华北克拉通胶东型金矿床成矿流体特征:含金黄铁矿地球化学的制约因素

IF 1.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS
Shisheng Li, Mingliang Wang, Lin Li, Shengrong Li, Songbao Feng
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引用次数: 0

摘要

华北克拉通早白垩世金矿床被称为胶东型金矿床。在此,我们总结了胶东、小秦岭和中太行山金矿区的大量黄铁矿微量元素、δ34S和铅同位素数据(包括本研究),以全面揭示胶东型金矿床成矿流体的特征。结果表明,胶东型金矿床黄铁矿中的Au浓度通常小于8.12ppm,与As不相关,但与Bi和Te呈显著正相关,这意味着Bi和Te可能控制着黄铁矿中Au的富集。黄铁矿中的砷浓度总体相对较低,只有胶东金矿区明显较高,这可能是流体流经富含砷的变质沉积岩所致。在胶东型金矿床中,金主要以可见金的形式存在,其次是隐形金。隐形金一般为固溶体(Au+),只有小秦岭金矿区的纳米颗粒(Au0)比例略高(20%)。硫化和流体不溶或沸腾是导致可见金沉淀的主要机制。Co/Ni比、δ34S和Pb同位素表明,胶东型金矿床的成矿流体具有显著的岩浆特征,成矿物质主要来源于下地壳和地幔混合段。其中,中太行山金矿田下地壳成矿物质含量略高。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Ore-forming fluid characteristics of Jiaodong-type gold deposits in the North China Craton: constraints from the geochemistry of auriferous pyrite

The Early Cretaceous gold deposits in the North China Craton are known as Jiaodong-type gold deposits. Here, we summarize a quantity of reported (including this study) pyrite trace element, δ34S, and Pb isotope data from the Jiaodong, Xiaoqinling, and Central Taihangshan gold fields to comprehensively reveal the characteristics of the ore-forming fluids in Jiaodong-type gold deposits. The results show that the Au concentrations in the pyrites from the Jiaodong-type gold deposits are typically less than 8.12 ppm and do not correlate with As but have significant positive correlations with Bi and Te, implying that Bi and Te may govern Au enrichment in pyrite. The overall As concentrations in the pyrites are relatively low, and only the Jiaodong gold field is significantly higher, which may be caused by fluid flowing through As-rich metamorphic sedimentary rocks. In Jiaodong-type gold deposits, Au is dominantly found as visible gold, followed by invisible gold. Invisible gold generally occurs as a solid solution (Au+), and only the proportion of nanoparticles (Au0) in the Xiaoqinling gold field is slightly higher (20%). Sulfidation and fluid immiscibility or boiling were the key mechanisms leading to visible gold precipitation. The Co/Ni ratio, δ34S, and Pb isotopes indicate that the ore-forming fluids in the Jiaodong-type gold deposits exhibit remarkable magmatic features, and the ore-forming materials are primarily derived from a mixture of lower crust and mantle sections. Among them, the ore-forming materials from the lower crust of the Central Taihangshan gold field are slightly higher.

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来源期刊
Mineralogy and Petrology
Mineralogy and Petrology 地学-地球化学与地球物理
CiteScore
2.60
自引率
0.00%
发文量
0
审稿时长
1 months
期刊介绍: Mineralogy and Petrology welcomes manuscripts from the classical fields of mineralogy, igneous and metamorphic petrology, geochemistry, crystallography, as well as their applications in academic experimentation and research, materials science and engineering, for technology, industry, environment, or society. The journal strongly promotes cross-fertilization among Earth-scientific and applied materials-oriented disciplines. Purely descriptive manuscripts on regional topics will not be considered. Mineralogy and Petrology was founded in 1872 by Gustav Tschermak as "Mineralogische und Petrographische Mittheilungen". It is one of Europe''s oldest geoscience journals. Former editors include outstanding names such as Gustav Tschermak, Friedrich Becke, Felix Machatschki, Josef Zemann, and Eugen F. Stumpfl.
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