Physics and Chemistry of Minerals最新文献

{"title":"In situ observation of shock-induced structural evolution of calcite","authors":"Yuhei Umeda,&nbsp;Norimasa Ozaki,&nbsp;Toshimori Sekine,&nbsp;Yoichiro Hironaka,&nbsp;Yuichi Inubushi,&nbsp;Kento Katagiri,&nbsp;Ryosuke Kodama,&nbsp;Kohei Miyanishi,&nbsp;Hirotaka Nakamura,&nbsp;Tomoko Sato,&nbsp;Yusuke Seto,&nbsp;Keiichi Sueda,&nbsp;Tadashi Togashi,&nbsp;Naotaka Tomioka,&nbsp;Toshinori Yabuuchi,&nbsp;Makina Yabashi,&nbsp;Takuo Okuchi","doi":"10.1007/s00269-025-01320-0","DOIUrl":"10.1007/s00269-025-01320-0","url":null,"abstract":"<div><p>In this study, we aimed to evaluate the shock-induced behavior of calcite (CaCO₃), a potential source of CO and/or CO₂. To this end, we experimentally investigated the time evolution of calcite during shock compression and decompression processes at shock pressures up to 234 ± 19 GPa using an ultrafast time-resolved X-ray diffraction (XRD) coupled with a laser-driven shock compression system. The XRD analysis of shocked calcite showed that the amorphization occurred in the shock compression stage at pressures above 86 ± 7 GPa, and that the decomposition reaction, i.e., CaCO₃ = CaO + CO₂, was not observed in the decompression stage within the nanosecond timescale. This observation indicated that in addition to pressure and temperature, the shock duration (reaction time) is also a critical factor affecting shock-induced structural changes, such as amorphization and decomposition. Furthermore, the nanosecond laser shock employed in this study may be applied to enhance understanding regarding the impact phenomena of micrometer to submillimeter sized projectiles. The present results suggest that the shock-induced decomposition of calcite does not occur during micrometeorite impacts.</p></div>","PeriodicalId":20132,"journal":{"name":"Physics and Chemistry of Minerals","volume":"52 2","pages":""},"PeriodicalIF":1.2,"publicationDate":"2025-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00269-025-01320-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Experimental observations of CaSiO3-CaTiO3 perovskites: implications for Ca-rich inclusions observed in sub-lithospheric diamonds","authors":"A. R. Thomson,&nbsp;W. A. Crichton,&nbsp;N. C. Siersch,&nbsp;I. S. Ezad,&nbsp;D. P. Dobson,&nbsp;J. P. Brodholt","doi":"10.1007/s00269-025-01321-z","DOIUrl":"10.1007/s00269-025-01321-z","url":null,"abstract":"<div><p>Calcium perovskite is a major component of deep mantle phase assemblages and has been frequently identified, in retrograde form, as polyphase mineral inclusions within sub-lithospheric diamonds. Here experimental observations of synthetic samples demonstrate various properties of calcium perovskite minerals which have relevance for the interpretation of diamond-hosted inclusions. Ambient pressure diffraction and spectroscopy confirm the linear dependence of crystallographic unit cell volume and Raman peak shifts across the entire CaSiO₃-CaTiO₃ binary join. These systematics will allow verification of perovskite structure and constraint of inclusion composition, without destructive analyses, in future studies. Additionally, high pressure observations confirm that calcium perovskite minerals ≳ 80 mol.% CaSiO₃ undergo spontaneous amorphization during decompression at room temperature, meaning they are unrecoverable. Finally, the presence of water appears to expand the calcium perovskite stability field to lower pressure conditions, implying at least some appreciable water-solubility in these minerals.</p></div>","PeriodicalId":20132,"journal":{"name":"Physics and Chemistry of Minerals","volume":"52 2","pages":""},"PeriodicalIF":1.2,"publicationDate":"2025-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00269-025-01321-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The effect of Fe incorporation on the single-crystal elasticity of δ-AlOOH","authors":"Niccolò Satta,&nbsp;Giacomo Criniti,&nbsp;Tiziana Boffa Ballaran,&nbsp;Alexander Kurnosov,&nbsp;Takayuki Ishii,&nbsp;Johannes Buchen,&nbsp;Hauke Marquardt","doi":"10.1007/s00269-025-01319-7","DOIUrl":"10.1007/s00269-025-01319-7","url":null,"abstract":"<div><p>The seismic mapping of hydrous materials in the Earth’s deep interior requires experimental constraints on the elastic anisotropy of hydrous minerals and phases. Oxyhydroxides like δ-(Al,Fe)OOH are arguably the main hosts of water in the lower mantle. Therefore, constraints on the single-crystal elastic tensor of δ-(Al,Fe)OOH solid solutions are crucial to quantify the elastic anisotropy of this material, and advance the current understanding of the recycling of water into the lower mantle. Yet, experimental data for intermediate compositions are scarce, limiting the understanding of how Fe incorporation affects the single-crystal elastic properties of δ-AlOOH. In this study, we provide experimental constraints on the single-crystal elasticity of two δ-(Al,Fe)OOH solid solutions, with Fe/(Al + Fe) of 0.06(1) and 0.133(3). Large single-crystal samples of δ-(Al,Fe)OOH were synthetized at high pressures and temperatures using a multi-anvil press, and the full elastic stiffness tensors were determined at ambient conditions by combining X-ray diffraction and Brillouin scattering measurements. We show that replacing Al³⁺ with Fe³⁺ in δ-(Al,Fe)OOH lowers the magnitude of most coefficients of the elastic stiffness tensor (<i>c</i>_ij), which translates into a substantial reduction of aggregate moduli and acoustic wave velocities. We further show that, at ambient conditions, the acoustic anisotropy of δ-(Al,Fe)OOH displays no sensitivity to Fe–Al substitution.</p></div>","PeriodicalId":20132,"journal":{"name":"Physics and Chemistry of Minerals","volume":"52 2","pages":""},"PeriodicalIF":1.2,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00269-025-01319-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143848971","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Thermophysical properties and phase diagrams in the system MgO–SiO2–FeO at lower mantle conditions derived from a multiple-Einstein method","authors":"Michael H. G. Jacobs,&nbsp;Rainer Schmid-Fetzer,&nbsp;Arie P. van den Berg","doi":"10.1007/s00269-025-01316-w","DOIUrl":"10.1007/s00269-025-01316-w","url":null,"abstract":"<div><p>In a previous paper we showed that the multiple Einstein method is suitable to determine consistency of data on thermophysical properties and phase diagrams in the system MgO–FeO–SiO₂ for upper mantle and transition zone conditions in the Earth. Here we extend this work to conditions covering the lower mantle, in the temperature range between 0 and 3000 K and pressure range between 20 and 140 GPa, with the goal to determine which data are consistent with each other. The resulting database is used to study the effect of the spin transition in ferropericlase on thermophysical properties and phase diagrams. Although trade-off is present in the model parameters due to the lack of experimental data, we show that models, reduced in complexity, can be used to study the effect of Fe³⁺ on these properties and phase equilibria. We show that the effect of the miscibility gap in ferropericlase, its spin transition and the valence state of Fe does not have a significant visibility in seismic density and velocities isentropes. We demonstrate that the overall composition derived by Chust et al. (J Geophys Res Solid Earth 122:9881–9920, 2018) is suitable to represent PREM and AK135 seismic data to within experimental uncertainty.</p></div>","PeriodicalId":20132,"journal":{"name":"Physics and Chemistry of Minerals","volume":"52 2","pages":""},"PeriodicalIF":1.2,"publicationDate":"2025-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143840461","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Structural peculiarities of a moissanite (natural SiC) single crystal from Manchary kimberlite pipe, Yakutia","authors":"Andrey A. Shiryaev,&nbsp;Anton D. Pavlushin,&nbsp;Vasily O. Yapaskurt,&nbsp;Alexei E. Voloshin,&nbsp;Alexei A. Averin,&nbsp;Denis A. Zolotov,&nbsp;Radmir V. Gainutdinov,&nbsp;Vadim V. Grebenev","doi":"10.1007/s00269-025-01318-8","DOIUrl":"10.1007/s00269-025-01318-8","url":null,"abstract":"<div><p>Morphological features and internal structure of a large single crystal of moissanite - natural SiC - from a Manchary kimberlite pipe are characterized in detail using complementary methods including optical, atomic force and electron microscopy, cathodoluminescence, Raman spectroscopy and X-ray topography. The sample combines atomically flat (0001) faces decorated with growth macrosteps and with remarkably complex secondary (e.g., (10–13)) faces. These faces contain outcrops of dislocations, remnants of a crystalline film, features consistent with attachment of 3D growth nuclei and other peculiarities. The specimen mainly consists of 6H polytype with admixture of 4H and 15R polytypes. The overall crystalline quality is high, only few growth-related dislocations are visible in X-ray topographs. Morphological features suggest growth of the SiC crystal on a substrate in relatively stable, but nevertheless gradually changing conditions. These changes are reflected in complex internal zoning. As suggested by the growth features, at the last stages the supersaturation increased considerably, possibly resulting from closure of a growth chamber. The growth features are consistent with moissanite formation from a reduced supercritical fluid at moderate temperatures.</p></div>","PeriodicalId":20132,"journal":{"name":"Physics and Chemistry of Minerals","volume":"52 2","pages":""},"PeriodicalIF":1.2,"publicationDate":"2025-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143824594","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mössbauer-derived equilibrium iron isotope fractionation factors for troilite (FeS) and aegirine (NaFeSi2O6)","authors":"Mikhail V. Voronin,&nbsp;Veniamin B. Polyakov,&nbsp;Evgeniy G. Osadchii","doi":"10.1007/s00269-025-01317-9","DOIUrl":"10.1007/s00269-025-01317-9","url":null,"abstract":"<div><p>Troilite was synthesized and its Mössbauer spectra in the temperature range 90 ÷ 295 K were obtained. The equilibrium iron isotope fractionation factors (β-factors) for troilite were estimated from the temperature shift (TS) in the Mössbauer spectra. The TS was described by the Debye model, and the Mössbauer temperature (<i>θ</i>_<i>M</i>) was calculated. It is shown that the quantum component of TS, at temperatures above ~ 0.6<i>θ</i>_<i>M</i>, does not exceed the statistical error of the measurements. The use of experimental results at these temperatures leads to significant errors in the estimation of <i>θ</i>_<i>M</i>. Based on Mössbauer data at temperatures below 0.6<i>θ</i>_<i>M</i> (from 90 to 190 K), <i>θ</i>_<i>M</i> = 319 K was found. The temperature dependence of the iron β-factor for troilite, calculated from this value of <i>θ</i>_<i>M</i>, is as follows: ⁵⁷Fe/⁵⁴Fe 10³ln<i>β</i> = 0.42388<i>x − </i>0.51351 × 10⁻³<i>x</i>² + 0.96769 × 10⁻⁶<i>x</i>³; <i>x</i> = 10⁶/<i>T</i>² where <i>T</i> is the absolute temperature. The Mössbauer temperature dependence of the iron β-factor for troilite agrees well with the results of its estimation by nuclear resonance inelastic X-ray scattering on ⁵⁷Fe nuclei. The same approach was applied to assess the iron β-factors for aegirine. Previously obtained <i>θ</i>_<i>M</i> = 540 K for aegirine was corrected down to <i>θ</i>_<i>M</i> = 479 K using Mössbauer data at temperatures below 0.6<i>θ</i>_<i>M</i>. The temperature dependence of the iron β-factor for aegirine: ⁵⁷Fe/⁵⁴Fe 10³ln<i>β</i> = 0.95573<i>x − </i>2.6105 × 10⁻³<i>x</i>² 11.09185 × 10⁻⁶<i>x</i>³ matches with that from the first principal calculations. This resolves the contradiction between Mössbauer-derived and first principle calculated iron β-factors for aegirine.</p></div>","PeriodicalId":20132,"journal":{"name":"Physics and Chemistry of Minerals","volume":"52 2","pages":""},"PeriodicalIF":1.2,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143778164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The thermal expansion of the clinopyroxene and garnet polymorphs of Na2MgSi5O12 determined by X-ray powder diffraction","authors":"E. K. Tripoliti,&nbsp;A. R. Thomson,&nbsp;D. P. Dobson,&nbsp;P. F. Schofield,&nbsp;I. G. Wood","doi":"10.1007/s00269-025-01315-x","DOIUrl":"10.1007/s00269-025-01315-x","url":null,"abstract":"<div><p>The temperature dependence of the unit-cell parameters of synthetic Na(Mg_0.5Si_0.5)Si₂O₆ clinopyroxene and Na₂MgSi₅O₁₂ garnet were measured, at atmospheric pressure, using X-ray powder diffraction, from 40 K up to their decomposition temperatures (673 K and 793 K respectively). At 300 K the cell parameters were found to be: (i) <i>a</i> = 9.4073(3) Å, <i>b</i> = 8.6487(3) Å, <i>c</i> = 5.2685(2) Å, <i>β</i> = 108.113(2)°, <i>V</i> = 407.41(3) ų and <i>ρ</i> = 3.286 g/cm³, for Na(Mg_0.5Si_0.5)Si₂O₆ pyroxene in space-group <i>P2/n</i> with Z = 4 and (ii) <i>a</i> = 11.4155(7) Å, <i>V</i> = 1487.61(5) ų and <i>ρ</i> = 3.561 g/cm³ for Na₂MgSi₅O₁₂ garnet in space-group <i>Ia</i><span>(overline{3})</span><i>d</i> with Z = 8. The thermal expansion tensors have been calculated and analysis of the lattice parameters in terms of a Grüneisen-Debye model is used to estimate the Debye temperature and the incompressibility of the two materials at ambient pressure.</p></div>","PeriodicalId":20132,"journal":{"name":"Physics and Chemistry of Minerals","volume":"52 2","pages":""},"PeriodicalIF":1.2,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00269-025-01315-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-pressure Raman spectroscopy of Al-rich and pure-Mg phase D","authors":"Chaowen Xu,&nbsp;Li Zhang,&nbsp;Xiaofeng Lu,&nbsp;Yanhao Lin,&nbsp;Shuo Qu,&nbsp;Shuchang Gao,&nbsp;Fengxia Sun,&nbsp;Ying Li","doi":"10.1007/s00269-025-01314-y","DOIUrl":"10.1007/s00269-025-01314-y","url":null,"abstract":"<div><p>High-pressure Raman spectra of Al-rich phase D (Mg_0.93Al_0.70Si_1.29O₆H_2.88) and pure-Mg phase D (Mg_1.03Si_1.71O₆H_3.05) were measured up to 20 GPa in diamond-anvil cells using argon as a pressure medium. The results show that the intensity of the major 777 cm^− 1 band in the Raman spectra of the pure-Mg phase D exhibits a significant intensity reduction within the 18–20 GPa range during compression. However, this band displays a highly linear shift in the Raman spectra of the Al-rich phase D without notable decrease in intensity in the same pressure range. This implies that the pressure stability of the M2 octahedra in the Al-rich phase D is higher than that in the pure-Mg phase D due to the substitution of Al³⁺ for Si⁴⁺. The major OH band at about 2900 cm^− 1 in the Raman spectra of the pure-Mg phase D sample shifts continuously toward higher frequencies with increasing pressure due to the pressure-induced transition from straight H bonds to bent ones. Whereas, this transition occurs at pressures above 10 GPa in the Al-rich phase D, indicating that Al³⁺ substitution in the crystal structure of phase D can also alter the high-pressure response of hydroxyl ion.</p></div>","PeriodicalId":20132,"journal":{"name":"Physics and Chemistry of Minerals","volume":"52 2","pages":""},"PeriodicalIF":1.2,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143612076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Solids and liquids in the (Fe, Mg, Ca)S-system: experimentally determined and thermodynamically modelled phase relations","authors":"Stefan Pitsch,&nbsp;James A. D. Connolly,&nbsp;Max W. Schmidt,&nbsp;Paolo A. Sossi,&nbsp;Christian Liebske","doi":"10.1007/s00269-025-01313-z","DOIUrl":"10.1007/s00269-025-01313-z","url":null,"abstract":"<div><p>Thermodynamic descriptions and experimentally verified phase relations in the FeS-MgS-CaS system are important both for steelmaking and for natural reduced systems. Experimental and thermodynamic data for such oxygen-poor systems are sparse due to the difficulty of conducting experiments under conditions at which these sulfides are stable. In this study, phase relationships were determined for FeS-MgS at 1170–1550 °C, for FeS-CaS at 1025–1600 °C, for MgS-CaS at 900–1500 °C and for FeS-MgS-CaS at 1050 and 1360 °C. Experiments were performed in evacuated silica glass tubes with excess Fe⁰ to favour troilite (FeS) rather than pyrrhotite (Fe_1–xS) for the FeS-rich phase. Textural interpretations and measured compositions indicate that the FeS-CaS system melts eutectically at 1063 ± 3 °C at 7 ± 1 mol% CaS. The FeS-MgS system is also modelled to be eutectic (at 1180 and 2.5 mol% MgS), yet, experimentally, its eutectic or peritectic character could not be unequivocally determined. This system’s liquidus has a higher d<i>T</i>/d<i>X</i> than previously reported. The MgS-CaS system was found to have a symmetric miscibility gap that closes at 1210 °C. Differences to the outcome of previous experimental studies can be explained by the presence of troilite rather than pyrrhotite in our experiments when Fe-rich solid solution coexists with liquid or solid solution. The experimental data are fit by a thermodynamic model that reproduces the experimentally determined phase relations, and is capable of predicting melting phase relations for the FeS-MgS-CaS ternary.</p></div>","PeriodicalId":20132,"journal":{"name":"Physics and Chemistry of Minerals","volume":"52 2","pages":""},"PeriodicalIF":1.2,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00269-025-01313-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143571066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Thermodynamic stabilization in metal organic frameworks based on 1,3,5-benzenetricarboxylate linkers and rare earth metals","authors":"Gerson J. Leonel,&nbsp;Mohit Verma,&nbsp;Godwin A. Agbanga,&nbsp;Laura Bonatti,&nbsp;Hakim Boukhalfa,&nbsp;Alexandra Navrotsky,&nbsp;Hongwu Xu","doi":"10.1007/s00269-024-01303-7","DOIUrl":"10.1007/s00269-024-01303-7","url":null,"abstract":"<div><p>This work systematically investigates the thermodynamic stability in M-BTC metal organic frameworks, where M = Y, Eu, or La and BTC = (1,3,5-benzenetricarboxylate) linker. Enthalpies of formation obtained from calorimetric measurements of Y(BTC)·5.43(H₂O), Eu(BTC)·5.82(H₂O) and La(BTC)·4.85(H₂O) enable determination of the energetic landscape for metal substitution (Y, Eu, and La) in M-BTC materials. The enthalpies of formation from linker plus metal of La-BTC, Eu-BTC, and Y-BTC are − 3219.3 ± 3.4, 3.9 ± 2.0 and 713.3 ± 3.0 kJ mol^− 1_, respectively. The highly endothermic enthalpy of formation of Y(BTC)·5.43(H₂O) reflects a thermodynamic penalty for a change in the coordination environment of Y metal atoms in the BTC framework compared to Y₂O₃. The high thermodynamic stability of the M-BTC framework employing La metal confirms greater stabilization from the use of larger metal atoms in frameworks with oxygen-based linkers. The results from thermodynamic analysis suggest water is a stabilizing agent. Thus, the choice of metal atom and presence of guest water molecules can enthalpically stabilize the M-BTC materials by as much as ~ 3932 kJ mol^− 1. More broadly, the results indicate complex interplay among choice of metal, water content, and thermodynamic stability in M-BTC frameworks.</p></div>","PeriodicalId":20132,"journal":{"name":"Physics and Chemistry of Minerals","volume":"52 2","pages":""},"PeriodicalIF":1.2,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143554083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}