Materials Characterization最新文献

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Resistance upsetting welding of Zr-Sn/Zr-Nb alloy: Material flow behavior, bonding mechanism and performance in extreme environments Zr-Sn/Zr-Nb合金抗镦粗焊接:极端环境下材料流动行为、结合机理及性能
IF 4.8 2区 材料科学
Materials Characterization Pub Date : 2025-05-02 DOI: 10.1016/j.matchar.2025.115111
Yuanbo Bi , Bingbing Chen , Zhiqiang Sun , Zhongfeng Xu , Li Lu , Xueliang Zhang , Zhen Luo
{"title":"Resistance upsetting welding of Zr-Sn/Zr-Nb alloy: Material flow behavior, bonding mechanism and performance in extreme environments","authors":"Yuanbo Bi ,&nbsp;Bingbing Chen ,&nbsp;Zhiqiang Sun ,&nbsp;Zhongfeng Xu ,&nbsp;Li Lu ,&nbsp;Xueliang Zhang ,&nbsp;Zhen Luo","doi":"10.1016/j.matchar.2025.115111","DOIUrl":"10.1016/j.matchar.2025.115111","url":null,"abstract":"<div><div>In the process of resistance upsetting welding (RUW) of Zr-Sn/Zr-Nb alloy in nuclear fuel rods, the quality of the joint is unstable, the bonding is not strong and the sealing is poor because of the inaccurate control of the parameters such as forging forces and current. The effects of different forging forces on the joint were investigated through microstructure characterization and thermal-electric-mechanical coupling numerical simulation. By revealing the evolution of grain morphology, twin density, material flow, grain boundary proportion, so as to explain the plastic deformation characteristics and microstructure evolution of joints under large current, local high strain and high temperature. The comprehensive properties of the joint are evaluated by water corrosion, bursting test and tensile test. Water corrosion only thickens the oxide layer near the self-healing line, with the thickness of the oxide layer in other areas being similar to that of the base metal. The joints with different forging forces fractured in the area far from the weld regardless of the bursting or tensile tests. The large forging force accelerates the material flow of the joint, resulting in a rapid narrowing and elongation of the weld nugget compared to the low forging force.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"225 ","pages":"Article 115111"},"PeriodicalIF":4.8,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Formation mechanism of carbide-coated oxide core-shell structure in FGH96 superalloys FGH96高温合金中碳化物包覆氧化物核壳结构的形成机理
IF 4.8 2区 材料科学
Materials Characterization Pub Date : 2025-05-02 DOI: 10.1016/j.matchar.2025.115108
Yang Liu , Yuanchen Liang , Chenguang Guo , Peng Zhang , Lin Zhang , Shaorong Zhang , Xuanhui Qu
{"title":"Formation mechanism of carbide-coated oxide core-shell structure in FGH96 superalloys","authors":"Yang Liu ,&nbsp;Yuanchen Liang ,&nbsp;Chenguang Guo ,&nbsp;Peng Zhang ,&nbsp;Lin Zhang ,&nbsp;Shaorong Zhang ,&nbsp;Xuanhui Qu","doi":"10.1016/j.matchar.2025.115108","DOIUrl":"10.1016/j.matchar.2025.115108","url":null,"abstract":"<div><div>The carbide-encapsulated oxide is a crucial component of prior particle boundaries (PPB), yet there still lacks direct evidence regarding its microscopic formation mechanism. In this work, Atom Probe Tomography and Transmission Electron Microscopy techniques were employed to investigate PPB in intermediate sintering states. It was found that the core-shell structure is related to the carbides and oxides already present on the powder surfaces, which slightly differs from the previously held conclusion that carbide nucleation and growth occur around isolated oxides as cores. When oxides and carbides (primarily M(<em>Ti</em>, <em>Nb</em>)C) from different powder surfaces come into contact, carbon elements from the interior of the powders migrate to the contact surfaces during sintering, triggering the growth of existing carbides. Ultimately, these growing carbides encapsulate adjacent oxide particles, forming a carbide-encapsulated oxide core-shell structure. Furthermore, inferring from the poor orientational relationship between MC carbides and the matrix, it is more likely that the carbides represent the growth of existing carbides rather than new nucleation. These findings provide insights into the formation mechanism of core-shell structure appeared in powder metallurgy superalloys, and suggests O may not influence the MC particles during sintering.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"225 ","pages":"Article 115108"},"PeriodicalIF":4.8,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904336","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of temperature on microstructure and mechanical properties of Ti/steel bimetallic composite component fabricated by hot compression bonding 温度对热压结合制备Ti/钢双金属复合构件组织和力学性能的影响
IF 4.8 2区 材料科学
Materials Characterization Pub Date : 2025-05-02 DOI: 10.1016/j.matchar.2025.115112
Mingyue Sun , He Xiao , Shaofei Ren , Huiqi Guo , Sheng Liu , Bin Xu
{"title":"Effect of temperature on microstructure and mechanical properties of Ti/steel bimetallic composite component fabricated by hot compression bonding","authors":"Mingyue Sun ,&nbsp;He Xiao ,&nbsp;Shaofei Ren ,&nbsp;Huiqi Guo ,&nbsp;Sheng Liu ,&nbsp;Bin Xu","doi":"10.1016/j.matchar.2025.115112","DOIUrl":"10.1016/j.matchar.2025.115112","url":null,"abstract":"<div><div>The objective of this study is to develop a hot compression bonding (HCB) process for Ti/steel bimetallic composite component in solid-state. The influence of temperature (800–1000 °C) on interfacial reaction, microstructure and tensile property of Ti/steel composites were investigated and the mechanisms were clarified. The results indicate the composite exhibited the highest ultimate tensile strength (UTS) of 489 MPa bonded at 850 °C (below α-β transition temperature), which is equivalent to 82 % of steel matrix and 100 % of titanium matrix. When the bonding temperature is above α-β transition temperature, the UTS achieved the highest 523 MPa at 1000 °C (equivalent to 86 % of steel matrix and 97 % of titanium matrix). The variation of tensile properties with increase of temperature is mainly due to the difference in interfacial intermetallic compounds (IMCs). Therefore, the phase formation and distribution under different temperature were systematically investigated. Theoretically, the formation sequence of the reaction phase is determined by the Gibbs free energy of the IMCs. The result shows the sequence is TiC &gt; Fe<sub>2</sub>Ti &gt; FeTi all the time, suggesting TiC always initially forms at the interface.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"225 ","pages":"Article 115112"},"PeriodicalIF":4.8,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143916537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanoscale 3D characterization of an Al-1Fe-1Zr alloy for additive manufacturing 用于增材制造的Al-1Fe-1Zr合金的纳米级3D表征
IF 4.8 2区 材料科学
Materials Characterization Pub Date : 2025-05-02 DOI: 10.1016/j.matchar.2025.115109
Deepak Mani , Peter Cloetens , Dmitry Karpov , Federico Monaco , Bechir Chehab , Ravi Shahani , Steven Van Petegem , Pere Barriobero-Vila , Katrin Bugelnig , Guillermo Requena
{"title":"Nanoscale 3D characterization of an Al-1Fe-1Zr alloy for additive manufacturing","authors":"Deepak Mani ,&nbsp;Peter Cloetens ,&nbsp;Dmitry Karpov ,&nbsp;Federico Monaco ,&nbsp;Bechir Chehab ,&nbsp;Ravi Shahani ,&nbsp;Steven Van Petegem ,&nbsp;Pere Barriobero-Vila ,&nbsp;Katrin Bugelnig ,&nbsp;Guillermo Requena","doi":"10.1016/j.matchar.2025.115109","DOIUrl":"10.1016/j.matchar.2025.115109","url":null,"abstract":"<div><div>The Al-1Fe-1Zr alloy exploits the non-equilibrium solidification dynamics inherent to laser powder bed fusion, characterized by high thermal gradients and rapid solidification front velocities. Here, we investigate the alloy's 3D microstructure using state-of-the-art synchrotron-based nano-tomography techniques. High-resolution holographic and near-field ptychographic X-ray computed tomography were employed, achieving spatial resolutions as small as 57 nm. Our comparative analysis shows that near-field ptychographic tomography offers superior signal-to-noise ratio and spatial resolution, while holographic tomography allows for faster data acquisition with minimal loss in quality. These methods reveal the 3D distribution, morphology, and interconnectivity of Fe-rich and Zr-rich intermetallic phases. Complementary X-ray fluorescence computed tomography further provides quantitative local information on elemental wt%, revealing Fe and Zr distribution with a resolution of 0.1 wt%. The findings highlight key microstructural features that contribute to the alloy's enhanced strength and thermal conductivity, offering critical insights for optimizing its performance in LPBF applications.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"225 ","pages":"Article 115109"},"PeriodicalIF":4.8,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143916633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure evolution and shear strength optimization in SiC ceramic/MA956 ODS steel joints brazed with Cu5Ti filler Cu5Ti钎料钎焊SiC陶瓷/MA956 ODS钢接头的组织演变及抗剪强度优化
IF 4.8 2区 材料科学
Materials Characterization Pub Date : 2025-05-02 DOI: 10.1016/j.matchar.2025.115107
S. Su , X.G. Song , W.L. Zhou , W. Fu , Y.Y. Song , F. Long , J. Qin , S.P. Hu
{"title":"Microstructure evolution and shear strength optimization in SiC ceramic/MA956 ODS steel joints brazed with Cu5Ti filler","authors":"S. Su ,&nbsp;X.G. Song ,&nbsp;W.L. Zhou ,&nbsp;W. Fu ,&nbsp;Y.Y. Song ,&nbsp;F. Long ,&nbsp;J. Qin ,&nbsp;S.P. Hu","doi":"10.1016/j.matchar.2025.115107","DOIUrl":"10.1016/j.matchar.2025.115107","url":null,"abstract":"<div><div>Joining of SiC ceramic and ODS steel is of great significance for the next-generation candidate component of nuclear reactors. In this work, SiC ceramic and MA956 ODS steel were brazed successfully using Cu<img>5Ti filler alloy. The effects of brazing temperature on the microstructure evolution and mechanical properties of the joints were investigated, and the microstructure evolution mechanism was explored. The joints brazed at 1060 °C for 10 min exhibited a typical interfacial microstructure composed of SiC /Cu<sub>6.69</sub>Si + graphite/TiC/Ti<sub>5</sub>Si<sub>3</sub>/Cu(s,s) /TiFeSi /Ti(<em>Fe</em>,<em>Cr</em>)Si/MA956. SiC exhibited pronounced thermal sensitivity and easily over-reacted with Cu, resulting in an excessively thick ceramic decomposition layer, which was widely observed on the joint fracture surface. The shear strength of the joints initially increased and then decreased with rising brazing temperature. At 1060 °C, the maximum shear strength of 42 MPa was obtained due to the moderate reaction between the base materials and the filler. This work will help provide more options for the selection of nuclear reactor structural materials.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"225 ","pages":"Article 115107"},"PeriodicalIF":4.8,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143916535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of a clustering algorithm for texture data 纹理数据聚类算法的评价
IF 4.8 2区 材料科学
Materials Characterization Pub Date : 2025-05-01 DOI: 10.1016/j.matchar.2025.115122
Alois C. Ott , Johannes Kronsteiner , Leo Schwarzmeier , Elias Theil , Aurel R. Arnoldt , Nikolaus P. Papenberg
{"title":"Evaluation of a clustering algorithm for texture data","authors":"Alois C. Ott ,&nbsp;Johannes Kronsteiner ,&nbsp;Leo Schwarzmeier ,&nbsp;Elias Theil ,&nbsp;Aurel R. Arnoldt ,&nbsp;Nikolaus P. Papenberg","doi":"10.1016/j.matchar.2025.115122","DOIUrl":"10.1016/j.matchar.2025.115122","url":null,"abstract":"<div><div>In forming simulations of complex part designs, material texture can play a crucial role. However, spatially resolved integration of texture is challenging due to large data size. A reduction in data size can be achieved by meso-scale approaches, such as the viscoplastic self-consistent (VPSC) model. The VPSC model calculates individual grain responses within a deformed matrix, therefore the total number of grains has a substantial impact on the computation time. In this work, an algorithm is presented that cumulatively reduces the number of grains, without causing significant deviations in the simulation results.</div><div>Our approach is based on a k-means algorithm. Instead of setting the number of k clusters, a fixed radius is used. The size of this cluster radius determines the degree of data reduction.</div><div>The impact of clustering-induced errors is evaluated for an extruded EN AW-6082 alloy via texture investigations and the flow curves of simulated tensile tests. These simulations were performed using the VPSC approach as well as a finite element model in combination with VPSC. The results provide an upper limit for data reduction with the presented algorithm.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"225 ","pages":"Article 115122"},"PeriodicalIF":4.8,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144071072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of microalloying with La and Nd on adiabatic shear behavior in ultra-coarse grained Cu alloy under quasistatic tensile loading 准静态拉伸载荷下La和Nd微合金化对超粗晶Cu合金绝热剪切行为的影响
IF 4.8 2区 材料科学
Materials Characterization Pub Date : 2025-04-30 DOI: 10.1016/j.matchar.2025.115105
Mingyi Zhang , Kunyu Chen , Yang Li , Wei Wang , Lehui Zhang , Chongyuan Huang , Puyou Ying , Jiaqiang Li , Yong Huan , Chong Zhao , Chi Xiao , Fei Liu
{"title":"Effect of microalloying with La and Nd on adiabatic shear behavior in ultra-coarse grained Cu alloy under quasistatic tensile loading","authors":"Mingyi Zhang ,&nbsp;Kunyu Chen ,&nbsp;Yang Li ,&nbsp;Wei Wang ,&nbsp;Lehui Zhang ,&nbsp;Chongyuan Huang ,&nbsp;Puyou Ying ,&nbsp;Jiaqiang Li ,&nbsp;Yong Huan ,&nbsp;Chong Zhao ,&nbsp;Chi Xiao ,&nbsp;Fei Liu","doi":"10.1016/j.matchar.2025.115105","DOIUrl":"10.1016/j.matchar.2025.115105","url":null,"abstract":"<div><div>Generally, adiabatic shear bands (ASBs) are formed under the conditions of dynamic loading and high strain rate deformation. Recently, we have observed the formation of the ASBs in ultra-coarse grained copper (Cu) alloys under quasi-static tensile loading. Our experimental results extend the formation mechanism and conditions of the ASBs. The results show that the addition of trace La and Nd elements in pure copper can promote the randomization and diversification of deformation texture, and inhibit the dynamic recovery process. The deformation mechanism of the as-casted rare-earth modified Cu alloy mainly includes grain boundary coordination deformation, dislocation slip and adiabatic shear deformation. The strengthening mechanism of the alloy mainly involves dispersion strengthening, grain refinement strengthening and strain hardening. The ASBs are formed in the pure Cu and Cu alloys during quasi-static tensile deformation, which is mainly related to the dynamic recrystallization process and the low strain rate sensitivity of the ultra-coarse grained Cu alloys.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"225 ","pages":"Article 115105"},"PeriodicalIF":4.8,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143899410","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure tailoring of Nb-based MAX phase by low temperature synthesis with layer-structured Nb2C powder and molten salt method 层状Nb2C粉末和熔盐法低温合成nb基MAX相的微观结构裁剪
IF 4.8 2区 材料科学
Materials Characterization Pub Date : 2025-04-30 DOI: 10.1016/j.matchar.2025.115106
Chaehyun Lim , Wonjune Choi , Jongmin Byun
{"title":"Microstructure tailoring of Nb-based MAX phase by low temperature synthesis with layer-structured Nb2C powder and molten salt method","authors":"Chaehyun Lim ,&nbsp;Wonjune Choi ,&nbsp;Jongmin Byun","doi":"10.1016/j.matchar.2025.115106","DOIUrl":"10.1016/j.matchar.2025.115106","url":null,"abstract":"<div><div>This study introduced a novel method to synthesize the Nb<sub>2</sub>AlC, i.e., MAX phase, using the molten salt method. The Nb<sub>2</sub>C phase was preferentially prepared using the Nb, Al, and graphite powders as starting materials. The parametric study enables the optimization of the synthesis condition, including the type of salt, the ratio of powder mixture to salt, synthesis temperature and time. High-quality Nb<sub>2</sub>C powder was prepared following the optimized recipe, which was used to synthesize the Nb<sub>2</sub>AlC powder. We confirmed that the Nb<sub>2</sub>C phase using the molten salt method offers several advantages for Nb<sub>2</sub>AlC MAX phase synthesis, compared to the NbC phase; Molten salt provided the diffusion path for the Al element to form a MAX phase while solid-to-solid diffusion required in the synthesis process without salt. In addition, the MAX phase was successfully synthesized at a relatively low temperature, 1100 °C, for 2 h.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"225 ","pages":"Article 115106"},"PeriodicalIF":4.8,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143906422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailorable elastic modulus of aluminum matrix composites via creation of interfacial intermetallic compounds 通过创建界面金属间化合物的铝基复合材料的可定制弹性模量
IF 4.8 2区 材料科学
Materials Characterization Pub Date : 2025-04-29 DOI: 10.1016/j.matchar.2025.115098
Xue Zhang , Xuexi Zhang , Mingfang Qian , Lin Geng
{"title":"Tailorable elastic modulus of aluminum matrix composites via creation of interfacial intermetallic compounds","authors":"Xue Zhang ,&nbsp;Xuexi Zhang ,&nbsp;Mingfang Qian ,&nbsp;Lin Geng","doi":"10.1016/j.matchar.2025.115098","DOIUrl":"10.1016/j.matchar.2025.115098","url":null,"abstract":"<div><div>The modulus is an intrinsic parameter of metals and alloys and is often difficult to be tailored by conventional alloying method. A feasible strategy to increase the elastic modulus (E) of metals and alloys is to introduce hard, high-modulus ceramics. However, these traditional ceramic reinforcers often have poor interfacial bonding with the base alloy and are difficult to control the content and distribution. In this paper, ductile NiTi particle (NiTip) was added in pure Al alloy by ball milling and spark plasma sintering (SPS). The modulus of the NiTi/Al composite was modulated via in-situ tailorable interfacial reaction and formation of different contents and types of intermetallic compounds between NiTip and Al during SPS process. The composite sintered at 530 °C for 10 min (530 °C-10 min) was free of interfacial reaction product. While the 560 °C-10 min composite showed 100–500 nm thick reaction layer composed of Al-Ti and Al-Ni compounds (in-situ interfacial phase content ∼5.2 vol%). At even higher sintering temperature, the 600 °C-10 min composite exhibited 3–10 μm thick interfacial reaction layer (in situ interfacial phase content ∼36.8 vol%). As a result, the E of the 600 °C-10 min composite reached 107.21 GPa and was 58.34 % higher than that of the 530 °C-10 min composite (67.71 GPa). The increase of E is mainly attributed to the introduction of the interfacial Al-Ti and Al-Ni intermetallic compounds in the composite formed during SPS. The interfacial reaction also enhanced the interfacial bonding strength between NiTip and Al matrix, which is also favorable for the composite modulus.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"225 ","pages":"Article 115098"},"PeriodicalIF":4.8,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143899560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Intermetallics growth behavior and microstructure-mechanical properties relationship of Mo/BNi-2/FeCrAl brazed joint Mo/BNi-2/FeCrAl钎焊接头的金属间化合物生长行为及显微组织-力学性能关系
IF 4.8 2区 材料科学
Materials Characterization Pub Date : 2025-04-29 DOI: 10.1016/j.matchar.2025.115092
Jincheng Lin , Bangyang Xiao , Hanyu Zhan , Xiujie He , Tiesong Lin , Peng He , Weiqi Yang , Lili Xing
{"title":"Intermetallics growth behavior and microstructure-mechanical properties relationship of Mo/BNi-2/FeCrAl brazed joint","authors":"Jincheng Lin ,&nbsp;Bangyang Xiao ,&nbsp;Hanyu Zhan ,&nbsp;Xiujie He ,&nbsp;Tiesong Lin ,&nbsp;Peng He ,&nbsp;Weiqi Yang ,&nbsp;Lili Xing","doi":"10.1016/j.matchar.2025.115092","DOIUrl":"10.1016/j.matchar.2025.115092","url":null,"abstract":"<div><div>The pure Mo metal was brazed to FeCrAl alloy by using the BNi-2 filler alloy. The wetting process, interfacial microstructure, reaction layer growth kinetics and joint mechanical properties were investigated. It's found that the reactive wetting involves a transition from Mo-Ni-Si reaction layer at liquid front to Mo<img>Ni reaction layer in wetting area. The growth kinetics of MoNi reaction layer is controlled by Mo<img>Ni short-circuit diffusion. Based on the diffusion-reaction model and experimental data, the time exponent <em>n</em> is calculated as 2.98 and the activation energy <em>Q</em> is 353.9 kJ·mol<sup>−1</sup>. At higher brazing temperature or prolonging the brazing time, a Si-rich layer composed of Mo<sub>2</sub>Ni<sub>3</sub>Si and MoNi<sub>4</sub> preferentially grows between Mo and MoNi layer. The mutual diffusion between filler alloy and FeCrAl promotes the formation of (Ni, Fe)Al, strip-shape <em>σ</em>(Fe,Cr) and (Fe,Ni)<sub>3</sub>Al nanophases in FeCrAl. The highest shear strength of 258 ± 41 MPa was obtained for the joint brazed at 990 °C for 10 min. The fracture morphology demonstrates that the thick MoNi layer degrades the joint performance.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"225 ","pages":"Article 115092"},"PeriodicalIF":4.8,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143895194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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