ACS Materials LettersPub Date : 2025-02-24DOI: 10.1021/acsmaterialslett.4c0183610.1021/acsmaterialslett.4c01836
Edgar J. Castanheira, Luís P. G. Monteiro, Rita Sobreiro-Almeida, Vítor M. Gaspar, Nina Kølln Wittig, Tiago R. Correia, Henrik Birkedal, João M. M. Rodrigues* and João F. Mano*,
{"title":"Freeform 3D Printing of Cell-Adsorptive Cryogels with Shape-Recoverability","authors":"Edgar J. Castanheira, Luís P. G. Monteiro, Rita Sobreiro-Almeida, Vítor M. Gaspar, Nina Kølln Wittig, Tiago R. Correia, Henrik Birkedal, João M. M. Rodrigues* and João F. Mano*, ","doi":"10.1021/acsmaterialslett.4c0183610.1021/acsmaterialslett.4c01836","DOIUrl":"https://doi.org/10.1021/acsmaterialslett.4c01836https://doi.org/10.1021/acsmaterialslett.4c01836","url":null,"abstract":"<p >The intricate porous network of cryogels enhances diffusivity, injectability, and shape-recovery properties, providing a valuable tool for minimally invasive biomedical applications. However, the injection of cell-loaded complex structures remains highly challenging. Here, we demonstrate the freeform 3D printing of fully protein-based macroporous cryogels with cell-adsorptive and shape-recoverable features. The 3D-printed cryogels surpass conventional cryogels, revealing successful injection, cell-adsorptive features, and a high interconnected porosity (99.2%). The rapid hydration process enables the efficient incorporation of individual cells or spheroids into the cryogel network. Using an in-liquid cell aspiration method, the constructs retained cellular content up to 89%, with <i>in vitro</i> culture revealing high viability and cell spreading over 14 days. Our findings highlight the potential of the cryogels’ macroporosity for cell loading and injectability. We anticipate that these off-the-shelf cryogels will pave the way for a new generation of self-adsorptive and injectable cryogels.</p>","PeriodicalId":19,"journal":{"name":"ACS Materials Letters","volume":"7 4","pages":"1152–1161 1152–1161"},"PeriodicalIF":9.6,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Macromolecular Chain Aggregation-Induced Multiscale Reinforcement for Strong and Antifatigue Hydrogels","authors":"Wenqian Xing, Yongchuan Wu, Hechuan Zhang, Haidi Wu and Jiefeng Gao*, ","doi":"10.1021/acsmaterialslett.4c0257010.1021/acsmaterialslett.4c02570","DOIUrl":"https://doi.org/10.1021/acsmaterialslett.4c02570https://doi.org/10.1021/acsmaterialslett.4c02570","url":null,"abstract":"<p >Hydrogels have potential applications in artificial cartilage, tendons, and ligaments, while still facing great challenges in simultaneous improvement of strength, toughness, and fatigue resistance. In this work, strong, tough, and ionically conductive hydrogels are prepared via the macromolecular chain aggregation engineered multiscale reinforcement strategy. The tensile strength, fracture strain, fracture energy and fatigue threshold can reach values as high as 10.21 ± 0.79 MPa, 1942.84 ± 162.92%, 71.58 ± 4.23 kJ/m<sup>2</sup>, and 1040.12 J/m<sup>2</sup>, respectively. The hydrogels with ionic conductivity up to 1.45 S/m can be used as piezoresistive sensors for detection of various human body motions. This article provides a strategy for fabricating strong, tough, stretchable, and fatigue-resistant hydrogels with promising applications in flexible and wearable electronics.</p>","PeriodicalId":19,"journal":{"name":"ACS Materials Letters","volume":"7 4","pages":"1162–1170 1162–1170"},"PeriodicalIF":9.6,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Circularly Polarized Room-Temperature Phosphorescence from Marine Polysaccharide-Based Helical Assemblies","authors":"Mingjie Wang, Zhaocun Shen*, Fang Zhang, Qiuya Yang, Zihan Han, Yu An, Hongze Ma, Zhichao Xu, Jiancheng Liu, Wei Yuan, Kunyan Sui* and Yanli Zhao*, ","doi":"10.1021/acsmaterialslett.5c0000410.1021/acsmaterialslett.5c00004","DOIUrl":"https://doi.org/10.1021/acsmaterialslett.5c00004https://doi.org/10.1021/acsmaterialslett.5c00004","url":null,"abstract":"<p >Development of circularly polarized room-temperature phosphorescence (CP-RTP) materials based on natural macromolecules remains a great challenge. Herein, we demonstrate a chiral coassembly approach to construct CP-RTP materials using marine polysaccharides. The chiral anionic λ-carrageenan (λ-Car) coassembles with the achiral cationic phosphor bromophenyl-methyl-pyridinium iodide (PYI) through an electrostatic attraction interaction to form helical microfibers, which display blue fluorescence with circularly polarized luminescence. Moreover, the obtained helical λ-Car@PYI microfibers can be spin-coated into thin films, emitting orange CP-RTP due to the inhibition of RTP quenching in the solid state. Interestingly, further study reveals that the molecular structures and conformation of carrageenans have an important influence on their assembled structures and CP-RTP performance. This study provides a perspective on the design and preparation of CP-RTP materials from natural macromolecules.</p>","PeriodicalId":19,"journal":{"name":"ACS Materials Letters","volume":"7 4","pages":"1171–1178 1171–1178"},"PeriodicalIF":9.6,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784902","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synergizing Multiple Active Sites for Boosting Activity and Inhibiting Overoxidation in Photocatalytic Methane Valorization","authors":"Yanduo Liu, Xiyu Li*, Ferdi Karadas, Chao Gao* and Yujie Xiong*, ","doi":"10.1021/acsmaterialslett.5c0008810.1021/acsmaterialslett.5c00088","DOIUrl":"https://doi.org/10.1021/acsmaterialslett.5c00088https://doi.org/10.1021/acsmaterialslett.5c00088","url":null,"abstract":"<p >The pursuit of ecofriendly methane utilization has prompted the innovation of photocatalytic techniques to convert methane into profitable chemicals while achieving zero-waste output. However, the readily formed overoxidized products pose a significant challenge due to the oxidation by lattice oxygen in catalysts. To overcome this challenge, we have proposed a strategy of synergizing multiple active sites by integrating Ag nanoparticles and ZnIn<sub>2</sub>S<sub>4</sub> nanosheets onto ultrathin Ti(HPO<sub>4</sub>)<sub>2</sub>. The formed Ti(HPO<sub>4</sub>)<sub>2</sub>/ZnIn<sub>2</sub>S<sub>4</sub> heterojunction promotes the formation of active Ti<sup>3+</sup> sites induced by photogenerated electrons, while the synergistic interaction between Ti<sup>3+</sup> sites (methane adsorption centers), lattice oxygen (activation sites), and Ag nanoparticles (methyl desorption sites) boosts activity and inhibits overoxidation in methane conversion. The constructed photocatalyst demonstrates a remarkable 98% selectivity for ethane production at a rate of 280 μmol·g<sup>–1</sup>·h<sup>–1</sup>, accompanied by stoichiometric hydrogen production. This work highlights a strategy of synergizing multiple active sites for designing photocatalysts for methane valorization.</p>","PeriodicalId":19,"journal":{"name":"ACS Materials Letters","volume":"7 4","pages":"1144–1151 1144–1151"},"PeriodicalIF":9.6,"publicationDate":"2025-02-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Materials LettersPub Date : 2025-02-23DOI: 10.1021/acsmaterialslett.5c0005710.1021/acsmaterialslett.5c00057
Tao Zhang, Qingquan He*, Xiuyuan Chen, An Chen, Jiewen Yu, Shicheng Pan, Gang Xu, Zenan Zhang, Xiaolong Bian, Gaopeng Xu, Kun Zhou, Ting Chen, Guochao Lu, Lisha Fan, Jing Li, Benjamin Agyei-Tuffour, David Dodoo-Arhin and Jun Pan*,
{"title":"Tailoring Molecular Conjugation Size for Efficient Defect Passivation in Perovskite Photovoltaics","authors":"Tao Zhang, Qingquan He*, Xiuyuan Chen, An Chen, Jiewen Yu, Shicheng Pan, Gang Xu, Zenan Zhang, Xiaolong Bian, Gaopeng Xu, Kun Zhou, Ting Chen, Guochao Lu, Lisha Fan, Jing Li, Benjamin Agyei-Tuffour, David Dodoo-Arhin and Jun Pan*, ","doi":"10.1021/acsmaterialslett.5c0005710.1021/acsmaterialslett.5c00057","DOIUrl":"https://doi.org/10.1021/acsmaterialslett.5c00057https://doi.org/10.1021/acsmaterialslett.5c00057","url":null,"abstract":"<p >Film surface defects impede the performance of perovskite solar cells. Conjugated molecules with electron-donating/withdrawing groups have demonstrated efficacy in passivating these defects. However, the influence of the conjugated backbone on the passivation state of functional groups has remained insufficiently explored. In this study, we investigated the passivation effectiveness of C═O and N–H groups in different conjugated environments using 2,3-dihydroquinolin-4(1H)-one (DQLO), quinolin-4(1H)-one (QLO), and acridin-9(10H)-one (ADO). Our findings revealed that underconjugated DQLO failed to passivate and even diminished the device performance. Conversely, the larger conjugated ADO led to an averaged electron density distribution and self-aggregation, reducing passivation effectiveness. Optimal passivation was achieved with QLO, resulting in a power conversion efficiency of 23.05% and enhanced stability, retaining 89.0% of initial performance after 1050 h at 30% R.H. and 92.1% after 230 h at 70 °C in N<sub>2</sub>. This research underscores the crucial role of conjugated backbones in enhancing the molecular passivation efficiency.</p>","PeriodicalId":19,"journal":{"name":"ACS Materials Letters","volume":"7 4","pages":"1135–1143 1135–1143"},"PeriodicalIF":9.6,"publicationDate":"2025-02-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Engineering an Inorganic-Rich Interphase with Versatile Nonflammable Electrolytes toward Stable Alkali Metal Batteries","authors":"Shuo Zhang, Guo Yang, Yanan Lai, Tongyue Xu, Xinwei Shi, Xin Zhong, Mingjin Cui*, Menghao Yang*, Jiwoong Bae and Yu Ding*, ","doi":"10.1021/acsmaterialslett.4c0261810.1021/acsmaterialslett.4c02618","DOIUrl":"https://doi.org/10.1021/acsmaterialslett.4c02618https://doi.org/10.1021/acsmaterialslett.4c02618","url":null,"abstract":"<p >Alkali metal-based anodes are considered key to increasing the energy density of batteries thanks to the low redox potential and high capacity. Nevertheless, their practical application has been hampered by safety issues caused by the high reactivity of alkali metals, as well as the flammability of conventional organic electrolytes. In this study, we report a type of intrinsically nonflammable, cost-effective, and high-performance electrolytes. Such a novel flame-retardant electrolyte consists of heptafluoro-1-methoxypropane and fluoroethylene carbonate. In the proof-of-concept demonstration, the LiCoO<sub>2</sub>-based battery achieves the capacity of 182.6 mAh g<sup>–1</sup> at a rate of 5C, with 81.2% capacity retention after 300 cycles even at a high upper cutoff voltage of 4.6 V. The Na ion battery can reach a capacity retention of 90.6% at an ultrahigh rate of 30C, and the K ion battery retains 84.2% of its initial capacity after 200 cycles.</p>","PeriodicalId":19,"journal":{"name":"ACS Materials Letters","volume":"7 4","pages":"1127–1134 1127–1134"},"PeriodicalIF":9.6,"publicationDate":"2025-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Materials LettersPub Date : 2025-02-20DOI: 10.1021/acsmaterialslett.4c0233810.1021/acsmaterialslett.4c02338
Yingxiang Zhai, Jingyi Zhou, Ben Dang, Xingping Cui, Shouxin Liu, Xuetong Shi, Ran Bi, Jian Li, Shujun Li*, Orlando J. Rojas* and Zhijun Chen*,
{"title":"Room-Temperature Phosphorescence from Bamboo Fibers and Designed Materials","authors":"Yingxiang Zhai, Jingyi Zhou, Ben Dang, Xingping Cui, Shouxin Liu, Xuetong Shi, Ran Bi, Jian Li, Shujun Li*, Orlando J. Rojas* and Zhijun Chen*, ","doi":"10.1021/acsmaterialslett.4c0233810.1021/acsmaterialslett.4c02338","DOIUrl":"https://doi.org/10.1021/acsmaterialslett.4c02338https://doi.org/10.1021/acsmaterialslett.4c02338","url":null,"abstract":"<p >Recent developments in room-temperature phosphorescence (RTP) from biobased polymers have shown great promise in realizing sustainable RTP systems. Here, we introduce an efficient “top-down” method to achieve RTP biofibers using bamboo following partial delignification (B-fibers). The photophysical characterization combined with structural, surface, and chemical inquiries along with DFT calculations revealed the fundamental reasons for RTP, associated with the interactions between cellulose, hemicelluloses, and the residual lignin. Multiple emissive oxygen-containing clusters and aromatic chromophores in the B-fibers were shown to be RTP-active with a lifetime of 294.9 ms. The RTP emission of the B-fibers was found to be sensitive to temperature, excitation, and humidity. Moreover, when combined with a water-soluble fluorescent dye, red afterglow emission was demonstrated under the effect of energy transfer. Following these results, we synthesized functional luminescent materials (paper, films, textiles, and aerogels), proposed herein as practical, sustainable, and compostable choices for photoexcitation in the visible range.</p>","PeriodicalId":19,"journal":{"name":"ACS Materials Letters","volume":"7 3","pages":"1119–1126 1119–1126"},"PeriodicalIF":9.6,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsmaterialslett.4c02338","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143528600","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Materials LettersPub Date : 2025-02-20DOI: 10.1021/acsmaterialslett.4c0261210.1021/acsmaterialslett.4c02612
Jinyu Chang, Ning Ding, Qi Sun*, Zihao Wei, Ziheng Zhan, Xiaoting Ren, Jinxuan He, Shenghua Li* and Siping Pang*,
{"title":"In-Situ Modulation of Weak Interactions within a Hydrogen-Bonded Metal–Organic Framework (HMOF) for Superior Propellant Application","authors":"Jinyu Chang, Ning Ding, Qi Sun*, Zihao Wei, Ziheng Zhan, Xiaoting Ren, Jinxuan He, Shenghua Li* and Siping Pang*, ","doi":"10.1021/acsmaterialslett.4c0261210.1021/acsmaterialslett.4c02612","DOIUrl":"https://doi.org/10.1021/acsmaterialslett.4c02612https://doi.org/10.1021/acsmaterialslett.4c02612","url":null,"abstract":"<p >In this study, we demonstrate the targeted insertion of additional Cu(II) into a hydrogen-bonded metal–organic framework, HMOF(Cu-atrz-nt), thereby achieving the in-situ modulation of hydrogen bonds (HBs) into coordination bonds (CBs) with virtually no alteration to the framework structure, converting HMOF(Cu-atrz-nt) into a purely coordinated MOF(Cu-atrz-nt). Significantly different from classical MOF-5 and ZIF-8, HMOF(Cu-atrz-nt) and MOF(Cu-atrz-nt) exhibit markedly stronger exothermicity along with truncated HB and CB characteristics and electronic properties, showing outstanding but distinct catalytic combustion effects on key propellant components such as RDX, HMX, CL-20, and AP. This study aims to enhance the comprehension of the weak interactions of framework materials while uncovering novel and exciting prospects for practical applications.</p>","PeriodicalId":19,"journal":{"name":"ACS Materials Letters","volume":"7 3","pages":"1112–1118 1112–1118"},"PeriodicalIF":9.6,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143528549","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Multifunctional Antireflection Layer of a Bifacial Perovskite ((FA0.95Cs0.05)PbI3)0.975(MAPbBr3)0.025) Solar Cell Enhances Its Bifaciality, Stability, and Environmental Adaptability","authors":"Yaliang Han, Xiaopeng Feng, Yijin Wei, Lin Han, Bingqian Zhang, Qichao Meng, Boyang Lu, Changcheng Cui, Hao Wei, Yimeng Li, Zucheng Wu, Rongxiu Liu, Shengren Xia, Xiao Wang, Qingfu Wang, Lan Cao*, Zhipeng Shao*, Shuping Pang* and Guanglei Cui*, ","doi":"10.1021/acsmaterialslett.5c0011510.1021/acsmaterialslett.5c00115","DOIUrl":"https://doi.org/10.1021/acsmaterialslett.5c00115https://doi.org/10.1021/acsmaterialslett.5c00115","url":null,"abstract":"<p >Bifacial perovskite solar cells (PSCs) can significantly enhance power generation by utilizing both front- and rear-side light, yet rear-side efficiency is often limited by reflection losses and environmental factors. A dual-functional organic–inorganic bilayer antireflective coating (ARC) composed of PMMA and MgF<sub>2</sub> was designed to improve both bifaciality and device stability. Three-dimensional finite-difference time-domain (FDTD) simulations optimized the ARC thickness, achieving a 2.37% increase in the rear-side transmittance. The champion cell demonstrated a front-side efficiency of 24.12%, a rear-side efficiency of 21.37%, and 88% bifaciality. Under simulated sand conditions (20% rear-side reflectance), the equivalent bifacial efficiency reached 28.33%. Additionally, the bilayer ARC effectively blocked moisture and oxygen ingress, enhancing device stability under high-humidity and high-temperature conditions, making these PSCs ideal for environments with varying reflectance.</p>","PeriodicalId":19,"journal":{"name":"ACS Materials Letters","volume":"7 3","pages":"1077–1084 1077–1084"},"PeriodicalIF":9.6,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143528547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Materials LettersPub Date : 2025-02-19DOI: 10.1021/acsmaterialslett.4c0211310.1021/acsmaterialslett.4c02113
Lihua Fan, Yixin Dong, Balarabe Bilyaminu Ismail, Luyao Zhang, Yiheng Shi, Di Wu, Yongning Wu and Guoliang Li*,
{"title":"The Antimicrobial Activity and Resistance Evolution of Nanomaterials: A Review","authors":"Lihua Fan, Yixin Dong, Balarabe Bilyaminu Ismail, Luyao Zhang, Yiheng Shi, Di Wu, Yongning Wu and Guoliang Li*, ","doi":"10.1021/acsmaterialslett.4c0211310.1021/acsmaterialslett.4c02113","DOIUrl":"https://doi.org/10.1021/acsmaterialslett.4c02113https://doi.org/10.1021/acsmaterialslett.4c02113","url":null,"abstract":"<p >The pervasive threat of microbial infections, compromising human health, compounded by the rising incidence of multidrug-resistant bacteria, has underscored the urgent need for the development of innovative antimicrobial strategies. Nanomaterials have garnered substantial attention as alternative antimicrobial materials, owing to their remarkable chemical and physical properties. Despite the prominent bactericidal activity of these nanomaterials, some studies have proposed otherwise, suggesting that certain nanomaterials can potentially trigger the evolution of antimicrobial resistance (AMR). Therefore, it is urgent to elucidate the underlying mechanism governing the dual characteristics of antimicrobial nanomaterials. This Review commences by providing an overview of the antimicrobial properties of three distinct nanomaterials. Subsequently, it delves into the primary inactivation mechanisms and analyzes the physicochemical factors influencing their antimicrobial activity. Concurrently, the impact of molecular initiation events on AMR evolution via nanomicrobe interactions is systematically elucidated, enabling the proposal of four guiding design principles to mitigate AMR evolution.</p>","PeriodicalId":19,"journal":{"name":"ACS Materials Letters","volume":"7 3","pages":"1085–1111 1085–1111"},"PeriodicalIF":9.6,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143528551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}