Reviews in Inorganic Chemistry最新文献_第3页

Water desalination, and energy consumption applications of 2D nano materials: hexagonal boron nitride, graphenes, and quantum dots 二维纳米材料：六方氮化硼、石墨烯和量子点的海水淡化和能耗应用

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2024-05-29 DOI: 10.1515/revic-2024-0013

Shahab Khan, Faizan Ur Rahman, Inam Ullah, Salman Khan, Zarif Gul, Fazal Sadiq, Tufail Ahmad, Sayed M. Shakil Hussain, Ijaz Ali, Muhammad Israr

引用次数: 0

Green synthesis and applications of mono/bimetallic nanoparticles on mesoporous clay: a review 介孔粘土上单/双金属纳米粒子的绿色合成与应用：综述

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2024-05-27 DOI: 10.1515/revic-2024-0008

Manash Pratim Barman, Dipanwita Basak, Debasis Borah, Deepmoni Brahma, Mandira Debnath, Hemaprobha Saikia

{"title":"Green synthesis and applications of mono/bimetallic nanoparticles on mesoporous clay: a review","authors":"Manash Pratim Barman, Dipanwita Basak, Debasis Borah, Deepmoni Brahma, Mandira Debnath, Hemaprobha Saikia","doi":"10.1515/revic-2024-0008","DOIUrl":"https://doi.org/10.1515/revic-2024-0008","url":null,"abstract":"Green nanotechnology comprises the use of natural sources such as plant extracts as both reducing and stabilizing agents thereby reducing the reliance on hazardous chemicals. Recent breakthroughs in nanotechnology involve the incorporation of various metals to create mono and bimetallic nanoparticles, catalyzing transformative shifts. However, concerns arise due to the environmental impact of traditional synthesis methods. An alternative approach focuses on biosynthesized metal nanoparticles using clay, specifically Bentonite, MMT (Montmorillonite) and Kaolinite as supportive materials, emphasizing the prevention of agglomeration with clay and the use of plant extracts. The integration of clay, especially Bentonite, MMT and Kaolinite enhances the stability and functionality. The review emphasizes mitigating environmental impact by reducing metal ions and explores the use of phytochemicals fro environmentally friendly nanoparticle synthesis. Incorporating clay minerals not only improves synthesis efficiency but also minimizes the ecological footprint. Future research is expected to focus on integrative approaches in plant nanotechnology, particularly in agriculture and broader plant science. The comprehensive review covers literature from 2015 to 2023, providing systematic and interpretative data, highlighting progress and potential in eco-friendly metal nanoparticles synthesis supported on clay minerals.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"63 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141169712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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BiVO4-based heterojunction nanophotocatalysts for water splitting and organic pollutant degradation: a comprehensive review of photocatalytic innovation 用于水分离和有机污染物降解的基于 BiVO4 的异质结纳米光催化剂：光催化创新综述

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2024-05-13 DOI: 10.1515/revic-2024-0009

Baneesh Patial, Ajay Bansal, Renu Gupta, Susheel K. Mittal

{"title":"BiVO4-based heterojunction nanophotocatalysts for water splitting and organic pollutant degradation: a comprehensive review of photocatalytic innovation","authors":"Baneesh Patial, Ajay Bansal, Renu Gupta, Susheel K. Mittal","doi":"10.1515/revic-2024-0009","DOIUrl":"https://doi.org/10.1515/revic-2024-0009","url":null,"abstract":"The novel semiconductor photocatalytic material bismuth vanadate (BiVO4) is gaining significant attention in research due to its unique characteristics, which include a low band gap, good responsiveness to visible light, and non-toxic nature. However, intrinsic constraints such as poor photogenerated charge transfer, slow water oxidation kinetics, and fast electron–hole pair recombination limit the photocatalytic activity of BiVO4. Building heterojunctions has shown to be an effective strategy for enhancing charge separation and impeding electron–hole pair recombination over the last few decades. This review covers the state-of-the-art developments in heterojunction nanomaterials based on BiVO4 for photocatalysis. It explores heterojunction design, clarifies reaction mechanisms, and highlights the current developments in applications including photocatalytic water splitting and organic matter degradation. Finally, it offers a preview of the development paths and opportunities for BiVO4-based heterojunction nanomaterials in the future. This comprehensive assessment of BiVO4-based heterojunctions provides insightful knowledge to researchers in materials science, chemistry, and environmental engineering that will drive advances and breakthroughs in these important fields.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"23 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140934329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base 源自糖和席夫碱的金属（II）络合物的合成、表征、热学、理论研究、抗菌、抗氧化活性、超氧化物歧化酶样活性和过氧化氢酶模拟物

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2024-05-02 DOI: 10.1515/revic-2023-0028

Saleh Bufarwa, Reem El-Seifat, Hana Binhamad, Rehab Hesien

{"title":"Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base","authors":"Saleh Bufarwa, Reem El-Seifat, Hana Binhamad, Rehab Hesien","doi":"10.1515/revic-2023-0028","DOIUrl":"https://doi.org/10.1515/revic-2023-0028","url":null,"abstract":"Scientists are searching for reactive oxygen species, which have been associated with various health issues like heart problems, neurological disorders, inflammation, and aging. Salen complexes have proven to be effective in multiple oxidative stress situations and have been used as catalase and superoxide mimetics. To explore this further, three mixed complexes were synthesized using a Schiff base (salen) and a sugar (d-glucose) with Co(II), Ni(II), and Cu(II) ions. These complexes were then diagnosed by different analytical and spectral techniques. Stoichiometry, stereochemistry, some physical properties, and the method of bonding complexes were measured. Comparisons of the IR and 1HNMR spectra of the ligands with the complexes demonstrated the involvement of the azomethine group of the ligand in the chelation process. The mass spectra and TGA agree with the proposed formula of the complexes, and the conductivity and UV–Vis data supported the octahedral geometry of the complexes, and information was obtained from partial parameter calculations by molecular modeling. The metal complexes exhibited strong antimicrobial and antioxidant properties when compared to standard drugs. The like-superoxide and catalyst mimetic complexes were screened using DPPH ABTS, revealing their effectiveness.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"59 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140828899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Reduction mechanism and energy transfer between Eu3+ and Eu2+ in Eu-doped materials synthesized in air atmosphere 在空气中合成的掺 Eu 材料中 Eu3+ 和 Eu2+ 的还原机制和能量转移

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2024-04-30 DOI: 10.1515/revic-2024-0011

Shahab Khan, Hong-Wei Zheng, Huan Jiao, Shahroz Saleem, Zarif Gul, Jehan Y. Al-Humaidi, Areej Al Bahir, Raed H. Althomali, Arshad Ali, Mohammed M. Rahman

{"title":"Reduction mechanism and energy transfer between Eu3+ and Eu2+ in Eu-doped materials synthesized in air atmosphere","authors":"Shahab Khan, Hong-Wei Zheng, Huan Jiao, Shahroz Saleem, Zarif Gul, Jehan Y. Al-Humaidi, Areej Al Bahir, Raed H. Althomali, Arshad Ali, Mohammed M. Rahman","doi":"10.1515/revic-2024-0011","DOIUrl":"https://doi.org/10.1515/revic-2024-0011","url":null,"abstract":"This article critically examines the reduction mechanisms and energy transfer processes between trivalent europium ions (Eu3+) and divalent europium ions (Eu2+) in materials synthesized in an air atmosphere. It also encompasses various materials and conditions, including a critical analysis of the reduction mechanism and energy transfer between Eu3+ and Eu2+ in Eu-doped materials. Specific investigations include exploring the reduction process in BaMgSiO4:Eu, focusing on factors influencing the reaction. The article also covers low-temperature self-reduction, addressing conditions and mechanisms such as the charge compensation model and laser-induced reduction. Additionally, it explores the influence of charge compensation on luminescent properties, emphasizing enhancements in red emission. Investigations into the role of oxygen vacancies in the reduction of Eu3+ and their implications on material properties are presented. This article further digs into abnormal reduction processes and the formation of defect centers in Eu3+-doped pollucite, proposing a substitution defect model for the self-reduction of europium ions in silicate Ba(Eu)MgSiO4 phosphors. Unusual reduction phenomena, such as reduction via boiling water in Yb2Si2O7:Eu3+ phosphors, and reductions in various glass systems, including porous glass, ZnO–B2O3–P2O5 glasses, aluminoborosilicate glasses, europium-doped Li2B4O7 glass, and aluminosilicate oxyfluoride glass (AOG), are also thoroughly examined.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"9 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140828706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The environmental impact of using gold nanoparticles and 3HFWC in cosmetics, as determined with LCA methodology 采用生命周期评估方法确定在化妆品中使用金纳米粒子和 3HFWC 对环境的影响

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2024-04-30 DOI: 10.1515/revic-2024-0012

Rebeka Rudolf, Peter Majerič, Žiga Jelen, Andrej Horvat, Damjan Krajnc

引用次数: 0

Solid-phase extraction of organophosphates from polluted waters on a matrix-imprinted sorbent 用基质压印吸附剂固相萃取污染水体中的有机磷酸酯

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2024-04-22 DOI: 10.1515/revic-2024-0010

Bandar R. Alsehli

{"title":"Solid-phase extraction of organophosphates from polluted waters on a matrix-imprinted sorbent","authors":"Bandar R. Alsehli","doi":"10.1515/revic-2024-0010","DOIUrl":"https://doi.org/10.1515/revic-2024-0010","url":null,"abstract":"The study aims to synthesize a selective matrix imprinted sorbent for the extraction of parathion and malathion. The structural unit of the polymeric framework was 2-methylpropanoic acid, the intermolecular crosslinker was ethylene glycol dimethacrylate, the polymerization initiator was azobisisobutyronitrile, the porogen was xylene, and the analyte was parathion. The synthesis was carried out under conditions of heating the reaction mixture to 65 °C, after which the matrix was washed with methanol to remove the analyte. For comparison purposes, non-imprinted control polymer was used as a negative control, which was prepared similarly, but without the addition of the analyte. The identification and quantification of organophosphates were performed by gas chromatography, and the morphological characteristics of the sorbents were evaluated by scanning electron microscopy. The optimal buffer for the purification of organophosphates was acetate buffer with a pH of 4; the optimal organic eluent was methanol. The limit of detection for para- and malathion was 0.1 μg/ml; the limit of quantification was 0.3 μg/ml. Linearity in the extraction conditions was observed in the range of 0.1–1 μg/ml for parathion and 0.1–2 μg/ml for malathion. The developed method will enable quick, selective, and cost-effective extraction of organophosphates from various substrates.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"4 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140636552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Carbon materials derived by crystalline porous materials for capacitive energy storage 用于电容式储能的多孔结晶碳材料

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2024-04-08 DOI: 10.1515/revic-2023-0039

Hang Wang, Yiting Li, Longyu Wang, Jieting Jin

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Bioinorganic metal nanoparticles and their potential applications as antimicrobial, antioxidant and catalytic agents: a review 生物无机金属纳米颗粒及其作为抗菌剂、抗氧化剂和催化剂的潜在应用：综述

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2024-04-08 DOI: 10.1515/revic-2023-0040

Khalida Naseem, Asad Aziz, Mohammad Ehtisham Khan, Shahzaib Ali, Awais Khalid

{"title":"Bioinorganic metal nanoparticles and their potential applications as antimicrobial, antioxidant and catalytic agents: a review","authors":"Khalida Naseem, Asad Aziz, Mohammad Ehtisham Khan, Shahzaib Ali, Awais Khalid","doi":"10.1515/revic-2023-0040","DOIUrl":"https://doi.org/10.1515/revic-2023-0040","url":null,"abstract":"This review article covers the biogenic synthesis of metal nanoparticles (MNPs) having definite shape and size while using extract obtained from different biological sources such as bacteria, fungi, algae and plants. These biological materials are composed of chloroplast, thylakoid, different types of enzymes extracted from different biogenic sources, different phytochemicals such as phenols, flavonoids, and citric acid having functional groups such as sulfate, carboxyl, amino, amide and hydroxyl groups. These functional groups and enzymes act as efficient reductants to convert metal ions into metal atoms and alternatively metal atoms combine to form MNPs while long hydrocarbon chains present in these bio-macromolecules act as cage to stabilize them for prolong time. Effect of nature of source extract, different reaction conditions such as extract amount, salt amount and solvent used during MNPs preparation process have been critically discussed here in detail. Use of synthesized bioinorganic NPs in various areas including their effectiveness in fighting against bacteria, viruses, fungi, cancer, inflammation, and their potential role in catalytic reduction of environmental harmful substances into friendly products has also been described in a clear and concise manner along with their future consideration.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"37 1","pages":""},"PeriodicalIF":4.1,"publicationDate":"2024-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140585007","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Applications of samarium complexes as cytotoxic, bioimaging and DNA interacting agents: a comprehensive review 钐配合物在细胞毒性、生物成像和 DNA 相互作用剂方面的应用：全面综述

IF 4.1 3区化学

Reviews in Inorganic Chemistry Pub Date : 2024-03-08 DOI: 10.1515/revic-2023-0026

Poonam R. Inamdar, Shashikant Bhandari, Mrunalini Kulkarni, Neeta Rai, Anuja Kolsure

引用次数: 0