{"title":"氧化物+ TiN使等轴δ-铁素体晶粒形核,提高铁素体不锈钢焊缝的拉伸性能","authors":"Yuyang Hou , Kota Kadoi","doi":"10.1016/j.matchar.2025.115270","DOIUrl":null,"url":null,"abstract":"<div><div>This study investigated the tensile properties of ferritic stainless steel welds with Oxide+TiN and the crystal orientation relationship between oxides and TiN. It revealed that the ultimate tensile strength and elongation were improved by 15 % and 50 % in the equiaxed specimen nucleated by Oxide+TiN, respectively. The formation of TiN was accelerated on the oxides Ti<sub>2</sub>O<sub>3</sub>, Al<sub>2</sub>O<sub>3</sub>, Al<sub>2</sub>Ti<sub>7</sub>O<sub>15</sub>, and MgAl<sub>2</sub>O<sub>4</sub> for elucidating the δ-ferrite nucleation. Ti<sub>2</sub>O<sub>3</sub> and Al<sub>2</sub>O<sub>3</sub> exhibited {0001}oxide // {111}TiN and [1010]oxide // [110]TiN orientations, resulting in misfits of 0.6 % and 8.1 % with TiN, respectively. MgAl<sub>2</sub>O<sub>4</sub> was fully parallel to TiN in all crystal orientations and exhibited a misfit of 4.8 % with TiN. Al<sub>2</sub>Ti<sub>7</sub>O<sub>15</sub> was newly discovered as a nucleation site for TiN, attributed to a 3.6 % misfit in the orientation relationships of {204}Al<sub>2</sub>Ti<sub>7</sub>O<sub>15</sub> // {002}TiN, [20−1]Al<sub>2</sub>Ti<sub>7</sub>O<sub>15</sub> // [1−10]TiN, and [020]Al<sub>2</sub>Ti<sub>7</sub>O<sub>15</sub> // [220]TiN. The brittle to ductile transition of the tensile fracture was promoted by formation of equiaxed grain, which greatly random the slip system for larger intragranular deformation.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"227 ","pages":"Article 115270"},"PeriodicalIF":4.8000,"publicationDate":"2025-06-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Nucleation of equiaxed δ-ferrite grain by Oxide + TiN to improve tensile properties of ferritic stainless steel welds\",\"authors\":\"Yuyang Hou , Kota Kadoi\",\"doi\":\"10.1016/j.matchar.2025.115270\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study investigated the tensile properties of ferritic stainless steel welds with Oxide+TiN and the crystal orientation relationship between oxides and TiN. It revealed that the ultimate tensile strength and elongation were improved by 15 % and 50 % in the equiaxed specimen nucleated by Oxide+TiN, respectively. The formation of TiN was accelerated on the oxides Ti<sub>2</sub>O<sub>3</sub>, Al<sub>2</sub>O<sub>3</sub>, Al<sub>2</sub>Ti<sub>7</sub>O<sub>15</sub>, and MgAl<sub>2</sub>O<sub>4</sub> for elucidating the δ-ferrite nucleation. Ti<sub>2</sub>O<sub>3</sub> and Al<sub>2</sub>O<sub>3</sub> exhibited {0001}oxide // {111}TiN and [1010]oxide // [110]TiN orientations, resulting in misfits of 0.6 % and 8.1 % with TiN, respectively. MgAl<sub>2</sub>O<sub>4</sub> was fully parallel to TiN in all crystal orientations and exhibited a misfit of 4.8 % with TiN. Al<sub>2</sub>Ti<sub>7</sub>O<sub>15</sub> was newly discovered as a nucleation site for TiN, attributed to a 3.6 % misfit in the orientation relationships of {204}Al<sub>2</sub>Ti<sub>7</sub>O<sub>15</sub> // {002}TiN, [20−1]Al<sub>2</sub>Ti<sub>7</sub>O<sub>15</sub> // [1−10]TiN, and [020]Al<sub>2</sub>Ti<sub>7</sub>O<sub>15</sub> // [220]TiN. The brittle to ductile transition of the tensile fracture was promoted by formation of equiaxed grain, which greatly random the slip system for larger intragranular deformation.</div></div>\",\"PeriodicalId\":18727,\"journal\":{\"name\":\"Materials Characterization\",\"volume\":\"227 \",\"pages\":\"Article 115270\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2025-06-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Characterization\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1044580325005595\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CHARACTERIZATION & TESTING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Characterization","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1044580325005595","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
Nucleation of equiaxed δ-ferrite grain by Oxide + TiN to improve tensile properties of ferritic stainless steel welds
This study investigated the tensile properties of ferritic stainless steel welds with Oxide+TiN and the crystal orientation relationship between oxides and TiN. It revealed that the ultimate tensile strength and elongation were improved by 15 % and 50 % in the equiaxed specimen nucleated by Oxide+TiN, respectively. The formation of TiN was accelerated on the oxides Ti2O3, Al2O3, Al2Ti7O15, and MgAl2O4 for elucidating the δ-ferrite nucleation. Ti2O3 and Al2O3 exhibited {0001}oxide // {111}TiN and [1010]oxide // [110]TiN orientations, resulting in misfits of 0.6 % and 8.1 % with TiN, respectively. MgAl2O4 was fully parallel to TiN in all crystal orientations and exhibited a misfit of 4.8 % with TiN. Al2Ti7O15 was newly discovered as a nucleation site for TiN, attributed to a 3.6 % misfit in the orientation relationships of {204}Al2Ti7O15 // {002}TiN, [20−1]Al2Ti7O15 // [1−10]TiN, and [020]Al2Ti7O15 // [220]TiN. The brittle to ductile transition of the tensile fracture was promoted by formation of equiaxed grain, which greatly random the slip system for larger intragranular deformation.
期刊介绍:
Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials.
The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal.
The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include:
Metals & Alloys
Ceramics
Nanomaterials
Biomedical materials
Optical materials
Composites
Natural Materials.