Vandana Kachhwaha, Pooja Kumari, Naresh Giri, P. Mishra
{"title":"Evaluation of Lead Removal by Activated Citrus Sinensis Biochar Impregnated with Calcium Alginate Beads","authors":"Vandana Kachhwaha, Pooja Kumari, Naresh Giri, P. Mishra","doi":"10.13005/ojc/390615","DOIUrl":"https://doi.org/10.13005/ojc/390615","url":null,"abstract":"This study introduces an innovative method of using activated carbon derived from orange peels incorporated into calcium alginate beads to remove lead from synthetic water efficiently. This novel approach demonstrates remarkable effectiveness in addressing lead pollution in water. Established techniques such as SEM and FTIR were employed to characterize the adsorbents created in the laboratories. Batch studies confirmed the lead adsorbed were conducted to evaluate the efficiency of lead removal, with the highest removal efficiencies achieved at pH 6.5 (90.3%), an adsorbent dose of 2 mg (90.3%), a contact time of 50 minutes (92.3%), and an initial lead solution concentration of 20 ppm (93.2%). The study employed various adsorption models, including Langmuir, Freundlich, and Tempkin models. The Langmuir model exhibited an excellent fit to the adsorption isotherm at 60 °C, as indicated by a high linear regression correlation coefficient. For the bioadsorption process, pseudo-second-order kinetics fits well (R2 = 0.9992). The analytical results verify that activated carbon from discarded orange peels and calcium alginate beads effectively removes Pb, offering an encouraging solution for water purification challenges.","PeriodicalId":19599,"journal":{"name":"Oriental Journal Of Chemistry","volume":"3 4","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139153483","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Efficient Adsorption of Trivalent Rare Earth Elements Using Nano Copper Ferrite: Kinetics, Isotherms and Thermodynamics","authors":"Sudha Thotakura","doi":"10.13005/ojc/390628","DOIUrl":"https://doi.org/10.13005/ojc/390628","url":null,"abstract":"Rare earth elements (REEs) have versatile applications in various industries and are thrown as industrial waste waters, which leads to serious environmental issues.This paper describes the adsorption efficiency of nano copper ferrite on REEs namely lanthanum and cerium in their trivalent states at room temperature and at the optimum conditions of pH, contact time, adsorbent, adsorbate dosage,temperature etc. The batch adsorption studies were conducted for the adsorption studies using ICPAES (Inductive coupled plasma atomic emission spectro photometer). In addition the data is studied for Langmuir and Freundlich models and observed that data well fitted to Langmuir monolayer adsorption. From the graph and intercept values of theoretical and experimental values, the pseudo second order kinetics are followed. Thermodynamic parameters reveal that reaction is spontaneous and endothermic. From the over all observations like fast kinetics, chemical stability, high adsorption capacity it is concluded that nano CuFe 2 O 4 has maximum efficiency for the adsorption of REEs","PeriodicalId":19599,"journal":{"name":"Oriental Journal Of Chemistry","volume":"2 4","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139153621","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Rheology of Cottonseed (Gossypium hirsutum) Oil used as Biodegradable Lubricant","authors":"Ioana Stanciu","doi":"10.13005/ojc/390633","DOIUrl":"https://doi.org/10.13005/ojc/390633","url":null,"abstract":"Vegetable oils are often associated with well-known varieties like sunflower, olive, and corn. However, there are lesser-known options worth exploring to appreciate their distinct qualities. One such overlooked oil is cottonseed oil, derived from the Malvaceae cotton family plant. In a recent study, we delved into the rheological behavior of cottonseed oil. Similar to many vegetable oils, it exhibits a non-Newtonian behavior, making it a viable alternative to mineral oils. The rheological analysis was conducted using the Brookfield RVDV II I Ultra Rheometer, with shear rates incrementally increasing.","PeriodicalId":19599,"journal":{"name":"Oriental Journal Of Chemistry","volume":"159 5","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139153829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mokhlesur R. M, Tahmid C. A, Hassan S, Zubaer M, Awang M, Hasan M
{"title":"Enhancing Cannabis Extraction Efficiency and Sustainability through Quantum Computing: A Review","authors":"Mokhlesur R. M, Tahmid C. A, Hassan S, Zubaer M, Awang M, Hasan M","doi":"10.13005/ojc/390604","DOIUrl":"https://doi.org/10.13005/ojc/390604","url":null,"abstract":"The plant is also known as hemp, although this term is often used only to refer to varieties of cannabis cultivated for non-drug use. Cannabis has long been used as hemp fiber, hemp seeds and their oil, hemp leaves as vegetable and juice, for medicinal purposes and as a recreational drug. It has been widely used specifically in incense, peaceful sleep for cancer affected patients and traditional medicine. Its common uses include treating knee joint pain, inflammatory-related complaints, diarrhea, and a tonic, sedative, and cardio caring agent. Cannabis sativa is the hemp plant from which marijuana and cannabinoids (leaves, stems, seeds) are derived. The most potent form of this plant's extracts is hash oil, a liquid. Quantum computing, on the other hand, offers unprecedented computational power and can revolutionize various scientific fields. The study's goal is to explore the potential of quantum computing to enhance the extraction process. By employing quantum algorithms, the project aims to optimize critical parameters such as pressure, temperature, and extraction time, leading to improved efficiency and higher yields. Quantum simulations will model the behavior of CO2 as a supercritical fluid within the cannabis matrix, supplying insights into the complex dynamics of the extraction process. Finally, the use of quantum algorithms promises to ease the development of more efficient and sustainable extraction methods, resulting in the production of high-quality cannabis-derived products with enhanced medicinal and industrial applications.","PeriodicalId":19599,"journal":{"name":"Oriental Journal Of Chemistry","volume":"113 4","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139153955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Utilization of Granular Activated Carbon for Sustainable Environmental Contaminants Remediation","authors":"Y. K. Meshram, R. U. Khope, Reshal A. Deshmukh","doi":"10.13005/ojc/390631","DOIUrl":"https://doi.org/10.13005/ojc/390631","url":null,"abstract":"An environment eco-friendly adsorbents such as filtrasorb-816 and filtrasorb-820 were used in this work. For the evaluation of the adsorption of manganese from the aqueous phase, granular activated carbons were used in conjunction with organic ligands such as 3,5-Dinitrobenzoic acid. The phenomenon of adsorption characteristics of manganese in an aqueous phase was studied at a constant temperature of 25 ±1℃ C and pH 5. Granular activated carbons were characterized by SEM analysis. Experimental data were tested by using Pseudo first and Pseudo second-order kinetic models. From the results, it was investigated that Pesudo second-order data is more favorable than the pseudo-first-order for this system. The Langmuir, Freundlich, and Temkin isotherms models were used to describe the equilibrium characteristics of adsorption of Mn2+ onto activated carbon but the R2 value of the Langmuir isotherm model was higher than other isotherms and hence it is the best fit. From this study, it was found that F-820 has more adsorption capacity to scavenge Mn2+ than F-816 from aqueous phase","PeriodicalId":19599,"journal":{"name":"Oriental Journal Of Chemistry","volume":"118 17","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139154810","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis, Structures and Antimicrobial Activities of Novel Schiff Base Ligand and Its Metal Complexes","authors":"S. Adhao, Rahul Ramchandra Wagh","doi":"10.13005/ojc/390617","DOIUrl":"https://doi.org/10.13005/ojc/390617","url":null,"abstract":"A novel ligand (E)-7-hydroxy-4-methyl-8-(1-(naphthalen-1-ylimino) ethyl)-2H-chromen-2-one [HOMNIEC] was synthesized by condensation of 8-acetyl-7-hydroxy-4-methyl-2H-chromen-2-one and Naphthalen-1-amine by the reported method. The metal complexes with this ligand were synthesized by using a common new method. FTIR, 1H NMR, Mass Spectrometry and TGA techniques were used to confirm their structures. The FTIR spectral data indicate that the ligand was coordinated with the metal ions through the phenolic oxygen on coumarin moiety and nitrogen of azomethine. The ligand and complexes were examined for in vitro antimicrobial activities using broth microdilution method in DMSO medium against Escherichia Coli (MTCC 443) and Pseudomonas Aeruginosa (MTCC 1688) a gram-negative bacterial strain, Staphylococcus Aureus (MTCC 96) and Streptococcus Pyogenes (MTCC 442) a gram-positive bacterial strain, and Candida Albicans (MTCC 227), Aspergillus Clavatus (MTCC 1323) and Aspergillus Niger (MTCC 280) fungal strains. The metal complexes were found to have enhanced antimicrobial activities compare to the Schiff base [HOMNIEC] ligand. Especially, the antifungal activity of Cu(II) and Zn(II) ions complexes was found to be twofold more than the standard drug griseofulvin against C. Albicans.","PeriodicalId":19599,"journal":{"name":"Oriental Journal Of Chemistry","volume":"159 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139153833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D.China Babu, M. Alagusundaram, G. S. S. Harsha, Shailender Sing Nerwarya, G. Venkateshwarlu, A. Parameswari, SK. Aleesha
{"title":"LC/MS/MS Method Development and Validation for the Estimation of Lasmiditan in Bulk and Pharmaceutical Formulation","authors":"D.China Babu, M. Alagusundaram, G. S. S. Harsha, Shailender Sing Nerwarya, G. Venkateshwarlu, A. Parameswari, SK. Aleesha","doi":"10.13005/ojc/390625","DOIUrl":"https://doi.org/10.13005/ojc/390625","url":null,"abstract":"Background: Lasmiditan is an agonist of 5HT1F receptor, acute migraine is treated and oral dose is safe and effective. No analytical methods were reported on Lasmiditan Drug. Objectives: The goal of the current project is to create a quick, effective, and reproducible LC/MS/MS method for the estimation of Lasmiditan. The mobile phase was used Acetonitrile: 0.1% formic acid (70:30) in the developed method, and it was running down a C18 column (SP) with dimensions of 150 mm, 4.6 mm i.d., and 3.5 µm at a rate of 1 mL/min. The [M+H]+ ion m/z ratio for the substance was observed in the mass spectrum was 378.24. The drug had a retention time of 2.3 minutes. The linearity range was found to be in between 12.50 ng/mL and 75 ng/mL. The regression coefficient value was found to be 0.999, which is good satisfactory value for linearity. The LOD and LOQ for baseline measurement and detection were 0.66 ng/mL and 2.22 ng/mL, respectively; the method was shown good accuracy and precision levels, and it was proved through the assay values. The method was proved as robust after deliberated changes in parameters of flow rate (±0.2mL) and organic phase (±3 mL) in mobile phase composition and values were found to be 99.50%-100.73% & 99.10%- 101.83% respectively. Conclusion: The LC/MS/MS method is more advanced and sensitive to determine the drugs at nanograms level. Hence developed method used for the regular assay. This is more sensitive, selective, and rapid for identification and quantification of LMT in the bulk and Pharmaceutical formulation.","PeriodicalId":19599,"journal":{"name":"Oriental Journal Of Chemistry","volume":"115 3","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139153953","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Syed Kashif Ali, G. Gambhir, G. Khuwaja, Sayeed Shabi, Safaa F. Saleh, Angum M M Ibrahim, Amal. A. Noureideen, Mawada Abubaker Abdelgadir Mohammed
{"title":"Determination of Caffeic acid in Cigarette Smoke and Urine by Electrochemical Methods Using Supramolecular Electroactive Materials grafted in Screen Printed Carbon Electrode","authors":"Syed Kashif Ali, G. Gambhir, G. Khuwaja, Sayeed Shabi, Safaa F. Saleh, Angum M M Ibrahim, Amal. A. Noureideen, Mawada Abubaker Abdelgadir Mohammed","doi":"10.13005/ojc/390606","DOIUrl":"https://doi.org/10.13005/ojc/390606","url":null,"abstract":"Selective determination of caffeic acid, was carried out by using Screen Printed Carbon Electrode (SPCE) to give a reliable, scalable, and inexpensive electrochemical method with enhanced analytical performance. SPCE was first activated by linear sweep voltammetry using KOH solution, followed by its electrochemical grafting with cyclodextrins. Britton Robinson buffer (BRB) solution having pH 8.1, demonstrated a clear electrocatalytic impact towards caffeic acid oxidation, which indicated a greater current response compared to the activated electrode in the cyclic voltammetric and square wave voltammetric (SWV) investigations. The SWV waves at the activated SPCE was used under ideal conditions to produce a linear calibration curve with detection limits of (LoD, 4 sb/m) and quantification limits of (LoQ, 11 sb/m) of 0.38 M and 1.1 M, respectively.","PeriodicalId":19599,"journal":{"name":"Oriental Journal Of Chemistry","volume":"100 8","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139154142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Applications of Guar gum 6-amino Caproic acid (GACA) Resin for Extraction of Cobalt and Zinc Metal Ions from References Waste Water Using Batch Method","authors":"Punam Singh Bhati, Ishwar Singh, A. V. Singh","doi":"10.13005/ojc/390611","DOIUrl":"https://doi.org/10.13005/ojc/390611","url":null,"abstract":"Natural Guar gum based resin which containing 6-amino caproic acid as a functional group has been synthesized. This modified ion exchange resin was used for removal of toxic metal ions from synthetic waste water using the principle of ion exchange mechanism. GACA resin was used for removal of Zn (II) and Co (II) metal ions from aqueous solution containing these metal ions. Zn (II) ion show maximum adsorption and Kd value at pH 5 while Co (II) show at pH 6. Zn (II) show maximum adsorption on GACA resin is 81.34% and for Co (II) is 73.3% which is good result.","PeriodicalId":19599,"journal":{"name":"Oriental Journal Of Chemistry","volume":"20 S31","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139154632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Characterization of Platinum (Pt) Based Nanocomposite Thin films","authors":"S. P. Singh, U. C. Srivastava","doi":"10.13005/ojc/390634","DOIUrl":"https://doi.org/10.13005/ojc/390634","url":null,"abstract":"In the present communication we are reporting experimentally observed data of Platinum (Pt) based nano composite thin films. Platinum (Pt) shows crystalline behavior whereas Antimony tri sulfide (Sb2S3) shows amorphous behavior, and it has layered structure. In this observation the ratio of Pt and Sb2S3 is taken in 1:10 respectively, due to which multiple peaks shown in X-ray Diffraction (XRD) and have studied its variation by doing UV-VIS spectroscopy of different thickness of deposited material. Therefore, by this analysis of the nano composite materials we can synthesize nanomaterials which have great applications in photodetectors, solar cells, drug delivery, Fuel Cell, sensors, bioimaging and many other materials fabrications.","PeriodicalId":19599,"journal":{"name":"Oriental Journal Of Chemistry","volume":"4 5","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139153727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}