Processing and Application of Ceramics最新文献

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Fabrication, structure and complex dielectric properties of SrFeO3-LaFeO3 ceramic composites SrFeO3-LaFeO3陶瓷复合材料的制备、结构及复合介电性能
4区 材料科学
Processing and Application of Ceramics Pub Date : 2025-01-01 DOI: 10.2298/pac2501050w
Wu Xiaoyu, Wei Li, Ziheng Huang, Depeng Wang, Weitian Wang
{"title":"Fabrication, structure and complex dielectric properties of SrFeO3-LaFeO3 ceramic composites","authors":"Wu Xiaoyu, Wei Li, Ziheng Huang, Depeng Wang, Weitian Wang","doi":"10.2298/pac2501050w","DOIUrl":"https://doi.org/10.2298/pac2501050w","url":null,"abstract":"In this study, SrFeO3-LaFeO3 ceramic composite was prepared from mixture of SrFeO3 and LaFeO3 powders (synthesized by solid state reactionmethod) by pressing and sintering at 1400?C for 6 h. The composite exhibits single orthorhombic structure with coexistence of SrFeO3 and LaFeO3 phases. Chemical composition and complex dielectric properties were investigated. The obtained permittivity of the SrFeO3-LaFeO3 composite is 2 to 3 times higher than that of the pure SrFeO3 or LaFeO3 perovskite samples. The observed dielectric behaviour can be explained by the localized dipolar effect and dielectric relaxation processes, arising from the presence of mixed-valence state of Fe (i.e., Fe2+/Fe3+/Fe4+ pairs) and oxygen vacancies with activation energies of 0.38 and 0.73 eV, respectively. Resistances of grain boundaries and grains were revealed by impedance spectroscopy.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"19 1","pages":"50-56"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"http://www.doiserbia.nb.rs/ft.aspx?id=1820-61312501050W","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147899120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and properties of novel tungstate SrLa6W10O40: Eu3+ phosphors 新型钨酸盐SrLa6W10O40: Eu3+荧光粉的制备及性能研究
4区 材料科学
Processing and Application of Ceramics Pub Date : 2024-01-01 DOI: 10.2298/pac2401109f
Guo Feng, Xiao‐Long Huang, Feng Jiang, Qing Yang, Wenwei Jin, Chuan Shao, Jianmin Liu, Dahai Wang, Jian Liang
{"title":"Preparation and properties of novel tungstate SrLa6W10O40: Eu3+ phosphors","authors":"Guo Feng, Xiao‐Long Huang, Feng Jiang, Qing Yang, Wenwei Jin, Chuan Shao, Jianmin Liu, Dahai Wang, Jian Liang","doi":"10.2298/pac2401109f","DOIUrl":"https://doi.org/10.2298/pac2401109f","url":null,"abstract":"Novel tungstate SrLa6-xW10O40: xEu3+ (x = 0, 0.03, 0.06, 0.09, 0.12, 0.15, 0.18, 0.21) red phosphors were prepared by solid state method at 1150 ?C by using SrCO3, La2O3, WO3 and Eu2O3 as raw materials. The powders were agglomerated with particles having mostly spheroidal morphology, mean particle size D50 = 12.8 ?m and narrow particle size distribution. With the increase of doping amount x, there is no significant difference in the diffraction peak position of the phosphor, but the cell volume of SrLa6W10O40 slowly decreases. The relative strength of diffraction peaks decreases gradually and the half-peak width widens gradually, indicating that the inclusion of Eu3+ ions affects the crystallization of the SrLa6W10O40 matrix. Excitation and emission spectra of the prepared samples were obtained. The optimal doping content has the SrLa5.85W10O4: 0.15Eu3+ phosphor and is characterised with the colour coordinate of (0.652, 0.348), which is closer to the red standard colour (0.67, 0.33) than the near-ultraviolet red phosphor Y2O2S: Eu3+ (0.622, 0.351) used for commercial LED.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"18 1","pages":"109-116"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"http://www.doiserbia.nb.rs/ft.aspx?id=1820-61312401109F","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147883156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Conch-shell-inspired porcelain ceramic tile/Kevlar fabric composites with excellent combination of strength, toughness and shock resistance 以海螺为灵感的陶瓷瓷砖/凯夫拉纤维复合材料,具有优异的强度,韧性和抗震性
4区 材料科学
Processing and Application of Ceramics Pub Date : 2024-01-01 DOI: 10.2298/pac2401020z
Xinzi Zhong, Liyun Cao, Jianfeng Huang, Yijun Liu, Xuetao Shen, Zhao Yong, Dongping Wang, Zhiwen Cheng, Ting Liu, Shuai Zhang, Chenlei Zhang
{"title":"Conch-shell-inspired porcelain ceramic tile/Kevlar fabric composites with excellent combination of strength, toughness and shock resistance","authors":"Xinzi Zhong, Liyun Cao, Jianfeng Huang, Yijun Liu, Xuetao Shen, Zhao Yong, Dongping Wang, Zhiwen Cheng, Ting Liu, Shuai Zhang, Chenlei Zhang","doi":"10.2298/pac2401020z","DOIUrl":"https://doi.org/10.2298/pac2401020z","url":null,"abstract":"For various engineering applications in public, ceramics with exceptional strength, toughness and shock resistance are imminently required, but traditional ceramics struggle to meet these demands due to their fragility. Inspired by the shape of natural conch shells, this work offers a simple hot press approach to fabricate layered porcelain ceramic tile/Kevlar fabric composites, yielding excellent mechanical properties and the capacity for non-catastrophic failure. It was concluded that composites? excellent mechanical performance is attributed to the resin/fabric content. The composite with the resin/fabric content of 45.5 vol.% had an outstanding combination of high strength (310.5 ? 6.2MPa) and excellent fracture toughness (6.83 ? 0.09MPa?m1/2), whereas the sample with 36.4 vol.% resin/fabric content had the maximal impact energy of 2.04 ? 0.09 J, which is much better than those of traditional ceramics. The strong resistance to fracture is a result of the proper interfacial bonding and the presence of elastic component, which enables toughening mechanisms such as crack deflection, fibre pull-out and interfacial debonding. This finding provides useful guidance for replacing lowperformance ceramics in engineering applications with cost-effective ceramic composites.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"18 1","pages":"20-28"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"http://www.doiserbia.nb.rs/ft.aspx?id=1820-61312401020Z","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147897820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sm/Al modified Sn0.94Sb0.06O2 ceramics for NTC thermistors Sm/Al改性sn0.94 sb0.060 o2陶瓷NTC热敏电阻
4区 材料科学
Processing and Application of Ceramics Pub Date : 2024-01-01 DOI: 10.2298/pac2402162z
You Zhang, Hong Zhang, Hao Chen, Yifei Zhan, Zhicheng Li, Senlin Leng
{"title":"Sm/Al modified Sn0.94Sb0.06O2 ceramics for NTC thermistors","authors":"You Zhang, Hong Zhang, Hao Chen, Yifei Zhan, Zhicheng Li, Senlin Leng","doi":"10.2298/pac2402162z","DOIUrl":"https://doi.org/10.2298/pac2402162z","url":null,"abstract":"Negative temperature coefficient (NTC) thermistors are key components for temperature sensors and actuators. In this work, Sn0.94-x-yAlxSmySb0.06O2+? (0 ? x ? 0.05, 0 ? y ? 0.15) ceramics were prepared by solid-state reaction method for potential application of NTC thermistors. The Sm/Al co-doped SnO2 ceramics had the main phase with tetragonal structure as that of SnO2 crystal. The prepared ceramics presented adjustable room temperature resistivity (?25) and temperature sensitivity (B value) for various Al contents. Sm/Al co-doping significantly improved the ageing stability, the resistance shift rate was below 3% after ageing at 150?C for 500 h, while the average resistance shift rate was 41.4% of the ceramics without Sm-doping. The conduction mechanisms and the effect of dopants on the ageing stability were investigated by analysis of impedance spectra and element valences combined with defect chemistry theory.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"18 2","pages":"162-171"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"http://www.doiserbia.nb.rs/ft.aspx?id=1820-61312402162Z","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147897803","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Preparation and properties of Eu3+ doped tungstate red phosphor powders 掺Eu3+钨酸盐红色荧光粉粉体的制备及性能研究
4区 材料科学
Processing and Application of Ceramics Pub Date : 2024-01-01 DOI: 10.2298/pac2402156w
Yaping Wang, Anqin Liu, Zhijuan Li, Zhuo Wang, Yunxia Chen
{"title":"Preparation and properties of Eu3+ doped tungstate red phosphor powders","authors":"Yaping Wang, Anqin Liu, Zhijuan Li, Zhuo Wang, Yunxia Chen","doi":"10.2298/pac2402156w","DOIUrl":"https://doi.org/10.2298/pac2402156w","url":null,"abstract":"NaY(WO4)2:Eu3+ phosphors were synthesized using high-temperature solid state method. The effects of Eu3+ doping concentrations on structure and photoluminescence properties of the powders were investigated. The results indicate that the pure NaY(WO4)2:Eu3+ phase can be produced by calcining at 800?C where Eu3+ doping does not alter the main phase structure. Eu3+ ions were successfully incorporated into the crystal lattice, replacing Y3+ at the B-site. This caused gradual shifts of the characteristic X-ray diffraction peaks to lower 2? angles. Morphological characterization revealed that the sample particles had irregular polygonal shapes with sizes ranging from 100 to 300 nm. There was minimal variation in morphology among samples with different doping concentrations. The samples exhibited the characteristic spectral emission of Eu3+ and emitted red light at a wavelength of 616 nm when excited by 394 nm near-ultraviolet light. The luminescence intensity of the nanophosphor gradually increased with increasing Eu3+ doping concentration, reaching its maximum at a doping ratio of 0.6, followed by a decrease due to the concentration quenching. The quenching mechanism was analysed to be primarily dipole-dipole interaction, in accordance with the Dexter?s theory of doping concentration. The luminescence positions of the phosphors slightly changed with varying Eu3+ doping concentrations, and the colour coordinates closely matched the standard value of the red colour in the National Television Standards Committee, confirming the stability of the obtained powders as red phosphors.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"18 2","pages":"156-161"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"http://www.doiserbia.nb.rs/ft.aspx?id=1820-61312402156W","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147901683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Influence of sintering temperature on structure and mechanical properties of polycrystalline cubic boron nitride composites 烧结温度对多晶立方氮化硼复合材料组织和力学性能的影响
4区 材料科学
Processing and Application of Ceramics Pub Date : 2024-01-01 DOI: 10.2298/pac2402180m
Peicheng Mo, Jia‐Rong Chen, Xiaoyi Pan, Zhang Jun, Kai Li, Chao Chen
{"title":"Influence of sintering temperature on structure and mechanical properties of polycrystalline cubic boron nitride composites","authors":"Peicheng Mo, Jia‐Rong Chen, Xiaoyi Pan, Zhang Jun, Kai Li, Chao Chen","doi":"10.2298/pac2402180m","DOIUrl":"https://doi.org/10.2298/pac2402180m","url":null,"abstract":"Polycrystalline cubic boron nitride (PcBN) cutting tool materials were prepared by mixing cBN (85 wt.%) and TiN-Ti-Co (15 wt.%) micropowders under high temperature and ultra-high pressure. X-ray diffraction and scanning electron microscopy were employed to analyse the phase composition and microstructure of the composites. The effects of sintering temperature on the mechanical properties and cutting performance of the PcBN ceramics were also investigated. The results indicated that at the ultra-high pressure of 6GPa and temperatures ranging from 1400 to 1700?C, the PcBN composites consist of BN, TiN, TiB2 and Co phases. The PcBN sintered at 1700?C exhibited the most favourable comprehensive mechanical properties, including a flexural strength of 909MPa and microhardness of 36.8GPa. In addition, the cutting tool fabricated from the PcBN composite sintered at 1700?C showed superior cutting performances in testing with 40Cr mechanical parts.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"18 2","pages":"180-185"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"http://www.doiserbia.nb.rs/ft.aspx?id=1820-61312402180M","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147906903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Low-temperature dielectric and impedance properties of Ba1-xSrxTiO3 and BaTi1-xTaxO3 ceramics Ba1-xSrxTiO3和BaTi1-xTaxO3陶瓷的低温介电和阻抗特性
4区 材料科学
Processing and Application of Ceramics Pub Date : 2023-01-01 DOI: 10.2298/pac2303286w
Depeng Wang, Ruifeng Niu, Liqi Cui, Weitian Wang
{"title":"Low-temperature dielectric and impedance properties of Ba1-xSrxTiO3 and BaTi1-xTaxO3 ceramics","authors":"Depeng Wang, Ruifeng Niu, Liqi Cui, Weitian Wang","doi":"10.2298/pac2303286w","DOIUrl":"https://doi.org/10.2298/pac2303286w","url":null,"abstract":"In this work, two series of BaTiO3-based ceramics, Ba1-xSrxTiO3 (x = 0, 0.2, 0.4, 0.6, 0.8) and BaTi1-xTaxO3 (x = 0.03, 0.06, 0.075, 0.09, 0.1), were synthesized by using standard solid-state reaction method at 1350 ?C, and then sintered at 1400 ?C for 10 h in air. Frequency-dependent dielectric and impedance properties were investigated at low temperature range of 100-300K. The changes in dielectric properties of the Ba1-xSrxTiO3 ceramics are believed to originate from the phase transition due to the different A-site Sr2+ doping concentration. The local electron-pinned defect-dipole effect is responsible for the enhancement of dielectric constant observed in the B-site Ta5+ doped BaTi1-xTaxO3 ceramics. The complex impedance analysis was used to discern the temperature and frequency dependence of grains and grain boundaries responses. The results suggest that A- and B-site doped BaTiO3 ceramics can be applied for different dielectric devices at low temperatures.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"131 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135311324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of grain growth in bimodal microstructure on cutting performance of self-toughening Dy-α-SiAlON ceramic tool inserts 双峰组织晶粒长大对自增韧Dy-α-SiAlON陶瓷刀具切削性能的影响
4区 材料科学
Processing and Application of Ceramics Pub Date : 2023-01-01 DOI: 10.2298/pac2303321g
Beichen Gao, Weinila Abulaiti, Zheng Guan, Limeng Liu
{"title":"Effect of grain growth in bimodal microstructure on cutting performance of self-toughening Dy-α-SiAlON ceramic tool inserts","authors":"Beichen Gao, Weinila Abulaiti, Zheng Guan, Limeng Liu","doi":"10.2298/pac2303321g","DOIUrl":"https://doi.org/10.2298/pac2303321g","url":null,"abstract":"Although significant increase in mechanical properties has been achieved in ?-SiAlON ceramics by introducing self-toughening bimodal microstructure, the bimodal microstructure may not always result in better cutting performance of ?-SiAlON tool inserts. Herein Dy-?-SiAlON ceramics were prepared by hot-pressing at 1900?C under 30MPa. Diameter and aspect ratio of the large elongated ?-SiAlON grains pivotal to formation of bimodal microstructures were regulated by using 0-5wt.% Dy2O3 as a sintering additive. Mechanical properties and cutting performance of ?-SiAlON tool inserts were evaluated. The results showed good Vickers hardness (19.0-19.7GPa) and fracture toughness (3.61-4.18MPa?m1/2) increasing with crack propagation length. However, transverse section of the large elongated grains was revealed as critical crack to cause premature fracture of the ?-SiAlON ceramics. Fracture rather than attrition wear was recognized as dominant mechanism for tool failure, indicating that for better cutting performance of the ?-SiAlON tool inserts a selftoughening microstructure consisting of thinner grains with large aspect ratio is required.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"51 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135312345","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of polycrystalline cubic boron nitride composites under high pressure 高压制备多晶立方氮化硼复合材料
IF 1.1 4区 材料科学
Processing and Application of Ceramics Pub Date : 2023-01-01 DOI: 10.2298/pac2302157m
P. Mo, Jiarong Chen, Chao Chen, Haiqing Qin, F. Lin
{"title":"Fabrication of polycrystalline cubic boron nitride composites under high pressure","authors":"P. Mo, Jiarong Chen, Chao Chen, Haiqing Qin, F. Lin","doi":"10.2298/pac2302157m","DOIUrl":"https://doi.org/10.2298/pac2302157m","url":null,"abstract":"The PCBN (polycrystalline cubic boron nitride) composites were synthesized by mixing cubic boron nitride micropowders with Ti and Al micropowders at a certain mass ratio under high temperature and ultra-high pressure conditions. Phase composition and microstructure of the samples were analysed by X-ray diffraction and scanning electron microscopy. The effects of sintering temperature on the mechanical properties and microstructure of the PCBN ceramics were investigated. It was shown that BN, AlN, TiN and TiB2 phases coexist in the PCBN ceramics fabricated at ultra-high pressure (5.5GPa) and high temperature (1400-1500?C). With the increase of sintering temperature, pores and gaps inside the PCBN composites gradually disappeared and densified structure was formed. The best comprehensive mechanical properties of the PCBN composites were obtained at 1500 ?C with a flexural strength of 1009MPa and microhardness of 35.8GPa.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"1 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68583341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Al2O3 on migration and distribution of chromium and chromium fixation effect in stainless-steel slag glass-ceramics Al2O3对不锈钢渣微晶玻璃中铬迁移分布及固铬效果的影响
IF 1.1 4区 材料科学
Processing and Application of Ceramics Pub Date : 2023-01-01 DOI: 10.2298/pac2301070z
Chuanbo Zhang, Z. Tong, Congcong Xu, Jiaxing Wang, Zhiheng Jia
{"title":"Effect of Al2O3 on migration and distribution of chromium and chromium fixation effect in stainless-steel slag glass-ceramics","authors":"Chuanbo Zhang, Z. Tong, Congcong Xu, Jiaxing Wang, Zhiheng Jia","doi":"10.2298/pac2301070z","DOIUrl":"https://doi.org/10.2298/pac2301070z","url":null,"abstract":"Stainless-steel slag was used to prepare glass-ceramics, which could solidify chromium (Cr) in the slag. The migration and distribution state of chromium in the slag during the preparation of the glass-ceramics have a great influence on the chromium fixation ability of the glass-ceramics. In this paper, the effects of Al2O3 content in the glass-ceramics on the migration and distribution of chromium during the nucleation and crystallization steps, and on the chromium fixation effect of the glass-ceramics were systematically studied. The results show that in the nucleation stage, with the increase of Al2O3 content, the number of chromium spinel (Cr-spinel) nanocrystals formed in the glass first increases and then decreases, and Cr in the glass phase gradually migrates to Cr-spinel nanocrystals. TEM and XPS analyses show that during crystallization, part of Cr in Cr-spinel diffuses into diopside lattice, and the other part of Cr still exists in Cr-spinel wrapped by diopside. Cr in the glass phase also diffuses and migrates into the diopside lattice with the formation of diopside crystals. The optimal Al2O3 content is 11.8wt.%, which results in 97.94wt.% of the total Cr being fixed in the diopside crystalline phase. The ability of chromium fixation is very high giving a very low Cr leaching concentration of 0.004mg/l. The research results provide theoretical and technical support for increased chromium fixation and realizing harmless and high-value utilization of stainless-steel slag.","PeriodicalId":20596,"journal":{"name":"Processing and Application of Ceramics","volume":"1 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68582840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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