Membranes最新文献

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A Set of Fluorescent Protein-Based Markers for Major Vesicle Coat Proteins in Yeast. 酵母主要囊泡外壳蛋白的一组荧光蛋白标记。
IF 3.6 4区 工程技术
Membranes Pub Date : 2025-07-13 DOI: 10.3390/membranes15070209
Xue-Fei Cui, Zheng-Tan Zhang, Jing Zhu, Li Cui, Zhiping Xie
{"title":"A Set of Fluorescent Protein-Based Markers for Major Vesicle Coat Proteins in Yeast.","authors":"Xue-Fei Cui, Zheng-Tan Zhang, Jing Zhu, Li Cui, Zhiping Xie","doi":"10.3390/membranes15070209","DOIUrl":"10.3390/membranes15070209","url":null,"abstract":"<p><p>In eukaryotic cells, vesicle-mediated transport interconnects the endomembrane system. These vesicles are formed by coat proteins via deformation of donor membranes. Here, we constructed a set of fluorescent protein-based markers for major coat protein complexes in the yeast model system, and examined their subcellular localization patterns. Our markers covered COPII, COPI, AP-1, AP-2, AP-3, and retromer complexes. Our live cell imaging demonstrates that COPII puncta were primarily associated with the endoplasmic reticulum (ER), and occasionally with early Golgi. COPI was present on both early Golgi and late Golgi/early endosomes. AP-1 puncta were present on late Golgi/early endosomes. AP-2 was present on plasma membrane (PM)-associated puncta, and around the bud neck. AP-3 puncta were present on late Golgi/early endosomes and on the surface of vacuoles. Retromer was present on the surface of vacuoles, late endosomes, and other perivacuolar puncta. Notably, more than half of AP-1 puncta and AP-3 puncta were not associated with the donor compartments where they are thought to be generated, implying that these were coated transport vesicles. This work provides a convenient tool set for the investigation of vesicular transport in yeast and live cell imaging evidence for the presence of certain coated transport vesicles.</p>","PeriodicalId":18410,"journal":{"name":"Membranes","volume":"15 7","pages":""},"PeriodicalIF":3.6,"publicationDate":"2025-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12299396/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144708017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Conceptual Approach to Reduce the Product Gas Crossover in Alkaline Electrolyzers. 减少碱性电解槽中产品气体交叉的概念方法。
IF 3.6 4区 工程技术
Membranes Pub Date : 2025-07-12 DOI: 10.3390/membranes15070206
Diogo Loureiro Martinho, Torsten Berning
{"title":"A Conceptual Approach to Reduce the Product Gas Crossover in Alkaline Electrolyzers.","authors":"Diogo Loureiro Martinho, Torsten Berning","doi":"10.3390/membranes15070206","DOIUrl":"10.3390/membranes15070206","url":null,"abstract":"<p><p>The crossover of the product gases hydrogen and oxygen in alkaline electrolyzer operation is a critical factor, severely limiting the operational window in terms of current density and pressure. In prior experiments, it was found that a large degree of oversaturation of the reaction products in the liquid electrolyte phase leads to high amounts of crossover. We are proposing to reduce this amount of oversaturation by introducing micro-cracks in the Zirfon diaphragm. These cracks are meant to induce the formation of hydrogen and oxygen bubbles on the respective sides, and thereby reduce the oversaturation and amount of crossover. In theory, the size of the bubble corresponds to the size of the cracks, and from our computational fluid dynamics simulations, we conclude that the bubbles should be as large as possible to minimize the ohmic resistance in the electrolyte phase. The results suggest that an increase in bubble diameter from 50 microns to 150 microns results in a 10% higher current density at a cell voltage of 2.1 V.</p>","PeriodicalId":18410,"journal":{"name":"Membranes","volume":"15 7","pages":""},"PeriodicalIF":3.6,"publicationDate":"2025-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12300266/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144708013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Membrane Processes for Remediating Water from Sugar Production By-Product Stream. 膜法处理制糖副产废水的研究。
IF 3.6 4区 工程技术
Membranes Pub Date : 2025-07-12 DOI: 10.3390/membranes15070207
Amal El Gohary Ahmed, Christian Jordan, Eva Walcher, Selma Kuloglija, Reinhard Turetschek, Antonie Lozar, Daniela Tomasetig, Michael Harasek
{"title":"Membrane Processes for Remediating Water from Sugar Production By-Product Stream.","authors":"Amal El Gohary Ahmed, Christian Jordan, Eva Walcher, Selma Kuloglija, Reinhard Turetschek, Antonie Lozar, Daniela Tomasetig, Michael Harasek","doi":"10.3390/membranes15070207","DOIUrl":"10.3390/membranes15070207","url":null,"abstract":"<p><p>Sugar production generates wastewater rich in dissolved solids and organic matter, and improper disposal poses severe environmental risks, exacerbates water scarcity, and creates regulatory challenges. Conventional treatment methods, such as evaporation and chemical precipitation, are energy-intensive and often ineffective at removing fine particulates and dissolved impurities. This study evaluates membrane-based separation as a sustainable alternative for water reclamation and sugar recovery from sugar industry effluents, focusing on replacing evaporation with membrane processes, ensuring high permeate quality, and mitigating membrane fouling. Cross-flow filtration experiments were conducted on a lab-scale membrane system at 70 °C to suppress microbial growth, comparing direct reverse osmosis (RO) of the raw effluent to an integrated ultrafiltration (UF)-RO process. Direct RO resulted in rapid membrane fouling. A tight UF (5 kDa) pre-treatment before RO significantly mitigated fouling and improved performance, enabling 28% water recovery and 79% sugar recovery, maintaining permeate conductivity below 0.5 mS/cm, sustaining stable flux, and reducing membrane blocking. Additionally, the UF and RO membranes were tested via SEM, EDS, and FTIR to elucidate the fouling mechanisms.</p>","PeriodicalId":18410,"journal":{"name":"Membranes","volume":"15 7","pages":""},"PeriodicalIF":3.6,"publicationDate":"2025-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12297894/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144707944","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Membrane Technologies for Bioengineering Microalgae: Sustainable Applications in Biomass Production, Carbon Capture, and Industrial Wastewater Valorization. 生物工程微藻的膜技术:在生物质生产、碳捕获和工业废水增值中的可持续应用。
IF 3.6 4区 工程技术
Membranes Pub Date : 2025-07-11 DOI: 10.3390/membranes15070205
Michele Greque Morais, Gabriel Martins Rosa, Luiza Moraes, Larissa Chivanski Lopes, Jorge Alberto Vieira Costa
{"title":"Membrane Technologies for Bioengineering Microalgae: Sustainable Applications in Biomass Production, Carbon Capture, and Industrial Wastewater Valorization.","authors":"Michele Greque Morais, Gabriel Martins Rosa, Luiza Moraes, Larissa Chivanski Lopes, Jorge Alberto Vieira Costa","doi":"10.3390/membranes15070205","DOIUrl":"10.3390/membranes15070205","url":null,"abstract":"<p><p>In accordance with growing environmental pressures and the demand for sustainable industrial practices, membrane technologies have emerged as key enablers for increasing efficiency, reducing emissions, and supporting circular processes across multiple sectors. This review focuses on the integration among microalgae-based systems, offering innovative and sustainable solutions for biomass production, carbon capture, and industrial wastewater treatment. In cultivation, membrane photobioreactors (MPBRs) have demonstrated biomass productivity up to nine times greater than that of conventional systems and significant reductions in water (above 75%) and energy (approximately 0.75 kWh/m<sup>3</sup>) footprints. For carbon capture, hollow fiber membranes and hybrid configurations increase CO<sub>2</sub> transfer rates by up to 300%, achieving utilization efficiencies above 85%. Coupling membrane systems with industrial effluents has enabled nutrient removal efficiencies of up to 97% for nitrogen and 93% for phosphorus, contributing to environmental remediation and resource recovery. This review also highlights recent innovations, such as self-forming dynamic membranes, magnetically induced vibration systems, antifouling surface modifications, and advanced control strategies that optimize process performance and energy use. These advancements position membrane-based microalgae systems as promising platforms for carbon-neutral biorefineries and sustainable industrial operations, particularly in the oil and gas, mining, and environmental technology sectors, which are aligned with global climate goals and the UN Sustainable Development Goals (SDGs).</p>","PeriodicalId":18410,"journal":{"name":"Membranes","volume":"15 7","pages":""},"PeriodicalIF":3.6,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12299323/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144707945","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Amyloid β 1-42 Can Form Ion Channels as Small as Gramicidin in Model Lipid Membranes. β淀粉样蛋白1-42可以在模型脂质膜上形成与革兰霉素一样小的离子通道。
IF 3.6 4区 工程技术
Membranes Pub Date : 2025-07-08 DOI: 10.3390/membranes15070204
Yue Xu, Irina Bukhteeva, Yurii Potsiluienko, Zoya Leonenko
{"title":"Amyloid β 1-42 Can Form Ion Channels as Small as Gramicidin in Model Lipid Membranes.","authors":"Yue Xu, Irina Bukhteeva, Yurii Potsiluienko, Zoya Leonenko","doi":"10.3390/membranes15070204","DOIUrl":"10.3390/membranes15070204","url":null,"abstract":"<p><p>The amyloid-beta 1-42 (Aβ1-42) oligomers are the most cytotoxic species of the amyloid family and play a key role in the pathology of Alzheimer's Disease (AD). They have been shown to damage cellular membranes, but the exact mechanism is complex and not well understood. Multiple routes of membrane damage have been proposed, including the formation of pores and ion channels. In this work, we study the membrane damage induced by Aβ1-42 oligomers using black lipid membrane (BLM) electrophysiology and compare their action with gramicidin, known to form ion channels. Our data show that Aβ1-42 oligomers can induce a variety of damage in the lipid membranes composed of 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC), 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine (POPC), and cholesterol (CHOL), including small ion channels, similar to the gramicidin channels, with an average inner diameter smaller than 5 Å. These channels have a short retaining time in lipid membranes, suggesting that they are highly dynamic. Our studies provide new insights into the mechanism of membrane damage caused by Aβ1-42 oligomers and extend the current perception of the Aβ channelopathy hypothesis. It provides a more in-depth understanding of the molecular mechanism by which small Aβ oligomers induce cytotoxicity by interacting with lipid membranes in AD.</p>","PeriodicalId":18410,"journal":{"name":"Membranes","volume":"15 7","pages":""},"PeriodicalIF":3.6,"publicationDate":"2025-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12299968/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144708019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent Advances in Thermochemical Water Splitting for Hydrogen Production Using Mixed Ionic-Electronic Conducting Membrane Reactors. 离子-电子混合导电膜反应器热化学水裂解制氢研究进展。
IF 3.6 4区 工程技术
Membranes Pub Date : 2025-07-04 DOI: 10.3390/membranes15070203
Jingjun Li, Qing Yang, Jie Liu, Qiangchao Sun, Hongwei Cheng
{"title":"Recent Advances in Thermochemical Water Splitting for Hydrogen Production Using Mixed Ionic-Electronic Conducting Membrane Reactors.","authors":"Jingjun Li, Qing Yang, Jie Liu, Qiangchao Sun, Hongwei Cheng","doi":"10.3390/membranes15070203","DOIUrl":"10.3390/membranes15070203","url":null,"abstract":"<p><p>Under the accelerating global energy restructuring and the deepening carbon neutrality strategy, hydrogen energy has emerged with increasing strategic value as a zero-carbon secondary energy carrier. Water electrolysis technology based on renewable energy is regarded as an ideal pathway for large-scale green hydrogen production. However, polymer electrolyte membrane (PEM) conventional water electrolysis faces dual constraints in economic feasibility and scalability due to its high electrical energy consumption and reliance on noble metal catalysts. The mixed ionic-electronic conducting oxygen transport membrane (MIEC-OTM) reactor technology offers an innovative solution to this energy efficiency-cost paradox due to its thermo-electrochemical synergistic energy conversion mechanism and process integration. This not only overcomes the thermodynamic equilibrium limitations in traditional electrolysis but also reduces electrical energy demand by effectively coupling with medium- to high-temperature heat sources such as industrial waste heat and solar thermal energy. Therefore, this review, grounded in the physicochemical mechanisms of oxygen transport membrane reactors, systematically examines the influence of key factors, including membrane material design, catalytic interface optimization, and parameter synergy, on hydrogen production efficiency. Furthermore, it proposes a roadmap and breakthrough directions for industrial applications, focusing on enhancing intrinsic material stability, designing multi-field coupled reactors, and optimizing system energy efficiency.</p>","PeriodicalId":18410,"journal":{"name":"Membranes","volume":"15 7","pages":""},"PeriodicalIF":3.6,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12298379/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144707949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hybrid Membranes Based on Track-Etched Membranes and Nanofiber Layer for Water-Oil Separation and Membrane Distillation of Low-Level Liquid Radioactive Wastes and Salt Solutions. 基于轨迹蚀刻膜和纳米纤维层的杂化膜用于低放射性液体废物和盐溶液的水-油分离和膜蒸馏。
IF 3.6 4区 工程技术
Membranes Pub Date : 2025-07-04 DOI: 10.3390/membranes15070202
Arman B Yeszhanov, Aigerim Kh Shakayeva, Maxim V Zdorovets, Daryn B Borgekov, Artem L Kozlovskiy, Pavel V Kharkin, Dmitriy A Zheltov, Marina V Krasnopyorova, Olgun Güven, Ilya V Korolkov
{"title":"Hybrid Membranes Based on Track-Etched Membranes and Nanofiber Layer for Water-Oil Separation and Membrane Distillation of Low-Level Liquid Radioactive Wastes and Salt Solutions.","authors":"Arman B Yeszhanov, Aigerim Kh Shakayeva, Maxim V Zdorovets, Daryn B Borgekov, Artem L Kozlovskiy, Pavel V Kharkin, Dmitriy A Zheltov, Marina V Krasnopyorova, Olgun Güven, Ilya V Korolkov","doi":"10.3390/membranes15070202","DOIUrl":"10.3390/membranes15070202","url":null,"abstract":"<p><p>In this work, hybrid membranes were fabricated by depositing polyvinyl chloride (PVC) fibers onto PET track-etched membranes (TeMs) using the electrospinning technique. The resulting structures exhibited enhanced hydrophobicity, with contact angles reaching 155°, making them suitable for applications in both water-oil mixture separation and membrane distillation processes involving low-level liquid radioactive waste (LLLRW), saline solutions, and natural water sources. The use of hybrids of TeMs and nanofiber membranes has significantly increased productivity compared to TeMs only, while maintaining a high degree of purification. Permeate obtained after MD of LLLRW and river water was analyzed by conductometry and the atomic emission spectroscopy (for Sr, Cs, Al, Mo, Co, Sb, Ca, Fe, Mg, K, and Na). The activity of radioisotopes (for <sup>124</sup>Sb, <sup>65</sup>Zn, <sup>60</sup>Co, <sup>57</sup>Co, <sup>137</sup>Cs, and <sup>134</sup>Cs) was evaluated by gamma-ray spectroscopy. In most cases, the degree of rejection was between 95 and 100% with a water flux of up to 17.3 kg/m<sup>2</sup>·h. These membranes were also tested in the separation of cetane-water emulsion with productivity up to 47.3 L/m<sup>2</sup>·min at vacuum pressure of 700 mbar and 15.2 L/m<sup>2</sup>·min at vacuum pressure of 900 mbar.</p>","PeriodicalId":18410,"journal":{"name":"Membranes","volume":"15 7","pages":""},"PeriodicalIF":3.6,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12300037/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144708030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hierarchical Affinity Engineering in Amine-Functionalized Silica Membranes for Enhanced CO2 Separation: A Combined Experimental and Theoretical Study. 胺功能化二氧化硅膜的分层亲和工程增强CO2分离:实验与理论相结合的研究。
IF 3.6 4区 工程技术
Membranes Pub Date : 2025-07-02 DOI: 10.3390/membranes15070201
Zhenghua Guo, Qian Li, Kaidi Guo, Liang Yu
{"title":"Hierarchical Affinity Engineering in Amine-Functionalized Silica Membranes for Enhanced CO<sub>2</sub> Separation: A Combined Experimental and Theoretical Study.","authors":"Zhenghua Guo, Qian Li, Kaidi Guo, Liang Yu","doi":"10.3390/membranes15070201","DOIUrl":"10.3390/membranes15070201","url":null,"abstract":"<p><p>Excessive carbon dioxide (CO<sub>2</sub>) emissions represent a critical challenge in mitigating global warming, necessitating advanced separation technologies for efficient carbon capture. Silica-based membranes have attracted significant attention due to their exceptional chemical, thermal, and mechanical stability under harsh operating conditions. In this study, we introduce a novel layered hybrid membrane designed based on amine-functionalized silica precursors, where a distinct affinity gradient is engineered by incorporating two types of amine-functionalized materials. The top layer was composed of high-affinity amine species to maximize CO<sub>2</sub> sorption, while a sublayer with milder affinity facilitated smooth CO<sub>2</sub> diffusion, thereby establishing a continuous solubility gradient across the membrane. A dual approach, combining comprehensive experimental testing and rigorous theoretical modeling, was employed to elucidate the underlying CO<sub>2</sub> transport mechanisms. Our results reveal that the hierarchical structure significantly enhances the intrinsic driving force for CO<sub>2</sub> permeation, leading to superior separation performance compared to conventional homogeneous facilitated transport membranes. This study not only provides critical insights into the design principles of affinity gradient membranes but also demonstrates their potential for scalable, high-performance CO<sub>2</sub> separation in industrial applications.</p>","PeriodicalId":18410,"journal":{"name":"Membranes","volume":"15 7","pages":""},"PeriodicalIF":3.6,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12300040/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144708027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Membrane-Based CO2 Capture Across Industrial Sectors: Process Conditions, Case Studies, and Implementation Insights. 跨工业部门基于膜的二氧化碳捕获:过程条件,案例研究和实施见解。
IF 3.6 4区 工程技术
Membranes Pub Date : 2025-07-02 DOI: 10.3390/membranes15070200
Jin Woo Park, Soyeon Heo, Jeong-Gu Yeo, Sunghoon Lee, Jin-Kuk Kim, Jung Hyun Lee
{"title":"Membrane-Based CO<sub>2</sub> Capture Across Industrial Sectors: Process Conditions, Case Studies, and Implementation Insights.","authors":"Jin Woo Park, Soyeon Heo, Jeong-Gu Yeo, Sunghoon Lee, Jin-Kuk Kim, Jung Hyun Lee","doi":"10.3390/membranes15070200","DOIUrl":"10.3390/membranes15070200","url":null,"abstract":"<p><p>Membrane-based CO<sub>2</sub> capture has emerged as a promising technology for industrial decarbonization, offering advantages in energy efficiency, modularity, and environmental performance. This review presents a comprehensive assessment of membrane processes applied across major emission-intensive sectors, including power generation, cement, steelmaking, and biogas upgrading. Drawing from pilot-scale demonstrations and simulation-based studies, we evaluate how flue gas characteristics, such as CO<sub>2</sub> concentration, pressure, temperature, and impurity composition, govern membrane selection, process design, and operational feasibility. Case studies highlight the technical viability of membrane systems under a wide range of industrial conditions, from low-CO<sub>2</sub> NGCC flue gas to high-pressure syngas and CO<sub>2</sub>-rich cement emissions. Despite these advances, this review discusses the key remaining challenges for the commercialization of membrane-based CO<sub>2</sub> capture and includes perspectives on process design and techno-economic evaluation. The insights compiled in this review are intended to support the design of application-specific membrane systems and guide future efforts toward scalable and economically viable CO<sub>2</sub> capture across industrial sectors.</p>","PeriodicalId":18410,"journal":{"name":"Membranes","volume":"15 7","pages":""},"PeriodicalIF":3.6,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12298987/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144707946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancement of Efficiency in an Ex Situ Coprecipitation Method for Superparamagnetic Bacterial Cellulose Hybrid Materials. 超顺磁性细菌纤维素杂化材料非原位共沉淀法效率的提高。
IF 3.6 4区 工程技术
Membranes Pub Date : 2025-07-01 DOI: 10.3390/membranes15070198
Thaís Cavalcante de Souza, Italo José Batista Durval, Hugo Moraes Meira, Andréa Fernanda de Santana Costa, Eduardo Padrón Hernández, Attilio Converti, Glória Maria Vinhas, Leonie Asfora Sarubbo
{"title":"Enhancement of Efficiency in an Ex Situ Coprecipitation Method for Superparamagnetic Bacterial Cellulose Hybrid Materials.","authors":"Thaís Cavalcante de Souza, Italo José Batista Durval, Hugo Moraes Meira, Andréa Fernanda de Santana Costa, Eduardo Padrón Hernández, Attilio Converti, Glória Maria Vinhas, Leonie Asfora Sarubbo","doi":"10.3390/membranes15070198","DOIUrl":"10.3390/membranes15070198","url":null,"abstract":"<p><p>Superparamagnetic magnetite nanoparticles (Fe<sub>3</sub>O<sub>4</sub>) have garnered considerable interest due to their unique magnetic properties and potential for integration into multifunctional biomaterials. In particular, their incorporation into bacterial cellulose (BC) matrices offers a promising route for developing sustainable and high-performance magnetic composites. Numerous studies have explored BC-magnetite systems; however, innovations combining ex situ coprecipitation synthesis within BC matrices, tailored reagent molar ratios, stirring protocols, and purification processes remain limited. This study aimed to optimize the ex situ coprecipitation method for synthesizing superparamagnetic magnetite nanoparticles embedded in BC membranes, focusing on enhancing particle stability and crystallinity. BC membranes containing varying concentrations of magnetite (40%, 50%, 60%, and 70%) were characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and vibrating sample magnetometry (VSM). The resulting magnetic BC membranes demonstrated homogenous dispersion of nanoparticles, improved crystallite size (6.96 nm), and enhanced magnetic saturation (Ms) (50.4 emu/g), compared to previously reported methods. The adoption and synergistic optimization of synthesis parameters-unique to this study-conferred greater control over the physicochemical and magnetic properties of the composites. These findings position the optimized BC-magnetite nanocomposites as highly promising candidates for advanced applications, including electromagnetic interference (EMI) shielding, electronic devices, gas sensors, MRI contrast agents, and targeted drug delivery systems.</p>","PeriodicalId":18410,"journal":{"name":"Membranes","volume":"15 7","pages":""},"PeriodicalIF":3.6,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12300837/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144708024","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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