Jun Zhang, Jie Pang, W. Jin, S. Chu, Martin Haarberg, S. Xiao
{"title":"Production of tib2 coatings on graphite substrates by electrophoretic deposition in NaF-AlF3 melt","authors":"Jun Zhang, Jie Pang, W. Jin, S. Chu, Martin Haarberg, S. Xiao","doi":"10.2298/pac2301009z","DOIUrl":"https://doi.org/10.2298/pac2301009z","url":null,"abstract":"In this paper a novel method for fabrication of TiB2 coatings on graphite substrates by electrophoretic deposition of TiB2 nanoparticles in NaF-AlF3 melt at 980?C has been explored. With an applied cell voltage of 1.2 V (i.e. electric field 0.6 V/cm), a flat and dense TiB2 coating with a thickness of around 50 ?m has been prepared. It was found that the surface consisted of TiB2 flakes with a nanoscale size. In addition, the average value of hardness of the TiB2 coating was determined as 3585 ? 139 HV0.1 (36.6 ? 1.4GPa) measured by a Vickers micro-hardness tester.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"1 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68582583","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gaolin Ye, Yifei Jiao, Peng Zhou, Jinxing Sun, Likuan Zhu, F. Gong, Jiaming Bai, Gang Liu, Ming Yan, Rubing Zhang
{"title":"Preparation of silicon carbide ceramic slurry for stereolithography based additive manufacturing","authors":"Gaolin Ye, Yifei Jiao, Peng Zhou, Jinxing Sun, Likuan Zhu, F. Gong, Jiaming Bai, Gang Liu, Ming Yan, Rubing Zhang","doi":"10.2298/pac2301047y","DOIUrl":"https://doi.org/10.2298/pac2301047y","url":null,"abstract":"Stereolithography-based additive manufacturing of ceramics has received tremendous attention in academic and industrial communities. In order to fabricate silicon carbide (SiC) components with complex shapes by stereolithography, a high SiC loaded ceramic slurry with low viscosity and excellent curing ability is required. However, it is challenging to meet these slurry requirements. In this work, the effects of resin formulation, dispersant, particle size, solid content and ball milling time on the properties of SiC ceramic slurry were systematically studied. The SiC slurries were prepared by using four precursor SiC powders having different particle sizes and modified by high temperature oxidation to reduce its UV absorbance. Additionally, the suitable SiC slurries for stereolithography were prepared by ball milling under appropriate processing parameters, and the geometrically complex SiC green bodies were subsequently fabricated.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"1 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68582749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. Isidorio, E. Santos, A. Filho, S. Da, Amal Eltom, Biasi de
{"title":"Use of cobalt ferrite and activated carbon in supercapacitors","authors":"D. Isidorio, E. Santos, A. Filho, S. Da, Amal Eltom, Biasi de","doi":"10.2298/pac2301014i","DOIUrl":"https://doi.org/10.2298/pac2301014i","url":null,"abstract":"Supercapacitors are energy storage devices that can cleanly and efficiently meet the growing energy demand. The presentwork describes the synthesis of nanoparticles of cobalt ferrite (CoFe2O4) by the combustion method and their use with activated carbon (AC) to manufacture supercapacitors. In order to study the influence of composition on the electrochemical properties, supercapacitors with three different compositions were produced: Fe90 (90% CoFe2O4 and 10% AC), Fe50 (50% CoFe2O4 and 50% AC) and Fe10 (10% CoFe2O4 and 90% AC). Microstructural and morphological analyses were performed by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electronmicroscopy (TEM), and Raman spectroscopy. Cyclic voltam-metry (CV), galvanostatic charge-discharge (GCD), floating and electrochemical impedance spectroscopy (EIS) tests were performed. XRD, SEM, TEM and Raman results showed that the combustion method was effective for the production of CoFe2O4 nanoparticles. SEM and Raman spectroscopy results showed that the AC has a porous structure and low crystallinity. According to CV, GCD and floating tests, all three supercapacitors presented excellent electrochemical stability. The Fe50 composition yielded the lowest equivalent series resistance, while the Fe10 composition yielded the highest capacitance. The results show that the combination of AC with CoFe2O4 is promising for the use in supercapacitors.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"92 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68582616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Linling Huang, Zhicheng Li, Kaifeng Li, You Zhang, Hong Zhang, S. Leng
{"title":"Electrical conductivity and electrical stability of Bi/Mg modified NiO ceramics for NTC thermistors","authors":"Linling Huang, Zhicheng Li, Kaifeng Li, You Zhang, Hong Zhang, S. Leng","doi":"10.2298/pac2302172h","DOIUrl":"https://doi.org/10.2298/pac2302172h","url":null,"abstract":"Thermistors with negative temperature coefficient (NTC) of resistivity are important components for temperature sensors and actuators. High material constant (B value) of NTC thermistor, i.e. high-temperature sensitivity, is one of key focuses. Herein, Bi/Mg modified NiO based ceramics for NTC thermistors were prepared by conventional solid-state reaction method. Introduction of Bi2O3 significantly enhances the sintering ability of ceramics and reduces the sintering temperature from 1380 to 1250?C. Mg-doping (i.e. preparation of Ni1-xMgxO ceramics, where x=0, 0.02, 0.05, 0.07 and 0.1) has significant effect on room temperature resistivity (?25). Phase composition, microstructure, electrical property and electrical stability were investigated. All prepared ceramics have the phase with rock-salt structure and show typical NTC characteristics with B values higher than 5300K. The electrical stability with an optimized resistance-change rate of 1.02%after being aged at 150?C for 500 h is achieved. The electrical properties of the ceramics were analysed by combining X-ray photoelectron spectra with complex impedance spectra.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"1 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68583043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Theoretical prediction by DFT on properties of β′-SrTa2O6 crystal","authors":"M. Aycibin, M. Erzen, H. Akkuş","doi":"10.2298/pac2301001a","DOIUrl":"https://doi.org/10.2298/pac2301001a","url":null,"abstract":"Based on the Density Functional Theory (DFT) electronic band structure, state density, linear optics, elastic, dynamic and thermodynamic properties of ??-SrTa2O6 crystal with P4/mbm (No. 127) space group were investigated with the help of ABINIT and Wien2k code. In the study, it was found that the ??-SrTa2O6 crystal is classified as a semiconductor with an indirect bandgap. For this crystal, the dielectric function was obtained and optical constants such as energy loss function, extinction coefficient, absorption coefficient and reflectivity were calculated. The components of the elastic stiffness tensor, the phonon dispersion, the state density and the contribution of each atom to the state density were obtained. Finally, thermodynamic properties were determined for the ??-SrTa2O6 crystal. Furthermore, the changes in free energy (F), internal energy (E), entropy (S) and heat capacity (C) depending on the temperature were investigated.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"1 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68582554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yinhao Li, Shuangyu Liu, Ping Lu, Mikhailovna Vasilieva, Fulong Zhang, Juan Hong
{"title":"Viscosity optimisation of photosensitive al2o3 slurry for stereolithography based additive manufacturing","authors":"Yinhao Li, Shuangyu Liu, Ping Lu, Mikhailovna Vasilieva, Fulong Zhang, Juan Hong","doi":"10.2298/pac2301091l","DOIUrl":"https://doi.org/10.2298/pac2301091l","url":null,"abstract":"Viscosity of alumina slurry is a key factor affecting the quality of ceramics formed by stereo photolithography, but it is closely related to the resin distribution ratio, dispersant content, plasticizer content and solid content. Most researchers utilize the single factor method to study the composition and ratio of the slurry. In this study, orthogonal experimental design and back propagation artificial neural networks methods were combined to solve the optimisation problem of multi-objective and multi-factor influence on alumina slurry performances. The results of optimal composition and content allocation were achieved by back propagation artificial neural networks and experimental testing. It was shown that the optimal conditions are: resin composition HDDA : PPTTA = 4 : 1, DS-165A dispersant content of 3.86wt.%, PEG plasticiser amount of 3.5wt.% and the solid content of 75.74wt.%. The predicted optimal viscosity value was 8787mPa?s and the shrinkage rate could reach 14.57%. The optimal values of viscosity and shrinkage were consistent with the experimental results, the viscosity and shrinkage errors were only 4.06% and 3.856%, respectively. The average density and bending strength of the sintered samples were 3.979 ? 0.005 g/cm3 and 365 ? 61MPa, respectively. According to the obtained data, stereolithography 3D printing alumina slurry with excellent flowability and low shrinkage was successfully prepared.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"1 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68582455","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Feng Jiang, Junling Yu, Guo Feng, Tao Wang, Xiaojun Zhang, Quan Zhang, Rongchi Zhang, Qian Wu, Qing Hu, Yun Yu, Jianmin Liu
{"title":"Synthesis and near-infrared reflection performance of (Cr,V)-ZrSiO4 jewel green pigments","authors":"Feng Jiang, Junling Yu, Guo Feng, Tao Wang, Xiaojun Zhang, Quan Zhang, Rongchi Zhang, Qian Wu, Qing Hu, Yun Yu, Jianmin Liu","doi":"10.2298/pac2303295j","DOIUrl":"https://doi.org/10.2298/pac2303295j","url":null,"abstract":"Novel (Cr,V)-ZrSiO4 jewel green pigments were synthesized by in situ mineralization at 900?C. The effects of Cr/Si molar ratio were investigated via DTA-TG, XRD, FE-SEM, TEM, UV-Vis-NIR, colorimeter and etc. The obtained results referred that the colour of pigment exhibits blue to jewel green, and then to dark green as the Cr/Si molar ratio increases from 0 to 0.4. When the Cr/Si molar ratio is 0.2, the (Cr,V)-ZrSiO4 pigment exhibits a jewel green hue (L* = 56.69, a* = ?18.52, b* = ?9.28), showing good rendering performance. In addition, the obtained pigment shows good thermal stability in the base glaze synthesized at 1200?C and near-infrared reflection performance. The results of this study show great potential for using the pigments for heat insulation.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135263158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shuang Zhao, Feiyue Yang, Jun Chen, Kunfeng Li, Zhifang Fei, Zichun Yang
{"title":"High-temperature oxidation behaviour of si3n4 nanowires with different diameters","authors":"Shuang Zhao, Feiyue Yang, Jun Chen, Kunfeng Li, Zhifang Fei, Zichun Yang","doi":"10.2298/pac2301039z","DOIUrl":"https://doi.org/10.2298/pac2301039z","url":null,"abstract":"?-Si3N4 nanowires with diameters of 100-180 nm (Si3N4-W1) and 420-510 nm (Si3N4-W2) were synthesized by a modified chemical vapour deposition (CVD) method and their microstructure changes after high-temperature oxidation were studied. The results showed that both Si3N4 nanowires were not significantly oxidized when the temperature was lower than 900?C. However, the Si3N4-W1 microstructure began to change significantly after oxidation at 1200?C, while the Si3N4-W2 microstructure remained almost unchanged. Moreover, the Si3N4- W1 and Si3N4-W2 nanowires oxidized significantly after treatment at 1400?C, with weight gain of 26.4% and 13.7%, respectively.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"1 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68582730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yichao Gong, Xin Chen, K. Kang, Yuefei Wang, Qingze Na, S. Ren, Guojun Zhang
{"title":"Low-temperature sintering of Li4SiO4 spheres with high crushing load using mesoporous silica as Si sources","authors":"Yichao Gong, Xin Chen, K. Kang, Yuefei Wang, Qingze Na, S. Ren, Guojun Zhang","doi":"10.2298/pac2301055g","DOIUrl":"https://doi.org/10.2298/pac2301055g","url":null,"abstract":"Li4SiO4 has been widely studied as tritium breeder and high temperature CO2 capture material. Tritium breeding rate and CO2 adsorption capacity are closely related to lithium content and microstructure. Since high sintering temperatures result in grain coarsening and lithium sublimation, it is a great challenge to prepare Li4SiO4 ceramics with a satisfactory mechanical strength at low sintering temperature. In this work, mesoporous silica was used as Si source to prepare Li4SiO4 spheres. The mesoporous structure might provide more reaction sites for lithium ions, thereby facilitating the reaction between LiOH and mesoporous silica. The sintering temperature of Li4SiO4 spheres was greatly reduced by using mesoporous silica as Si source. The Li4SiO4 spheres with a homogenous fine-grained microstructure (the average grain size of 2.2 ?m) and high crushing load (41.65N) could be obtained at 675?C.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"1 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68582762","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
B. Costa, M.I.A. De Silva, C. Tarley, E. Ribeiro, M. Segatelli
{"title":"Influence of polymer synthesis route and organic fraction content on structure and porosity of silicon oxycarbide ceramics","authors":"B. Costa, M.I.A. De Silva, C. Tarley, E. Ribeiro, M. Segatelli","doi":"10.2298/pac2302118c","DOIUrl":"https://doi.org/10.2298/pac2302118c","url":null,"abstract":"This paper describes the structural and textural characteristics of silicon oxycarbide ceramics obtained from three different hybrid polymers by varying pyrolysis temperature. The first polymer was prepared by hydrosilylation between poly(hydromethylsiloxane) and divinylbenzene in stoichiometric proportions; the second was similarly obtained, but with excess of divinylbenzene (60 wt.%) and the third was also synthesized with 60 wt.% divinylbenzene, involving simultaneously hydrosilylation and radical reactions. Precursors were pyrolysed under argon at 1000, 1200 and 1500?C to produce silicon oxycarbide-based ceramics. Silicon carbide phase development and devitrification resistance were influenced by the disordered and ordered residual carbon fraction, which was directly related to the polymer structure. High specific surface area and pore volume values were obtained in C-richer ceramics at 1500?C derived from poly(divinylbenzene) network-containing precursor. Silicon oxycarbide matrices, derived from hybrid polymers containing graphitic carbon and silicon carbide phases together with different amount of porosity, revealed desirable features for electrochemical applications and adsorbent systems.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"1 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68582879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}