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Chemistry of gem-difluorovinyl sulfonates 宝石-二氟乙烯基磺酸盐的化学性质
IF 2.3 4区 化学
Mini-reviews in Organic Chemistry Pub Date : 2022-09-29 DOI: 10.2174/1570193x19666220929114415
Cai Zhang
{"title":"Chemistry of gem-difluorovinyl sulfonates","authors":"Cai Zhang","doi":"10.2174/1570193x19666220929114415","DOIUrl":"https://doi.org/10.2174/1570193x19666220929114415","url":null,"abstract":"\u0000\u0000Among various emerging organofluorine molecules, gem-difluorovinyl sulfonates are attractive building blocks and less used in organic reactions. This review article is concerned with recent advances in the organic reactions using gem-difluorovinyl sulfonates in recent years. We discussed the reactions of gem-difluorovinyl sulfonates with aldehydes, amines, imines, amides, boronic acids, aryl halides, etc. or addition, reduction, substitution and intramolecular 1,3-sulfonyl migration of gem-difluorovinyl sulfonates in nine approaches. The synthetic strategies described in this review provided diversely substituted fluorinated molecules.\u0000","PeriodicalId":18632,"journal":{"name":"Mini-reviews in Organic Chemistry","volume":" ","pages":""},"PeriodicalIF":2.3,"publicationDate":"2022-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45052850","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comprehensive Insight into Synthetic Strategies of Enigmol and Its Analogs as Therapeutic Agents Enigmol及其类似物治疗药物合成策略的综合研究
IF 2.3 4区 化学
Mini-reviews in Organic Chemistry Pub Date : 2022-08-20 DOI: 10.2174/1570193x19666220820115630
Parleen Kaur, Vasundhara Singh
{"title":"Comprehensive Insight into Synthetic Strategies of Enigmol and Its Analogs as Therapeutic Agents","authors":"Parleen Kaur, Vasundhara Singh","doi":"10.2174/1570193x19666220820115630","DOIUrl":"https://doi.org/10.2174/1570193x19666220820115630","url":null,"abstract":"\u0000\u00001-Deoxysphingolipids are a class of sphingolipids which lacks the primary hydroxyl group\u0000(C1-OH). Hence, it does not get converted/degraded to complex corresponding products like sphingosine-1-phosphate (SIP), a pro-mitotic. Enigmol, an orally bioavailable 1-deoxyphingolipid has shown\u0000potential against various different types of cancer cells along with impressive cytotoxic/antiproliferative properties. Due to its unique structural properties, Enigmol and its analogs have\u0000attracted considerable attention from synthetic organic chemists. This review provides an overview of\u0000all the synthetic approaches being followed for the synthesis of Enigmol and its structural analogs.\u0000","PeriodicalId":18632,"journal":{"name":"Mini-reviews in Organic Chemistry","volume":" ","pages":""},"PeriodicalIF":2.3,"publicationDate":"2022-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42099855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Palladium (Pd) based Photocatalysts for Suzuki Coupling Reactions: an overview 用于Suzuki偶联反应的钯基光催化剂：综述
IF 2.3 4区 化学
Mini-reviews in Organic Chemistry Pub Date : 2022-08-19 DOI: 10.2174/1570193x19666220819093803
J. J. Boruah, Siva Prasad Das
{"title":"Palladium (Pd) based Photocatalysts for Suzuki Coupling Reactions: an overview","authors":"J. J. Boruah, Siva Prasad Das","doi":"10.2174/1570193x19666220819093803","DOIUrl":"https://doi.org/10.2174/1570193x19666220819093803","url":null,"abstract":"\u0000\u0000Extensive research has been documented in the last few decades on the utilization of near IR, visible and UV light in organic chemical transformations. In this brief review, we provide an overview of the most noteworthy achievements in the area of photocatalytic Suzuki coupling reactions by palladium (Pd) based catalytic systems. The works on different types of Pd based photocatalysts for Suzuki coupling reaction and their characteristic as well as catalytic activity in terms of substrate scope, recyclability, TON or TOF are discussed herein.\u0000","PeriodicalId":18632,"journal":{"name":"Mini-reviews in Organic Chemistry","volume":" ","pages":""},"PeriodicalIF":2.3,"publicationDate":"2022-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45744185","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Propiolic acids in the synthesis of N-heterocycles 丙酸在N-杂环合成中的应用
IF 2.3 4区 化学
Mini-reviews in Organic Chemistry Pub Date : 2022-08-04 DOI: 10.2174/1570193x19666220804145501
Zhanyong Wang, Zhantong Liu, Nan Wang, Yuan-feng Tong
{"title":"Propiolic acids in the synthesis of N-heterocycles","authors":"Zhanyong Wang, Zhantong Liu, Nan Wang, Yuan-feng Tong","doi":"10.2174/1570193x19666220804145501","DOIUrl":"https://doi.org/10.2174/1570193x19666220804145501","url":null,"abstract":"\u0000\u0000This review discussed the synthetic applications of propiolic acids in the preparation of diverse N-heterocycles. 3~9-membered rings like azirines, β-lactams, oxazolidin-2-ones, 2-oxindoles, indoles, isoindolin-1-ones, imidazo[1,2-a]pyridines, triazoles, 2-pyridones, 2-quinolones, 1,4-benzothiazines, thiazinones, spiroindolines et al could be constructed via radical addition, four-component Ugi reactions, 1,3-dipolar cycloadditions, or Diels-Alder reaction mechanism. We hope this review will promote future research in this area.\u0000• Introduction\u0000","PeriodicalId":18632,"journal":{"name":"Mini-reviews in Organic Chemistry","volume":" ","pages":""},"PeriodicalIF":2.3,"publicationDate":"2022-08-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47394491","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An Update with Recent Green Synthetic Approaches to Coumarins 香豆素绿色合成方法的最新进展
IF 2.3 4区 化学
Mini-reviews in Organic Chemistry Pub Date : 2022-07-01 DOI: 10.2174/1570193x19666220701111051
Bhargav Bhimani, Ashish D. Patel, Drashti Shah
{"title":"An Update with Recent Green Synthetic Approaches to Coumarins","authors":"Bhargav Bhimani, Ashish D. Patel, Drashti Shah","doi":"10.2174/1570193x19666220701111051","DOIUrl":"https://doi.org/10.2174/1570193x19666220701111051","url":null,"abstract":"\u0000\u0000Coumarin and its derivatives are privileged heterocyclic motifs and important building blocks for developing the biologically active compound due to its significant role in the development of new drugs. As a result, many methodologies have been developed to synthesize this important class of compounds. However, some methods are associated with toxic and corrosive catalysts, longer reaction time, poor yield, less purity, and by-products along with the desired product. In order to minimize the utilization and generation of toxic organic substances, green synthetic methods are applied in this manner. Green chemistry methods cover a wide range of methods, including the application of ultrasound and microwaves, ionic liquids and deep eutectic solvents, solvent-free and catalyst-free synthesis, and mechanosynthesis. These green synthetic methods have successfully performed all typical condensation reactions for coumarin synthesis like Knoevenagel, Perkin, Kostanecki-Robinson, Pechmann, and Reformatsky reactions. Compared to conventional methods, these methods not only minimize the use and generation of harmful chemicals but also improve reaction efficiency in terms of product yields, purity, energy consumption, and post-synthetic procedures. Due to the implication of coumarin (2-oxo-2H-1-benzopyran) backbone as a biologically active ubiquitous fragment and the recent demands of reducing toxic solvents, catalysts, and energy consumption, this review summarized various green synthetic methods for coumarin synthesis. Moreover, researchers working on this coumarin scaffold synthesis can find handy information from this review on the green synthetic approaches to their synthesis.\u0000","PeriodicalId":18632,"journal":{"name":"Mini-reviews in Organic Chemistry","volume":" ","pages":""},"PeriodicalIF":2.3,"publicationDate":"2022-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49457655","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemistry of 2-Aminoquinolines: Synthesis, Reactivity, and Biological Activities (Part III). 2-氨基喹啉的化学：合成、反应性和生物活性（第三部分）。
IF 2.3 4区 化学
Mini-reviews in Organic Chemistry Pub Date : 2022-06-29 DOI: 10.2174/1570193x19666220629103027
M. Gouda, G. G. El-Bana
{"title":"Chemistry of 2-Aminoquinolines: Synthesis, Reactivity, and Biological Activities (Part III).","authors":"M. Gouda, G. G. El-Bana","doi":"10.2174/1570193x19666220629103027","DOIUrl":"https://doi.org/10.2174/1570193x19666220629103027","url":null,"abstract":"This review described the preparation of 2-chloroquinoline-3-carbaldehyde derivatives through Vilsmeier-Haack formylation of N-arylacetamides and the use of them as a key intermediate for the preparation of 2-aminoquinoline-3-carbaldehydes. The synthesis of the 2-aminoquinolines was explained through the following chemical reactions: Claisen-Schmidt condensation, 1, 3-dipolar cycloaddition, one-pot multicomponent reactions (MCRs), and reductive amination.","PeriodicalId":18632,"journal":{"name":"Mini-reviews in Organic Chemistry","volume":" ","pages":""},"PeriodicalIF":2.3,"publicationDate":"2022-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45700189","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent Progress on the Development and Application of Polymeric Nanofiltration Membranes: A Mini-Review 聚合物纳滤膜的开发与应用进展
IF 2.3 4区 化学
Mini-reviews in Organic Chemistry Pub Date : 2022-06-23 DOI: 10.2174/1570193x19666220623151653
Fabiana Rodrigues de Almeida, Ivana Lourenço de Mello Ferreira, R. A. dos Reis
{"title":"Recent Progress on the Development and Application of Polymeric Nanofiltration Membranes: A Mini-Review","authors":"Fabiana Rodrigues de Almeida, Ivana Lourenço de Mello Ferreira, R. A. dos Reis","doi":"10.2174/1570193x19666220623151653","DOIUrl":"https://doi.org/10.2174/1570193x19666220623151653","url":null,"abstract":"\u0000\u0000The inefficiency of conventional water treatment methods in terms of removing micropollutants is prompting research into other technologies. Among these, the process of separation by nanofiltration membranes is particularly promising because of the low operating cost, rapid implementation of the system, high selectivity and easy integration with other treatment processes. Studies in this area are recent and there are many avenues for future research. This mini-review describes the main characteristics of the polymeric membranes used for nanofiltration, and the various methods and polymer materials under investigation. At the end, we report the result of a survey conducted in the ScienceDirect, Scopus and Web of Science platforms using different keywords, to depict a global panorama of the current research involving polymeric nanofiltration membranes. The results revealed a particular dearth of published studies involving application of these membranes to remove micropollutants with endocrine disruptive action. Furthermore, research involving nanofiltration membranes utilizing calcium alginate is very recent. This study provides an overview of the investigation of polymeric nanofiltration membranes.\u0000","PeriodicalId":18632,"journal":{"name":"Mini-reviews in Organic Chemistry","volume":" ","pages":""},"PeriodicalIF":2.3,"publicationDate":"2022-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49225345","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Organic Chemistry and its Important Role in the Creation of Novel Functional Materials 有机化学及其在新型功能材料研制中的重要作用
IF 2.3 4区 化学
Mini-reviews in Organic Chemistry Pub Date : 2022-06-20 DOI: 10.2174/1570193x19666220620003035
Liu Jialei
{"title":"Organic Chemistry and its Important Role in the Creation of Novel Functional Materials","authors":"Liu Jialei","doi":"10.2174/1570193x19666220620003035","DOIUrl":"https://doi.org/10.2174/1570193x19666220620003035","url":null,"abstract":"<jats:sec>\u0000<jats:title />\u0000<jats:p />\u0000</jats:sec>","PeriodicalId":18632,"journal":{"name":"Mini-reviews in Organic Chemistry","volume":" ","pages":""},"PeriodicalIF":2.3,"publicationDate":"2022-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47467940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An Overview of Palladium-Catalyzed Fabrication of Some Heterocyclic Frameworks 钯催化制备杂环骨架的研究进展
IF 2.3 4区 化学
Mini-reviews in Organic Chemistry Pub Date : 2022-06-15 DOI: 10.2174/1570193x19666220615095645
A. P. Devi, A. Penoni, V. Akhmetova, R. Pawar, I. Fatimah, K. L. Ameta
{"title":"An Overview of Palladium-Catalyzed Fabrication of Some Heterocyclic Frameworks","authors":"A. P. Devi, A. Penoni, V. Akhmetova, R. Pawar, I. Fatimah, K. L. Ameta","doi":"10.2174/1570193x19666220615095645","DOIUrl":"https://doi.org/10.2174/1570193x19666220615095645","url":null,"abstract":"\u0000\u0000Heterocycles are the largest family of organic compounds due to their wide applications as therapeutic agents, synthetic intermediates, scaffolds, building blocks or fine chemicals. Heterocyclic compounds are continuously used in material science, biotechnology, pharmaceutical and agrochemical industries. In the past few years, the use of transition metal complexes especially palladium as a heterogeneous catalyst has become a trend for the synthesis of various organic compounds. Pd-catalyzed reactions have proven to be effective ways for synthesising a variety of heterocyclic compounds, which are a popular class of molecules in chemical study. Hence, in this review we have discussed the palladium catalyzed synthesis of various heterocyclic compounds i,e. furan, indole, quinoline, coumarin and some other heterocycle derivatives.\u0000","PeriodicalId":18632,"journal":{"name":"Mini-reviews in Organic Chemistry","volume":" ","pages":""},"PeriodicalIF":2.3,"publicationDate":"2022-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48210280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green is the New Black: Emerging Environmentally Friendly Prospects in the Synthesis of Quinoxaline Derivatives 绿色是新的黑色：喹喔啉衍生物合成中的环保前景
IF 2.3 4区 化学
Mini-reviews in Organic Chemistry Pub Date : 2022-06-06 DOI: 10.2174/1570193x19666220606100319
Lacksany Phongphane, M. N. Azmi
{"title":"Green is the New Black: Emerging Environmentally Friendly Prospects in the Synthesis of Quinoxaline Derivatives","authors":"Lacksany Phongphane, M. N. Azmi","doi":"10.2174/1570193x19666220606100319","DOIUrl":"https://doi.org/10.2174/1570193x19666220606100319","url":null,"abstract":"\u0000\u0000Functionalized polysubstituted quinoxalines have been widely reported to possess appealing biological activities of great pharmaceutical importance which drew researchers into exploring promising synthetical protocols. On top of that, prospects on green chemistry are driving research paradigms into more cost-effective, facile, environmental-friendly, sustainable, and scalable approaches. This paper reviews the green synthesis methods of quinoxaline derivatives using recyclable heterogeneous catalysts, green solvents and energy-mediated methods that have been extensively studied and published since 2010 to offer an insight into the ongoing greener trend in the scientific field.\u0000","PeriodicalId":18632,"journal":{"name":"Mini-reviews in Organic Chemistry","volume":" ","pages":""},"PeriodicalIF":2.3,"publicationDate":"2022-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43082353","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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