Progress in Organic Coatings最新文献

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A review of the use of natural pigments in multilayer and composite films for intelligent biodegradable food packaging 天然色素在生物可降解食品智能包装多层膜和复合膜中的应用综述
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-12 DOI: 10.1016/j.porgcoat.2026.109955
Meral Yildirim-Yalcin , Tansel Kemerli-Kalbaran , Tugce Ceyhan , Esin Mojtahedi , Hatice Sena Olcay , Selin Sahin , Seid Reza Falsafi , Omer Said Toker
{"title":"A review of the use of natural pigments in multilayer and composite films for intelligent biodegradable food packaging","authors":"Meral Yildirim-Yalcin ,&nbsp;Tansel Kemerli-Kalbaran ,&nbsp;Tugce Ceyhan ,&nbsp;Esin Mojtahedi ,&nbsp;Hatice Sena Olcay ,&nbsp;Selin Sahin ,&nbsp;Seid Reza Falsafi ,&nbsp;Omer Said Toker","doi":"10.1016/j.porgcoat.2026.109955","DOIUrl":"10.1016/j.porgcoat.2026.109955","url":null,"abstract":"<div><div>Composite and multilayered forms of biodegradable packaging are manufactured in order to improve the qualities of the films. This kind of packaging has gained attention as a consequence of the problem of plastic waste. Natural pigments alter the color of packaging films as a result of pH changes due to components released during food deterioration, thus providing information about the food's status and functioning as intelligent packaging. This review covers the recent studies on the use of natural pigments for the production of biodegradable composite and multilayer intelligent packaging. In addition, a coating-design perspective is adopted to examine how layer structure, pigment incorporation, and polymer–pigment interactions shape the functional performance of multilayer and composite films. The review emphasizes structure property relationships central to coating science by summarizing key characterization techniques including mechanical, barrier, optical, and thermal analyses and explaining how natural pigment incorporation modifies the performance of multilayer and composite films. The possibilities of using biodegradable films containing natural pigments as spoilage indicators in food packaging are also summarized. The selection of appropriate biopolymers and pigments is important for the production of a high-quality film that can act as an indicator at the desired pH. Overall, this review integrates advancements in intelligent biodegradable packaging with principles of organic coating technology, outlines current challenges associated with pigment stability and coating durability, and highlights future research directions for developing scalable, high-performance functional coatings.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109955"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145978397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research progress on lignin-based composite coatings for wood protection 木质素基复合木材防护涂料的研究进展
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-17 DOI: 10.1016/j.porgcoat.2026.109971
Shuyuan Chen , Xinyue Wei , Yongyue Peng , Yi Liang , Xiaohan Wang , Xiaoting Niu
{"title":"Research progress on lignin-based composite coatings for wood protection","authors":"Shuyuan Chen ,&nbsp;Xinyue Wei ,&nbsp;Yongyue Peng ,&nbsp;Yi Liang ,&nbsp;Xiaohan Wang ,&nbsp;Xiaoting Niu","doi":"10.1016/j.porgcoat.2026.109971","DOIUrl":"10.1016/j.porgcoat.2026.109971","url":null,"abstract":"<div><div>Wood materials are vulnerable to degradation induced by multiple biotic and abiotic factors, and surface coating serves as the most straightforward protective approach. However, traditional petroleum-derived coatings pose environmental risks and exhibit poor biodegradability. Consequently, the development of bio-based coatings has attracted extensive research attention. Lignin, the world's second most abundant organic polymer, exhibits potential to enhance coating properties such as UV resistance, mechanical strength, and durability due to its inherent chemical structure. Nevertheless, challenges in lignin application include poor dispersibility and inadequate interfacial compatibility. This review systematically summarizes progressive modification strategies to enhance lignin's hydrophobicity, environmental durability, and stability, thereby improving its utilization efficiency. Finally, it outlines recent research progress on lignin as a coating material and multifunctional filler.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109971"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145978394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structure-directed and filler-assisted strategy for high thermal conductivity, low dielectric porous triazole-imide films 高导热、低介电介质多孔三唑-亚胺薄膜的结构导向和填料辅助策略
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-23 DOI: 10.1016/j.porgcoat.2026.109993
Xueying Wu , Baoyue Zhang , Peipei Xu , Baijie Cheng , Ruixue Wang , Shanyi Guang , Hongyao Xu
{"title":"Structure-directed and filler-assisted strategy for high thermal conductivity, low dielectric porous triazole-imide films","authors":"Xueying Wu ,&nbsp;Baoyue Zhang ,&nbsp;Peipei Xu ,&nbsp;Baijie Cheng ,&nbsp;Ruixue Wang ,&nbsp;Shanyi Guang ,&nbsp;Hongyao Xu","doi":"10.1016/j.porgcoat.2026.109993","DOIUrl":"10.1016/j.porgcoat.2026.109993","url":null,"abstract":"<div><div>The performance of traditional packaging materials can no longer meet the requirements of the advanced semiconductor industry for high thermal conductivity and improved signal transmission rate. Therefore, the development of new polymer materials with both high thermal conductivity and low dielectric constant has become a huge challenge. A dual-regulation strategy was demonstrated, using ionic liquid as a “structure-directing agent” and magnesium oxide (MgO) as a thermal conductive filler. Through the strong interaction between the ionic liquid and the polymer main chain, further enhanced by MgO induced chain segment orientation and close packing. It integrates a porous membrane with excellent comprehensive performance, featuring a high thermal conductivity of 7.09 W∙m<sup>−1</sup>∙K<sup>−1</sup> and a low dielectric constant of 1.45. Additionally, it boasts good thermal stability with a glass transition temperature (Tg) as high as 265 °C and excellent mechanical properties, with a tensile strength of up to 179.8 MPa. This dual regulation strategy is expected to be extended to other high performance polymer systems to achieve synergistic optimization of multiple properties, not just thermal and dielectric. This porous membrane demonstrates enormous potential as the next generation solution for electronic packaging, thermal management, and energy device applications.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109993"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146023561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On-demand underwater adhesion and self-healing superhydrophilic/underwater superoleophobic coating 按需水下粘附和自修复超亲水/水下超疏油涂层
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-24 DOI: 10.1016/j.porgcoat.2026.109978
Funing Zhang , Jihua Yu , Jiwu Zhao , Jingxue Xu , Weina Kong , Mingjian Luo , Huaiyuan Wang , Fatang Liu
{"title":"On-demand underwater adhesion and self-healing superhydrophilic/underwater superoleophobic coating","authors":"Funing Zhang ,&nbsp;Jihua Yu ,&nbsp;Jiwu Zhao ,&nbsp;Jingxue Xu ,&nbsp;Weina Kong ,&nbsp;Mingjian Luo ,&nbsp;Huaiyuan Wang ,&nbsp;Fatang Liu","doi":"10.1016/j.porgcoat.2026.109978","DOIUrl":"10.1016/j.porgcoat.2026.109978","url":null,"abstract":"<div><div>On-demand adhesion superhydrophilic/underwater superoleophobic coatings can significantly simplify the functionalization and regeneration processes of equipment surfaces, while also offering significant economic benefits and environmental sustainability advantages. However, preparing superhydrophilic/underwater superoleophobic coatings that can simultaneously satisfy high adhesion and on-demand adhesion remains a critical challenge. In this study, an on-demand adhesion, self-healing superhydrophilic/underwater superoleophobic coating (EDPE) based on nonwoven fabric was designed and fabricated by integrating the temperature-responsive mechanism of tardigrades with the superhydrophilic properties of fish mucus through a multi-level biomimetic structure. The produced EDPE coating retained its structural integrity and underwater superoleophobicity after 160 friction cycles and immersion in complex water environments (pH=2, pH=12, and artificial seawater), achieving self-healing and the restoration of underwater superoleophobicity in complex water environments. The coating also exhibited excellent adhesion properties on various materials, as well as repeatable adhesion and retention of its underwater superoleophobic performance through temperature response, offering outstanding resistance to external forces and environmental changes. In addition, the coating demonstrated excellent antifouling, drag reduction, and antibacterial properties. Notably, this work proposed a simple and effective design strategy for on-demand adhesion and self-healing superhydrophilic coatings. The approach could enable scalable manufacturing processes, offering new insights for industrial applications requiring advanced surface engineering solutions.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109978"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146023567","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Catechol-based zwitterionic polymers with antibacterial and antifouling properties for biomedical surface coatings 用于生物医学表面涂层的具有抗菌和防污性能的儿茶酚基两性离子聚合物
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2025-12-30 DOI: 10.1016/j.porgcoat.2025.109915
Shan-Wei Hou , Jui-Jen Chang , Li-Ying Lin , Uyen Khanh Pham , Thi Thu Ha Do , Cheng-Kang Lee , Wesley Wei-Wen Hsiao
{"title":"Catechol-based zwitterionic polymers with antibacterial and antifouling properties for biomedical surface coatings","authors":"Shan-Wei Hou ,&nbsp;Jui-Jen Chang ,&nbsp;Li-Ying Lin ,&nbsp;Uyen Khanh Pham ,&nbsp;Thi Thu Ha Do ,&nbsp;Cheng-Kang Lee ,&nbsp;Wesley Wei-Wen Hsiao","doi":"10.1016/j.porgcoat.2025.109915","DOIUrl":"10.1016/j.porgcoat.2025.109915","url":null,"abstract":"<div><div>Persistent biofilms on medical device surfaces account for up to 80 % of chronic clinical infections, posing a major challenge to infection control and patient safety. To overcome this limitation, a zwitterionic polymer–PEGDGE-TAU-CCDP (PTC), was synthesized using polyethylene glycol diglycidyl ether (PEGDGE), taurine (TAU), and 2-chloro-3′,4′-dihydroxyacetophenone (CCDP). The incorporation of catechol functionalities enabled the polymer with redox activity under aerobic and ion-rich environments, a property previously associated with antibacterial behavior in catechol-based systems. Ultraviolet–visible (UV–Vis), Fourier-transform infrared (FTIR), and proton nuclear magnetic resonance (<sup>1</sup>H NMR) spectroscopy confirmed the successful synthesis and catechol incorporation. Quantitative analysis revealed a CCDP grafting efficiency of approximately 29 %. Notably, the addition of ε-Polylysine (EPL) enhanced coating adhesion to various substrates without compromising the intrinsic antibacterial activity of the material. Bacterial growth curves, minimum inhibitory concentration (MIC), and minimum bactericidal concentration (MBC) assays demonstrated that EPL/PTC had an MIC of 0.31 mg/mL and an MBC of 1.25 mg/mL. Furthermore, the EPL/PTC-coated silicone rubber exhibited approximately 85 % biofilm inhibition and 76 % antifouling efficiency. By combining antifouling and antibacterial properties within a single system, this strategy achieves multifunctional performance that is rarely observed in conventional surface treatments. These findings highlight EPL/PTC as a promising candidate for reducing surface fouling and infection risks, thereby supporting its potential application in developing safer biomedical device materials.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109915"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145885978","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic effect of zirconia and zinc oxide incorporation in polyether ether ketone based coating deposited via electrophoretic deposition for orthopedic implants 电泳沉积聚醚醚酮基骨科植入物涂层中氧化锆和氧化锌的协同效应
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-05 DOI: 10.1016/j.porgcoat.2025.109909
Saad Ahmed , Muhammad Abdullah , Chaudhry Hassan Rawaiz , Khalil Ahmed , Aneela Wakeel , Khurram Yaqoob , Amber Fareed , Abdul Wadood , Akbar Niaz , Muhammad Atiq Ur Rehman
{"title":"Synergistic effect of zirconia and zinc oxide incorporation in polyether ether ketone based coating deposited via electrophoretic deposition for orthopedic implants","authors":"Saad Ahmed ,&nbsp;Muhammad Abdullah ,&nbsp;Chaudhry Hassan Rawaiz ,&nbsp;Khalil Ahmed ,&nbsp;Aneela Wakeel ,&nbsp;Khurram Yaqoob ,&nbsp;Amber Fareed ,&nbsp;Abdul Wadood ,&nbsp;Akbar Niaz ,&nbsp;Muhammad Atiq Ur Rehman","doi":"10.1016/j.porgcoat.2025.109909","DOIUrl":"10.1016/j.porgcoat.2025.109909","url":null,"abstract":"<div><div>A critical issue that contributes to implant failure is poor tribocorrosion resistance of 316L SS implants in the human body. In this study, a novel composite coating of polyether ether ketone (PEEK)–zirconia (ZrO<sub>2</sub>)–zinc oxide (ZnO) with optimized concentration of ZrO<sub>2</sub> was deposited at an electric field of 25 V/cm for 3 min by electrophoretic deposition (EPD). This optimized concentration of ZrO<sub>2</sub> enhanced the tribocorrosion resistance of 316L SS as a result of functional improvement in the composite coating for dental and orthopedics applications. The Scanning Electron Microscopy (SEM) analysis revealed thickness of 96 μm of the composite coating with a fairly uniform morphology with the presence of agglomerates. The Fourier Trasform Infrared (FTIR) spectroscopy identified the functional groups of PEEK, ZrO<sub>2</sub>, ZnO, and the composite coating and confirmed their presence in the composite coating. Bend test and pencil scratch test confirmed the adhesion strength of and rated it as 4B. Surface profilometry determined an average surface roughness (R<sub>a</sub>) 1.001 ± 0.035 μm with a slightly hydrophilic nature expressed by contact angle 64 ± 2° (by using distilled water). The composite coating not only demonstrated the potential antibacterial effect against gram-positive and gram-negative bacteria by showing a zone of inhibition of 23.9 ± 0.10 mm and 24 ± 0.12 mm respectively, while maintaining the cytocompatibility with (MG-63) osteoblast cells. The pin on disc test of the composite coating demonstrated a stable COF ∼ 0.0002 ± 0.00003 and specific wear rate 4.81 ± 1.3 10<sup>−6</sup> (mm<sup>3</sup>/Nm) indicating the improved tribological performance due to the incorporation of ZrO<sub>2</sub>. Electrochemical Impedance Spectroscopy indicated the barrier properties, which was further confirmed by the Potentiodynamic Polarization technique by shifting the potential from −0.231 to −0.152 V towards the more noble direction and reducing the corresponding corrosion current density from 2.79 to 0.014 μA/cm<sup>2</sup> by the composite coating, such findings demonstrate that the composite coating has potential for in-vivo and clinical trials for dental and orthopedic applications.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109909"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145927829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Eco-friendly, compatible, and recyclable all-cellulose-based radiative cooling coating for building energy savings 环保、兼容、可回收的全纤维素基建筑节能辐射冷却涂料
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2025-12-30 DOI: 10.1016/j.porgcoat.2025.109907
Lishi Wei , Yushan Zou , Shihao Wang , Shanshan Song , Jinhong Li , Yachong Zhu , Kunlin Li , Yongming Song
{"title":"Eco-friendly, compatible, and recyclable all-cellulose-based radiative cooling coating for building energy savings","authors":"Lishi Wei ,&nbsp;Yushan Zou ,&nbsp;Shihao Wang ,&nbsp;Shanshan Song ,&nbsp;Jinhong Li ,&nbsp;Yachong Zhu ,&nbsp;Kunlin Li ,&nbsp;Yongming Song","doi":"10.1016/j.porgcoat.2025.109907","DOIUrl":"10.1016/j.porgcoat.2025.109907","url":null,"abstract":"<div><div>Passive radiative cooling (PRC) technology offers a sustainable cooling approach for buildings without energy consumption. However, traditional polymer-based PRC materials are limited by environmentally harmful preparation techniques, poor substrate compatibility, and low recyclability. To address these challenges, this study innovatively presents an ethyl cellulose (EC)-based PRC coating prepared via an eco-friendly non-solvent-induced phase separation (NIPS) method. Owing to the hierarchical micro-nano porous structure and strong molecular vibrations, the coating demonstrates an ultrahigh solar reflectance of 0.96 and a mid-infrared emissivity of 0.96, resulting in a notable cooling effect of 8.3 °C. Importantly, the coating exhibits excellent compatibility with diverse building substrates, including wood, glass, textiles, plastics, metals, and tiles, enabling broad application across various architectural components. Moreover, the coating can be recycled using a simple ethanol/water solvent system, while maintaining its cooling performance even after multiple recycling cycles. This study provides a promising strategy for addressing the limitations of traditional polymer-based PRC materials and facilitates the development of energy-efficient buildings.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109907"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145886075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic ester and hydrogen bonding networks enable superior hydrogen barrier in PVA/LDH films 协同的酯和氢键网络使PVA/LDH薄膜具有优异的氢屏障
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2025-12-29 DOI: 10.1016/j.porgcoat.2025.109916
Sicheng Yuan , Jintao Wei , Sheng Zhang , Yanji Zhu , Songhai Wu , Huaiyuan Wang
{"title":"Synergistic ester and hydrogen bonding networks enable superior hydrogen barrier in PVA/LDH films","authors":"Sicheng Yuan ,&nbsp;Jintao Wei ,&nbsp;Sheng Zhang ,&nbsp;Yanji Zhu ,&nbsp;Songhai Wu ,&nbsp;Huaiyuan Wang","doi":"10.1016/j.porgcoat.2025.109916","DOIUrl":"10.1016/j.porgcoat.2025.109916","url":null,"abstract":"<div><div>The development of high-performance hydrogen barrier films is crucial for ensuring the safety and integrity of hydrogen energy infrastructure. This study presents a novel strategy to significantly enhance the hydrogen barrier properties of polyvinyl alcohol (PVA) films by constructing a synergistic covalent and non-covalent bonding network. Maleic acid (MA) was employed as a dual-functional agent to crosslink PVA chains and covalently bridge them with MgAl-Layered Double Hydroxide (LDH) nanosheets via esterification. This molecular-level design resulted in a dense composite film with superior properties. The optimized PVA/0.5LDH/15MA film exhibited an ultra-low hydrogen gas transmission rate of 1.439 ± 0.027 cm<sup>3</sup>/(m<sup>2</sup>·day·atm), which is 73 % lower than that of pristine PVA. It also demonstrated excellent mechanical performance, with a tensile strength of 53 MPa and an elongation at break of 370.71 %. This work provides a promising material solution for enhancing safety in hydrogen applications and offers a new paradigm for designing high-barrier polymer composites through interface engineering.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109916"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145845528","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of self-healing coatings based on PDA@BTA@MOF active fillers for low-temperature corrosion protection 基于PDA@BTA@MOF活性填料的自修复低温防腐涂料的研制
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-06 DOI: 10.1016/j.porgcoat.2025.109944
Xiaohua Chen, Hongzhi Cui, Lingyun Tang, Jinlai Yang, Cheng Man
{"title":"Development of self-healing coatings based on PDA@BTA@MOF active fillers for low-temperature corrosion protection","authors":"Xiaohua Chen,&nbsp;Hongzhi Cui,&nbsp;Lingyun Tang,&nbsp;Jinlai Yang,&nbsp;Cheng Man","doi":"10.1016/j.porgcoat.2025.109944","DOIUrl":"10.1016/j.porgcoat.2025.109944","url":null,"abstract":"<div><div>Motivated by the demand for enhanced coating toughness and self-healing capabilities in polar low-temperature environments, a pH-responsive active filler, which was named as PDA@BTA@MOF, was synthesized through the layer-by-layer self-assembly of a metal–organic framework (MOF), benzotriazole (BTA) corrosion inhibitor molecules, and polydopamine (PDA). And then, the obtained fillers denoted as, was incorporated into an epoxy resin to prepare a composite coating (termed the PDA coating) that exhibited superior toughness and excellent low-temperature corrosion protection. Physicochemical characterization revealed that the PDA@BTA@MOF filler possesses a core-shell structure with cubic BTA@MOF as the core and PDA nanoparticles forming the shell, and the special structure ensure that the PDA@BTA@MOF filler could uniformly disperse within the PDA coating matrix. The active filler could significantly enhance the toughness, barrier properties against corrosive media penetration, and adhesion under various conditions of the PDA coating, primarily attributed to mechanisms such as the “pinning effect”. Electrochemical impedance spectroscopy (EIS) and salt spray tests reveals that the PDA coating containing PDA@BTA@MOF filler possesses more excellent anti-corrosion resistance that the pure epoxy coating (EP coating). Even under harsh alternating freeze-salt spray test conditions, where the diffusion of corrosive media through the is coating significantly accelerated and adhesion was substantially degraded, the PDA coating maintained remarkable protective efficacy. Furthermore, immersion tests and EIS analysis on scratched samples confirmed the pH-responsive release behavior of the PDA@BTA@MOF particles and the effective self-healing functionality of the PDA coating.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109944"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145927832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self-healing polyurethane coatings with multi-dynamic bonds: Fabrication and applications 具有多动态键的自愈聚氨酯涂料:制造与应用
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-07 DOI: 10.1016/j.porgcoat.2025.109932
Aihua Tang , Hao Liu , Qingsong Wu , Weixiang Xu , Tingzhe Wang , Shunbao Hu , Yiping Xu , Yiting Xu , Birong Zeng , Guorong Chen , Lizong Dai
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