Water SA最新文献

{"title":"Monitoring seasonal variations of haloacetic acids (HAAS) in low-TOC and low-chlorine networks and assessing risk to public health: Muş, Türkiye case","authors":"E. Avşar, Adile Kılıç","doi":"10.17159/wsa/2023.v49.i3.4004","DOIUrl":"https://doi.org/10.17159/wsa/2023.v49.i3.4004","url":null,"abstract":"Chlorine not only removes parasitic pathogenic microorganisms in water, but also causes the formation of disinfection by-products (DBPs) that can be carcinogenic to humans, due to  reacting with natural organic matter (NOMs) in raw water sources. Haloacetic acids (HAAs) are one of the most well-known and common disinfection by-product groups (DBPs) in the literature.  In the risk definitions of the EPA, some of its components have been identified as carcinogenic. Therefore, determination of HAA concentration in water and execution of a risk analysis are very important in terms of determining the possible effects on public health. This study aimed to monitor the seasonal and spatial variations of haloacetic acids (HAAs) in 2 different water supplies (surface and groundwater) serving the city center of Muş Province, Türkiye, and to demonstrate their public health implications. In this context, an analytical study was conducted covering 4 seasons. According to the results, although the amount of NOM in water bodies was less than 1 mg‧L−1, the HAA5 content may occasionally exceed the USEPA limits of 60 µg‧L−1, but did not exceed the Canadian 80 µg‧L−1 limit. When the WHO limit values were examined on a component basis, it was determined that the MCAA concentrations in both water sources sometimes exceeded the limit of 20 µg‧L−1 in the July and October sampling periods. The risk level related to maximum DCAA level in the main network by means of ingestion pathway was found to be 18.7 times higher for women and 16.5 times higher for men when compared with USEPA risk criteria. Also, in the Muratpaşa water network, risk from DCAA exceeds the USEPA risk level 15.2-fold in women and 13.4-fold in men. However, since it was also found that the level of free chlorine in the network does not meet the required level, it should be noted that there may be an increase in the risk level if there is adequate chlorination in the supply.","PeriodicalId":23623,"journal":{"name":"Water SA","volume":"72 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74672397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The effect of the linear alkylbenzene sulfonate, sodium-dodecyl-sulfonate (SDS), on the bioaccumulation of Al, Sr and Mn by Brassica oleracea and Solanum tuberosum","authors":"G. Pindihama, M. Gitari","doi":"10.17159/wsa/2023.v49.i3.4008","DOIUrl":"https://doi.org/10.17159/wsa/2023.v49.i3.4008","url":null,"abstract":"The hyper-eutrophic conditions in impoundments used for irrigation around South Africa’s major cities promote the co-existence of linear alkylbenzene sulfonate (LAS) and other pollutants such as metals. The combined effects of LAS and metals, when such water is used to irrigate crops, has not been properly investigated in light of human health risks and prevailing local conditions. To understand the potential risks, pot-culture experiments were conducted to assess the effect of the LAS, sodium-dodecyl-sulfonate (SDS), on the accumulation of aluminum (Al), manganese (Mn) and strontium (Sr) in Brassica oleracea (cabbage) and Solanum tuberosum (potato) plants. The plants were watered with dam water containing 3.48 mg‧L−1 of the LAS (sodium dodecyl sulfonate) and Mn (0.257 mg‧L−1), Al (0.6 mg‧L−1) and Sr (0.16 mg‧L−1) as determined by field surveys, for 20 days. The presence of SDS in the irrigation water at environmentally relevant concentrations did not enhance uptake of Sr, Mn, Al in the two plants, as demonstrated by statistically insignificant differences in the means of the treatments (with and without SDS). In addition, the presence of the metals, high pH, EC and presence of cyanotoxins in the water did not affect total chlorophyll and growth of the plants. These findings imply that the prevailing levels of anionic surfactants such as SDS, metals and other contaminants in the hyper-eutrophic reservoirs pose little risk to crop yields, quality of crops and human health, due to the possible accumulation of these contaminants in irrigated plants. Despite the study reporting no immediate inherent risk to the plants and human health, continuous monitoring of the contaminants in water, soil and irrigated plants is recommended since the conditions, concentrations and other factors can quickly change if the management of the catchment does not improve in the near future.","PeriodicalId":23623,"journal":{"name":"Water SA","volume":"20 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78641608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Relationships between reference site quality and baetid mayfly assemblages in mountainous streams of the Luvuvhu catchment, South Africa","authors":"P. Ramulifho, N. Rivers‐Moore, S. Foord","doi":"10.17159/wsa/2023.v49.i3.4023","DOIUrl":"https://doi.org/10.17159/wsa/2023.v49.i3.4023","url":null,"abstract":"With water quality deteriorating rapidly at a global scale, river sections suited to serve as reference sites are being increasingly lost. It thus becomes critical to develop rapid methods to confirm that previously monitored sites continue meet the requirements of reliable reference sites. In the absence of pristine sites, 9 near-natural sites, as defined by the Kleynhans (1996) classification, were used as reference sites for the Luvuvhu River catchment to compare the quality of physico-chemical factors against a biological metric. Baetid mayfly community structure at a site was chosen as an index of water quality, since this family is common in all types of freshwaters, highly diverse and adapted to unpolluted running water. Baetid larvae were sampled monthly from stones-in-current biotopes across 9 sites for over 1 year, between December 2016 and January 2018. A Spearman’s correlation test was used to evaluate the relationship between physico-chemical factors and identify redundant variables. Water quality standards were measured against the national water quality guidelines for aquatic ecosystems. We used a generalized linear model to determine the effect of physico-chemical variables on baetid species, and canonical correspondence analysis to show the relationships between baetid species, sites, and physico-chemical variables. A total of 3 039 individuals belonging to 12 mayfly species were recorded. Our findings indicated that while the physico-chemical factors were highly variable, they were within favourable ranges to reflect reference site conditions. While water temperature was the most important driver of baetid community structure in general, as it negatively affected their abundances, a subset of species (Pseudoponnota sp., Pseudocloeon sp., Acanthiops varius and Demoulinia crassi) showed clear responses to changes in TDS and stream width. We conclude that specific baetid species show good potential as biological indicators of reference sites and chronic water temperature stress, making assessment of reference sites easier.","PeriodicalId":23623,"journal":{"name":"Water SA","volume":"43 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82531226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The inability of organic coagulants to purify potable water to its best attainable quality","authors":"P. Polášek, CJ Wantenaar","doi":"10.17159/wsa/2023.v49.i3.3906","DOIUrl":"https://doi.org/10.17159/wsa/2023.v49.i3.3906","url":null,"abstract":"Organic coagulants have gained increasing popularity over the past 30 years because they are considered cheaper and more user-friendly than traditional mineral hydrolysing coagulants. Regrettably, in-depth studies have not yet been conducted on their ability to purify water to a healthy palatable drinking quality which is risk-free for lifetime consumption in terms of the national standard for drinking water quality of various countries worldwide, and does not become a source of secondary pollution in the reticulation system. The objective of this paper is to provide information about the natural organic matter (NOM) removal efficiency attained at different waterworks purifying water with different organic coagulants, and to compare this with that attained using mineral coagulants. The findings presented in this article prove that organic coagulants are not an equivalent replacement for mineral coagulants, as the purified water is of an inferior quality which does not comply with the limits set by national standards of different countries worldwide.","PeriodicalId":23623,"journal":{"name":"Water SA","volume":"60 8","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72486022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Probabilistic vs deterministic forecasts – interpreting skill statistics for the benefit of users","authors":"W. Landman, M. Tadross, E. Archer, P. Johnston","doi":"10.17159/wsa/2023.v49.i3.4058","DOIUrl":"https://doi.org/10.17159/wsa/2023.v49.i3.4058","url":null,"abstract":"Owing to probabilistic uncertainties associated with seasonal forecasts, especially over areas such as southern Africa where forecast skill is limited, non-climatologists and users of such forecasts frequently prefer them to be presented or distributed in terms of the likelihood (expressed as a probability) of certain categories occurring or thresholds being exceeded. Probabilistic forecast verification is needed to verify such forecasts. Whilst the resulting verification statistics can provide clear insights into forecast attributes, they are often difficult to understand, which might hinder forecast uptake and use. This problem can be addressed by issuing forecasts with some understandable evidence of skill, with the purpose of reflecting how similar forecasts may have performed in the past. In this paper, we present a range of different probabilistic forecast verification scores, and determine if these statistics can be readily compared to more commonly known and understood ‘ordinary’ correlations between forecasts and their associated observations – assuming that ordinary correlations are more intuitively understood and informative to seasonal forecast users. Of the range of scores considered, the relative operating characteristics (ROC) was found to be the most intrinsically similar to correlation.","PeriodicalId":23623,"journal":{"name":"Water SA","volume":"62 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84052996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"An evaluation of three evapotranspiration models to determine water fluxes over hillslopes encroached by invasive alien plants in Eastern Cape Province, South Africa","authors":"Anthony Palmer, Craig Weideman, Heidi-Jane Hawkins, Perushan Rajah, Tawanda Marandure, Cletos Mapiye, Lianhai Wu, Onalenna Gwate, James Bennett","doi":"10.17159/wsa/2023.v49.i3.3964","DOIUrl":"https://doi.org/10.17159/wsa/2023.v49.i3.3964","url":null,"abstract":"Ecosystem services in the South African grassland biome are being impacted by the presence of invasive alien plants (IAPs), particularly from the Australian genus Acacia. IAPs have elevated landscape water use and determining water fluxes is crucial to defining suitable interventions. This study evaluates three models of water flux over IAP-invaded grassland against evapotranspiration (ET) measured by a large-aperture scintillometer (LAS). ET was modelled using an energy balance model (MEDRUSH), a biophysical model (Penman-Monteith-Leuning (PML)) and a remotely sensed product (MOD16), and their results compared with ET measured by the LAS. ETLAS was measured during an abbreviated field campaign in November 2019 over a dense silver wattle (A. dealbata) stand associated with hillslope seeps. Of the three models tested against the LAS campaign, MEDRUSH performed well-enough to be used to model ET over the continuous scientific-grade micro-meteorological record (315 days). We used MEDRUSH to model ET over the invaded hillslope seeps and compared this with the expected ET that would occur over the adjacent, un-invaded grassland. Total ET over the IAP-invaded area was approximately 536 mm (60% of reference ET) as compared with the grassland (202 mm), showing that woody encroachment significantly increases landscape water use. To estimate the local impact of this, we used earth observation to determine the area of woody invasion in a 2 664 km2 regional window. Approximately 10% (274 km2) of this window was invaded by IAPs and, assuming the geographic window was representative of all the areas invaded by wattle, this represents ~ 89 000 ML of water used annually by the IAPs. Removal of wattle, followed by suitable restoration of landscape functionality, would greatly enhance rangeland productivity and water production from hillslope seeps.","PeriodicalId":23623,"journal":{"name":"Water SA","volume":"30 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83590762","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Multiple linear regression models for the estimation of water flows for forest management and planning in Türkiye","authors":"Hayati Zengin, M. Özcan, Ahmet Salih Değermenci, Tarık Çitgez","doi":"10.17159/wsa/2023.v49.i3.4000","DOIUrl":"https://doi.org/10.17159/wsa/2023.v49.i3.4000","url":null,"abstract":"While there are many factors, including climatology, geography, topography, vegetation and soil, that affect hydrologic processes, understanding the role of forests seems most essential, due to their manageable nature. In this study, a holistic approach was taken, and possible factors affecting streamflow, including tree, sapling, shrub, herb and soil strata, were measured for 29 small catchments/stream basins located in Turkey. Linear regression models were developed in order to estimate water flow (m³‧ha−1). Several models were suggested for use in practice. These models were based on the data on hand and displayed a sufficient level of explained variance in the dependent variable. Model 5, based on the variablesof catchment area (ha), drainage density, ratio of coniferous stand areas in the catchment (%), tree volume (m³‧ha−1), leaf area index, number of short saplings (number‧ha−1), and topsoil sand rate (%), was recommended for flow estimation, achieving a 0.73 adjR² value for test data. These variables can be obtained as part of a survey and water managers can use them to estimate water flow of the catchment. The generated models can be used in multiple-use planning of forests, e.g. in adjusting the volume of stands to get optimum benefit from wood and water production. One of the most interesting results and one that was opposite to that documented in the general literature, was the positive correlation between tree volume and flow per hectare, which suggests a strategy of growing older tree stands to enable greater water production.","PeriodicalId":23623,"journal":{"name":"Water SA","volume":"2 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86581771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The water quality status of estuarine micro-system types along the coast of KwaZulu-Natal Province, South Africa","authors":"G. Bate, D. Lemley, M. Nunes, J. Adams","doi":"10.17159/wsa/2023.v49.i3.4038","DOIUrl":"https://doi.org/10.17159/wsa/2023.v49.i3.4038","url":null,"abstract":"A survey of the quality of water flowing from micro-system types to the ocean, along the subtropical east coast of South Africa, showed a wide variation in the concentrations of total nitrogen, phosphorus and phytoplankton biomass in the different systems located, in many cases, only a short distance from each other along the coastline. The origins of the high phytoplankton growth indicate pollutants caused by the land-use in this highly populated coastal region. The main agricultural activities in the area are sugarcane, permanent orchards, and forestry. The levels of N and P in the water varied from ‘good’ to ‘poor’, i.e., TN 0.15–3.99 mg‧L−1, TP 0.02–0.33 mg‧L−1 and chlorophyll-a from 0 to almost 45 µg‧L−1. Rapid coastal population densification appears to have been the cause of the pollution levels measured for total nitrogen, phosphorus, and phytoplankton biomass. Most of the micro-systems with a total modified peri-catchment above 80% were enriched by both TN and TP. While the hypothesis tested was that the main cause was residential development (e.g., septic tank effluent), it was not possible to show any statistical significance to support such a specific conclusion. Although these systems are small individually, the great number along the coastline warrants recognition as important sources of freshwater inflow and nutrients to the marine environment.","PeriodicalId":23623,"journal":{"name":"Water SA","volume":"11 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75516572","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Assessing the performance of techniques for disaggregating daily rainfall in South Africa","authors":"R. Ramlall, J. Smithers","doi":"10.17159/wsa/2023.v49.i3.3967","DOIUrl":"https://doi.org/10.17159/wsa/2023.v49.i3.3967","url":null,"abstract":"Design flood estimation (DFE) methods are used to limit the risk of failure and ensure the safe design of hydrological and related infrastructure, and to inform water resources management. In order to improve DFE methods which are based on event or continuous simulation rainfall–runoff models, it is generally necessary to use sub-daily rainfall data. However, sub-daily rainfall gauges are relatively sparse and have shorter record lengths than daily rainfall gauges in South Africa. Rainfall temporal disaggregation (RTD) techniques can be used to produce finer resolution data from coarser resolution daily rainfall data. Several RTD approaches have been developed and are used in South Africa. However, there is a need to review and assess the performance of the available RTD methods. This paper contains an overview of selected RTD approaches and the performance of the methods at selected sites in South Africa, for disaggregating daily rainfall into 15-min intervals. Temporal distributions of rainfall were represented by dimensionless Huff curves, which served as the basis for comparison of observed and disaggregated rainfall. In a pilot study it was found that the SCS-SA (Soil Conservation Service model South Africa) distributions and the Knoesen model approaches performed considerably better than the other approaches. The RTD approaches were further assessed using data from 14 additional rainfall stations. For the additional stations, the Knoesen model and SCS-SA disaggregated rainfall generally provided the most realistic temporal distributions.","PeriodicalId":23623,"journal":{"name":"Water SA","volume":"306 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77932666","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Selenium quantification in wastewaters from selected coal-fired power plants and river waters in South Africa using ICP-MS","authors":"Harold H Shiri, T. W. Godeto, P. Nomngongo, O. Zinyemba","doi":"10.17159/wsa/2023.v49.i3.4050","DOIUrl":"https://doi.org/10.17159/wsa/2023.v49.i3.4050","url":null,"abstract":"South Africa mainly relies on Eskom's coal-fired power plants for electricity generation. However, the use of coal causes several adverse environmental impacts, including the release of selenium into the hydrosphere. Selenium is an essential nutrient for humans, animals, and microbes, but excess selenium is toxic. This paper describes the determination of total dissolved selenium in wastewater from selected coal-fired power plants and river waters near coal-fired power plants in South Africa. A sensitive and robust inductively coupled plasma mass spectrometry (ICP-MS) method for determining total dissolved selenium in wastewater and river water was developed using a certified reference material (NIST SRM 1640a Trace Elements in Natural Water). The results agreed with the certified values, with percentage recoveries ranging from 92–96%. The method detection limit was 0.13 µg/L. Total Se concentrations in wastewater samples from Kriel and Lethabo Power Stations ranged between 4.86 and 8.53 µg/L, and in river water samples from the Olifants and Wilge Rivers, the concentrations ranged from 2.63–8.20 µg/L. These results indicate that the Se levels in the wastewater are too low to pose a health hazard to humans and livestock but pose an environmental threat to aquatic life. The low concentrations in the river samples also show that there may be slight Se pollution (regarding aquatic life) from the selected coal-fired power plants in South Africa. There may be slight Se pollution (with regards to aquatic life) from Duvha and Kendal Power Stations because an increase from 2–8 µg/L was observed in river water samples collected near these selected coal-fired power plants.","PeriodicalId":23623,"journal":{"name":"Water SA","volume":"12 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87500406","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}