Chemistry of gem-difluorovinyl sulfonates

IF 1.9 4区 化学 Q2 CHEMISTRY, ORGANIC
Cai Zhang
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引用次数: 0

Abstract

Among various emerging organofluorine molecules, gem-difluorovinyl sulfonates are attractive building blocks and less used in organic reactions. This review article is concerned with recent advances in the organic reactions using gem-difluorovinyl sulfonates in recent years. We discussed the reactions of gem-difluorovinyl sulfonates with aldehydes, amines, imines, amides, boronic acids, aryl halides, etc. or addition, reduction, substitution and intramolecular 1,3-sulfonyl migration of gem-difluorovinyl sulfonates in nine approaches. The synthetic strategies described in this review provided diversely substituted fluorinated molecules.
宝石-二氟乙烯基磺酸盐的化学性质
在各种新兴的有机氟分子中,宝石二氟乙烯基磺酸盐是有吸引力的组成部分,在有机反应中较少使用。本文综述了近年来宝石-二氟乙烯基磺酸盐有机反应的研究进展。讨论了宝石-二氟乙烯基磺酸盐与醛类、胺类、亚胺类、酰胺类、硼酸类、芳基卤化物等的反应,以及宝石-二氟乙烯基磺酸盐的加成、还原、取代和分子内1,3-磺酰基迁移的九种途径。本综述中描述的合成策略提供了不同取代的氟化分子。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Mini-reviews in Organic Chemistry
Mini-reviews in Organic Chemistry 化学-有机化学
CiteScore
4.50
自引率
4.30%
发文量
116
审稿时长
>12 weeks
期刊介绍: Mini-Reviews in Organic Chemistry is a peer reviewed journal which publishes original reviews on all areas of organic chemistry including organic synthesis, bioorganic and medicinal chemistry, natural product chemistry, molecular recognition, and physical organic chemistry. The emphasis will be on publishing quality papers very rapidly, without any charges. The journal encourages submission of reviews on emerging fields of organic chemistry including: Bioorganic Chemistry Carbohydrate Chemistry Chemical Biology Chemical Process Research Computational Organic Chemistry Development of Synthetic Methodologies Functional Organic Materials Heterocyclic Chemistry Macromolecular Chemistry Natural Products Isolation And Synthesis New Synthetic Methodology Organic Reactions Organocatalysis Organometallic Chemistry Theoretical Organic Chemistry Polymer Chemistry Stereochemistry Structural Investigations Supramolecular Chemistry
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