna Baldycheva , Andrey Somov
{"title":"Data-centric approach for instance segmentation in optical waste sorting","authors":"Anna Iliushina ,&nbsp;Gleb Mazanov ,&nbsp;Sergey Nesteruk ,&nbsp;Andrey Pimenov ,&nbsp;Anton Stepanov ,&nbsp;Nadezhda Mikhaylova ,&nbsp;Anna Baldycheva ,&nbsp;Andrey Somov","doi":"10.1016/j.wasman.2024.11.002","DOIUrl":"10.1016/j.wasman.2024.11.002","url":null,"abstract":"<div><div>Computer vision systems have been integrated into facilities dealing with the sorting of household waste. This solution allows for the sorting efficiency improvement and cost reduction. However, challenges associated with the poor annotation quality of existing waste segmentation datasets, unsuitable environment for recognition on a conveyor belt, or limited data for creating an effective and cost-efficient sorting system using visible range cameras significantly limit the application efficiency of computer vision systems. In this article, we report on the data-centric pipeline for enhancing the precision of predictions in multiclass household waste segmentation on a conveyor belt. In particular, we have demonstrated that by employing a pseudo-annotation approach combined with an object-based data augmentation algorithm, it is possible to train a model on a set of ’simple’ images and achieve satisfactory results when estimating the model on a set of ’complex’ images. We collected and prepared the dataset consisting of 5 k manually labeled data and additionally 10 k pseudo-labeled data by object-based augmentation. The proposed pipeline incorporates data balancing, transfer learning, and pseudo-labeling to improve the mean Average Precision (mAP) of the YOLOV8 segmentation model from 67 % to 83 % for ’simple’ use case scenarios and from 42 % to 59 % or ’complex’ industrial solutions.</div></div>","PeriodicalId":23969,"journal":{"name":"Waste management","volume":"191 ","pages":"Pages 70-80"},"PeriodicalIF":7.1,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142606118","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Triple water rinsing does not always render waste plastic pesticide containers non-hazardous waste 三倍水冲洗并不总能使废弃塑料杀虫剂容器成为无害废物
IF 7.1 2区 环境科学与生态学
Waste management Pub Date : 2024-11-06 DOI: 10.1016/j.wasman.2024.11.004
Georgios Garbounis , Helen Karasali , Dimitrios Komilis
{"title":"Triple water rinsing does not always render waste plastic pesticide containers non-hazardous waste","authors":"Georgios Garbounis ,&nbsp;Helen Karasali ,&nbsp;Dimitrios Komilis","doi":"10.1016/j.wasman.2024.11.004","DOIUrl":"10.1016/j.wasman.2024.11.004","url":null,"abstract":"<div><div>After pesticide application onto crops, waste plastic pesticide containers (WPPC) may still contain residual active substances (AS) that are typically hazardous. Specific limits exist per pesticide active substance to classify WPPC as hazardous or non-hazardous wastes. The most frequent limit is 0.1% w/w (mass of active substance per mass of as received container). Triple rinsing is a widely used management technique to decontaminate WPPC and determine their downstream management. However, its efficiency needs to be evaluated for new types of pesticides. The goal of the work was to measure the residual contents of 15 new pesticide AS, widely used all over the world, before and after triple rinsing using 56 WPPC. In addition, the contents of pesticide AS sorbed onto the plastic containers are analyzed for the first time. Results show that all unrinsed WPPC had residual AS contents above the hazard limits except for four AS. Triple rinsing removed from 68.3% (minimum) to 99.9% (maximum) of the liquid contents of 15 active substances. However, due to high variances of the AS contents after triple rinsing, mean values before and after rinsing were statistically equal for 8 out of 14 AS. The sorbed AS contents ranged from 3% to 97% of the total AS content. Only Azoxystrobin’s total content (i.e. the sum of liquid and sorbed phases) slightly exceeded the hazard limit of 0.1% w/w. Conclusively, triple rinsing may not always lead to AS content reductions below hazard limits. The sorbed contents should be considered to check legal compliances.</div></div>","PeriodicalId":23969,"journal":{"name":"Waste management","volume":"191 ","pages":"Pages 47-55"},"PeriodicalIF":7.1,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142592671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Promoting effect of ammonia oxidation on sulfur oxidation during composting: Nitrate as a bridge 堆肥过程中氨氧化对硫氧化的促进作用:硝酸盐作为桥梁
IF 7.1 2区 环境科学与生态学
Waste management Pub Date : 2024-11-05 DOI: 10.1016/j.wasman.2024.10.032
Lingxiao Wang, Zhiping Ren, Zhao Xu, Lixin Liu, Ruixue Chang, Yanming Li
{"title":"Promoting effect of ammonia oxidation on sulfur oxidation during composting: Nitrate as a bridge","authors":"Lingxiao Wang,&nbsp;Zhiping Ren,&nbsp;Zhao Xu,&nbsp;Lixin Liu,&nbsp;Ruixue Chang,&nbsp;Yanming Li","doi":"10.1016/j.wasman.2024.10.032","DOIUrl":"10.1016/j.wasman.2024.10.032","url":null,"abstract":"<div><div>Ammonia (NH<sub>3</sub>) and hydrogen sulfide (H<sub>2</sub>S) are the main odor components in the composting process. Controlling their emissions is very important to reduce environmental pollution and improve the quality of composting products. This study explored the effects of functional bacteria on nitrogen and sulfur metabolism in the composting process of food waste (FW) by adding ammonia-oxidizing bacteria (AOB, A treatment), sulfur-oxidizing bacteria (SOB, S treatment), and combined AOB and SOB (AS treatment), respectively. The key bacterial species involved in nitrogen and sulfur transformation were identified, and the intrinsic mechanisms by which ammonia oxidation drove sulfur oxidation during composting were deciphered. Compared with control treatment (CK), the combined addition of functional microorganisms increased the maximum of <em>soxB</em> gene abundance by 1.72 times, thus resulting in the increase in the SO<sub>4</sub><sup>2-</sup> content by 44.00 %. AS treatment decreased the cumulative H<sub>2</sub>S emission and total sulfur (TS) loss by 40.24 % and 34.69 %, respectively, meanwhile lowering NH<sub>3</sub> emission. Correlation network analysis showed that the simultaneous addition of AOB and SOB enhanced the correlation between microorganisms and sulfur oxidation genes, and <em>Acinetobacter</em>, <em>Aeribacillus</em>, <em>Brevibacterium</em> and <em>Ureibacillus</em> might be involved in the ammonia oxidation-promoted sulfur oxidation process. In summary, the optimized inoculation strategy of AOB and SOB could drive biological transformation of nitrogen and sulfur by regulating microbial community, ultimately reducing odor emissions and improving sulfur conservation.</div></div>","PeriodicalId":23969,"journal":{"name":"Waste management","volume":"191 ","pages":"Pages 13-22"},"PeriodicalIF":7.1,"publicationDate":"2024-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142586597","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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