David Orejana, María García-Rodríguez, Cristina de Ignacio, Sergio Ruiz-Molina
{"title":"Noble and base metal geochemistry of late- to post-orogenic mafic dykes from central Spain","authors":"David Orejana, María García-Rodríguez, Cristina de Ignacio, Sergio Ruiz-Molina","doi":"10.1007/s00710-023-00844-z","DOIUrl":"10.1007/s00710-023-00844-z","url":null,"abstract":"<div><p>The post-tectonic and post-orogenic mafic rocks from the Spanish Central System (SCS) (Iberian Massif) include dyke swarms of shoshonitic (microgabbros) and alkaline (lamprophyres and diabases) geochemical affinity, which register the nature of the metasomatic lithospheric mantle under central Spain. Such magmas sometimes show a direct (or indirect) relationship with the formation of orogenic and intrusion-related gold deposits, which are relatively abundant in the Iberian Massif. The noble and base metal composition of these intrusions shows Primitive Mantle-normalized patterns characterized by positive Au and Co anomalies and fractionated platinum group elements (PGE): from lower Ir-group PGE (IPGE; Ir–Ru) to higher Pd-group PGE (PPGE; Rh–Pt–Pd). The low contents of PGE, together with the base metal contents of pyrite (which is the dominant sulphide phase in the alkaline dykes), is in accordance with low degrees of mantle partial melting and the early segregation of sulphides during magma differentiation. The scarcity of PGE mineral deposits in the Iberian Massif could be explained in part by the apparent lack of PGE enrichment in the Iberian lithospheric mantle. On the contrary, the positive Au anomaly of the SCS mafic dykes represents relatively high Au contents, similar to (and higher than) those of mafic rocks derived from metasomatized subcontinental lithospheric mantle underlying Au-endowed cratons. Several geochemical features point to subduction-related metasomatism of either oceanic or continental nature as the main source of Au enrichment. The Au re-fertilization of the lithospheric mantle under central Spain makes it a potential source in the formation of gold mineralizations.</p></div>","PeriodicalId":18547,"journal":{"name":"Mineralogy and Petrology","volume":"118 1","pages":"71 - 88"},"PeriodicalIF":1.4,"publicationDate":"2023-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00710-023-00844-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41462481","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kirtikumar Randive, Anton Chakhmouradian, Peter Downes
{"title":"A tribute to Lanchand (Lalou) Govindram Gwalani","authors":"Kirtikumar Randive, Anton Chakhmouradian, Peter Downes","doi":"10.1007/s00710-023-00845-y","DOIUrl":"https://doi.org/10.1007/s00710-023-00845-y","url":null,"abstract":"","PeriodicalId":18547,"journal":{"name":"Mineralogy and Petrology","volume":"367 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135304558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jens Götze, Robert Möckel, Yuanming Pan, Axel Müller
{"title":"Geochemistry and formation of agate-bearing lithophysae in Lower Permian volcanics of the NW-Saxonian Basin (Germany)","authors":"Jens Götze, Robert Möckel, Yuanming Pan, Axel Müller","doi":"10.1007/s00710-023-00841-2","DOIUrl":"10.1007/s00710-023-00841-2","url":null,"abstract":"<div><p>Geochemical and mineralogical investigations of the Lower Permian Kemmlitz rhyolite within the NW-Saxonian Basin (Germany) and associated lithophysae (high-temperature crystallization domains) as well as agates were carried out to constrain the genesis and characteristics of these volcanic rocks and the origin of the agate-bearing lithophysae. The volcanic rocks of rhyolitic composition are dominated by quartz, sanidine, and orthoclase and most likely derive from lava flows. Agate-bearing lithophysae were exclusively formed in a glassy facies (pitchstone) of the rhyolites, which was afterwards altered to illite-smectite mixed-layer clays. The results of this study show that agate formation can be related to the alteration of the volcanic rocks accompanied by the infill of mobilized silica into cavities of lithophysae. Fluid inclusion studies point to temperatures of agate formation above 150 °C, indicating that the mobilization and accumulation of silica started already during a late phase of or soon after the volcanic activities. Remarkable high concentrations of B (29 ppm), Ge (> 18 ppm), and U (> 19 ppm) as well as chondrite-normalized rare earth element (REE) distribution patterns of the agates with pronounced negative Eu-anomalies, slightly positive Ce-anomalies and enriched heavy rare earth elements (HREE) indicate interactions of the host rocks and transport of SiO<sub>2</sub> with magmatic volatiles (F/Cl, CO<sub>2</sub>) and heated meteoric water. Characteristic yellow cathodoluminescence (CL), heterogeneous internal textures as well as high defect density of micro- and macrocrystalline quartz detected by electron paramagnetic resonance (EPR) spectroscopy point to crystallization processes via an amorphous silica precursor under non-equilibrium conditions.</p></div>","PeriodicalId":18547,"journal":{"name":"Mineralogy and Petrology","volume":"118 1","pages":"23 - 40"},"PeriodicalIF":1.4,"publicationDate":"2023-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00710-023-00841-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43484812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mineralogy of Pakkanadu carbonatites and associated rocks, South India: constraints on evolution and evidences for REE enrichment","authors":"S. Mahapatro, T. Meshram, Mahesh Korakappa","doi":"10.1007/s00710-023-00843-0","DOIUrl":"https://doi.org/10.1007/s00710-023-00843-0","url":null,"abstract":"","PeriodicalId":18547,"journal":{"name":"Mineralogy and Petrology","volume":"117 1","pages":"595 - 617"},"PeriodicalIF":1.8,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49261508","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Eliana M. Branches Farias, Cristiano C. Lana, Stefano A. Zincone, Glaucia N. Queiroga, Leonardo M. Graça
{"title":"Mineral-scale insights into the petrogenesis of the 3.30 Ga rhyolite in the Contendas-Mirante region, northern São Francisco Craton, Brazil: implications from results of plagioclase and biotite analyses","authors":"Eliana M. Branches Farias, Cristiano C. Lana, Stefano A. Zincone, Glaucia N. Queiroga, Leonardo M. Graça","doi":"10.1007/s00710-023-00842-1","DOIUrl":"10.1007/s00710-023-00842-1","url":null,"abstract":"<div><p>The 3.30 Ga high-silica volcanic system of the Gavião Block, São Francisco Craton, represents the remnants of within-plate magmatism related to an intracontinental rift. However, the petrogenetic processes that may have taken place in the relatively shallow primitive continental crust has not been fully constrained due to a scarce record. Petrographic and chemical analyses in biotite, as well as in-situ Sr isotope ratios in plagioclase, were used to trace petrogenetic processes and physicochemical conditions of the magmatic system. The subvolcanic rock has a well-preserved primary volcanic feature represented by magma flow textures, euhedral to subhedral plagioclases, rapakivi microstructures, and glomerocrysts. Plagioclase populations formed at two distinct stages recorded by trace elements and Sr isotope. Plagioclase phenocrysts and rapakivi phenocrysts have a slight enrichment of light rare earth elements (LREE), Sr/Ba ratio, and slight variation of Sr isotopes composition. Meanwhile, other phenocrysts and rapakivi crystals have low LREE, Sr/Ba, and a limited variation of Sr isotope ratio. Mineral chemistry evidence points to country rock assimilation during plagioclase formation and a crustal source for primary biotites under oxidized conditions.</p></div>","PeriodicalId":18547,"journal":{"name":"Mineralogy and Petrology","volume":"118 1","pages":"41 - 54"},"PeriodicalIF":1.4,"publicationDate":"2023-08-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42443736","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nejib Jemmali, Larbi Rddad, Marta Sośnicka, Emna Rahali, Fouad Souissi, Emmanuel John Carranza
{"title":"Reply to the comment by S. Bouhlel","authors":"Nejib Jemmali, Larbi Rddad, Marta Sośnicka, Emna Rahali, Fouad Souissi, Emmanuel John Carranza","doi":"10.1007/s00710-023-00838-x","DOIUrl":"10.1007/s00710-023-00838-x","url":null,"abstract":"","PeriodicalId":18547,"journal":{"name":"Mineralogy and Petrology","volume":"117 4","pages":"797 - 800"},"PeriodicalIF":1.4,"publicationDate":"2023-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44778783","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Comment on “Genesis of Zn‑Pb‑(Ba‑Sr) mineralization in the peridiapiric cover of Jebel El Akhouat, Ech Chehid salt dome, Northern Tunisia” (2022) by N. Jemmali, L. Rddad, M. Sośnicka, E. Rahali, F. Souissi and E. J. Carranza","authors":"Salah Bouhlel","doi":"10.1007/s00710-023-00839-w","DOIUrl":"10.1007/s00710-023-00839-w","url":null,"abstract":"","PeriodicalId":18547,"journal":{"name":"Mineralogy and Petrology","volume":"117 4","pages":"793 - 796"},"PeriodicalIF":1.4,"publicationDate":"2023-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49602442","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhuanrong Sun, Guochen Dong, Jiahui Tang, Jianheng Guo, Zhongbao Wang
{"title":"Apatite chemistry of Late Triassic granitic rocks from Yidun Terrane: Implications for petrogenesis and mineralization","authors":"Zhuanrong Sun, Guochen Dong, Jiahui Tang, Jianheng Guo, Zhongbao Wang","doi":"10.1007/s00710-023-00836-z","DOIUrl":"10.1007/s00710-023-00836-z","url":null,"abstract":"<div><p>The Yidun Terrane hosts huge amounts of Late Triassic granitic plutons. While the southern Yidun Terrane, also referred to as the Zhongdian arc, mainly includes Late Triassic porphyry and related porphyry Cu-Au deposits, rare mineralization was found related to the contemporary granitic batholiths in the northern Yidun terrane (NYT). This paper has explored the chemical compositions of the apatite from these intrusions, which provide insights into the petrogenesis and the mineralization potential. The higher Mg and V concentrations and La/Sm ratios of the Zhongdian apatite than the Cuojiaoma and Daocheng apatite in the NYT suggestes that the Zhongdian porphyries were derived from a mixed source with both mantle and crustal contributions, while the Cuojiaoma and Daocheng granites are dominantly crustal derived. Compared with the Cuojiaoma and Daocheng apatite, the Zhongdian apatite are characterized by higher Sr, Eu/Eu* [Eu<sub>N</sub>/(Sm<sub>N</sub>×Gd<sub>N</sub>)<sup>0.5</sup>], S and Cl, and low Mn and Y concentrations with adakitic affinity, indicating an environment with high oxygen fugacity and S and Cl contents for their parental magmas, which is favorable for the formation of porphyry Cu-Au deposits. By comparing the chemical characteristics of apatite from the ore-bearing porphyries and ore-barren granites in the Yidun Terrane, this study proposes that the apatite from the ore-bearing rocks commonly has relatively high Sr, S and Fe concentrations and low Mn, Y and Si/S ratio. These geochemical characteristics can be good indicators for predicting the metallogenic potential of the rocks.</p></div>","PeriodicalId":18547,"journal":{"name":"Mineralogy and Petrology","volume":"117 4","pages":"745 - 759"},"PeriodicalIF":1.4,"publicationDate":"2023-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41274205","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Rare native Ni, Fe, Cu, and Sn metals in Hemrin Basalt, northern Iraq: implications for mineral chemistry and ore genesis","authors":"Yawooz A. Kettanah","doi":"10.1007/s00710-023-00840-3","DOIUrl":"10.1007/s00710-023-00840-3","url":null,"abstract":"<div><p>The Hemrin Basalt (HB) is an abnormal occurrence because of its genesis, mineralogy, textures, rare native metals content, and odd geographic-geologic-tectonic setting. It occurs as a caprock for few NW/SE trending hills in a nearly flat-lying area. The HB is a high-K calc-alkaline, collision-related, continental-arc basalt and consists of diopside, labradorite and volcanic glass as the predominant constituents displaying rare firework and feathery textures. The accessory minerals in HB comprise small, discrete grains of native Ni, Fe, Cu, and Sn metals, and scattered grains of sulfides (pyrrhotite, pentlandite, molybdenite), oxides (magnetite, ilmenite, Cr-spinel), and apatite. These minerals occur as disseminated individual or composite grains of variable shapes within the groundmass of HB. Vesicle-filling secondary minerals are zeolite, calcite, anhydrite, and gypsum. The native metals were formed under reducing conditions. The reducing conditions were created as a result of assimilation of C- and S-rich sedimentary rocks by the ascending magma from the continental lithospheric mantle through the thick pile of sedimentary formations. The possible C- and S-rich rocks include the carbonates and evaporites of Fatha Formation and the Hemrin Coal Seam within the upper part of Injana Formation hosting the HB and overlying the Fatha Formation, and possibly the petroleum source, reservoir and caprocks forming the sedimentary column underlying the area. Assimilation of S from these rocks created sulfides, while assimilated C resulted in the formation of native metals.\u0000</p></div>","PeriodicalId":18547,"journal":{"name":"Mineralogy and Petrology","volume":"117 4","pages":"709 - 728"},"PeriodicalIF":1.4,"publicationDate":"2023-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45637483","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Genesis of the Kenticha rare-metal granite-pegmatite, Southern Ethiopia","authors":"Barsisa Bekele, Amit Kumar Sen","doi":"10.1007/s00710-023-00835-0","DOIUrl":"10.1007/s00710-023-00835-0","url":null,"abstract":"<div><p>The Kenticha pegmatite field comprises suites of barren to fertile pegmatite swarms. It shows textural, mineralogical, and geochemical variations. The pegmatites are structurally controlled and emplaced in mafic–ultramafic belts during the Neoproterozoic. This study aims to constrain the genetic and tectonic setting of the Kenticha rare-metal (RM) pegmatite and the associated granite. The presence of minerals such as biotite, muscovite, spodumene, spessartine-almandine garnet, gahnite, beryl, tourmaline, cordierite, and topaz indicate the peraluminous nature of the granite and associated pegmatites. The Kenticha rare-metal granite-pegmatite shows ASI > 1.1, low V, Y, very low Sr, Ba, Th, Zr and REE, very high Be, Li, Rb, Cs, Ga, Nb, and Ta than the upper continental crust. The parental two-mica granite has higher Co, Rb, Ba, and Ce and lower V, Zr, Y, Nb, Ni, La, Pb, Sr, and Th than the upper continental crust. The Ta/Nb value in the two-mica granite is nearly equal to the average upper crustal value. In both parental granite and pegmatites, the normative corundum (C) is greater than 1%. The P<sub>2</sub>O<sub>5</sub> content is low in the assumed parental granite. However, in the main ore body, the P<sub>2</sub>O<sub>5</sub> content increases towards the more fractionated pegmatite. Due to its peraluminous character and high content of Be, Cs, Li, Ta, and Rb, we can categorise the granite-pegmatite under the LCT subclass of the rare-element pegmatite. It's associated with S-type granite. HFSE and LIL elements show characteristics of bulk continental crust composition and syn-collisional felsic magmatism. Biotite composition suggests partial melting of the metasedimentary protolith as the source of the two-mica granite. The plots of Y vs. SO<sub>2</sub>, P<sub>2</sub>O<sub>5</sub> vs. SiO<sub>2</sub>, % normative C vs. Rb, Y vs. Rb, and Th vs. Rb support the S-type magma source. Geochemical and mineralogical data show a nearly vertical evolutional trend of the granite-pegmatite. It varies from the basal granitic unit to the pegmatite core unit. The mineralization of rare metals in the granite-pegmatite was mainly controlled by genetic (processes).\u0000</p></div>","PeriodicalId":18547,"journal":{"name":"Mineralogy and Petrology","volume":"117 4","pages":"685 - 707"},"PeriodicalIF":1.4,"publicationDate":"2023-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45981153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}